CN104277670A - Heat-insulating self-cleaning architectural coating and preparation method thereof - Google Patents
Heat-insulating self-cleaning architectural coating and preparation method thereof Download PDFInfo
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- CN104277670A CN104277670A CN201410590727.XA CN201410590727A CN104277670A CN 104277670 A CN104277670 A CN 104277670A CN 201410590727 A CN201410590727 A CN 201410590727A CN 104277670 A CN104277670 A CN 104277670A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a heat-insulating self-cleaning architectural coating, which is characterized by being prepared from the following raw materials in parts by weight: 30-40 parts of a bisphenol epoxy resin, 20-30 parts of a nano silicon resin, 3-4 parts of 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate, 0.5-1.0 part of aluminium oxide, 1-2 parts of glyceryl tristearate, 3-5 parts of polytetrafluoroethylene powder, 1-2 parts of shell-lac, 2-3 parts of polyethylene wax, 3-4 parts of fly ash floating beads, 0.3-0.4 part of azodiisobutyronitrile, 0.2-0.4 part of polyether modified siloxane, 1-2 parts of zinc naphthenate, 1-3 parts of polymerized silica, 6-9 parts of self-cleaning slurry, 1-2 parts of aminopropyltriethoxysilane, 10-13 parts of ethyl acetate, and 5-7 parts of ethylene glycol. The coating disclosed by the invention is used for solving the problem that a coat is poor in fouling resistance, easily polluted, and not ideal enough in heat insulation effect. The added fly ash floating beads are good in heat insulation effect and low in cost, and the added self-cleaning slurry has a good self-cleaning effect; the coating disclosed by the invention is high in adhesion and good in abrasion resistance, and has excellent heat insulation and self-cleaning functions; and the coating is low in production cost, simple in operation and wide in application range.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of thermal-insulation, self-cleaning building coating and preparation method thereof.
Background technology
Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.Belong to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The decoration of buildings and protection have many approach, but employing coating is wherein the simplest, economical and maintenance renewal one easily, therefore widely adopts in construction work at home and abroad.But traditional coating becomes through there is look after a while, comes off, glass curtain wall or ceramic tile veneer can bring again light pollution, increase buildings deadweight, there is the problems such as potential safety hazard.Therefore, the self-cleaning coating of development of new is the important method overcome the above problems at present.Sun power is maximum thermal radiation source, and the sun is continuous outwards quantity of radiant energy in the form of an electromagnetic wave, and the solar energy be radiated on earth surface is approximately 75w/m per second
2.By solar light irradiation, the accumulation due to heat can make air and body surface temperature constantly raise, and heat enters internal medium by thermal conduction.In order to make the temperature of many internal mediums such as buildings be in relatively suitable condition, the use of the refrigeration equipment such as air-conditioning, electric fan will be increased, add power consumption and compromise environment, so the coating with effect of heat insulation is also the trend of research at present.The present invention is directed to this situation, by there is the self-cleaning material of photo-catalysis function and there is the macromolecular compound doping of conduction property, then through forming slurry with other substance reactions, add in coating as auxiliary agent and serve good automatically cleaning effect, and add the heat-proof quality that some materials with effect of heat insulation improve coating.
Summary of the invention
The object of this invention is to provide a kind of thermal-insulation, self-cleaning building coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of thermal-insulation, self-cleaning building coating, is made up of the raw material of following weight part: bisphenol epoxy 30-40, nano-silicon resin 20-30, Lauryl Alcohol ester 3-4, aluminium sesquioxide 0.5-1.0, Tristearoylglycerol 1-2, polytetrafluoroethylene powder 3-5, shellac 1-2, polyethylene wax 2-3, fly ash float 3-4, Diisopropyl azodicarboxylate 0.3-0.4, polyether modified siloxane 0.2-0.4, zinc naphthenate 1-2, polymer/silicon dioxide 1-3, automatically cleaning slurry 6-9, aminopropyl triethoxysilane 1-2, ethyl acetate 10-13, ethylene glycol 5-7;
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of thermal-insulation, self-cleaning building coating of the present invention, be made up of following concrete steps:
(1) ethyl acetate, ethylene glycol, polyethylene wax are mixed and heated to 90-100 ° of C, add aluminium sesquioxide again, polytetrafluoroethylene powder, fly ash float, polymer/silicon dioxide, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-70 ° of C after 20-30 minute, add Diisopropyl azodicarboxylate and continue to stir 5-10 minute;
(2) bisphenol epoxy, nano-silicon resin, Lauryl Alcohol ester, zinc naphthenate, Tristearoylglycerol, aminopropyl triethoxysilane are added in Scattered Kettle and mix, be heated to 50-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Advantage of the present invention is: coating of the present invention solves coating anti-stain characteristic can be poor, and coating is the contaminated and dissatisfactory problem of effect of heat insulation easily.The fly ash float good heat-insulation effect of adding, cost is low, and the automatically cleaning slurry of interpolation has good automatically cleaning effect, paint adhesion of the present invention is high, and wear resistance is good, also has excellent heat insulation and self-cleaning function, production cost is low, simple to operate, and use range is wide.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of thermal-insulation, self-cleaning building coating, is made up of the raw material of following weight part (kilogram): bisphenol epoxy 36, nano-silicon resin 25, Lauryl Alcohol ester 4, aluminium sesquioxide 0.8, Tristearoylglycerol 1, polytetrafluoroethylene powder 4, shellac 1, polyethylene wax 3, fly ash float 3, Diisopropyl azodicarboxylate 0.3, polyether modified siloxane 0.3, zinc naphthenate 1, polymer/silicon dioxide 2, automatically cleaning slurry 8, aminopropyl triethoxysilane 1, ethyl acetate 12, ethylene glycol 6;
Described automatically cleaning slurry is made up of the raw material of following weight part (kilogram): polyisobutene 3, tetrabutyl titanate 0.8, zinc oxide 7, dispersion agent 50403, titanium dioxide 26, zirconium white 14, ethanol 40, Diisopropyl azodicarboxylate 1, sodium laurylsulfonate 1.2, antimony-doped stannic oxide 6, sodium acetate 2, Vltra tears 2, polyaniline 2, bipyridyl ruthenium 1, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
A kind of thermal-insulation, self-cleaning building coating of the present invention, be made up of following concrete steps:
(1) ethyl acetate, ethylene glycol, polyethylene wax are mixed and heated to 90-100 ° of C, add aluminium sesquioxide again, polytetrafluoroethylene powder, fly ash float, polymer/silicon dioxide, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-70 ° of C after 20-30 minute, add Diisopropyl azodicarboxylate and continue to stir 5-10 minute;
(2) bisphenol epoxy, nano-silicon resin, Lauryl Alcohol ester, zinc naphthenate, Tristearoylglycerol, aminopropyl triethoxysilane are added in Scattered Kettle and mix, be heated to 50-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Coating ageing resistance experiment of the present invention: 3000 hours unchanged, salt fog resistance is tested: 1000 hours unchanged, resistance to boiling water experiment (240H): unchanged, alkaline-resisting experiment (the sodium hydroxide of 10%, 100H): unchanged, contamination resistance experiment (5 circulations) :≤30%, coating temperature-change resistance is tested: 5 circulations are without exception, hardness: 3H, film is to contact angle >=130 of water ° C.
Claims (2)
1. a thermal-insulation, self-cleaning building coating, it is characterized in that, be made up of the raw material of following weight part: bisphenol epoxy 30-40, nano-silicon resin 20-30, Lauryl Alcohol ester 3-4, aluminium sesquioxide 0.5-1.0, Tristearoylglycerol 1-2, polytetrafluoroethylene powder 3-5, shellac 1-2, polyethylene wax 2-3, fly ash float 3-4, Diisopropyl azodicarboxylate 0.3-0.4, polyether modified siloxane 0.2-0.4, zinc naphthenate 1-2, polymer/silicon dioxide 1-3, automatically cleaning slurry 6-9, aminopropyl triethoxysilane 1-2, ethyl acetate 10-13, ethylene glycol 5-7;
Described automatically cleaning slurry is made up of the raw material of following weight part: polyisobutene 2-3, tetrabutyl titanate 0.5-1.0, zinc oxide 6-10, dispersion agent 50403-4, titanium dioxide 20-30, zirconium white 10-15, ethanol 30-50, Diisopropyl azodicarboxylate 1-2, sodium laurylsulfonate 1-2, antimony-doped stannic oxide 5-7, sodium acetate 1-2, Vltra tears 2-4, polyaniline 1-2, bipyridyl ruthenium 1-2, preparation method is by zinc oxide, titanium dioxide, zirconium white, antimony-doped stannic oxide ball milling becomes nano-powder, be added to polyaniline, in the ethanolic soln of bipyridyl ruthenium, mix and blend 2-3 hour under baking oven 60-80 ° C dry 1-2 hour for subsequent use, again by Vltra tears, sodium laurylsulfonate, sodium acetate, dispersion agent 5040 and remaining ethanol are mixed and heated to 40-60 ° of C, add the nano-powder ultrasonic disperse 0.5-1 hour of above-mentioned preparation, meanwhile add all the other surplus materials mixing and stirring, the weight that drying is concentrated into titanium dioxide accounts for the 10-30% of slurry weight.
2. a kind of thermal-insulation, self-cleaning building coating according to claim 1, is characterized in that, be made up of following concrete steps:
(1) ethyl acetate, ethylene glycol, polyethylene wax are mixed and heated to 90-100 ° of C, add aluminium sesquioxide again, polytetrafluoroethylene powder, fly ash float, polymer/silicon dioxide, automatically cleaning slurry ultrasonic disperse reduce temperature at 50-70 ° of C after 20-30 minute, add Diisopropyl azodicarboxylate and continue to stir 5-10 minute;
(2) bisphenol epoxy, nano-silicon resin, Lauryl Alcohol ester, zinc naphthenate, Tristearoylglycerol, aminopropyl triethoxysilane are added in Scattered Kettle and mix, be heated to 50-60 ° of C, under the rotating speed of 200-400 rev/min, stir 30-50 minute;
(3) mixed by all the other surplus materialss, the material added in step (1) and step (2) stirs with the rotating speed of 200-300 rev/min, filters and packages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590727.XA CN104277670A (en) | 2014-10-29 | 2014-10-29 | Heat-insulating self-cleaning architectural coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410590727.XA CN104277670A (en) | 2014-10-29 | 2014-10-29 | Heat-insulating self-cleaning architectural coating and preparation method thereof |
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| CN201410590727.XA Pending CN104277670A (en) | 2014-10-29 | 2014-10-29 | Heat-insulating self-cleaning architectural coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946081A (en) * | 2015-06-25 | 2015-09-30 | 苏州洋杰电子有限公司 | Wear-resisting scratch-resisting electronic product shell coating and preparation method thereof |
| CN111607325A (en) * | 2020-06-18 | 2020-09-01 | 江苏保平信息科技有限公司 | Nano heat-insulating coating |
| CN112111227A (en) * | 2020-10-09 | 2020-12-22 | 江苏徐工工程机械研究院有限公司 | Laser quenching light absorption coating and preparation method thereof |
| CN112280451A (en) * | 2020-10-29 | 2021-01-29 | 上海阳森精细化工有限公司 | Preparation method of bionic fractal bio-based stain-resistant terrace material easy to clean |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110240064A1 (en) * | 2002-09-09 | 2011-10-06 | Reactive Surfaces, Ltd. | Polymeric Coatings Incorporating Bioactive Enzymes for Cleaning a Surface |
| CN102464933A (en) * | 2010-11-18 | 2012-05-23 | 沈阳理工大学 | Fiber-reinforced high-temperature-resistant thermal insulation and heat preserving ceramic coating and preparation method thereof |
| CN102604522A (en) * | 2012-03-05 | 2012-07-25 | 南京信息工程大学 | Thermal insulation composite coating and preparation method as well as application thereof |
| CN102888186A (en) * | 2012-10-30 | 2013-01-23 | 广西梧州龙鱼漆业有限公司 | Nano self-cleaning external wall paint |
| CN102898942A (en) * | 2012-10-30 | 2013-01-30 | 广西梧州龙鱼漆业有限公司 | Nanometer silicon heat-insulating coating |
-
2014
- 2014-10-29 CN CN201410590727.XA patent/CN104277670A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110240064A1 (en) * | 2002-09-09 | 2011-10-06 | Reactive Surfaces, Ltd. | Polymeric Coatings Incorporating Bioactive Enzymes for Cleaning a Surface |
| CN102464933A (en) * | 2010-11-18 | 2012-05-23 | 沈阳理工大学 | Fiber-reinforced high-temperature-resistant thermal insulation and heat preserving ceramic coating and preparation method thereof |
| CN102604522A (en) * | 2012-03-05 | 2012-07-25 | 南京信息工程大学 | Thermal insulation composite coating and preparation method as well as application thereof |
| CN102888186A (en) * | 2012-10-30 | 2013-01-23 | 广西梧州龙鱼漆业有限公司 | Nano self-cleaning external wall paint |
| CN102898942A (en) * | 2012-10-30 | 2013-01-30 | 广西梧州龙鱼漆业有限公司 | Nanometer silicon heat-insulating coating |
Non-Patent Citations (1)
| Title |
|---|
| 唐光斌: "环氧树脂纳米涂料研究进展", 《热固性树脂》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946081A (en) * | 2015-06-25 | 2015-09-30 | 苏州洋杰电子有限公司 | Wear-resisting scratch-resisting electronic product shell coating and preparation method thereof |
| CN111607325A (en) * | 2020-06-18 | 2020-09-01 | 江苏保平信息科技有限公司 | Nano heat-insulating coating |
| CN112111227A (en) * | 2020-10-09 | 2020-12-22 | 江苏徐工工程机械研究院有限公司 | Laser quenching light absorption coating and preparation method thereof |
| CN112280451A (en) * | 2020-10-29 | 2021-01-29 | 上海阳森精细化工有限公司 | Preparation method of bionic fractal bio-based stain-resistant terrace material easy to clean |
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Application publication date: 20150114 |