CN104277680A - Germicidal negative-radical waterproof coating and preparation method thereof - Google Patents
Germicidal negative-radical waterproof coating and preparation method thereof Download PDFInfo
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- CN104277680A CN104277680A CN201410590340.4A CN201410590340A CN104277680A CN 104277680 A CN104277680 A CN 104277680A CN 201410590340 A CN201410590340 A CN 201410590340A CN 104277680 A CN104277680 A CN 104277680A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a germicidal negative-radical waterproof coating, which is characterized by being prepared from the following raw materials in parts by weight: 0.2-0.4 part of a dispersant EFKA4010, 0.1-0.2 part of a defoaming agent BYK-390, 0.2-0.3 part of a defoaming agent BYK-057, 0.1-0.3 part of a dodecylbenzene sulfonic acid, 40-50 parts of an organosilicone modified polyester resin, 10-15 parts of an acrylic resin, 6-8 parts of a hexamethoxymethyl melamine resin, 4-6 parts of rutile titania, 2-4 parts of silicon sol, 0.3-0.5 part of methyl cellulose, 0.3-0.5 part of palm wax, 3-6 parts of barium sulfate, 4-5 parts of mica powder, 1-2 parts of a matting agent, 0.2-0.4 part of an anti-scratch agent BYK-980, 7-9 parts of S-150, 3-5 parts of diacetone alcohol, 5-7 parts of butyl acetate, 0.5-1.0 part of quizalofop-p-ethyl, and 5-7 parts of a negative-radical additive. According to the coating disclosed by the invention, the added silicon sol is used for enhancing the hardness and wear resistance of a coated film, the added anti-scratch agent is used for improving the scratch resistance of the coated film, the added rutile titania achieves good bacteriostatic and germicidal effects and the like on the soil, and the added negative-radical additive has a good negative-radical effect and has no adverse effect on plants.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of sterilization root-resistant type waterproof paint and preparation method thereof.
Background technology
Water-proof material is widely used in building materials protection field, use water-proof coating to buildings to carry out after application can by buildings and external environment isolated, prevent the corrosion because the moisture intrusion buildings material in the corrosive liquid such as rainwater, underground water and air causes thus, extend the work-ing life of material of construction.But general architectural waterproof material difficulty has resisted the puncture of root system of plant.Mainly contain root-resistance waterproof coiled material and root resistance waterproof paint in the market, root-resistance waterproof coiled material mainly contains complex copper tire base modified asphalt waterproof coiled material, and the root resistance effect of this coiled material is no doubt reliable, but cost is also very expensive; Another kind of is metal tire base waterproof roll, and the defect of such material is that tire base is positioned in the middle of material and causes coiled material lapping place metal tire base can not be formed closed, leaves passage to the root system of plant that can change the direction of growth, root resistance waterproof effect was lost efficacy; A class is metal coiled material again, such material welding joint close, reliable for effect, but defect is that cost height and metal ion are toxic to root system of plant, can cause plant-growth deformity, and the manufacture craft of waterproof roll is very complicated, cost is high, higher to the requirement of workmen, it is very difficult that the later stage carries out care and maintenance, so use range is limited.The present invention is directed to root resistance auxiliary agent prepared by this situation, add in coating as auxiliary agent, there is production cost low, root system of plant is not almost affected, play the effect of good anti-root system of plant puncture, and waterproof paint of the present invention also has the function of sterilization, greatly reduce the impact of unwanted bacteria on root system of plant of soil, ensure that the normal growth of plant.
Summary of the invention
The object of this invention is to provide a kind of sterilization root-resistant type waterproof paint and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of sterilization root-resistant type waterproof paint, be made up of the raw material of following weight part: dispersion agent EFKA40100.2-0.4, defoamer BYK-3900.1-0.2, defoamer BYK-0570.2-0.3, Witco 1298 Soft Acid 0.1-0.3, silicone modified polyester resin 40-50, acrylic resin 10-15, hexamethoxymethyl melamine resin 6-8, rutile titanium dioxide 4-6, silicon sol 2-4, methylcellulose gum 0.3-0.5, palm wax 0.3-0.5, barium sulfate 3-6, mica powder 4-5, matting agent 1-2, scratching resistant BYK-9800.2-0.4, S-1507-9, diacetone alcohol 3-5, N-BUTYL ACETATE 5-7, quizalofopPethyl 0.5-1.0, root resistance auxiliary agent 5-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
A kind of sterilization root-resistant type waterproof paint of the present invention, comprises following concrete steps:
(1) by N-BUTYL ACETATE, diacetone alcohol, S-150 mixing, add rutile titanium dioxide, silicon sol, palm wax, barium sulfate, mica powder ultrasonic disperse 10-20 minute, root resistance auxiliary agent, quizalofopPethyl and dispersion agent EFKA4010 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer BYK-390, defoamer BYK-057, Witco 1298 Soft Acid, silicone modified polyester resin, acrylic resin, methylcellulose gum stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Advantage of the present invention is: waterproof paint sticking power of the present invention is good, ageing-resistant performance is high, the water resistance that scratch resistant performance is superior and excellent, the silicon sol added enhances hardness and the wear resistance of film, the scratching resistant added improves the scratch-proofness of film, the rutile titanium dioxide added plays the effect of the aspects such as good restraining and sterilizing bacteria to soil, the root resistance auxiliary agent root resistance of interpolation is effective, has no adverse effects to plant.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of sterilization root-resistant type waterproof paint, is made up of the raw material of following weight part (kilogram): dispersion agent EFKA40100.4, defoamer BYK-3900.1, defoamer BYK-0570.2, Witco 1298 Soft Acid 0.3, silicone modified polyester resin 46, acrylic resin 13, hexamethoxymethyl melamine resin 7, rutile titanium dioxide 6, silicon sol 4, methylcellulose gum 0.4, palm wax 0.4, barium sulfate 4, mica powder 4, matting agent 1, scratching resistant BYK-9800.4, S-1508, diacetone alcohol 4, N-BUTYL ACETATE 7, quizalofopPethyl 0.6, root resistance auxiliary agent 6;
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part (kilogram): root resistance agent B24, petroleum pitch AH-8033, petroleum resin 14, gum resin 5, nano titanium oxide 3, turps 12, ethyl acetate 7, epoxy soybean oil 3, copper nanoparticle 7, calcined kaolin powder 16, calcining calcite in powder 15, silicon carbide whisker powder 7, sodium lauryl sulphate 1, silane coupling agent KH5600.9, Ethylene glycol dimethacrylate 1, dilaurate dibutyl tin 0.6, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
A kind of sterilization root-resistant type waterproof paint of the present invention, comprises following concrete steps:
(1) by N-BUTYL ACETATE, diacetone alcohol, S-150 mixing, add rutile titanium dioxide, silicon sol, palm wax, barium sulfate, mica powder ultrasonic disperse 10-20 minute, root resistance auxiliary agent, quizalofopPethyl and dispersion agent EFKA4010 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer BYK-390, defoamer BYK-057, Witco 1298 Soft Acid, silicone modified polyester resin, acrylic resin, methylcellulose gum stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Paint adhesion experiment (cross-hatching) of the present invention: 0 grade, experiment of hardness: 3H, T curved experiment: 3T, resistance to impact shock is tested: 6J, artificial ageing resistance experiment (2000H): film is unchanged, resistance to boiling water experiment (2H): unchanged, root puncture resistant capacity experimental: without penetration phenomenon.
Claims (2)
1. a sterilization root-resistant type waterproof paint, it is characterized in that, be made up of the raw material of following weight part: dispersion agent EFKA40100.2-0.4, defoamer BYK-3900.1-0.2, defoamer BYK-0570.2-0.3, Witco 1298 Soft Acid 0.1-0.3, silicone modified polyester resin 40-50, acrylic resin 10-15, hexamethoxymethyl melamine resin 6-8, rutile titanium dioxide 4-6, silicon sol 2-4, methylcellulose gum 0.3-0.5, palm wax 0.3-0.5, barium sulfate 3-6, mica powder 4-5, matting agent 1-2, scratching resistant BYK-9800.2-0.4, S-1507-9, diacetone alcohol 3-5, N-BUTYL ACETATE 5-7, quizalofopPethyl 0.5-1.0, root resistance auxiliary agent 5-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
2. a kind of sterilization root-resistant type waterproof paint according to claims 1, is characterized in that, comprise following concrete steps:
(1) by N-BUTYL ACETATE, diacetone alcohol, S-150 mixing, add rutile titanium dioxide, silicon sol, palm wax, barium sulfate, mica powder ultrasonic disperse 10-20 minute, root resistance auxiliary agent, quizalofopPethyl and dispersion agent EFKA4010 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer BYK-390, defoamer BYK-057, Witco 1298 Soft Acid, silicone modified polyester resin, acrylic resin, methylcellulose gum stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410590340.4A CN104277680A (en) | 2014-10-29 | 2014-10-29 | Germicidal negative-radical waterproof coating and preparation method thereof |
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| CN201410590340.4A CN104277680A (en) | 2014-10-29 | 2014-10-29 | Germicidal negative-radical waterproof coating and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927592A (en) * | 2015-05-27 | 2015-09-23 | 芜湖县双宝建材有限公司 | Modified polyester resin coating for ships |
| CN105086685A (en) * | 2015-07-29 | 2015-11-25 | 安徽鹏峰新型建材科技有限公司 | Weather-resistance water-resistance acrylate paint for scaffold |
| CN105440644A (en) * | 2015-12-01 | 2016-03-30 | 雷小卫 | Root resistant agent for production of root resistant material and preparation method of root resistant agent |
| CN106046991A (en) * | 2016-08-01 | 2016-10-26 | 安庆瑞泰化工有限公司 | Ash-sticking-proof waterborne coating and preparation method thereof |
| CN106147548A (en) * | 2016-08-14 | 2016-11-23 | 安庆市沁之源电器有限公司 | A kind of electric fan sound deadening coating and preparation method thereof |
| WO2018158486A1 (en) * | 2017-03-03 | 2018-09-07 | Laboratorio Jaer, S.A. | Phyllosilicate-copper solid materials with biocidal activity |
| CN112359602A (en) * | 2020-10-31 | 2021-02-12 | 梁露榕 | Waterproof antibacterial non-woven fabric and preparation method thereof |
| CN116262668A (en) * | 2021-12-15 | 2023-06-16 | 泉州市德化县恒峰陶瓷有限公司 | Preparation process of antibacterial high-strength ceramic |
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| CN103965707A (en) * | 2014-05-16 | 2014-08-06 | 湖州百胜涂料有限公司 | Improved anti-aging waterproof coating |
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| WO2012002095A1 (en) * | 2010-06-28 | 2012-01-05 | 関西ペイント株式会社 | Contamination resistant coating composition with excellent durability |
| CN101935488A (en) * | 2010-09-30 | 2011-01-05 | 北京立高科技股份有限公司 | Plant root resistant waterproof coating and preparation method thereof |
| CN102226054A (en) * | 2011-06-14 | 2011-10-26 | 德美建筑材料（太原）工程有限公司 | Sunlight reflective insulation paint |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927592A (en) * | 2015-05-27 | 2015-09-23 | 芜湖县双宝建材有限公司 | Modified polyester resin coating for ships |
| CN105086685A (en) * | 2015-07-29 | 2015-11-25 | 安徽鹏峰新型建材科技有限公司 | Weather-resistance water-resistance acrylate paint for scaffold |
| CN105440644A (en) * | 2015-12-01 | 2016-03-30 | 雷小卫 | Root resistant agent for production of root resistant material and preparation method of root resistant agent |
| CN106046991A (en) * | 2016-08-01 | 2016-10-26 | 安庆瑞泰化工有限公司 | Ash-sticking-proof waterborne coating and preparation method thereof |
| CN106147548A (en) * | 2016-08-14 | 2016-11-23 | 安庆市沁之源电器有限公司 | A kind of electric fan sound deadening coating and preparation method thereof |
| WO2018158486A1 (en) * | 2017-03-03 | 2018-09-07 | Laboratorio Jaer, S.A. | Phyllosilicate-copper solid materials with biocidal activity |
| US11412738B2 (en) | 2017-03-03 | 2022-08-16 | Laboratorio Jaer, S.A. | Phyllosilicate-copper solid materials with biocidal activity |
| CN112359602A (en) * | 2020-10-31 | 2021-02-12 | 梁露榕 | Waterproof antibacterial non-woven fabric and preparation method thereof |
| CN116262668A (en) * | 2021-12-15 | 2023-06-16 | 泉州市德化县恒峰陶瓷有限公司 | Preparation process of antibacterial high-strength ceramic |
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Application publication date: 20150114 |