CN106046991A - Ash-sticking-proof waterborne coating and preparation method thereof - Google Patents
Ash-sticking-proof waterborne coating and preparation method thereof Download PDFInfo
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- CN106046991A CN106046991A CN201610620020.8A CN201610620020A CN106046991A CN 106046991 A CN106046991 A CN 106046991A CN 201610620020 A CN201610620020 A CN 201610620020A CN 106046991 A CN106046991 A CN 106046991A
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- waterborne coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an ash-sticking-proof waterborne coating. The ash-sticking-proof waterborne coating is prepared from the following raw materials: hydroxyl acrylic resin, silicone acrylic emulsion, polyamide resin, nano titanium dioxide, alkyd resin, iso-propanol, methyl isobutyl ketone, a synergist, a de-foaming agent, a drier, matting powder, kaolin, de-ionized water and rosin resin. A preparation method of the ash-sticking-proof waterborne coating comprises the following steps: (1) preparing a mixed solution; (2) preparing suspension; (3) preparing a solution; (4) uniformly mixing the liquid of the steps above and filtering to obtain a finished product. By carrying out optimized combination on organic high molecular materials with relatively good comprehensive performance, the ash-sticking-proof performance of a composition is improved; the preparation method is simple, and sufficient utilization of resources and energy sources is realized; a production process is environment-friendly and has no pollution, the cost is relatively low and a production period is short, so that the ash-sticking-proof waterborne coating is suitable for industrial production in a large batch and has relatively good economic benefits and social benefits.
Description
Technical field
The invention belongs to coating industry technical field, relate to a kind of water paint, particularly relate to the aqueous of a kind of anti-dust
Coating and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and
Play protection, a class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of early stage
Coating is mostly with vegetable oil as primary raw material, therefore also referred to as paint.Synthetic resin instead of vegetable oil now, therefore is referred to as being coated with
Material.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.Current according to the modern times
The classification of chemical products, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering of class
Material, is an important industry in chemical industry.
At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in the overall situation of green economy globalization
Under, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " environmental law " promulgates, country is " green
Environmental protection, beautiful China " etc. environmental protection advocate the most no longer to stay on slogan, but implement to perform, implement to promote energetically green
The development of color science and technology industry.Traditional coating is one of important sources of air major pollutants VOC, by the aqueous of environmental protection
Paint replacement paint is the most imperative.Compare traditional paint, and water paint is the one of environment-friendly type paint, and it saves oil
Coal resources, and free from environmental pollution, it is to guide consumption to realize energy-saving and emission-reduction.2015, China's Coating Market sales volume 15,000,000
About Dun, the industrial paint accounting by 70% converts, and paint consumption then reaches ten million ton, not only wastes 5,000,000 tons of energy, crucial
It is to cause 5,000,000 tons of toxic and harmful discharges to air.Paint consumes the energy and pollutes environment, and it is big row in the common people consume
Its road, runs in the opposite direction with national energy consumption revolution requirement and guide.Along with the enhancing of people's environmental consciousness, water paint will
Being widely used, research and development water paint has the biggest economic benefit and social benefit.Existing water paint can
To apply the application in industries such as pharmacy, food, hospital, weaving, chemical industry, electronics.Water paint from raw material sources to produce and
The Life cycle used, the most beneficially sound development of environment.It is the most in process of production by volatile organic solvent
Substitute, and when using, coating tool can wash by water, and decreases the consumption of cleaning solvent.The production of organic solvent needs to disappear
Consumption fossil feedstock, is a major challenge to resource in the present stage of resource scarcity, and the appearance of water paint solves this and asks
Topic.Meanwhile, the reduction of solvent, greatly reduce the discharge of VOC during producing and using, for improving week
Limit atmospheric environment has made positive contribution.
Country curbs environmental pollution severely, and national environmental consciousness promotes, consuming behavior changes, the sealing wax coating of energy-conserving and environment-protective
Industry is just welcoming unprecedented opportunity to develop, and market presents " blowout formula " Requirement.Efforts To Develop basic research, reduces
The difficulty of construction of water paint, improve serviceability, be water paint expansive approach field, extensive popularization and application when business
Anxious.Meanwhile, strengthen policy guides, promotional technique, transformation concept, the elimination public the prejudice of water paint and misgivings etc.
The attention of related work, also will play the effect of promotion to the application development of water paint.As Green Product, aqueous is coated with
Material necessarily obtains the accreditation of people and is widely used.Before the market demand huge in the face of water paint and ever-increasing application
Scape, strengthens research and development capabilities, and updates and promote the properties of product of water paint, accelerates product quality upgrading, develops in skill
The water paint more showing powerful competitive advantage in art, on cost, in performance has the meaning of reality and wide market
Space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that the water paint of a kind of anti-dust and
Its preparation method, this coating products excellent performance, there are good anti-dust performance, and energy-conserving and environment-protective, possess preferable economy
Benefit and social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 15~35 parts, silicon
Acrylic emulsion 5~20 parts, polyamide 5~20 parts, nano titanium oxide 3~15 parts, alkyd resin 3~15 parts, isopropanol 0.3
~1.5 parts, hexone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, drier 0.2~1
Part, flatting silica 1~5 parts, Kaolin 2~8 parts, deionized water 20~45 parts, rosin resin 3~15 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol
Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight
To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100~200 mesh sieves, gets product.
Preferably, described synergist is that butyl triphenyl is fluorinated phosphine.
Preferably, described defoamer is polyester modification siloxanes.
Preferably, described drier is manganese naphthenate.
The beneficial effects of the present invention is:
The present invention, by using combination property preferably high-molecular organic material and carrying out optimum organization, improves compositions
Anti-dust performance, use the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, and hot strength and fracture are stretched
Long rate is superior to common coating, can meet coated-body and use requirement for anticorrosion, weather-proof etc.;Preparation method of the present invention is simple, real
Having showed making full use of of resource and the energy, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialization and criticizes
Amount produces, and possesses preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 15 parts, silicon the third breast
Liquid 5 parts, polyamide 5 parts, nano titanium oxide 3 parts, alkyd resin 3 parts, isopropanol 0.3 part, hexone 0.5
Part, synergist 0.3 part, defoamer 0.3 part, drier 0.2 part, flatting silica 1 part, Kaolin 2 parts, deionized water 20 parts, Colophonium
Resin 3 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol
Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight
To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 100 mesh sieves, gets product.
Embodiment 2:
The water paint of a kind of anti-dust, is prepared by the raw materials in: Hydroxylated acrylic resin 35 parts, silicon the third breast
Liquid 20 parts, polyamide 20 parts, nano titanium oxide 15 parts, alkyd resin 15 parts, isopropanol 1.5 parts, methyl-isobutyl first
Ketone 2 parts, synergist 1.5 parts, defoamer 1.2 parts, drier 1 part, flatting silica 5 parts, Kaolin 8 parts, deionized water 45 parts, Colophonium
Resin 15 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol
Put in reaction vessel, be slowly heated to 40~50 DEG C, be stirred continuously and be uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone are joined in blender with rosin resin, be stirred continuously straight
To mix homogeneously, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step is added
Suddenly the solution that (3) prepare, continues to stir, and crosses 150 mesh sieves, gets product.
In the above embodiment of the present invention:
Described synergist is that butyl triphenyl is fluorinated phosphine;
Described defoamer is polyester modification siloxanes;
Described drier is manganese naphthenate.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve
The anti-dust performance of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, hot strength
It is superior to common coating with elongation at break, coated-body can be met requirement is used for anticorrosion, weather-proof etc.;Preparation method of the present invention
Simply, production process is environment friendly and pollution-free, and cost is relatively low, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (4)
1. the water paint of an anti-dust, it is characterised in that be prepared by the raw materials in: Hydroxylated acrylic resin 15
~35 parts, silicone acrylic emulsion 5~20 parts, polyamide 5~20 parts, nano titanium oxide 3~15 parts, alkyd resin 3~15 parts,
Isopropanol 0.3~1.5 parts, hexone 0.5~2 parts, synergist 0.3~1.5 parts, defoamer 0.3~1.2 parts, urge
Dry agent 0.2~1 part, flatting silica 1~5 parts, Kaolin 2~8 parts, deionized water 20~45 parts, rosin resin 3~15 parts;
Its preparation method in turn includes the following steps:
(1) Hydroxylated acrylic resin, silicone acrylic emulsion, polyamide, nano titanium oxide, alkyd resin and isopropanol are put into
In reaction vessel, it is slowly heated to 40~50 DEG C, is stirred continuously and is uniformly completely dissolved to material, obtain mixed liquor standby;
(2) flatting silica, Kaolin, hexone being joined in blender with rosin resin, being stirred continuously until mixing
Close uniformly, obtain suspension standby;
(3) synergist, defoamer, drier are dissolved in deionized water and obtain solution;
(4), after the suspension that mixed liquor step (1) prepared and step (2) prepare is mixed and stirred for uniformly, step (3) is added
The solution prepared, continues to stir, and crosses 100~200 mesh sieves, gets product.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described synergist is butyl triphen
Base fluorination phosphine.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described defoamer is polyester modification
Siloxanes.
The water paint of a kind of anti-dust the most according to claim 1, it is characterised in that described drier is aphthenic acids
Manganese.
Priority Applications (1)
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CN201610620020.8A CN106046991A (en) | 2016-08-01 | 2016-08-01 | Ash-sticking-proof waterborne coating and preparation method thereof |
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CN201610620020.8A CN106046991A (en) | 2016-08-01 | 2016-08-01 | Ash-sticking-proof waterborne coating and preparation method thereof |
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CN201610620020.8A Pending CN106046991A (en) | 2016-08-01 | 2016-08-01 | Ash-sticking-proof waterborne coating and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107201111A (en) * | 2017-04-18 | 2017-09-26 | 安徽华辉塑业科技股份有限公司 | A kind of perambulator steelwork topical oil paint preparation method |
CN107964338A (en) * | 2017-12-29 | 2018-04-27 | 安徽科邦树脂科技有限公司 | A kind of anti-fouling type water paint synthetic method |
CN108034343A (en) * | 2017-12-29 | 2018-05-15 | 安徽科邦树脂科技有限公司 | A kind of anti-fouling type water paint |
CN108912876A (en) * | 2017-04-18 | 2018-11-30 | 重庆瑞恩涂料有限公司 | A kind of aqueous coating process for electronic product |
CN112959752A (en) * | 2021-02-03 | 2021-06-15 | 北京尚德智美环境科技有限公司 | Processing technology of anti-sticking cloth |
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CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
CN103666275A (en) * | 2013-12-10 | 2014-03-26 | 张家港市民扬塑胶科技有限公司 | Water-based anti-bacterial mould-proof paint |
CN104277680A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Germicidal negative-radical waterproof coating and preparation method thereof |
CN104449130A (en) * | 2014-10-23 | 2015-03-25 | 安徽省实防新型玻璃科技有限公司 | Corrosion-oxidation-resistant and environment-friendly waterborne coating for glass door and preparation method of waterborne coating |
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2016
- 2016-08-01 CN CN201610620020.8A patent/CN106046991A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
CN103666275A (en) * | 2013-12-10 | 2014-03-26 | 张家港市民扬塑胶科技有限公司 | Water-based anti-bacterial mould-proof paint |
CN104449130A (en) * | 2014-10-23 | 2015-03-25 | 安徽省实防新型玻璃科技有限公司 | Corrosion-oxidation-resistant and environment-friendly waterborne coating for glass door and preparation method of waterborne coating |
CN104277680A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Germicidal negative-radical waterproof coating and preparation method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107201111A (en) * | 2017-04-18 | 2017-09-26 | 安徽华辉塑业科技股份有限公司 | A kind of perambulator steelwork topical oil paint preparation method |
CN108912876A (en) * | 2017-04-18 | 2018-11-30 | 重庆瑞恩涂料有限公司 | A kind of aqueous coating process for electronic product |
CN107964338A (en) * | 2017-12-29 | 2018-04-27 | 安徽科邦树脂科技有限公司 | A kind of anti-fouling type water paint synthetic method |
CN108034343A (en) * | 2017-12-29 | 2018-05-15 | 安徽科邦树脂科技有限公司 | A kind of anti-fouling type water paint |
CN112959752A (en) * | 2021-02-03 | 2021-06-15 | 北京尚德智美环境科技有限公司 | Processing technology of anti-sticking cloth |
CN112959752B (en) * | 2021-02-03 | 2022-07-08 | 北京尚德智美环境科技有限公司 | Processing technology of anti-sticking cloth |
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Application publication date: 20161026 |