CN104250498A - Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof - Google Patents
Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof Download PDFInfo
- Publication number
- CN104250498A CN104250498A CN201410521957.0A CN201410521957A CN104250498A CN 104250498 A CN104250498 A CN 104250498A CN 201410521957 A CN201410521957 A CN 201410521957A CN 104250498 A CN104250498 A CN 104250498A
- Authority
- CN
- China
- Prior art keywords
- agent
- proof
- heat
- coating
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 73
- 239000011248 coating agent Substances 0.000 title claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000009413 insulation Methods 0.000 title abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- 238000003756 stirring Methods 0.000 claims abstract description 32
- 239000000839 emulsion Substances 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 239000004005 microsphere Substances 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 238000004806 packaging method and process Methods 0.000 claims abstract description 6
- 239000013530 defoamer Substances 0.000 claims description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 18
- 230000008719 thickening Effects 0.000 claims description 17
- 239000003899 bactericide agent Substances 0.000 claims description 15
- 238000004581 coalescence Methods 0.000 claims description 15
- 239000000080 wetting agent Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 239000000919 ceramic Substances 0.000 claims description 10
- -1 polynite Chemical compound 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 230000008961 swelling Effects 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- 235000013618 yogurt Nutrition 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 241000276489 Merlangius merlangus Species 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000010408 film Substances 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 claims description 3
- ZCUFTCUMEDALHC-UHFFFAOYSA-N CC[K] Chemical compound CC[K] ZCUFTCUMEDALHC-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004111 Potassium silicate Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical group O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- XTIIITNXEHRMQL-UHFFFAOYSA-N tripotassium methoxy(trioxido)silane Chemical compound [K+].[K+].[K+].CO[Si]([O-])([O-])[O-] XTIIITNXEHRMQL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- 230000002940 repellent Effects 0.000 abstract 2
- 239000005871 repellent Substances 0.000 abstract 2
- 239000012855 volatile organic compound Substances 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 239000008235 industrial water Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000011109 contamination Methods 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000009288 screen filtration Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based weather-proof stain-proof thermal reflective insulation coating which comprises the following components in percentage by mass: 30%-50% of film forming emulsion, 10%-20% of heat reflection pigment, 6%-15% of hollow microspheres, 5%-10% of fillers, 3%-8% of a water repellent agent, 4%-8% of an assistant and the balance of de-ionized water. By introducing the industrial water repellent agent, the coating is excellent in weather resistance, stain resistance and adhesion on basic materials, and then the reflective insulation property is kept for a long time. The invention further provides a preparation method of the coating; the preparation method comprises the following steps: stirring, uniformly mixing, filtering, and packaging. According to the preparation method, the damage on the hollow microsphere structures can be reduced to the maximum extent, and the coating is guaranteed to be good in heat insulation property; in addition, the coating is low in VOC (volatile organic compound) content and environment-friendly, and the preparation process is simple and easy for large-scale industrialized production.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of thermal insulating coating, particularly relate to a kind of thermal insulating coating for peripheral equipments (facility) such as external wall, building roof, oil gas storage tanks and preparation method thereof.
Background technology
Along with the development of coating technology, a kind of partially or completely substitute air-conditioning, air conditioner, electric fan, cold water spray etc. to building and outdoor equipment cooling new coating---thermal insulating coating is subject to the favor of people gradually.Thermal insulating coating is all design according to the transfer principle of heat by conduction, convection current and radiation: it otherwise reflect, be radiated the solar heat of coatingsurface by high reflectivity, reduce self absorption to solar heat; The heat of coatingsurface absorption is reduced to coat inside transmission by self low thermal conductivity; Or by the ir radiation from height, the heat that coating absorbs is passed, thus make protected substrate temperature unlikely too high; Also having is the combination of this several mode.Just because there being various insulating mechanism, the kind of thermal insulating coating is also varied.
The Study and appliance time of thermal insulating coating is not long, but its tempo is exceedingly fast.Early stage has solvent type heat insulation coating, as a kind of thermal insulating coating that Chinese patent application 200410048047.1 is announced.This kind of coating has heat-proof quality, but all containing a certain amount of organic solvent in its formula, belongs to non-ambient friendly coating, along with social development will be eliminated.In nearly ten years, there is aqueous environment protection thermal insulating coating successively in market, as Chinese patent CN102127346B discloses a kind of thermal insulating coating, comprise the component of following weight percent: the emulsion of 34 ~ 54%, the titanium dioxide of 15 ~ 20%, 10 ~ 20% ceramic hollow microspheres, 5 ~ 10% aluminium silicate powder, 5 ~ 10% kaolin, the sepiolite powder of 5 ~ 10%, the water of 5 ~ 10% and 0.2 ~ 0.3% defoamer.Meanwhile, the preparation method of above-mentioned thermal insulating coating is also disclosed.The thermal insulating coating that this patent provides, owing to can cancel the operation of equipment spray cooling after the spraying of exterior house paint tank, has saved energy consumption widely; This thermal insulating coating resistance to acids and bases by force in addition, nontoxic without dangerous, and long service life, brushing, spraying are conveniently.But this thermal insulating coating is in order to pursue the feature of environmental protection and effect of heat insulation, often Shortcomings in weathering resistance and contamination resistance etc., therefore this kind of coating also needs to be coated with finishing paint further after a procedure mostly, both improves painting cost, and also reduces working efficiency.Also some Water-based thermal insulation coatings are had to take into account contamination resistance, as a kind of Staining-resistant heat-insulationcoatiand that Chinese patent CN102676014B announces and preparation method thereof, with parts by weight, be made up of the filming emulsions of 15 ~ 40 parts, the fluoro-resin emulsion of 10 ~ 40 parts, the heat reflection pigment of 10 ~ 30 parts, the hollow ceramic microspheres of 5 ~ 15 parts, the filler of 8 ~ 16 parts, the auxiliary agent of 1.5 ~ 5 parts and appropriate deionized water, by introducing the compositions such as water-based fluororesin emulsion in filming emulsion, reach contamination resistance and heat insulation object.The invention also discloses a kind of preparation method of Staining-resistant heat-insulationcoatiand, comprise the following steps: deionized water, part of auxiliary, heat reflection pigment, filler and hollow ceramic microspheres are added into grinding machine for grinding, obtain slurry; Be transferred in dispersion machine by the slurry obtained, add in this slurry by filming emulsion, fluoro-resin emulsion and remaining auxiliary agent, after dispersed with stirring, through screen filtration, obtain Staining-resistant heat-insulationcoatiand, preparation technology is simple, easy to implement, easy and simple to handle.This kind of coating had both had good effect of heat insulation, had again good contamination resistance.But this kind of coating or merely interpolation organosilicon crylic acid latex or fluorine carbon emulsion, coating contamination resistance promotes limited; Extra add fluorine-containing auxiliary agent or fluoro-resin emulsion or resin emulsion, coating contamination resistance is better, but coating cost is higher.In addition, above-mentioned partial coating is when using hollow glass micropearl or hollow ceramic microspheres, all these cenospheres are disperseed together with conventional color stuffing or is ground to regulation fineness, then membrane-forming agent is added and paint, preparation technology is reasonable not, because the hollow structure of hollow glass micropearl or hollow ceramic microspheres can be damaged after high-speed stirring or grinding, thus loses its good heat-proof quality.
Summary of the invention
Object of the present invention is exactly the problems referred to above of existing for prior art and provides that a kind of coating cost is low, heat-proof quality good, there is excellent weathering resistance, contamination resistance, ventilation property and stronger substrate adhesion, and low, the environment amenable water-based of VOC content is weather-proof, the heat-reflecting insulating coating of stain resistant.
Another object of the present invention is to provide the preparation method of above-mentioned heat-reflecting insulating coating.
For realizing above-mentioned purpose of the present invention, a kind of water-based of the present invention is weather-proof, the heat-reflecting insulating coating of stain resistant by the following technical solutions.
A kind of water-based of the present invention is weather-proof, the heat-reflecting insulating coating of stain resistant is prepared from by following component, and the mass percentage of each component is:
Filming emulsion 30 ~ 50%
Heat reflection pigment 10 ~ 20%
Cenosphere 6 ~ 15%
Filler 5 ~ 10%
Hydrophobizing agent 3 ~ 8%
Auxiliary agent 4 ~ 8%
Deionized water surplus
The mass percentage of above-mentioned each component is preferably:
Filming emulsion 37 ~ 45%
Heat reflection pigment 15 ~ 20%
Cenosphere 8 ~ 12%
Filler 5 ~ 10%
Hydrophobizing agent 4 ~ 6%
Auxiliary agent 5.1 ~ 5.7%
Deionized water surplus
Described filming emulsion is a kind of or any two kinds and above mixture in ACRYLIC EMULSION, elastomeric propylene yogurt liquid, organosilicon crylic acid latex and fluorine carbon emulsion, the mixture of a kind of or their arbitrary combination in preferred organosilicon crylic acid latex, fluorine carbon emulsion and elastomeric propylene yogurt liquid, and all can adopt commercially available prod.
Described heat reflection pigment is a kind of or any two kinds and above mixture in titanium dioxide, barium sulfate, zinc sulphide, zinc oxide; Preferentially select Rutile type Titanium Dioxide.
Described cenosphere is that the hollow glass micropearl of maximum particle diameter within 300 μm is or/and hollow ceramic microspheres; Preferentially select particle diameter at the hollow glass micropearl of 0 ~ 150 μm or hollow ceramic microspheres.
Described filler is a kind of or any two kinds and above mixture in coarse whiting, kaolin, diatomite, polynite, aluminum oxide;
Described hydrophobizing agent is a kind of or any two kinds and above mixture in sodium methyl silicate hydrophobizing agent, sodium ethylsiliconate hydrophobizing agent, potassium methyl silicate hydrophobizing agent, ethyl potassium silicate hydrophobizing agent;
Described auxiliary agent is the mixture of wetting agent, dispersion agent, anticorrosion and bactericidal agent, thickening material, defoamer, film coalescence aid, frostproofer.
The mass percentage that described wetting agent, dispersion agent, anticorrosion and bactericidal agent, thickening material, defoamer, film coalescence aid, frostproofer account for total component is: wetting agent 0.3 ~ 0.8%, dispersion agent 0.6 ~ 1.2%, anticorrosion and bactericidal agent 0.15 ~ 0.25%, thickening material 0.08 ~ 0.15%, defoamer 0.4 ~ 0.8%, film coalescence aid 1.1 ~ 2.5%, frostproofer 1.3 ~ 2.5%.
Described wetting agent is alkylphenol polyoxyethylene class or succsinic acid segmented copolymer class non-ionic wetting agent; Described dispersion agent is polycarboxylic acid salt or polyacrylate anionic dispersing agents; Described anticorrosion and bactericidal agent is isothiazolinone anticorrosion and bactericidal agent; Described thickening material be alkali swelling type thickening material and associative thickener or polyurethane thickener with the use of; Described defoamer is the oily defoamer of mineral oil antifoam agent or hydrophobic particles modified mineral or silicone antifoam agent; Described film coalescence aid is alkoxide or alcohol ethers film coalescence aid; Described frostproofer is low molecular weight diols class or low molecular weight diols ethers frostproofer.
A kind of water-based of the present invention is weather-proof, the heat-reflecting insulating coating of stain resistant, and its preparation method comprises the following steps:
(1) under envrionment temperature, deionized water is joined in Scattered Kettle, add under the stirring at low speed of 300r/min ~ 800r/min wetting agent, dispersion agent, anticorrosion and bactericidal agent, alkali swelling type thickening material, 1/3 defoamer, heat reflection pigment, filler and hydrophobizing agent is added after dissolving is uniformly dispersed, and under the high speed of 2000r/min ~ 3500r/min dispersed with stirring 30min ~ 60min, obtain finely dispersed slip;
(2) under the stirring velocity of 500r/min ~ 1500r/min by film coalescence aid, frostproofer and 1/3 defoamer join in the slip of step (1) gained, add filming emulsion after stirring, and continue dispersion 10min ~ 20min with identical stirring velocity;
(3) cenosphere is joined in the mixture of step (2) gained, and under the rotating speed of 500r/min ~ 1000r/min after dispersed with stirring 10min ~ 20min, add residue 1/3 defoamer and association type or polyurethane-type thickening material, under 300r/min ~ 500r/min, 10min ~ 15min is stirred after mixing, filter, packaging, obtains the finished product.
The hydrophobizing agent that the present invention uses is alkyl silicic acids salt hydrophobizing agent, when after applying coating to substrate surface, alkyl silicate can generate alkylsilanol under the effect of water and carbonic acid gas, and producing two kinds of different effects: alkylsilanol generates the insoluble netted silicone resin of one deck at coating outer surface on the one hand, this resin molding has waterproof, antiseepage, protection against the tide, antirust, anti-aging, antipollution, the advantage such as ventilative, thus can strengthen the weathering resistance of coating, contamination resistance and self-cleaning property, and guarantee the reflective insulation that coating is permanent; Alkylsilanol generates Si-O-Si key at coating inner surface by the hydroxyl reaction on self silicone hydroxyl and base material on the other hand, strengthens the sticking power of coating and base material, improves the work-ing life of coating.
Compared with prior art, the heat-reflecting insulating coating and preparation method thereof of weather-proof, the stain resistant of a kind of water-based of the present invention has following advantage:
(1) adopt regular industrial hydrophobizing agent to give durability of coating and contamination resistance, coating cost is lower.
(2) defoamer segmentation is added, effectively inhibit the generation of system bubble, and take cenosphere to add and the mode of low speed dispersion in the coating later stage, maintain the structural integrity of cenosphere, thus guarantee that coating has good heat-proof quality.
(3) coating has excellent weathering resistance, contamination resistance, ventilation property and stronger substrate adhesion, can the reflective insulation of long sustaining coating, and extends the work-ing life of coating.
(4) a kind of water-based of the present invention heat-reflecting insulating coating that is weather-proof, stain resistant is water-based system, and VOC content is low, belongs to environmentally friendly product, and preparation technology is simple, can large-scale industrial production.
Embodiment
Heat-reflecting insulating coating of, stain resistant weather-proof to a kind of water-based of the present invention below in conjunction with embodiment and preparation method thereof is described further, but the scope of protection of present invention is not limited to the scope of embodiment statement.In embodiment, involved per-cent all by weight percentage.
Embodiment 1:
(1) 12% deionized water is joined in Scattered Kettle, 0.4% wetting agent, 1.0% dispersion agent, 0.2% anticorrosion and bactericidal agent, 0.1% alkali swelling type thickening material, 0.2% defoamer is added under the stirring at low speed of 600r/min, 15% Rutile type Titanium Dioxide, 5% coarse whiting and 5% sodium ethylsiliconate is added after dissolving is uniformly dispersed, and under the high speed of 3000r/min dispersed with stirring 40min, obtain finely dispersed slip;
(2) under the stirring velocity of 1000r/min, 1.5% film coalescence aid, 2% frostproofer and 0.2% defoamer are joined in the slip of step (1) gained, after stirring, add 45% elastomeric propylene yogurt liquid, and continue dispersion 10min with identical stirring velocity;
(3) 12% hollow glass micropearl is joined in the mixture of step (2) gained, and under the rotating speed of 600r/min after dispersed with stirring 15min, add 0.2% defoamer and 0.2% associative thickener, under 400r/min, 15min is stirred after mixing, filter, packaging, obtains the weather-proof contamination resistant heat reflection thermal insulating coating of water-based.
Embodiment 2:
(1) 10% deionized water is joined in Scattered Kettle, 0.5% wetting agent, 0.8% dispersion agent, 0.2% anticorrosion and bactericidal agent, 0.1% alkali swelling type thickening material, 0.2% defoamer is added under the stirring at low speed of 400r/min, 20% Rutile type Titanium Dioxide, 10% kaolin and 6% sodium methyl silicate is added after dissolving is uniformly dispersed, and under the high speed of 2500r/min dispersed with stirring 60min, obtain finely dispersed slip;
(2) under the stirring velocity of 1000r/min, 1.5% film coalescence aid, 2% frostproofer and 0.2% defoamer are joined in the slip of step (1) gained, after stirring, add 40% organosilicon crylic acid latex, and continue dispersion 15min with identical stirring velocity;
(3) 8% hollow glass micropearl is joined in the mixture of step (2) gained, and under the rotating speed of 900r/min after dispersed with stirring 10min, add 0.2% defoamer and 0.3% associative thickener, under 500r/min, 15min is stirred after mixing, filter, packaging, obtains the weather-proof contamination resistant heat reflection thermal insulating coating of water-based.
Embodiment 3:
(1) 18.5% deionized water is joined in Scattered Kettle, 0.6% wetting agent, 0.8% dispersion agent, 0.2% anticorrosion and bactericidal agent, 0.1% alkali swelling type thickening material, 0.2% defoamer is added under the stirring at low speed of 800r/min, 16% Rutile type Titanium Dioxide, 8% coarse whiting and 4% sodium ethylsiliconate is added after dissolving is uniformly dispersed, and under the high speed of 3500r/min dispersed with stirring 40min, obtain finely dispersed slip;
(2) under the stirring velocity of 800r/min, 2% film coalescence aid, 2% frostproofer and 0.2% defoamer are joined in the slip of step (1) gained, after stirring, add 37% fluorine carbon emulsion, and continue dispersion 15min with identical stirring velocity;
(3) 10% hollow ceramic microspheres is joined in the mixture of step (2) gained, and under the rotating speed of 1000r/min after dispersed with stirring 10min, add 0.2% defoamer and 0.2% associative thickener, under 400r/min, 10min is stirred after mixing, filter, packaging, obtains the weather-proof contamination resistant heat reflection thermal insulating coating of water-based.
The water-based weather-proof contamination resistant heat reflection thermal insulating coating obtained by above-described embodiment 1 ~ 3, its sunlight reflectivity is all more than 0.85, and hemispherical emissivity is all more than 0.88, and 5 times circulation contamination resistance is all no more than 12%, and by after coating inclination 45 degree, water droplet tumbles from coating does not have continuous washmarking; After artificial weathering test 500h, outside the light discolouration of removing coating pole, coating is all non-foaming, do not peel off, flawless, without phenomenons such as efflorescence.
The heat-proof quality of the weather-proof contamination resistant heat reflection thermal insulating coating of water-based obtained according to heat insulating temperature difference testing method difference testing example 1 ~ 3 in JC/T 235-2008, result shows: the obtained a kind of water-based of brushing embodiment 1 ~ 3 is weather-proof, after the heat-reflecting insulating coating of stain resistant, test plate (panel) front (just to light source one side) temperature all reduces by more than 18 DEG C, and the test plate (panel) back side (back to light source one side) temperature all reduces by more than 15 DEG C.
Claims (6)
1. a heat-reflecting insulating coating for weather-proof, the stain resistant of water-based, it is characterized in that being prepared from by following component, the mass percentage of each component is:
Filming emulsion 30 ~ 50%
Heat reflection pigment 10 ~ 20%
Cenosphere 6 ~ 15%
Filler 5 ~ 10%
Hydrophobizing agent 3 ~ 8%
Auxiliary agent 4 ~ 8%
Deionized water surplus
Described filming emulsion is a kind of or any two kinds and above mixture in ACRYLIC EMULSION, elastomeric propylene yogurt liquid, organosilicon crylic acid latex and fluorine carbon emulsion;
Described heat reflection pigment is a kind of or any two kinds and above mixture in titanium dioxide, barium sulfate, zinc sulphide, zinc oxide;
Described cenosphere is that the hollow glass micropearl of maximum particle diameter within 300 μm is or/and hollow ceramic microspheres;
Described filler is a kind of or any two kinds and above mixture in coarse whiting, kaolin, diatomite, polynite, aluminum oxide;
Described hydrophobizing agent is a kind of or any two kinds and above mixture in sodium methyl silicate hydrophobizing agent, sodium ethylsiliconate hydrophobizing agent, potassium methyl silicate hydrophobizing agent, ethyl potassium silicate hydrophobizing agent;
Described auxiliary agent is the mixture of wetting agent, dispersion agent, anticorrosion and bactericidal agent, thickening material, defoamer, film coalescence aid, frostproofer.
2. the heat-reflecting insulating coating of weather-proof, the stain resistant of a kind of water-based as claimed in claim 1, is characterized in that the mass percentage of each component is:
Filming emulsion 37 ~ 45%
Heat reflection pigment 15 ~ 20%
Cenosphere 8 ~ 12%
Filler 5 ~ 10%
Hydrophobizing agent 4 ~ 6%
Auxiliary agent 5.1 ~ 5.7%
Deionized water surplus.
3. the heat-reflecting insulating coating of weather-proof, the stain resistant of a kind of water-based as claimed in claim 1 or 2, it is characterized in that: the mass percentage that described wetting agent, dispersion agent, anticorrosion and bactericidal agent, thickening material, defoamer, film coalescence aid, frostproofer account for total component is: wetting agent 0.3 ~ 0.8%, dispersion agent 0.6 ~ 1.2%, anticorrosion and bactericidal agent 0.15 ~ 0.25%, thickening material 0.08 ~ 0.15%, defoamer 0.4 ~ 0.8%, film coalescence aid 1.1 ~ 2.5%, frostproofer 1.3 ~ 2.5%.
4. the heat-reflecting insulating coating of weather-proof, the stain resistant of a kind of water-based as claimed in claim 3, is characterized in that: described wetting agent is alkylphenol polyoxyethylene class or succsinic acid segmented copolymer class non-ionic wetting agent; Described dispersion agent is polycarboxylic acid salt or polyacrylate anionic dispersing agents; Described anticorrosion and bactericidal agent is isothiazolinone anticorrosion and bactericidal agent; Described thickening material be alkali swelling type thickening material and associative thickener or polyurethane thickener with the use of; Described defoamer is the oily defoamer of mineral oil antifoam agent or hydrophobic particles modified mineral or silicone antifoam agent; Described film coalescence aid is alkoxide or alcohol ethers film coalescence aid; Described frostproofer is low molecular weight diols class or low molecular weight diols ethers frostproofer.
5. the heat-reflecting insulating coating of weather-proof, the stain resistant of a kind of water-based as claimed in claim 4, it is characterized in that: described filming emulsion is the mixture of a kind of or their arbitrary combination of organosilicon crylic acid latex, fluorine carbon emulsion and elastomeric propylene yogurt liquid, described heat reflection pigment is Rutile type Titanium Dioxide, and described cenosphere is hollow glass micropearl or the hollow ceramic microspheres of 0 ~ 150 μm.
6. the preparation method of the heat-reflecting insulating coating of weather-proof, the stain resistant of a kind of water-based as claimed in claim 4, is characterized in that comprising following technique, step:
(1) under envrionment temperature, deionized water is joined in Scattered Kettle, add under the stirring at low speed of 300r/min ~ 800r/min wetting agent, dispersion agent, anticorrosion and bactericidal agent, alkali swelling type thickening material, 1/3 defoamer, heat reflection pigment, filler and hydrophobizing agent is added after dissolving is uniformly dispersed, and under the high speed of 2000r/min ~ 3500r/min dispersed with stirring 30min ~ 60min, obtain finely dispersed slip;
(2) under the stirring velocity of 500r/min ~ 1500r/min by film coalescence aid, frostproofer and 1/3 defoamer join in the slip of step (1) gained, add filming emulsion after stirring, and continue dispersion 10min ~ 20min with identical stirring velocity;
(3) cenosphere is joined in the mixture of step (2) gained, and under the rotating speed of 500r/min ~ 1000r/min after dispersed with stirring 10min ~ 20min, add residue 1/3 defoamer and association type or polyurethane-type thickening material, under 300r/min ~ 500r/min, 10min ~ 15min is stirred after mixing, filter, packaging, obtains the finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410521957.0A CN104250498A (en) | 2014-10-08 | 2014-10-08 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410521957.0A CN104250498A (en) | 2014-10-08 | 2014-10-08 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104250498A true CN104250498A (en) | 2014-12-31 |
Family
ID=52185762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410521957.0A Pending CN104250498A (en) | 2014-10-08 | 2014-10-08 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104250498A (en) |
Cited By (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927502A (en) * | 2015-04-24 | 2015-09-23 | 安徽华强防水防腐材料有限公司 | Important component factor for elastic building-material heat-insulation weather-resistant waterproof coating |
| CN105017916A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | Water-based paint high in weather resistance |
| CN105295624A (en) * | 2015-12-04 | 2016-02-03 | 河北晨阳工贸集团有限公司 | Dark-color reflective and heat insulation varnish and preparation method thereof |
| CN105802415A (en) * | 2016-04-20 | 2016-07-27 | 安徽巨力新型环保材料有限公司 | Reflective heat-insulating coating |
| CN105925088A (en) * | 2016-05-27 | 2016-09-07 | 广西梧州龙鱼漆业有限公司 | Antifouling paint |
| CN106366790A (en) * | 2016-08-31 | 2017-02-01 | 常熟市优德爱涂料有限公司 | Elastic fluorocarbon emulsion paint and preparation method thereof |
| CN106380977A (en) * | 2016-08-31 | 2017-02-08 | 广东慧信环保有限公司 | Hydrophobic heat-insulation coating and preparation method therof |
| CN106381045A (en) * | 2016-10-16 | 2017-02-08 | 成都蒲江珂贤科技有限公司 | Building external wall temperature-change-resistant anti-oxidative color coating |
| CN106479282A (en) * | 2016-10-26 | 2017-03-08 | 黄远明 | A kind of crystal type reflective insulation surface lacquer |
| CN106590260A (en) * | 2016-12-26 | 2017-04-26 | 哈尔滨拓百世环保涂料有限公司 | High-tensile-strength energy-saving waterproof paint and preparation method thereof |
| CN106609104A (en) * | 2015-10-27 | 2017-05-03 | 丹阳市海信涂料化工厂 | Waterborne sun protection and heat insulation coating |
| CN106609102A (en) * | 2015-10-27 | 2017-05-03 | 丹阳市海信涂料化工厂 | Aqueous sunscreen thermal insulation coating and preparation method thereof |
| CN107746590A (en) * | 2017-09-22 | 2018-03-02 | 南京洞见环境科技有限公司 | A kind of organo-mineral complexing insulating moulding coating and preparation method thereof |
| CN107880675A (en) * | 2017-11-23 | 2018-04-06 | 广东华兹卜新材料科技有限公司 | A kind of high-performance hollow glass micropearl insulating moulding coating and preparation method thereof |
| CN107936626A (en) * | 2017-11-16 | 2018-04-20 | 江门市亚国建筑涂料有限公司 | The anti-condensation coating of sink |
| CN108017961A (en) * | 2017-12-29 | 2018-05-11 | 铁科创恒新材料科技有限公司 | A kind of stain resistant draining blind pipe |
| CN108587360A (en) * | 2018-07-05 | 2018-09-28 | 袁兵 | A kind of formula of insulating moulding coating |
| CN108641584A (en) * | 2018-03-12 | 2018-10-12 | 苏州甫众塑胶有限公司 | A kind of ageing-resistant building coating of stain resistant and preparation method thereof |
| CN108795241A (en) * | 2018-06-28 | 2018-11-13 | 湖南鑫长胜材料科技有限公司 | A kind of heat-reflective coating and preparation method |
| CN108892984A (en) * | 2018-06-05 | 2018-11-27 | 广州市康超信息科技有限公司 | A kind of green environmental friendly coatings of highly effective flame-retardant |
| CN109486278A (en) * | 2018-11-27 | 2019-03-19 | 江苏泰格油墨有限公司 | Water repellent protects ink and preparation method thereof |
| CN109486305A (en) * | 2018-11-12 | 2019-03-19 | 山西大学 | A kind of dedicated Eyeshield energy-saving blast coating in classroom and its preparation method and application |
| CN110016261A (en) * | 2019-04-10 | 2019-07-16 | 湖北鲁邦建材股份有限公司 | A kind of heat-insulated radiation protection water-repellent paint and preparation method thereof |
| CN110204970A (en) * | 2019-01-21 | 2019-09-06 | 文光洲 | A kind of exterior wall reflective heat-insulation paint and preparation method thereof |
| CN111004573A (en) * | 2019-11-12 | 2020-04-14 | 立邦涂料(四川)有限公司 | Coating for decoration and protection of bridge pier and bridge and preparation method thereof |
| CN111303710A (en) * | 2020-04-02 | 2020-06-19 | 广东筑龙涂料有限公司 | Reflective heat-insulation elastic stone-like paint and preparation method thereof |
| CN111417468A (en) * | 2017-11-30 | 2020-07-14 | 艾仕得涂料系统有限责任公司 | Coating compositions applied using high transfer efficiency applicators and methods and systems thereof |
| CN111635681A (en) * | 2020-05-07 | 2020-09-08 | 上海大学 | Water-based reflective heat-insulating hydrophobic coating and preparation method thereof |
| CN112126291A (en) * | 2020-08-24 | 2020-12-25 | 沪宝新材料科技（上海）股份有限公司 | Exterior wall thermal insulation coating, preparation method and application thereof |
| CN112251091A (en) * | 2020-09-29 | 2021-01-22 | 湖南臻镜绿色建筑科技有限公司 | Formula and preparation process of super-hydrophobic building interior and exterior wall baseless coating |
| CN112724755A (en) * | 2020-12-24 | 2021-04-30 | 江门威富新材料科技有限公司 | Building exterior wall heat insulation coating and preparation method thereof |
| CN113025141A (en) * | 2021-03-11 | 2021-06-25 | 江苏筑立建筑科技有限公司 | Special heat-insulating sound-insulating hydrophobic water-based coating and preparation method thereof |
| CN113913064A (en) * | 2021-10-12 | 2022-01-11 | 湖南贵都建材有限公司 | Fade-proof building coating |
| CN114015314A (en) * | 2021-11-30 | 2022-02-08 | 广东德昱新材料科技有限公司 | Water-based super-white heat-insulating antirust waterproof coating |
| CN114196308A (en) * | 2021-12-16 | 2022-03-18 | 山东北方现代化学工业有限公司 | Ultrathin anti-radiation heat-insulating coating and preparation method thereof |
| CN114989678A (en) * | 2022-04-26 | 2022-09-02 | 郑州圣莱特空心微珠新材料有限公司 | Water-based nano heat-insulating material and preparation process thereof |
| CN115011195A (en) * | 2022-07-12 | 2022-09-06 | 武汉多戈科技发展有限公司 | Water-based heat-insulation reflective composite coating with low heat conductivity coefficient and preparation process thereof |
| CN115521669A (en) * | 2022-09-29 | 2022-12-27 | 大理大学 | Preparation method of waterproof heat-insulating material for building construction |
| CN116814122A (en) * | 2022-04-19 | 2023-09-29 | 三河方元绿洲节能科技有限公司 | Water-based thick crosslinking weight anti-corrosion primer coating and heavy anti-corrosion coating |
| CN117487422A (en) * | 2023-12-06 | 2024-02-02 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
| US12122932B2 (en) | 2023-03-27 | 2024-10-22 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250073A (en) * | 1998-12-31 | 2000-04-12 | 重庆阳彩实业有限公司 | White waterproof heat insulating elastic paint |
| JP2007217586A (en) * | 2006-02-17 | 2007-08-30 | Yamamoto Yogyo Kako Co Ltd | Heat-insulating coating and heat-insulating material |
| CN101775252A (en) * | 2010-02-04 | 2010-07-14 | 安徽天锦云漆业有限公司 | Reflective thermal insulation material waterproof paint of elastic outer wall |
| CN101775250A (en) * | 2010-02-04 | 2010-07-14 | 安徽天锦云漆业有限公司 | Reflecting heat-insulating metal fluorocarbon coating |
| CN102952441A (en) * | 2011-08-23 | 2013-03-06 | 庄斌文 | Heat-insulation waterproof coating |
-
2014
- 2014-10-08 CN CN201410521957.0A patent/CN104250498A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1250073A (en) * | 1998-12-31 | 2000-04-12 | 重庆阳彩实业有限公司 | White waterproof heat insulating elastic paint |
| JP2007217586A (en) * | 2006-02-17 | 2007-08-30 | Yamamoto Yogyo Kako Co Ltd | Heat-insulating coating and heat-insulating material |
| CN101775252A (en) * | 2010-02-04 | 2010-07-14 | 安徽天锦云漆业有限公司 | Reflective thermal insulation material waterproof paint of elastic outer wall |
| CN101775250A (en) * | 2010-02-04 | 2010-07-14 | 安徽天锦云漆业有限公司 | Reflecting heat-insulating metal fluorocarbon coating |
| CN102952441A (en) * | 2011-08-23 | 2013-03-06 | 庄斌文 | Heat-insulation waterproof coating |
Cited By (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927502A (en) * | 2015-04-24 | 2015-09-23 | 安徽华强防水防腐材料有限公司 | Important component factor for elastic building-material heat-insulation weather-resistant waterproof coating |
| CN105017916A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | Water-based paint high in weather resistance |
| CN106609104A (en) * | 2015-10-27 | 2017-05-03 | 丹阳市海信涂料化工厂 | Waterborne sun protection and heat insulation coating |
| CN106609102A (en) * | 2015-10-27 | 2017-05-03 | 丹阳市海信涂料化工厂 | Aqueous sunscreen thermal insulation coating and preparation method thereof |
| CN105295624A (en) * | 2015-12-04 | 2016-02-03 | 河北晨阳工贸集团有限公司 | Dark-color reflective and heat insulation varnish and preparation method thereof |
| CN105802415A (en) * | 2016-04-20 | 2016-07-27 | 安徽巨力新型环保材料有限公司 | Reflective heat-insulating coating |
| CN105925088A (en) * | 2016-05-27 | 2016-09-07 | 广西梧州龙鱼漆业有限公司 | Antifouling paint |
| CN106380977A (en) * | 2016-08-31 | 2017-02-08 | 广东慧信环保有限公司 | Hydrophobic heat-insulation coating and preparation method therof |
| CN106366790A (en) * | 2016-08-31 | 2017-02-01 | 常熟市优德爱涂料有限公司 | Elastic fluorocarbon emulsion paint and preparation method thereof |
| CN106381045A (en) * | 2016-10-16 | 2017-02-08 | 成都蒲江珂贤科技有限公司 | Building external wall temperature-change-resistant anti-oxidative color coating |
| CN106479282A (en) * | 2016-10-26 | 2017-03-08 | 黄远明 | A kind of crystal type reflective insulation surface lacquer |
| CN106590260A (en) * | 2016-12-26 | 2017-04-26 | 哈尔滨拓百世环保涂料有限公司 | High-tensile-strength energy-saving waterproof paint and preparation method thereof |
| CN107746590A (en) * | 2017-09-22 | 2018-03-02 | 南京洞见环境科技有限公司 | A kind of organo-mineral complexing insulating moulding coating and preparation method thereof |
| CN107936626A (en) * | 2017-11-16 | 2018-04-20 | 江门市亚国建筑涂料有限公司 | The anti-condensation coating of sink |
| CN107880675A (en) * | 2017-11-23 | 2018-04-06 | 广东华兹卜新材料科技有限公司 | A kind of high-performance hollow glass micropearl insulating moulding coating and preparation method thereof |
| US11649373B2 (en) | 2017-11-30 | 2023-05-16 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11655391B2 (en) | 2017-11-30 | 2023-05-23 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US12054634B2 (en) | 2017-11-30 | 2024-08-06 | Axalta Coating Systems Ip Co., Llc | Method of applying a coating composition to a substrate |
| US11965107B2 (en) | 2017-11-30 | 2024-04-23 | Axalta Coating Systems Ip Co., Llc | System for applying a coating composition |
| US11945964B2 (en) | 2017-11-30 | 2024-04-02 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11840639B2 (en) | 2017-11-30 | 2023-12-12 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11820910B2 (en) | 2017-11-30 | 2023-11-21 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11649371B2 (en) | 2017-11-30 | 2023-05-16 | Axalta Coating Systems Ip Co., Llc | Method of forming a coating composition for application to a substrate utilizing a high transfer efficiency applicator |
| US11649374B2 (en) | 2017-11-30 | 2023-05-16 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11649372B2 (en) | 2017-11-30 | 2023-05-16 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| US11613669B2 (en) | 2017-11-30 | 2023-03-28 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| CN111417468A (en) * | 2017-11-30 | 2020-07-14 | 艾仕得涂料系统有限责任公司 | Coating compositions applied using high transfer efficiency applicators and methods and systems thereof |
| US11453802B2 (en) | 2017-11-30 | 2022-09-27 | Axalta Coating Systems Ip Co., Llc | Method of applying a coating composition to a substrate |
| CN111417468B (en) * | 2017-11-30 | 2022-04-12 | 艾仕得涂料系统有限责任公司 | Coating compositions applied using high transfer efficiency applicators and methods and systems thereof |
| CN108017961A (en) * | 2017-12-29 | 2018-05-11 | 铁科创恒新材料科技有限公司 | A kind of stain resistant draining blind pipe |
| CN108641584A (en) * | 2018-03-12 | 2018-10-12 | 苏州甫众塑胶有限公司 | A kind of ageing-resistant building coating of stain resistant and preparation method thereof |
| CN108892984A (en) * | 2018-06-05 | 2018-11-27 | 广州市康超信息科技有限公司 | A kind of green environmental friendly coatings of highly effective flame-retardant |
| CN108795241A (en) * | 2018-06-28 | 2018-11-13 | 湖南鑫长胜材料科技有限公司 | A kind of heat-reflective coating and preparation method |
| CN108587360A (en) * | 2018-07-05 | 2018-09-28 | 袁兵 | A kind of formula of insulating moulding coating |
| CN109486305A (en) * | 2018-11-12 | 2019-03-19 | 山西大学 | A kind of dedicated Eyeshield energy-saving blast coating in classroom and its preparation method and application |
| CN109486278A (en) * | 2018-11-27 | 2019-03-19 | 江苏泰格油墨有限公司 | Water repellent protects ink and preparation method thereof |
| CN110204970A (en) * | 2019-01-21 | 2019-09-06 | 文光洲 | A kind of exterior wall reflective heat-insulation paint and preparation method thereof |
| CN110016261A (en) * | 2019-04-10 | 2019-07-16 | 湖北鲁邦建材股份有限公司 | A kind of heat-insulated radiation protection water-repellent paint and preparation method thereof |
| CN111004573A (en) * | 2019-11-12 | 2020-04-14 | 立邦涂料(四川)有限公司 | Coating for decoration and protection of bridge pier and bridge and preparation method thereof |
| CN111303710A (en) * | 2020-04-02 | 2020-06-19 | 广东筑龙涂料有限公司 | Reflective heat-insulation elastic stone-like paint and preparation method thereof |
| CN111635681A (en) * | 2020-05-07 | 2020-09-08 | 上海大学 | Water-based reflective heat-insulating hydrophobic coating and preparation method thereof |
| CN112126291A (en) * | 2020-08-24 | 2020-12-25 | 沪宝新材料科技（上海）股份有限公司 | Exterior wall thermal insulation coating, preparation method and application thereof |
| CN112251091A (en) * | 2020-09-29 | 2021-01-22 | 湖南臻镜绿色建筑科技有限公司 | Formula and preparation process of super-hydrophobic building interior and exterior wall baseless coating |
| CN112724755A (en) * | 2020-12-24 | 2021-04-30 | 江门威富新材料科技有限公司 | Building exterior wall heat insulation coating and preparation method thereof |
| CN113025141A (en) * | 2021-03-11 | 2021-06-25 | 江苏筑立建筑科技有限公司 | Special heat-insulating sound-insulating hydrophobic water-based coating and preparation method thereof |
| CN113913064A (en) * | 2021-10-12 | 2022-01-11 | 湖南贵都建材有限公司 | Fade-proof building coating |
| CN114015314A (en) * | 2021-11-30 | 2022-02-08 | 广东德昱新材料科技有限公司 | Water-based super-white heat-insulating antirust waterproof coating |
| CN114196308A (en) * | 2021-12-16 | 2022-03-18 | 山东北方现代化学工业有限公司 | Ultrathin anti-radiation heat-insulating coating and preparation method thereof |
| CN114196308B (en) * | 2021-12-16 | 2022-11-29 | 山东北方现代化学工业有限公司 | Ultrathin anti-radiation heat-insulating coating and preparation method thereof |
| CN116814122A (en) * | 2022-04-19 | 2023-09-29 | 三河方元绿洲节能科技有限公司 | Water-based thick crosslinking weight anti-corrosion primer coating and heavy anti-corrosion coating |
| CN114989678A (en) * | 2022-04-26 | 2022-09-02 | 郑州圣莱特空心微珠新材料有限公司 | Water-based nano heat-insulating material and preparation process thereof |
| CN115011195A (en) * | 2022-07-12 | 2022-09-06 | 武汉多戈科技发展有限公司 | Water-based heat-insulation reflective composite coating with low heat conductivity coefficient and preparation process thereof |
| CN115521669A (en) * | 2022-09-29 | 2022-12-27 | 大理大学 | Preparation method of waterproof heat-insulating material for building construction |
| US12122932B2 (en) | 2023-03-27 | 2024-10-22 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| CN117487422A (en) * | 2023-12-06 | 2024-02-02 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
| CN117487422B (en) * | 2023-12-06 | 2024-06-04 | 宜兴汉光高新石化有限公司 | Water-based ceramic particle heat reflection coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104250498A (en) | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof | |
| CN106752526B (en) | Water-based light-reflection industrial heat-insulating coating and preparation method thereof | |
| CN103740204B (en) | A kind of intelligence temperature-adjusting type heat-reflecting insulating coating and preparation method thereof | |
| CN101565581B (en) | Reflective heat-insulation coating and preparation method thereof | |
| CN105694629B (en) | Nano transparent insulating coating and preparation method thereof | |
| CN105331220B (en) | A kind of composite metal roof insulation water-repellent paint and preparation method thereof | |
| CN101885943B (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN101067062B (en) | High performance outer wall paint preparation method | |
| CN104087089A (en) | Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof | |
| CN101319121A (en) | Multifunctional high-efficiency thermal insulation insulating mold paint | |
| CN1844281A (en) | Environment-friendly antifouling weather-resistant heat-reflecting thermal-insulating coating and method for preparing same | |
| CN103224743B (en) | A kind of Fluorocarbon aluminum paint for ceramic substrate and manufacture method thereof | |
| CN103146269A (en) | Preparation method for water-based high reflection radiation compound heat preservation and heat insulation coatings | |
| CN102676014A (en) | Staining-resistant heat-insulationcoating and preparation method thereof | |
| CN101831229A (en) | Hollow microsphere thermal insulation coating and production method thereof | |
| CN107880754A (en) | A kind of compound heat-insulating energy-saving paint of polyurethane-modified polyacrylate and preparation method thereof | |
| CN101818013A (en) | Reflecting thermal insulating paint | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN108795191A (en) | A kind of aqueous reflective heat-insulation paint | |
| CN104231832A (en) | Building glass thermal insulation coating as well as preparation method and construction process thereof | |
| CN104610829A (en) | Reflective and heat-insulation coating for buildings and preparation method thereof | |
| CN106147471A (en) | A kind of preparation method of the thermal insulation coatings with water proof anti-soil performance | |
| CN105131764A (en) | Reflective heat-insulation texture coating and preparation method thereof | |
| CN107083185A (en) | A kind of aluminum alloy doors and windows heat-insulated protective coating and preparation method thereof | |
| CN105778676A (en) | Heat-insulating, waterproof and environment-friendly paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141231 |