CN106381045A - Building external wall temperature-change-resistant anti-oxidative color coating - Google Patents
Building external wall temperature-change-resistant anti-oxidative color coating Download PDFInfo
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- CN106381045A CN106381045A CN201610897712.7A CN201610897712A CN106381045A CN 106381045 A CN106381045 A CN 106381045A CN 201610897712 A CN201610897712 A CN 201610897712A CN 106381045 A CN106381045 A CN 106381045A
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- parts
- external wall
- color coating
- sodium
- deionized water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a building external wall temperature-change-resistant anti-oxidative color coating, which is prepared from the following raw materials in parts by weight: 20 to 25 parts of carboxylic waterborne polyurethane, 19 to 24 parts of pure silicon resin emulsion, 11 to 16 parts of cobalt blue, 10 to 15 parts of mill base, 8 to 12 parts of bentonite, 7 to 11 parts of mica powder, 6 to 10 parts of kaolin, 5 to 9 parts of talcum powder, 12 to 14 parts of sodium carbonate, 9 to 11 parts of sodium tripolyphosphate, 10 to 12 parts of polyoxyethylene aliphatic ester, 8 to 10 parts of sodium polyacrylate, 13 to 16 parts of sheet zinc powder, 7 to 11 parts of aluminum hydroxide, 5 to 8 parts of silicon nitride, and 30 to 35 parts of deionized water. A preparation method comprises the following steps of S1, adding the carboxylic waterborne polyurethane, the pure siliconresin emulsion, the cobalt blue, the mill base and the deionized water into a stirrer, and stirring with the stirring speed of 30 to 40rpm for 20 to 30min at the temperature of 40 to 50 DEG C; S2, adding the sheet zinc powder, the aluminum hydroxide and the silicon nitride for stirring with the stirring speed of 100 to 150rpm for 5 to 10min. The building external wall temperature-change-resistant anti-oxidativecolor coating provided by the invention has excellent temperature alternating resistance and oxidation resistance, has high tensile strength and favorable flexibility, and is simple in preparation process, convenient to use, and low in cost.
Description
Technical field
The present invention relates to technical field of coatings, more particularly, to a kind of external wall temp. variation resistant antioxidant color coating.
Background technology
Coating definition refers to be coated to after body surface with specific construction method, and cured so that body surface is formed attractive in appearance
And have the seriality protecting film of some strength, or form a kind of fine chemical product with certain specific function film, it
Various defects on coated surface can be covered so as to attractive in appearance, that is, there is dicoration；It can control moisture, isolation in the air
The corrosive gas such as carbon dioxide, sulfur dioxide, hydrogen chloride, prevent weather from coated article impact and metal substrate are got rusty, that is, have
There is defencive function；It can give coated article surface shades of colour, has mark effect.
Existing coating used for building exterior wall does not possess excellent temp. variation resistant performance and antioxygenic property mostly, and range has
Limit, relatively costly, yield rate is low, and the pollution to environment is more serious, therefore, we have proposed a kind of external wall temp. variation resistant and resists
Oxidation colour coating is used for solving the above problems.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of colored painting of external wall temp. variation resistant antioxidation
Material.
A kind of external wall temp. variation resistant antioxidant color coating proposed by the present invention, including the raw material of following weight portion：Carboxylic
Acid type aqueous polyurethane 20-25 part, neat silicone emulsion 19-24 part, cobalt blue 11-16 part, mill base 10-15 part, bentonite
8-12 part, mica powder 7-11 part, Kaolin 6-10 part, Pulvis Talci 5-9 part, sodium carbonate 12-14 part, sodium tripolyphosphate 9-
11 parts, polyoxyethylene fatty acid esterses 10-12 part, sodium polyacrylate 8-10 part, zinc flake 13-16 part, aluminium hydroxide
7-11 part, silicon nitride 5-8 part, deionized water 30-35 part；
Its preparation method comprises the following steps：
S1：Carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, in 40-
At 50 DEG C, 20-30min is stirred with the mixing speed of 30-40rpm；
S2：Zinc flake, aluminium hydroxide and silicon nitride is added to stir 5-10min, Ran Houjia with the mixing speed of 100-150rpm
Enter bentonite, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and polyacrylic acid
Sodium, high speed shear mix homogeneously, prepared external wall temp. variation resistant antioxidant color coating.
Preferably, including the raw material of following weight portion：Carboxylic acid type aqueous polyurethane 21-24 part, neat silicone emulsion 20-
23 parts, cobalt blue 12-15 part, mill base 11-14 part, bentonite 9-11 part, mica powder 8-10 part, Kaolin 7-9 part, Talcum
Powder 6-8 part, sodium carbonate 13-14 part, sodium tripolyphosphate 9-10 part, polyoxyethylene fatty acid esterses 11-12 part, polyacrylic acid
Sodium 9-10 part, zinc flake 14-15 part, aluminium hydroxide 8-10 part, silicon nitride 6-7 part, deionized water 31-34 part.
Preferably, the weight ratio of described carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water
For 21-24：20-23：12-15：11-14：31-34.
Preferably, in described S1, carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added
Enter in blender, at 42-48 DEG C, 22-28min is stirred with the mixing speed of 32-38rpm.
Preferably, in described S2, zinc flake, aluminium hydroxide and silicon nitride is added to stir with the mixing speed of 110-140rpm
Mix 6-9min, be subsequently adding bentonite, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyethylene glycol oxide fat
Acid esters and sodium polyacrylate, high speed shear mix homogeneously, prepared external wall temp. variation resistant antioxidant color coating.
In the present invention, a kind of described external wall temp. variation resistant antioxidant color coating is with carboxylic acid type aqueous polyurethane and pure silicon
Resin emulsion is base material, has high tensile and good pliability with the colour-wash that cobalt blue and mill base are obtained for pigment, and
Possess good temperature-change resistance and non-oxidizability, the temperature-change resistance of coating can be improved by adding zinc flake, by adding
Aluminium hydroxide and silicon nitride can improve the non-oxidizability of coating, made by adding bentonite, mica powder, Kaolin and Pulvis Talci
The mobility of coating can be strengthened for filler, and can reduces cost, be used as catalyst and can strengthen by adding sodium carbonate
The various performances of coating, and the preparation speed of coating can be accelerated, make pigment by adding sodium tripolyphosphate to be used as dispersant
Stable being dispersed in coating of grain, can reduce surface tension by adding polyoxyethylene fatty acid esterses to be used as wetting agent, have
Help keep the dispersion stabilization of coating, the apparent viscosity of coating can be strengthened as thickening agent by adding sodium polyacrylate,
And giving coating with thixotropy, the present invention possesses excellent temperature-change resistance and non-oxidizability, and possesses high tensile and good
Pliability, preparation process is simple, easy to use, low cost.
Specific embodiment
With reference to specific embodiment, the present invention is explained further.
Embodiment one
The present embodiment proposes a kind of external wall temp. variation resistant antioxidant color coating, including the raw material of following weight portion：Carboxylic acid
20 parts of type aqueous polyurethane, 19 parts of neat silicone emulsion, 11 parts of cobalt blue, 10 parts of mill base, 8 parts of bentonite, mica powder 7
Part, 6 parts of Kaolin, 5 parts of Pulvis Talci, 12 parts of sodium carbonate, 9 parts of sodium tripolyphosphate, 10 parts of polyoxyethylene fatty acid esterses,
8 parts of sodium polyacrylate, 13 parts of zinc flake, 7 parts of aluminium hydroxide, 5 parts of silicon nitride, 30 parts of deionized water；
Its preparation method comprises the following steps：
S1：Carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, at 40 DEG C
Under 20min is stirred with the mixing speed of 30rpm；
S2：Add zinc flake, aluminium hydroxide and silicon nitride to stir 5min with the mixing speed of 100rpm, be subsequently adding swelling
Soil, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and sodium polyacrylate, at a high speed
Shear-mixed is uniform, prepared external wall temp. variation resistant antioxidant color coating.
Embodiment two
The present embodiment proposes a kind of external wall temp. variation resistant antioxidant color coating, including the raw material of following weight portion：Carboxylic acid
23 parts of type aqueous polyurethane, 22 parts of neat silicone emulsion, 14 parts of cobalt blue, 13 parts of mill base, 10 parts of bentonite, mica powder 9
Part, 8 parts of Kaolin, 7 parts of Pulvis Talci, 13 parts of sodium carbonate, 10 parts of sodium tripolyphosphate, 11 parts of polyoxyethylene fatty acid esterses,
9 parts of sodium polyacrylate, 15 parts of zinc flake, 9 parts of aluminium hydroxide, 6 parts of silicon nitride, 33 parts of deionized water；
Its preparation method comprises the following steps：
S1：Carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, at 45 DEG C
Under 25min is stirred with the mixing speed of 35rpm；
S2：Add zinc flake, aluminium hydroxide and silicon nitride to stir 8min with the mixing speed of 130rpm, be subsequently adding swelling
Soil, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and sodium polyacrylate, at a high speed
Shear-mixed is uniform, prepared external wall temp. variation resistant antioxidant color coating.
Embodiment three
The present embodiment proposes a kind of external wall temp. variation resistant antioxidant color coating, including the raw material of following weight portion：Carboxylic acid
25 parts of type aqueous polyurethane, 24 parts of neat silicone emulsion, 16 parts of cobalt blue, 15 parts of mill base, 12 parts of bentonite, mica powder 11
Part, 10 parts of Kaolin, 9 parts of Pulvis Talci, 14 parts of sodium carbonate, 11 parts of sodium tripolyphosphate, polyoxyethylene fatty acid esterses 12
Part, 10 parts of sodium polyacrylate, 16 parts of zinc flake, 11 parts of aluminium hydroxide, 8 parts of silicon nitride, 35 parts of deionized water；
Its preparation method comprises the following steps：
S1：Carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, at 50 DEG C
Under 30min is stirred with the mixing speed of 40rpm；
S2：Add zinc flake, aluminium hydroxide and silicon nitride to stir 10min with the mixing speed of 150rpm, be subsequently adding swelling
Soil, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and sodium polyacrylate, at a high speed
Shear-mixed is uniform, prepared external wall temp. variation resistant antioxidant color coating.
The external wall temp. variation resistant antioxidant color coating that embodiment one, embodiment two and embodiment three are obtained is coated on
On industrial building, compared with general ordinary plant coating, in factory, temperature reduces 3-5 DEG C, after half a year, the coating of ordinary plant coating
Industrial building steel design corrosion, and the industrial building steel design of colour-wash coating has no corrosion, coating integrity is good.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (5)
1. a kind of external wall temp. variation resistant antioxidant color coating is it is characterised in that include the raw material of following weight portion：Carboxylic acid type
Aqueous polyurethane 20-25 part, neat silicone emulsion 19-24 part, cobalt blue 11-16 part, mill base 10-15 part, bentonite 8-12
Part, mica powder 7-11 part, Kaolin 6-10 part, Pulvis Talci 5-9 part, sodium carbonate 12-14 part, sodium tripolyphosphate 9-11 part,
Polyoxyethylene fatty acid esterses 10-12 part, sodium polyacrylate 8-10 part, zinc flake 13-16 part, aluminium hydroxide 7-11
Part, silicon nitride 5-8 part, deionized water 30-35 part；
Its preparation method comprises the following steps：
S1：Carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, in 40-
At 50 DEG C, 20-30min is stirred with the mixing speed of 30-40rpm；
S2：Zinc flake, aluminium hydroxide and silicon nitride is added to stir 5-10min, Ran Houjia with the mixing speed of 100-150rpm
Enter bentonite, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and polyacrylic acid
Sodium, high speed shear mix homogeneously, prepared external wall temp. variation resistant antioxidant color coating.
2. a kind of external wall temp. variation resistant antioxidant color coating according to claim 1 is it is characterised in that include following
The raw material of weight portion：Carboxylic acid type aqueous polyurethane 21-24 part, neat silicone emulsion 20-23 part, cobalt blue 12-15 part, mill base
11-14 part, bentonite 9-11 part, mica powder 8-10 part, Kaolin 7-9 part, Pulvis Talci 6-8 part, sodium carbonate 13-14 part,
Sodium tripolyphosphate 9-10 part, polyoxyethylene fatty acid esterses 11-12 part, sodium polyacrylate 9-10 part, zinc flake 14-15
Part, aluminium hydroxide 8-10 part, silicon nitride 6-7 part, deionized water 31-34 part.
3. a kind of external wall temp. variation resistant antioxidant color coating according to claim 1 is it is characterised in that described carboxylic acid
Type aqueous polyurethane, neat silicone emulsion, the weight of cobalt blue, mill base and deionized water are than for 21-24：20-23：12-15：11-
14：31-34.
4. a kind of external wall temp. variation resistant antioxidant color coating according to claim 1 is it is characterised in that described S1
In, carboxylic acid type aqueous polyurethane, neat silicone emulsion, cobalt blue, mill base and deionized water are added in blender, at 42-48 DEG C
Under 22-28min is stirred with the mixing speed of 32-38rpm.
5. a kind of external wall temp. variation resistant antioxidant color coating according to claim 1 is it is characterised in that described S2
In, add zinc flake, aluminium hydroxide and silicon nitride to stir 6-9min with the mixing speed of 110-140rpm, be subsequently adding swelling
Soil, mica powder, Kaolin, Pulvis Talci, sodium carbonate, sodium tripolyphosphate, polyoxyethylene fatty acid esterses and sodium polyacrylate, at a high speed
Shear-mixed is uniform, prepared external wall temp. variation resistant antioxidant color coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610897712.7A CN106381045A (en) | 2016-10-16 | 2016-10-16 | Building external wall temperature-change-resistant anti-oxidative color coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610897712.7A CN106381045A (en) | 2016-10-16 | 2016-10-16 | Building external wall temperature-change-resistant anti-oxidative color coating |
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| CN106381045A true CN106381045A (en) | 2017-02-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610897712.7A Pending CN106381045A (en) | 2016-10-16 | 2016-10-16 | Building external wall temperature-change-resistant anti-oxidative color coating |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108410339A (en) * | 2018-03-25 | 2018-08-17 | 安徽东泰建筑装饰材料有限公司 | External wall elastic keeps the temperature stone-like coating |
| CN108410355A (en) * | 2018-03-29 | 2018-08-17 | 安徽东泰建筑装饰材料有限公司 | The extra-weather-proof water-water coating of fluorine silicon |
| CN108504199A (en) * | 2018-03-25 | 2018-09-07 | 安徽东泰建筑装饰材料有限公司 | Insulation stone-like coating |
| CN116063103A (en) * | 2023-03-06 | 2023-05-05 | 江西宁和达新材料有限公司 | Preparation method of antioxidant graphite gasket |
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| CN103360881A (en) * | 2013-08-01 | 2013-10-23 | 长沙学院 | Nano-silica sol-modified outer wall paint and preparation method thereof |
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| CN104250498A (en) * | 2014-10-08 | 2014-12-31 | 中钢集团马鞍山矿山研究院有限公司 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
| CN104559787A (en) * | 2014-12-30 | 2015-04-29 | 青岛佳尚创意文化有限公司 | Thermal insulation coating |
| CN105238253A (en) * | 2015-10-09 | 2016-01-13 | 滁州环球聚氨酯科技有限公司 | Weather-proof wear-resistant modified polyurethane external wall coating |
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2016
- 2016-10-16 CN CN201610897712.7A patent/CN106381045A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| CN103360881A (en) * | 2013-08-01 | 2013-10-23 | 长沙学院 | Nano-silica sol-modified outer wall paint and preparation method thereof |
| CN104250498A (en) * | 2014-10-08 | 2014-12-31 | 中钢集团马鞍山矿山研究院有限公司 | Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108410339A (en) * | 2018-03-25 | 2018-08-17 | 安徽东泰建筑装饰材料有限公司 | External wall elastic keeps the temperature stone-like coating |
| CN108504199A (en) * | 2018-03-25 | 2018-09-07 | 安徽东泰建筑装饰材料有限公司 | Insulation stone-like coating |
| CN108410355A (en) * | 2018-03-29 | 2018-08-17 | 安徽东泰建筑装饰材料有限公司 | The extra-weather-proof water-water coating of fluorine silicon |
| CN116063103A (en) * | 2023-03-06 | 2023-05-05 | 江西宁和达新材料有限公司 | Preparation method of antioxidant graphite gasket |
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Application publication date: 20170208 |
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