CN102993842B - A kind of benzene emulsion waterborne rusted paint and preparation method thereof - Google Patents
A kind of benzene emulsion waterborne rusted paint and preparation method thereof Download PDFInfo
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- CN102993842B CN102993842B CN201210391976.7A CN201210391976A CN102993842B CN 102993842 B CN102993842 B CN 102993842B CN 201210391976 A CN201210391976 A CN 201210391976A CN 102993842 B CN102993842 B CN 102993842B
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- percent
- water
- styrene
- emulsion
- emulsifier
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- 239000000839 emulsion Substances 0.000 title claims abstract description 28
- 239000003973 paint Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title abstract 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 230000001131 transforming effect Effects 0.000 claims abstract description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000013556 antirust agent Substances 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims 2
- AHVOFPQVUVXHNL-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.CCCCOC(=O)C=C AHVOFPQVUVXHNL-UHFFFAOYSA-N 0.000 claims 1
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 abstract description 6
- 239000010959 steel Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- LFZDEAVRTJKYAF-UHFFFAOYSA-L barium(2+) 2-[(2-hydroxynaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Ba+2].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21.C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 LFZDEAVRTJKYAF-UHFFFAOYSA-L 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 2
- 239000012528 membrane Substances 0.000 abstract 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 abstract 1
- 229910000165 zinc phosphate Inorganic materials 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of benzene emulsion waterborne rusted paint, the weight percent of each component of described coating is: benzene emulsion (solid content 40%) 35%, transforming agent 4%, iron oxide red 12%, primary zinc phosphate 3%, zinc yellow 6%, zinc oxide 5%, talcum powder 6%, barium sulfate 5%, water 40%.The invention has the advantages that: this coating can not done to construct under surface-treated condition; coating is directly applied in the steel product of band rust; it is made to form a solid protective membrane at steel surface; its sour alkaline resistance properties is excellent; can anti-block and aqueous vapor infiltrate, its rust-proof effect is much higher than existing rust proof paint.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a styrene-acrylic emulsion water-based rusty coating.
Background
The steel structure has a series of advantages of high strength, good toughness, convenient manufacture, high construction speed, short construction period and the like, and is widely applied to modern buildings. But the characteristic of easy corrosion brings huge loss to national economy, and the spraying of the anticorrosive paint is an essential process. The method has the function of forming a film layer with a compact structure on the surface of a base material to isolate the base material from the atmosphere so as to prevent corrosion, but because oxides or other compounds and impurities exist on the surface of the base material, the base material needs to be thoroughly derusted and decontaminated before a coating is used, the whole surface is clean, then the coating is carried out, the derusting and decontaminating labor intensity is high, and the complete and thorough derusting and decontaminating is almost impossible for large-scale machinery and steel components with complex structures.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the styrene-acrylic emulsion water-based rusted paint with low labor intensity, good antirust effect, low cost and excellent performance.
In order to achieve the purpose, the technical scheme provided by the invention is as follows: the styrene-acrylic emulsion water-based rusty paint comprises the following components in percentage by weight:
30 to 40 percent of styrene-acrylic emulsion with the solid content of 40 percent
3 to 6 percent of transforming agent
10 to 13 percent of iron oxide red
1 to 5 percent of zinc dihydrogen phosphate
3 to 8 percent of zinc yellow
4 to 7 percent of zinc oxide
5 to 8 percent of talcum powder
3 to 8 percent of barium sulfate
20-60% of water;
the preparation method of the formula comprises the following steps:
adding water into the pigment and the antirust agent to prepare pigment color paste, and putting the pigment color paste into a ball mill for ball milling to ensure that the color paste can pass through a 200-mesh sieve; preparing a transforming agent into an aqueous solution with a certain proportion; placing the color paste and the transforming agent solution into an enamel container for mixing, and quickly and uniformly stirring by using a stirrer; grinding the filler, sieving with a 200-mesh sieve, and adding into an enamel container to mix well; water was added to adjust the coating viscosity to 4 cups 25 s.
The styrene-acrylic emulsion comprises the following components:
13 to 17 percent of styrene
Acrylic acid 2.5-4%
16-20 percent of butyl acrylate
Methyl methacrylate 7-9%
0.7 to 1.2 percent of emulsifier
Ammonium persulfate 0.4-0.7%
30-62% of deionized water.
The preparation method of the styrene-acrylic emulsion comprises the following steps: preparing 5 percent (mass fraction) aqueous solution of ammonium persulfate for later use; weighing a metered emulsifier, dissolving the emulsifier in water, slowly adding the mixed monomer, and violently stirring for 15-20 min until the emulsifier is uniformly mixed to form emulsion; adding the 1/5 emulsion into a reaction kettle, adding 1/2 initiator, stirring and heating to 70-72 ℃, keeping the temperature until the material is slightly blue, and heating to 85 ℃; adding the rest of initiator, and continuously dropwise adding the rest of emulsion within 2h at the speed of controlling the temperature in the kettle; heating to 90-95 ℃, preserving heat for 1h, cooling to about 30 ℃, and adding ammonia water to adjust the pH value to 8-9.
The invention has the advantages that: the coating can be constructed under the condition of not performing surface treatment, and the coating is directly applied to a rusted steel product, so that a solid protective film is formed on the surface of the steel product, the acid and alkali resistance of the coating is excellent, oxygen and moisture can be prevented from permeating, and the antirust effect of the coating is greatly higher than that of the existing antirust coating.
Detailed Description
The present invention is further described below, and the preferred embodiments of the present invention are:
example 1
In this embodiment, a styrene-acrylic emulsion is first prepared, and the styrene-acrylic emulsion comprises the following components:
13 percent of styrene
Acrylic acid 2.5%
Butyl acrylate 16%
Methyl methacrylate 7%
0.7 percent of emulsifier
Ammonium persulfate 0.4%
60.4 percent of deionized water.
The preparation method of the formula comprises the following steps: preparing 5 percent (mass fraction) aqueous solution of ammonium persulfate for later use; weighing a metered emulsifier, dissolving the emulsifier in water, slowly adding the mixed monomer, and violently stirring for 15-20 min until the emulsifier is uniformly mixed to form emulsion; adding the 1/5 emulsion into a reaction kettle, adding 1/2 initiator, stirring and heating to 70-72 ℃, keeping the temperature until the material is slightly blue, and heating to 85 ℃; adding the rest of initiator, and continuously dropwise adding the rest of emulsion within 2h at the speed of controlling the temperature in the kettle; heating to 90-95 ℃, preserving heat for 1h, cooling to about 30 ℃, and adding ammonia water to adjust the pH value to 8-9; obtaining styrene-acrylic emulsion;
the styrene-acrylic emulsion water-based rusty paint comprises the following components in percentage by weight:
33 percent of styrene-acrylic emulsion with the solid content of 40 percent
Transforming agent 5%
Iron oxide red 12%
3 percent of zinc dihydrogen phosphate
5 percent of zinc yellow
5 percent of zinc oxide
Talcum powder 5%
Barium sulfate 5%
27% of water;
the preparation method of the formula comprises the following steps:
adding water into the pigment and the antirust agent to prepare pigment color paste, and putting the pigment color paste into a ball mill for ball milling to ensure that the color paste can pass through a 200-mesh sieve; preparing a transforming agent into an aqueous solution with a certain proportion; placing the color paste and the transforming agent solution into an enamel container for mixing, and quickly and uniformly stirring by using a stirrer; grinding the filler, sieving with a 200-mesh sieve, and adding into an enamel container to mix well; water was added to adjust the coating viscosity to 4 cups 25 s.
The above-mentioned embodiments are merely preferred embodiments of the present invention, and the scope of the present invention is not limited thereto, so that the changes in the shape and principle of the present invention should be covered within the protection scope of the present invention.
Claims (1)
1. The styrene-acrylic emulsion water-based rusty paint is characterized by comprising the following components in parts by weight: the coating comprises the following components in percentage by weight:
30 to 40 percent of styrene-acrylic emulsion with the solid content of 40 percent
3 to 6 percent of transforming agent
10 to 13 percent of iron oxide red
1 to 5 percent of zinc dihydrogen phosphate
3 to 8 percent of zinc yellow
4 to 7 percent of zinc oxide
5 to 8 percent of talcum powder
3 to 8 percent of barium sulfate
20-60% of water;
the sum of the weight percentages of the components is 100 percent;
wherein,
the raw material components for preparing the styrene-acrylic emulsion are as follows:
13 to 17 percent of styrene
Acrylic acid 2.5-4%
16-20 percent of butyl acrylate
Methyl methacrylate 7-9%
0.7 to 1.2 percent of emulsifier
Ammonium persulfate 0.4-0.7%
30-62% of deionized water;
the sum of the percentages of the raw materials is 100 percent;
the preparation method of the styrene-acrylic emulsion comprises the following steps: preparing 5 percent (mass fraction) aqueous solution of ammonium persulfate for later use; weighing a metered emulsifier, dissolving the emulsifier in water, slowly adding the mixed monomer, and violently stirring for 15-20 min until the emulsifier is uniformly mixed to form emulsion; adding the 1/5 emulsion into a reaction kettle, adding 1/2 initiator, stirring and heating to 70-72 ℃, keeping the temperature until the material is slightly blue, and heating to 85 ℃; adding the rest of initiator, and continuously dropwise adding the rest of emulsion within 2h at the speed of controlling the temperature in the kettle; heating to 90-95 ℃, preserving heat for 1h, cooling to about 30 ℃, and adding ammonia water to adjust the pH value to 8-9;
the preparation method of the coating comprises the following steps:
adding water into the pigment and the antirust agent to prepare pigment color paste, and putting the pigment color paste into a ball mill for ball milling to ensure that the color paste can pass through a 200-mesh sieve; preparing a transforming agent into an aqueous solution with a certain proportion; placing the color paste and the transforming agent solution into an enamel container for mixing, and quickly and uniformly stirring by using a stirrer; grinding the filler, sieving with a 200-mesh sieve, and adding into an enamel container to mix well; water was added to adjust the coating viscosity to 4 cups 25 s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210391976.7A CN102993842B (en) | 2012-10-16 | 2012-10-16 | A kind of benzene emulsion waterborne rusted paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210391976.7A CN102993842B (en) | 2012-10-16 | 2012-10-16 | A kind of benzene emulsion waterborne rusted paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102993842A CN102993842A (en) | 2013-03-27 |
| CN102993842B true CN102993842B (en) | 2015-07-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210391976.7A Expired - Fee Related CN102993842B (en) | 2012-10-16 | 2012-10-16 | A kind of benzene emulsion waterborne rusted paint and preparation method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103819975A (en) * | 2014-02-26 | 2014-05-28 | 南通顺阳化工有限公司 | Water-based antirust paint formula |
| CN104046149B (en) * | 2014-07-01 | 2016-04-06 | 国家电网公司 | A kind of waterborne rusted paint and preparation method thereof |
| CN105670441B (en) * | 2015-12-03 | 2018-04-10 | 陶栋梁 | A kind of water-based coating compositions and preparation method thereof |
| CN106009818A (en) * | 2016-05-31 | 2016-10-12 | 无锡伊佩克科技有限公司 | Antirust coating used for steel, and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323726A (en) * | 2007-06-13 | 2008-12-17 | 湖南大学 | Steel structure water-based anti-corrosion coating with rust and preparation method thereof |
| CN102241926A (en) * | 2011-05-26 | 2011-11-16 | 开平市日固力涂料有限公司 | Aqueous antirust paint with rust |
-
2012
- 2012-10-16 CN CN201210391976.7A patent/CN102993842B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323726A (en) * | 2007-06-13 | 2008-12-17 | 湖南大学 | Steel structure water-based anti-corrosion coating with rust and preparation method thereof |
| CN102241926A (en) * | 2011-05-26 | 2011-11-16 | 开平市日固力涂料有限公司 | Aqueous antirust paint with rust |
Non-Patent Citations (1)
| Title |
|---|
| "底面合一的水性带锈防锈漆";薛东星等;《涂料工业》;19980531(第5期);9-11 * |
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| CN102993842A (en) | 2013-03-27 |
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