CN104277637A - Self-cleaning flame-retardant exterior wall coating and preparation method thereof - Google Patents
Self-cleaning flame-retardant exterior wall coating and preparation method thereof Download PDFInfo
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- CN104277637A CN104277637A CN201410590446.4A CN201410590446A CN104277637A CN 104277637 A CN104277637 A CN 104277637A CN 201410590446 A CN201410590446 A CN 201410590446A CN 104277637 A CN104277637 A CN 104277637A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a self-cleaning flame-retardant exterior wall coating. The self-cleaning flame-retardant exterior wall coating is characterized by being prepared from the following raw materials in parts by weight: 36-42 parts of an acrylic resin emulsion, 30-35 parts of a vinyl epoxy resin emulsion, 3-4 parts of aluminum silver powder, 2-3 parts of polyisobutylene, 3-4 parts of rutile-type nanometer titanium dioxide powder, 2-4 parts of propylene glycol monomethyl ether, 0.3-0.5 part of sodium polycarboxylate, 2-3 parts of silica sol, 0.3-0.6 part of triethanolamine oleate, 2-3 parts of titanium phosphate, 2-3 parts of tin antimony phosphate, 1-2 parts of lithopone, 1-2 parts of kaolin, 0.4-0.8 part of an acrylic alkali-swellable thickener, 1-2 parts of tris(2-chloropropyl) phosphate, 1-2 parts of aminoethyl aminopropyl triethoxysilane, 6-9 parts of a self-cleaning slurry and 14-20 parts of deionized water. The exterior wall coating has the characteristics of high adhesion, good adhesive force, good weather resistance and high aging resistance and chalking resistance; due to addition of the silica sol, the hardness and abrasion resistance of the coating film are enhanced; the added aluminum silver powder has a bactericidal effect, the added self-cleaning slurry has an excellent self-cleaning effect; tin antimony phosphate has self-cleaning enhancing effect and thus the staining property of the exterior wall is reduced and the cost of manual cleaning is reduced; and the added tris(2-chloropropyl) phosphate has a flame-retardant effect and reduces risk factors causing the fire disaster.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of automatically cleaning flame retardant type exterior coating and preparation method thereof.
Background technology
According to China Chemical Industry net statistics, in the first two months, 2009, China's coating increase of production 13.3%, annual production reaches 5,000,000 tons, has become world's second largest producing country, but is not also power, having with international water product must gap, and the dynamics mainly owing to research and development is inadequate.At present, the research and development comparative maturity of part functionalities coating, comprising: wear-resistant paint, frie retardant coating, waterproof paint, weatherability coating, ornamental coating etc.But complicated along with social environment, the demand of functional coating is more and more extensive, some new demands constantly occur, exterior coating rich color, facing are versatile and flexible, the architectural style that energy expressed in abundance is colorful, easy construction, be easy to safeguard, from heavy and light, safe and reliable, become the exterior wall finish material that popularization is done one's utmost to advocate by country.But outer wall coating stain resistant scarce capacity governs the outstanding technical barrier that China's exterior coating is applied.Outer wall coating is contaminated, greatly have impact on aesthetic property and the weather resistance of building.So, in the important indicator investigating building external paint performance, introduce the contaminated resistance of coating.From environmental protection and energy-conservation consideration, the coating with stain resistant function receives the concern of people gradually or.Self-cleaning coating does not need special maintenance, low-carbon environment-friendly, being stained with property of resistant is strong, the present invention is directed to this situation, by there is the self-cleaning material of photo-catalysis function and there is the macromolecular compound doping of conduction property, then through forming slurry with other substance reactions, add in coating serving good automatically cleaning effect to as auxiliary agent.
Summary of the invention
The object of this invention is to provide a kind of automatically cleaning flame retardant type exterior coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of automatically cleaning flame retardant type exterior coating, be made up of the raw material of following weight part: Emulsion acrylic resin 36-42, vinyl epoxy resin emulsion 30-35, aluminium silver powder 3-4, polyisobutene 2-3, rutile type nano titanium dioxide 3-4, propylene glycol monobutyl ether 2-4, polycarboxylate sodium 0.3-0.5, silicon sol 2-3, Emulphor FM 0.3-0.6, titanium phosphate 2-3, phosphoric acid tin antimony 2-3, zinc sulfide white 1-2, kaolin 1-2, propylene soda acid swollen thickener 0.4-0.8, tricresyl phosphate (2-chloropropyl) ester 1-2, aminoethylaminopropyl triethoxyl silane 1-2, automatically cleaning slurry 6-9, deionized water 14-20,
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of automatically cleaning flame retardant type exterior coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyisobutene, kaolin and Emulphor FM are mixed and heated to 60-90 ° of C and form emulsion, add polycarboxylate sodium again, aluminium silver powder, rutile type nano titanium dioxide, titanium phosphate, phosphoric acid tin antimony, zinc sulfide white, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add aminoethylaminopropyl triethoxyl silane and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, vinyl epoxy resin emulsion, propylene glycol monobutyl ether, silicon sol are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
The invention has the advantages that: exterior coating cohesiveness of the present invention is high, sticking power is good, good weatherability, ageing-resistant and chalking resistance can be high, the silicon sol added enhances hardness and the wear resistance of paint film, the aluminium silver powder added has the effect of sterilization, the automatically cleaning slurry added has splendid automatically cleaning effect, phosphoric acid tin antimony has the effect of automatically cleaning synergy, reduce the contamination of exterior wall, reduce the expense of manual cleaning, tricresyl phosphate (2-chloropropyl) ester of interpolation has fire-retardant effect, reduces the Hazard Factor causing fire.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of automatically cleaning flame retardant type exterior coating, is made up of the raw material of following weight part (kilogram): Emulsion acrylic resin 39, vinyl epoxy resin emulsion 33, aluminium silver powder 4, polyisobutene 2, rutile type nano titanium dioxide 3, propylene glycol monobutyl ether 3, polycarboxylate sodium 0.4, silicon sol 3, Emulphor FM 0.4, titanium phosphate 2, phosphoric acid tin antimony 2, zinc sulfide white 2, kaolin 1, propylene soda acid swollen thickener 0.6, tricresyl phosphate (2-chloropropyl) ester 2, aminoethylaminopropyl triethoxyl silane 2, automatically cleaning slurry 9, deionized water 18;
Described automatically cleaning slurry is made up of the raw material of following weight part (kilogram): polyisobutene 3, tetrabutyl titanate 0.8, zinc oxide 7, dispersion agent 50403, titanium dioxide 26, zirconium white 14, ethanol 40, Diisopropyl azodicarboxylate 1, sodium laurylsulfonate 1.2, antimony-doped stannic oxide 6, sodium acetate 2, Vltra tears 2, polyaniline 2, bipyridyl ruthenium 1, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of automatically cleaning flame retardant type exterior coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyisobutene, kaolin and Emulphor FM are mixed and heated to 60-90 ° of C and form emulsion, add polycarboxylate sodium again, aluminium silver powder, rutile type nano titanium dioxide, titanium phosphate, phosphoric acid tin antimony, zinc sulfide white, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add aminoethylaminopropyl triethoxyl silane and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, vinyl epoxy resin emulsion, propylene glycol monobutyl ether, silicon sol are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Coating ageing resistance experiment of the present invention: 3000 hours unchanged, non-foaming, do not peel off, do not chap, salt fog resistance is tested: 1000 hours unchanged, resistance to boiling water experiment (240H): unchanged, alkaline-resisting experiment (sodium hydroxide of 10%, 100H): unchanged, contamination resistance experiment (5 circulations) :≤30%, coating temperature-change resistance is tested: 5 circulations are without exception, hardness: 3H, and film is to contact angle >=150 of water ° C.
Claims (2)
1. an automatically cleaning flame retardant type exterior coating, it is characterized in that, be made up of the raw material of following weight part: Emulsion acrylic resin 36-42, vinyl epoxy resin emulsion 30-35, aluminium silver powder 3-4, polyisobutene 2-3, rutile type nano titanium dioxide 3-4, propylene glycol monobutyl ether 2-4, polycarboxylate sodium 0.3-0.5, silicon sol 2-3, Emulphor FM 0.3-0.6, titanium phosphate 2-3, phosphoric acid tin antimony 2-3, zinc sulfide white 1-2, kaolin 1-2, propylene soda acid swollen thickener 0.4-0.8, tricresyl phosphate (2-chloropropyl) ester 1-2, aminoethylaminopropyl triethoxyl silane 1-2, automatically cleaning slurry 6-9, deionized water 14-20,
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
2. a kind of automatically cleaning flame retardant type exterior coating according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, polyisobutene, kaolin and Emulphor FM are mixed and heated to 60-90 ° of C and form emulsion, add polycarboxylate sodium again, aluminium silver powder, rutile type nano titanium dioxide, titanium phosphate, phosphoric acid tin antimony, zinc sulfide white, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-60 ° of C after 20-30 minute, add aminoethylaminopropyl triethoxyl silane and continue to stir 5-10 minute;
(2) Emulsion acrylic resin, vinyl epoxy resin emulsion, propylene glycol monobutyl ether, silicon sol are added in Scattered Kettle and mix, be heated to 40-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590446.4A CN104277637A (en) | 2014-10-29 | 2014-10-29 | Self-cleaning flame-retardant exterior wall coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410590446.4A CN104277637A (en) | 2014-10-29 | 2014-10-29 | Self-cleaning flame-retardant exterior wall coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105427962A (en) * | 2015-12-14 | 2016-03-23 | 东莞市瀛通电线有限公司 | Self-cleaning wire rod and manufacturing technology thereof |
| CN105419495A (en) * | 2015-12-29 | 2016-03-23 | 齐齐哈尔译夫经贸有限公司 | Building paint having flame retardation and antibiosis functions |
| CN107189500A (en) * | 2017-05-31 | 2017-09-22 | 江苏达克罗涂装技术有限公司 | A kind of coating with self-cleaning property and preparation method thereof |
| CN109517490A (en) * | 2018-11-30 | 2019-03-26 | 成都玉龙化工有限公司 | A kind of exterior coating agent of high-adhesion |
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| CN102391779A (en) * | 2011-09-29 | 2012-03-28 | 资阳赛特化工有限公司 | Metal base material corrosion-resistant coating and preparation method thereof |
| US20130078456A1 (en) * | 2011-09-28 | 2013-03-28 | Pangang Group Panzhihua Iron & Steel Research Institute Co., Ltd. | Metal protection coating, hot-dip zn metallic material and hot-dip al-zn metallic material using the same |
| CN103627227A (en) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | Solar glass self-cleaning antireflection paint and production method thereof |
| CN104017402A (en) * | 2014-05-23 | 2014-09-03 | 浙江鸿浩科技有限公司 | Flame retardation type exterior coating capable of automatically cleaning |
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2014
- 2014-10-29 CN CN201410590446.4A patent/CN104277637A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101824270A (en) * | 2010-04-30 | 2010-09-08 | 长沙新凯化工有限公司 | Waterborne heat-insulating flame-retardant multifunctional nano coating and preparation method thereof |
| US20130078456A1 (en) * | 2011-09-28 | 2013-03-28 | Pangang Group Panzhihua Iron & Steel Research Institute Co., Ltd. | Metal protection coating, hot-dip zn metallic material and hot-dip al-zn metallic material using the same |
| CN102391779A (en) * | 2011-09-29 | 2012-03-28 | 资阳赛特化工有限公司 | Metal base material corrosion-resistant coating and preparation method thereof |
| CN103627227A (en) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | Solar glass self-cleaning antireflection paint and production method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105427962A (en) * | 2015-12-14 | 2016-03-23 | 东莞市瀛通电线有限公司 | Self-cleaning wire rod and manufacturing technology thereof |
| CN105427962B (en) * | 2015-12-14 | 2017-11-21 | 东莞市瀛通电线有限公司 | A kind of automatically cleaning line Materials And Manufacturing Processes |
| CN105419495A (en) * | 2015-12-29 | 2016-03-23 | 齐齐哈尔译夫经贸有限公司 | Building paint having flame retardation and antibiosis functions |
| CN107189500A (en) * | 2017-05-31 | 2017-09-22 | 江苏达克罗涂装技术有限公司 | A kind of coating with self-cleaning property and preparation method thereof |
| CN109517490A (en) * | 2018-11-30 | 2019-03-26 | 成都玉龙化工有限公司 | A kind of exterior coating agent of high-adhesion |
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