CN106046991A - Ash-sticking-proof waterborne coating and preparation method thereof - Google Patents

Ash-sticking-proof waterborne coating and preparation method thereof Download PDF

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Publication number
CN106046991A
CN106046991A CN201610620020.8A CN201610620020A CN106046991A CN 106046991 A CN106046991 A CN 106046991A CN 201610620020 A CN201610620020 A CN 201610620020A CN 106046991 A CN106046991 A CN 106046991A
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Prior art keywords
parts
sticking
ash
resin
waterborne coating
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CN201610620020.8A
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Chinese (zh)
Inventor
张国文
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Anqing Ruitai Chemical Co Ltd
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Anqing Ruitai Chemical Co Ltd
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Priority to CN201610620020.8A priority Critical patent/CN106046991A/en
Publication of CN106046991A publication Critical patent/CN106046991A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an ash-sticking-proof waterborne coating. The ash-sticking-proof waterborne coating is prepared from the following raw materials: hydroxyl acrylic resin, silicone acrylic emulsion, polyamide resin, nano titanium dioxide, alkyd resin, iso-propanol, methyl isobutyl ketone, a synergist, a de-foaming agent, a drier, matting powder, kaolin, de-ionized water and rosin resin. A preparation method of the ash-sticking-proof waterborne coating comprises the following steps: (1) preparing a mixed solution; (2) preparing suspension; (3) preparing a solution; (4) uniformly mixing the liquid of the steps above and filtering to obtain a finished product. By carrying out optimized combination on organic high molecular materials with relatively good comprehensive performance, the ash-sticking-proof performance of a composition is improved; the preparation method is simple, and sufficient utilization of resources and energy sources is realized; a production process is environment-friendly and has no pollution, the cost is relatively low and a production period is short, so that the ash-sticking-proof waterborne coating is suitable for industrial production in a large batch and has relatively good economic benefits and social benefits.

Description

A kind of water paint of anti-dust and preparation method thereof
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, particularly relate to the aqueous of a kind of anti-dust Coating and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class Material, is an important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in the overall situation of green economy globalization Under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 15,000,000 About Dun, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, crucial It is to cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is big row in the common people consume Its road, runs in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint will Being widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint can To apply the application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics.Water paint from raw material sources to produce and The Life cycle used, the most beneficially sound development of environment.It is the most in process of production by volatile organic solvent Substitute, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs to disappear Consumption fossil feedstock, is a major challenge to resource in the present stage of resource scarcity, and the appearance of water paint solves this and asks Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating of energy-conserving and environment-protective Industry is just welcoming unprecedented opportunity to develop, and market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces The difficulty of construction of water paint, improve serviceability, be water paint expansive approach field, extensive popularization and application when business Anxious.Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public the prejudice of water paint and misgivings etc. The attention of related work, also will play the effect of promotion to the application development of water paint.As Green Product, aqueous is coated with Material necessarily obtains the accreditation of people and is widely used.Before the market demand huge in the face of water paint and ever-increasing application Scape, strengthens research and development capabilities, and updates and promote the properties of product of water paint, accelerates product quality upgrading, develops in skill The water paint more showing powerful competitive advantage in art, on cost, in performance has the meaning of reality and wide market Space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that the water paint of a kind of anti-dust and Its preparation method, this coating products excellent performance, there are good anti-dust performance, and energy-conserving and environment-protective, possess preferable economy Benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 15~35 parts, silicon Acrylic emulsion 5~20 parts, polyamide 5~20 parts, nano titanium oxide 3~15 parts, alkyd resin 3~15 parts, isopropanol 0.3 ~1.5 parts, hexone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, drier 0.2~1 Part, flatting silica 1~5 parts, Kaolin 2~8 parts, deionized water 20~45 parts, rosin resin 3~15 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 100~200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described defoamer is polyester modification siloxanes.
Preferably, described drier is manganese naphthenate.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves compositions Anti-dust performance, use the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, and hot strength and fracture are stretched Long rate is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.;Preparation method of the present invention is simple, real Having showed making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialization and criticizes Amount produces, and possesses preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 15 parts, silicon the third breast Liquid 5 parts, polyamide 5 parts, nano titanium oxide 3 parts, alkyd resin 3 parts, isopropanol 0.3 part, hexone 0.5 Part, synergist 0.3 part, defoamer 0.3 part, drier 0.2 part, flatting silica 1 part, Kaolin 2 parts, deionized water 20 parts, Colophonium Resin 3 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 35 parts, silicon the third breast Liquid 20 parts, polyamide 20 parts, nano titanium oxide 15 parts, alkyd resin 15 parts, isopropanol 1.5 parts, methyl-isobutyl first Ketone 2 parts, synergist 1.5 parts, defoamer 1.2 parts, drier 1 part, flatting silica 5 parts, Kaolin 8 parts, deionized water 45 parts, Colophonium Resin 15 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added Suddenly the solution that (3) prepare, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine;
Described defoamer is polyester modification siloxanes;
Described drier is manganese naphthenate.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve The anti-dust performance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength It is superior to common coating with elongation at break, coated-body can be met requirement is used for anticorrosion, weather-proof etc.;Preparation method of the present invention Simply, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (4)

1. the water paint of an anti-dust, it is characterised in that be prepared by the raw materials in: Hydroxylated acrylic resin 15 ~35 parts, silicone acrylic emulsion 5~20 parts, polyamide 5~20 parts, nano titanium oxide 3~15 parts, alkyd resin 3~15 parts, Isopropanol 0.3~1.5 parts, hexone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, urge Dry agent 0.2~1 part, flatting silica 1~5 parts, Kaolin 2~8 parts, deionized water 20~45 parts, rosin resin 3~15 parts;
Its preparation method in turn includes the following steps:
(1) Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol are put into In reaction vessel, it is slowly heated to 40~50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone being joined in blender with rosin resin, being stirred continuously until mixing Close uniformly, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step (3) is added The solution prepared, continues to stir, and crosses 100~200 mesh sieves, gets product.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described synergist is butyl triphen Base fluorination phosphine.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described defoamer is polyester modification Siloxanes.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described drier is aphthenic acids Manganese.
CN201610620020.8A 2016-08-01 2016-08-01 Ash-sticking-proof waterborne coating and preparation method thereof Pending CN106046991A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107201111A (en) * 2017-04-18 2017-09-26 安徽华辉塑业科技股份有限公司 A kind of perambulator steelwork topical oil paint preparation method
CN107964338A (en) * 2017-12-29 2018-04-27 安徽科邦树脂科技有限公司 A kind of anti-fouling type water paint synthetic method
CN108034343A (en) * 2017-12-29 2018-05-15 安徽科邦树脂科技有限公司 A kind of anti-fouling type water paint
CN108912876A (en) * 2017-04-18 2018-11-30 重庆瑞恩涂料有限公司 A kind of aqueous coating process for electronic product
CN112959752A (en) * 2021-02-03 2021-06-15 北京尚德智美环境科技有限公司 Processing technology of anti-sticking cloth

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486863A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly waterborne paint and preparation thereof
CN103666275A (en) * 2013-12-10 2014-03-26 张家港市民扬塑胶科技有限公司 Water-based anti-bacterial mould-proof paint
CN104277680A (en) * 2014-10-29 2015-01-14 安徽朗凯奇建材有限公司 Germicidal negative-radical waterproof coating and preparation method thereof
CN104449130A (en) * 2014-10-23 2015-03-25 安徽省实防新型玻璃科技有限公司 Corrosion-oxidation-resistant and environment-friendly waterborne coating for glass door and preparation method of waterborne coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486863A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly waterborne paint and preparation thereof
CN103666275A (en) * 2013-12-10 2014-03-26 张家港市民扬塑胶科技有限公司 Water-based anti-bacterial mould-proof paint
CN104449130A (en) * 2014-10-23 2015-03-25 安徽省实防新型玻璃科技有限公司 Corrosion-oxidation-resistant and environment-friendly waterborne coating for glass door and preparation method of waterborne coating
CN104277680A (en) * 2014-10-29 2015-01-14 安徽朗凯奇建材有限公司 Germicidal negative-radical waterproof coating and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107201111A (en) * 2017-04-18 2017-09-26 安徽华辉塑业科技股份有限公司 A kind of perambulator steelwork topical oil paint preparation method
CN108912876A (en) * 2017-04-18 2018-11-30 重庆瑞恩涂料有限公司 A kind of aqueous coating process for electronic product
CN107964338A (en) * 2017-12-29 2018-04-27 安徽科邦树脂科技有限公司 A kind of anti-fouling type water paint synthetic method
CN108034343A (en) * 2017-12-29 2018-05-15 安徽科邦树脂科技有限公司 A kind of anti-fouling type water paint
CN112959752A (en) * 2021-02-03 2021-06-15 北京尚德智美环境科技有限公司 Processing technology of anti-sticking cloth
CN112959752B (en) * 2021-02-03 2022-07-08 北京尚德智美环境科技有限公司 Processing technology of anti-sticking cloth

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Application publication date: 20161026