CN102277070A - Aqueous alcohol acid amino priming paint for anti-theft door and preparation method thereof - Google Patents

Aqueous alcohol acid amino priming paint for anti-theft door and preparation method thereof Download PDF

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Publication number
CN102277070A
CN102277070A CN201110174160A CN201110174160A CN102277070A CN 102277070 A CN102277070 A CN 102277070A CN 201110174160 A CN201110174160 A CN 201110174160A CN 201110174160 A CN201110174160 A CN 201110174160A CN 102277070 A CN102277070 A CN 102277070A
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China
Prior art keywords
agent
alcohol acid
priming paint
raw materials
composite
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Pending
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CN201110174160A
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Chinese (zh)
Inventor
郭晓峰
王瑞宏
花东栓
刘国旭
肖铭
刘宏亮
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Hebei Water Paint Engineering Technology Research Center
Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Water Paint Engineering Technology Research Center
Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201110174160A priority Critical patent/CN102277070A/en
Publication of CN102277070A publication Critical patent/CN102277070A/en
Pending legal-status Critical Current

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Abstract

The invention discloses aqueous alcohol acid amino priming paint for an anti-theft door and a preparation method thereof, and relates to the field of metal anticorrosion. The invention provides aqueous alcohol acid amino priming paint for an anti-theft door. The aqueous alcohol acid amino priming paint is prepared from aqueous alcohol acid resin and amino resin, which serve as base stocks, a cosolvent, a neutralizer, deionized water, a wetting dispersing agent, a defoamer and a base material wetting agent, which serve as aids, and iron oxide red, toluidine red, composite zinc phosphate, composite ferrotitanium powder and precipitated barium sulfate which serve as pigments and fillers. In the aqueous alcohol acid amino priming paint, aqueous coatings are applied to the coating of the anti-theft door for the first time; and the aqueous coating takes water as a solvent, so a large number of resources are saved, fire hazards during construction are eliminated, atmosphere pollution is reduced, the condition of operating environment is improved, a coating process of the conventional anti-theft door is not changed, and the constructional performance of products is high; the aqueous coating can be coated directly on wet surfaces and in moist environment, and is high in adaptability to material surfaces and adhesive force of coating layers; and a coating tool can be cleaned by using water, so the consumption of cleaning solvents is reduced greatly.

Description

A kind of antitheft door use alcohol acid amido priming paint and preparation method
Technical field
The invention belongs to the anti-corrosion of metal field, be specifically related to a kind of antitheft door use alcohol acid amido priming paint and preparation method.
Background technology
At present, China's antitheft door is anticorrosion also all to adopt conventional solvent type alcohol acid amido baking vanish with priming paint, contain a large amount of organic solvents in these lacquers, the antirust color stuffing that is added contains heavy metal compounds such as chromium or lead, a large amount of noxious solvent volatilizations are arranged in spraying and drying course, not only workers ' health is exerted an influence, increased disaster hidden-trouble, also atmosphere has been caused serious pollution.
Summary of the invention
Anticorrosion in order to improve antitheft door with the harm of priming paint to environment and health of human body, the invention provides a kind of antitheft door use alcohol acid amido priming paint, this paint vehicle belongs to the environmental type paint vehicle;
A kind of antitheft door use alcohol acid amido priming paint is counted by weight percentage, and it is made by following proportioning raw materials: described base-material: 25%~40% aqueous alkide resin and 2.5%~4% aminoresin; Described auxiliary agent: 1%~3% solubility promoter, 2%~3.5% neutralizing agent, 10%~15% deionized water, 0.6%~1% wetting dispersing agent, 0.2%~0.5% defoamer and 0.2%~0.4% base material wetting agent; Described color stuffing: 10%~15% red iron oxide, 2%~5% toluidine red, 3%~7% composite zinc phosphate, 12%~17% composite iron-titanium powder and 3%~7% process white.
Particularly, described antitheft door use alcohol acid amido priming paint is counted by weight percentage, and it is made by following proportioning raw materials: described base-material: 28% aqueous alkide resin and 2.8% aminoresin; Described auxiliary agent: 1.7% solubility promoter, 2.3% neutralizing agent, 15% deionized water, 0.8% wetting dispersing agent, 0.2% defoamer and 0.2% base material wetting agent; Described color stuffing: 15% red iron oxide, 5% toluidine red, 5% composite zinc phosphate, 17% composite iron-titanium powder and 7% process white.
Particularly, described antitheft door use alcohol acid amido priming paint is counted by weight percentage, and it is made by following proportioning raw materials: described base-material: 33% aqueous alkide resin and 3.3% aminoresin; Described auxiliary agent: 2% solubility promoter, 3% neutralizing agent, 14% deionized water, 0.7% wetting dispersing agent, 0.4% defoamer and 0.3% base material wetting agent; Described color stuffing: 13% red iron oxide, 4% toluidine red, 6% composite zinc phosphate, 15% composite iron-titanium powder and 5.3% process white.
Particularly, described antitheft door use alcohol acid amido priming paint is counted by weight percentage, and it is made by following proportioning raw materials: described base-material: 38% aqueous alkide resin and 3.8% aminoresin; Described auxiliary agent: 2.6% solubility promoter, 3.2% neutralizing agent, 13% deionized water, 0.6% wetting dispersing agent, 0.4% defoamer and 0.4% base material wetting agent; Described color stuffing: 10% red iron oxide, 3% toluidine red, 5% composite zinc phosphate, 13% composite iron-titanium powder and 7% process white.
A kind of making method of antitheft door use alcohol acid amido priming paint comprises the steps:
1), described aqueous alkide resin, solubility promoter, neutralizing agent, deionized water are added in the pot of getting the raw materials ready successively according to described proportioning raw materials;
2), the batching that will join in the described pot of getting the raw materials ready carries out stirring at low speed, after stirring, adds described wetting dispersing agent, defoamer and color stuffing according to described proportioning raw materials, high speed dispersion formed even mill base more than 20 minutes;
Wherein, described color stuffing comprises red iron oxide, toluidine red, composite zinc phosphate, composite iron-titanium powder and process white;
3), described even mill base is ground, be ground to fineness smaller or equal to 30 microns;
4), add described aminoresin and base material wetting agent successively, stir until evenly according to described proportioning raw materials.
Compared with prior art, the invention has the advantages that:
1, first water-borne coatings is applied to the application of antitheft door, water-borne coatings is saved ample resources with water as solvent, and fire hazard when water-borne coatings has been eliminated construction has reduced topsoil, has improved operating environmental condition;
2, do not change the coating process of existing antitheft door, the workability of product is better, and water-borne coatings can directly apply construction in wet surface and wet environment, and good to material surface adaptability, coating adhesion is strong;
3, coating tool can wash by water, and significantly reduces the consumption of cleaning solvent.
Embodiment
For making the purpose, technical solutions and advantages of the present invention clearer, do the present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
Present embodiment 1 is made by weight ratio by following raw material, 28% aqueous alkide resin and 2.8% aminoresin, 1.7% solubility promoter, 2.3% neutralizing agent, 15% deionized water, 0.8% wetting dispersing agent, 0.2% defoamer and 0.2% base material wetting agent, 15% red iron oxide, 5% toluidine red, 5% composite zinc phosphate, 17% composite iron-titanium powder and 7% process white;
Aqueous alkide resin uses Hebei sun in morning CY-919, solubility promoter is the propylene glycol ethers, and neutralizing agent is ammoniacal liquor or dimethylethanolamine, and aminoresin uses Ineos R-747, in system, add environment-friendly antirust pigment composite zinc phosphate, composite iron-titanium powder, make system have antiseptic and rustproof performance;
The making method of described above-mentioned engineering crawler belt use dipping lacquer specifically comprises the steps:
1), above-mentioned aqueous alkide resin, solubility promoter, neutralizing agent, deionized water are added in the pot of getting the raw materials ready successively according to the above-mentioned raw materials proportioning;
2), the batching that will join in the pot of getting the raw materials ready is carried out stirring at low speed, after stirring, wetting dispersing agent, defoamer and the color stuffing (red iron oxide, toluidine red, composite zinc phosphate, composite iron-titanium powder and process white) that add above-mentioned amount, high speed dispersion formed even mill base more than 20 minutes;
3), even mill base is ground, mesh-of-grind is smaller or equal to 30 microns;
4) aminoresin and the base material wetting agent that add above-mentioned described amount, successively stir until evenly.
Embodiment 2
Present embodiment 2 is made by weight ratio by following raw material, 33% aqueous alkide resin and 3.3% aminoresin, 2% solubility promoter, 3% neutralizing agent, 14% deionized water, 0.7% wetting dispersing agent, 0.4% defoamer and 0.3% base material wetting agent, 13% red iron oxide, 4% toluidine red, 6% composite zinc phosphate, 15% composite iron-titanium powder and 5.3% process white.
Its making method repeats no more here with embodiment 1.
Embodiment 3
Present embodiment 3 is made by weight ratio by following raw material, 38% aqueous alkide resin and 3.8% aminoresin, 2.6% solubility promoter, 3.2% neutralizing agent, 13% deionized water, 0.6% wetting dispersing agent, 0.4% defoamer and 0.4% base material wetting agent, 10% red iron oxide, 3% toluidine red, 5% composite zinc phosphate, 13% composite iron-titanium powder and 7% process white.
Its making method repeats no more here with embodiment 1.
Above-described embodiment is a more preferably embodiment of the present invention, and common variation that those skilled in the art carries out in the technical solution of the present invention scope and replacement all should be included in protection scope of the present invention.

Claims (5)

1. an antitheft door use alcohol acid amido priming paint is characterized in that count by weight percentage, it is made by following proportioning raw materials: described base-material: 25%~40% aqueous alkide resin and 2.5%~4% aminoresin; Described auxiliary agent: 1%~3% solubility promoter, 2%~3.5% neutralizing agent, 10%~15% deionized water, 0.6%~1% wetting dispersing agent, 0.2%~0.5% defoamer and 0.2%~0.4% base material wetting agent; Described color stuffing: 10%~15% red iron oxide, 2%~5% toluidine red, 3%~7% composite zinc phosphate, 12%~17% composite iron-titanium powder and 3%~7% process white.
2. antitheft door use alcohol acid amido priming paint according to claim 1 is characterized in that count by weight percentage, it is made by following proportioning raw materials: described base-material: 28% aqueous alkide resin and 2.8% aminoresin; Described auxiliary agent: 1.7% solubility promoter, 2.3% neutralizing agent, 15% deionized water, 0.8% wetting dispersing agent, 0.2% defoamer and 0.2% base material wetting agent; Described color stuffing: 15% red iron oxide, 5% toluidine red, 5% composite zinc phosphate, 17% composite iron-titanium powder and 7% process white.
3. antitheft door use alcohol acid amido priming paint according to claim 1 is characterized in that count by weight percentage, it is made by following proportioning raw materials: described base-material: 33% aqueous alkide resin and 3.3% aminoresin; Described auxiliary agent: 2% solubility promoter, 3% neutralizing agent, 14% deionized water, 0.7% wetting dispersing agent, 0.4% defoamer and 0.3% base material wetting agent; Described color stuffing: 13% red iron oxide, 4% toluidine red, 6% composite zinc phosphate, 15% composite iron-titanium powder and 5.3% process white.
4. antitheft door use alcohol acid amido priming paint according to claim 1 is characterized in that count by weight percentage, it is made by following proportioning raw materials: described base-material: 38% aqueous alkide resin and 3.8% aminoresin; Described auxiliary agent: 2.6% solubility promoter, 3.2% neutralizing agent, 13% deionized water, 0.6% wetting dispersing agent, 0.4% defoamer and 0.4% base material wetting agent; Described color stuffing: 10% red iron oxide, 3% toluidine red, 5% composite zinc phosphate, 13% composite iron-titanium powder and 7% process white.
5. according to any claim in the claim 1~4, a kind of making method of antitheft door use alcohol acid amido priming paint is characterized in that, comprises the steps:
1), described aqueous alkide resin, solubility promoter, neutralizing agent, deionized water are added in the pot of getting the raw materials ready successively according to described proportioning raw materials;
2), the batching that will join in the described pot of getting the raw materials ready carries out stirring at low speed, after stirring, adds described wetting dispersing agent, defoamer and color stuffing according to described proportioning raw materials, high speed dispersion formed even mill base more than 20 minutes;
Wherein, described color stuffing comprises red iron oxide, toluidine red, composite zinc phosphate, composite iron-titanium powder and process white;
3), described even mill base is ground, be ground to fineness smaller or equal to 30 microns;
4), add described aminoresin and base material wetting agent successively, stir until evenly according to described proportioning raw materials.
CN201110174160A 2011-06-27 2011-06-27 Aqueous alcohol acid amino priming paint for anti-theft door and preparation method thereof Pending CN102277070A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555163A (en) * 2013-10-18 2014-02-05 陆君军 Water-based alkyd amino environment-friendly paint
CN104962179A (en) * 2015-07-22 2015-10-07 河北晨阳工贸集团有限公司 Primer applicable to security door and preparation method of primer
CN106928791A (en) * 2017-01-06 2017-07-07 河北晨阳工贸集团有限公司 A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof
CN108864881A (en) * 2018-04-19 2018-11-23 河北晨阳工贸集团有限公司 A kind of special-purpose aqueous transfer varnish of security door and preparation method thereof
CN110684445A (en) * 2018-07-05 2020-01-14 节昌澎 Aqueous alcohol acid amino high-blackness and high-gloss intermediate paint and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1405254A (en) * 2001-09-18 2003-03-26 海洋化工研究院 Water-based acrylic acid modified alcoholic acid amino baking paint
CN101503563A (en) * 2009-03-17 2009-08-12 佛山市鲸鲨化工有限公司 Water soluble alkyd resin solution and water-soluble alcohol acid amino baking varnish
CN101831061A (en) * 2010-05-11 2010-09-15 浙江工业大学 Benzoic acid modified waterborne alkyd resin and amino plastic baking varnish prepared by same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1405254A (en) * 2001-09-18 2003-03-26 海洋化工研究院 Water-based acrylic acid modified alcoholic acid amino baking paint
CN101503563A (en) * 2009-03-17 2009-08-12 佛山市鲸鲨化工有限公司 Water soluble alkyd resin solution and water-soluble alcohol acid amino baking varnish
CN101831061A (en) * 2010-05-11 2010-09-15 浙江工业大学 Benzoic acid modified waterborne alkyd resin and amino plastic baking varnish prepared by same

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Title
刘国旭: "水性醇酸氨基烘烤漆的研制", 《上海涂料》, vol. 44, no. 10, 31 October 2006 (2006-10-31), pages 11 - 13 *
刘国旭等: "水性醇酸涂料耐盐雾的研究", 《上海涂料》, vol. 47, no. 6, 30 June 2009 (2009-06-30), pages 33 - 35 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555163A (en) * 2013-10-18 2014-02-05 陆君军 Water-based alkyd amino environment-friendly paint
CN104962179A (en) * 2015-07-22 2015-10-07 河北晨阳工贸集团有限公司 Primer applicable to security door and preparation method of primer
CN106928791A (en) * 2017-01-06 2017-07-07 河北晨阳工贸集团有限公司 A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof
CN108864881A (en) * 2018-04-19 2018-11-23 河北晨阳工贸集团有限公司 A kind of special-purpose aqueous transfer varnish of security door and preparation method thereof
CN110684445A (en) * 2018-07-05 2020-01-14 节昌澎 Aqueous alcohol acid amino high-blackness and high-gloss intermediate paint and preparation method thereof

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Application publication date: 20111214