CN106009818A - Antirust coating used for steel, and preparation method thereof - Google Patents

Antirust coating used for steel, and preparation method thereof Download PDF

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Publication number
CN106009818A
CN106009818A CN201610372352.9A CN201610372352A CN106009818A CN 106009818 A CN106009818 A CN 106009818A CN 201610372352 A CN201610372352 A CN 201610372352A CN 106009818 A CN106009818 A CN 106009818A
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parts
steel
iron
butanol
isopropanol
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灏や负
尤为
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Wuxi Epic Technology Co Ltd
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Wuxi Epic Technology Co Ltd
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Priority to CN201610372352.9A priority Critical patent/CN106009818A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antirust coating used for steel, and a preparation method thereof. The preparation method comprises the following steps: weighing epoxy resin, isopropanol, butanol, an aluminum paste, butyl acrylate, methyl methacrylate, acrylic acid, styrene, barium sulfate, zinc phosphate, modified aluminum triphosphate, sodium bicarbonate, ammonium persulfate and talcum powder, stirring above raw materials, and grinding the stirred raw materials to form the antirust coating. A coating film formed by the coating has flat and bright appearance, the viscosity is 100-120s, the surface drying time is 30-50min, and the hard drying time is 15-19h; the flexibility is 1-3mm, and the adhesion is 1-2 grade; the coating film has no foaming or shedding phenomenon after being immersed in 30DEG C water for 3-7d, and the impact resistance is 50-70cm; and the fineness is 25-45[mu]m, and the pencil hardness is H.

Description

A kind of iron and steel antirusting paint and preparation method thereof
Technical field
The present invention relates to steel surface coating, particularly relate to a kind of iron and steel antirusting paint and preparation method thereof.
Background technology
Antirusting paint can protect metal surfaces from the chemistry of air, sea water etc. or the coating of electrochemical corrosion.Coat antirusting paint in metal surface and can effectively avoid the direct invasion of various corrosive substances in air so that maximized prolongation metal useful life.Physical property and the big class of chemically antirust paint two can be divided into.The former is by Pulvis Talci and the suitable cooperation of paint vehicle, and the paint film of formation densification is to stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter presses down rust effect, such as Plumbum preparatium, zinc chromate anti-rust paint etc. by antirust talcous chemistry.Antirust for metals such as bridge, boats and ships, pipelines.The antirust paint substantially oily antirust varniss used and aqueous antirust paint two kinds.Oily antirust varniss makes material surface greasy removal difficulty, is rarely employed.Oily antirust varniss is easy to use, cheap, but because containing the noxious substance such as nitrite, chromate, relatively big to operator's harm, country has limited use, and these type of properties of product are single, it is impossible to meet the antirust requirement of magnetic alloy material.Selecting metal strength chelating agen inositol hexaphosphate is main component, compounds with other several aqueous promoters and forms.Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it uses as magnetic material antirust agent, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule complex protecting film, can effectively suppress corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can enter the next procedures such as application.The important component part of antirust paint. the antirust Pulvis Talci of physics be a class more antirust Pulvis Talci of chemical property own be stable Pulvis Talci, they are the physical properties by itself, stable chemical performance, quality is hard, granule is trickle, excellent fillibility, improve the consistency of paint film, reducing the permeable of paint film thus play antirust effect. iron oxide red just belongs to this kind of material. and the rust-preventing characteristic of metallic aluminium powder is owing to aluminium powder has sclay texture, formation paint film is tight, also have the ability of stronger uv reflectance light, paint film aging-resistant ability can be improved.
Antirusting paint can protect metal surfaces from the chemistry of air, sea water etc. or the coating of electrochemical corrosion.Coat antirusting paint in metal surface and can effectively avoid the direct invasion of various corrosive substances in air so that maximized prolongation metal useful life.Physical property and the big class of chemically antirust paint two can be divided into.The former is by pigment and the suitable cooperation of paint vehicle, and the paint film of formation densification is to stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter presses down rust effect, such as Plumbum preparatium, zinc chromate anti-rust paint etc. by the chemistry of rust resisting pigment.Antirust for metals such as bridge, boats and ships, pipelines.
Ingot coating is to eliminate ingot surface defect and to reduce the iron and steel inner surface Liniment for the purpose of iron and steel consumes.It being sprayed at equably on iron and steel inner surface with special spraying equipment during use, in casting process, this coating film makes the kinds of surface defects such as the scabbing of steel ingot, skull patch, crackle, blibbing and rimhole be suppressed greatly.Meanwhile, which reduce steel ingot weldering mould phenomenon and prevent molten steel to the erosion on ferrum surface and to wash away, playing the effect of protection iron and steel.Additionally, the setting time that the heat-blocking action of this coating makes steel ingot extends accordingly, decrease the formation of steel ingot shrinkage cavity to a certain extent and extend the floating interval of floating dock being mingled with accordingly, being conducive to it to get rid of.Ferrum coating is divided into two classes: a class is die wall coating, and another kind of is mould primer.Die wall coating was many with coal tar, heavy oil, graphite etc. as matrix material in the past, owing to its heat decomposition temperature differs carburizing that is relatively big and that can cause die wall carbon residue attachment area seriously with optimum, was replaced by water-soluble resin.The mechanism of action of water-soluble resin is: the splash droplet produced when cast is bonded at and scribbles the ferrum of resin when use, and this layer of resin can produce decomposition reaction under the temperature conditions of 400~600 DEG C, discharge gas so that splash droplet solidify after Automatic-falling.Research shows, when the high-temperature viscosity of water-soluble resin decomposition residue is between 1000~3000cst, the surface quality of steel ingot is more excellent.It addition, iron and steel coating to be also had some additional requirements.One is that heat conductivity is low, with ferrum with there being strong adhesive force, preferably has certain surface strength and anti-urgency hot under high temperature.Mould primer refers generally to base plate coating, base plate healant and leak preventive.This kind of coating mostly is siliceous, aluminum matter or magnesian, will not pollute molten steel.Use spraying method more, be the most also made into cement paste with manual coating.
Iron and steel is with being steel mill molding large casting unit of producing that indispensable, turnover uses, and the surface of steel ingot and internal soundness and steel ingot cost are had a major impact by it.Molten steel is so as to the press mold of coagulation forming.Iron and steel is with being steel mill molding large casting unit of producing that indispensable, turnover uses, and the surface of steel ingot and internal soundness and steel ingot cost are had a major impact by it.Iron and steel life-span (secondary) or iron and steel consume the main economic and technical indices that (kg/t steel) is STEELMAKING PRODUCTION.
Along with social city, technicalization, the development of hommization, design good iron and steel antirusting paint of a kind of hardness height, impact strength height, adhesive force height, fast drying and pliability and preparation method thereof, to meet the market demand, be very important.
Summary of the invention
Solve the technical problem that:
The application is low for existing steel surface coating hardness, poor impact resistance, adhesive force are low, it is slow to be dried and the technical problem of pliability difference, it is provided that one utilizes iron and steel antirusting paint and preparation method thereof.
Technical scheme:
A kind of iron and steel antirusting paint, raw materials by weight portion proportioning is as follows: epoxy resin 100 parts, isopropanol 1-5 part, butanol 15-35 part, aluminum paste 0.5-2.5 part, butyl acrylate 10-50 part, methyl methacrylate 6-14 part, acrylic acid 4-8 part, styrene 30-50 part, barium sulfate 2-6 part, zinc phosphate 3-7 part, modified aluminium triphosphate 5-9 part, sodium bicarbonate 0.2-0.6 part, Ammonium persulfate. 0.1-0.5 part, Pulvis Talci 6-10 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 2-4 part, butanol 20-30 part, aluminum paste 1-2 part, butyl acrylate 20-40 part, methyl methacrylate 8-12 part, acrylic acid 5-7 part, styrene 35-45 part, barium sulfate 3-5 part, zinc phosphate 4-6 part, modified aluminium triphosphate 6-8 part, sodium bicarbonate 0.3-0.5 part, Ammonium persulfate. 0.2-0.4 part, Pulvis Talci 7-9 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 2 parts, 20 parts of butanol, aluminum paste 1 part, butyl acrylate 20 parts, methyl methacrylate 8 parts, 5 parts of acrylic acid, styrene 35 parts, 3 parts of barium sulfate, zinc phosphate 4 parts, modified aluminium triphosphate 6 parts, sodium bicarbonate 0.3 part, Ammonium persulfate. 0.2 part, Pulvis Talci 7 parts.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 4 parts, 30 parts of butanol, aluminum paste 2 parts, butyl acrylate 40 parts, methyl methacrylate 12 parts, 7 parts of acrylic acid, styrene 45 parts, 5 parts of barium sulfate, zinc phosphate 6 parts, modified aluminium triphosphate 8 parts, sodium bicarbonate 0.5 part, Ammonium persulfate. 0.4 part, Pulvis Talci 9 parts.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 3 parts, 25 parts of butanol, aluminum paste 1.5 parts, butyl acrylate 30 parts, methyl methacrylate 10 parts, 6 parts of acrylic acid, styrene 40 parts, 4 parts of barium sulfate, zinc phosphate 5 parts, modified aluminium triphosphate 7 parts, sodium bicarbonate 0.4 part, Ammonium persulfate. 0.3 part, Pulvis Talci 8 parts.
As a preferred technical solution of the present invention: the preparation method step of described iron and steel antirusting paint is:
The first step: weigh epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate, acrylic acid, styrene, barium sulfate, zinc phosphate, modified aluminium triphosphate, sodium bicarbonate, Ammonium persulfate. and Pulvis Talci;
Second step: epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 10-30min, mixing speed is 200-300 rev/min;
3rd step: add surplus stock, in grinding machine for grinding 15-35min.
Beneficial effect:
Compared to the prior art a kind of iron and steel antirusting paint of the present invention and preparation method thereof uses above technical scheme, has following technical effect that 1, appearance of film smooth, and viscosity 100-120s, surface drying 30-50min do solid work 15-19h;2, pliability 1-3mm, adhesive force 1-2 level;3, resistance to water immerses 3-7d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 50-70cm;4, fineness 25-45 μm, pencil hardness H, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
Proportioning by weight weighs epoxy resin 100 parts, isopropanol 1 part, 15 parts of butanol, aluminum paste 0.5 part, butyl acrylate 10 parts, methyl methacrylate 6 parts, 4 parts of acrylic acid, styrene 30 parts, 2 parts of barium sulfate, zinc phosphate 3 parts, modified aluminium triphosphate 5 parts, sodium bicarbonate 0.2 part, Ammonium persulfate. 0.1 part, Pulvis Talci 6 parts.
Epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 10min, mixing speed is 200 revs/min.
Add surplus stock, in grinding machine for grinding 15min.
Appearance of film smooth, viscosity 100s, surface drying 50min, do solid work 19h;Pliability 1mm, adhesive force 2 grades;Resistance to water immerses 3d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 50cm;Fineness 45 μm, pencil hardness H.
Embodiment 2:
Proportioning by weight weighs epoxy resin 100 parts, isopropanol 5 parts, 35 parts of butanol, aluminum paste 2.5 parts, butyl acrylate 50 parts, methyl methacrylate 14 parts, 8 parts of acrylic acid, styrene 50 parts, 6 parts of barium sulfate, zinc phosphate 7 parts, modified aluminium triphosphate 9 parts, sodium bicarbonate 0.6 part, Ammonium persulfate. 0.5 part, Pulvis Talci 10 parts.
Epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 30min, mixing speed is 300 revs/min.
Add surplus stock, in grinding machine for grinding 35min.
Appearance of film smooth, viscosity 105s, surface drying 45min, do solid work 18h;Pliability 1.5mm, adhesive force 2 grades;Resistance to water immerses 4d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 55cm;Fineness 40 μm, pencil hardness H.
Embodiment 3:
Proportioning by weight weighs epoxy resin 100 parts, isopropanol 2 parts, 20 parts of butanol, aluminum paste 1 part, butyl acrylate 20 parts, methyl methacrylate 8 parts, 5 parts of acrylic acid, styrene 35 parts, 3 parts of barium sulfate, zinc phosphate 4 parts, modified aluminium triphosphate 6 parts, sodium bicarbonate 0.3 part, Ammonium persulfate. 0.2 part, Pulvis Talci 7 parts.
Epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 10min, mixing speed is 200 revs/min.
Add surplus stock, in grinding machine for grinding 15min.
Appearance of film smooth, viscosity 110s, surface drying 40min, do solid work 17h;Pliability 2mm, adhesion 1 grade;Resistance to water immerses 5d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 60cm;Fineness 35 μm, pencil hardness H.
Embodiment 4:
Proportioning by weight weighs epoxy resin 100 parts, isopropanol 4 parts, 30 parts of butanol, aluminum paste 2 parts, butyl acrylate 40 parts, methyl methacrylate 12 parts, 7 parts of acrylic acid, styrene 45 parts, 5 parts of barium sulfate, zinc phosphate 6 parts, modified aluminium triphosphate 8 parts, sodium bicarbonate 0.5 part, Ammonium persulfate. 0.4 part, Pulvis Talci 9 parts.
Epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 30min, mixing speed is 300 revs/min.
Add surplus stock, in grinding machine for grinding 35min.
Appearance of film smooth, viscosity 115s, surface drying 35min, do solid work 16h;Pliability 2mm, adhesion 1 grade;Resistance to water immerses 6d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 65cm;Fineness 40 μm, pencil hardness H.
Embodiment 5:
Proportioning by weight weighs epoxy resin 100 parts, isopropanol 3 parts, 25 parts of butanol, aluminum paste 1.5 parts, butyl acrylate 30 parts, methyl methacrylate 10 parts, 6 parts of acrylic acid, styrene 40 parts, 4 parts of barium sulfate, zinc phosphate 5 parts, modified aluminium triphosphate 7 parts, sodium bicarbonate 0.4 part, Ammonium persulfate. 0.3 part, Pulvis Talci 8 parts.
Epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 20min, mixing speed is 250 revs/min.
Add surplus stock, in grinding machine for grinding 25min.
Appearance of film smooth, viscosity 120s, surface drying 30min, do solid work 15h;Pliability 3mm, adhesion 1 grade;Resistance to water immerses 7d in 30 DEG C of water, non-foaming does not falls off, resistance to impact 70cm;Fineness 25 μm, pencil hardness H.
All components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, therefore any change in the implication suitable with claims of the present invention and scope, is all considered as being included within the scope of the claims.

Claims (6)

1. an iron and steel antirusting paint, it is characterised in that the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 1-5 part, butanol 15-35 part, aluminum paste 0.5-2.5 part, butyl acrylate 10-50 part, methyl methacrylate 6-14 part, acrylic acid 4-8 part, styrene 30-50 part, barium sulfate 2-6 part, zinc phosphate 3-7 part, modified aluminium triphosphate 5-9 part, sodium bicarbonate 0.2-0.6 part, Ammonium persulfate. 0.1-0.5 part, Pulvis Talci 6-10 part.
A kind of iron and steel antirusting paint the most according to claim 1, it is characterized in that, the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 2-4 part, butanol 20-30 part, aluminum paste 1-2 part, butyl acrylate 20-40 part, methyl methacrylate 8-12 part, acrylic acid 5-7 part, styrene 35-45 part, barium sulfate 3-5 part, zinc phosphate 4-6 part, modified aluminium triphosphate 6-8 part, sodium bicarbonate 0.3-0.5 part, Ammonium persulfate. 0.2-0.4 part, Pulvis Talci 7-9 part.
A kind of iron and steel antirusting paint the most according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 2 parts, 20 parts of butanol, aluminum paste 1 part, butyl acrylate 20 parts, methyl methacrylate 8 parts, 5 parts of acrylic acid, styrene 35 parts, 3 parts of barium sulfate, zinc phosphate 4 parts, modified aluminium triphosphate 6 parts, sodium bicarbonate 0.3 part, Ammonium persulfate. 0.2 part, Pulvis Talci 7 parts.
A kind of iron and steel antirusting paint the most according to claim 1, it is characterised in that: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 4 parts, 30 parts of butanol, aluminum paste 2 parts, butyl acrylate 40 parts, methyl methacrylate 12 parts, 7 parts of acrylic acid, styrene 45 parts, 5 parts of barium sulfate, zinc phosphate 6 parts, modified aluminium triphosphate 8 parts, sodium bicarbonate 0.5 part, Ammonium persulfate. 0.4 part, Pulvis Talci 9 parts.
A kind of iron and steel antirusting paint the most according to claim 1, it is characterised in that: the raw materials by weight portion proportioning of described iron and steel antirusting paint is as follows: epoxy resin 100 parts, isopropanol 3 parts, 25 parts of butanol, aluminum paste 1.5 parts, butyl acrylate 30 parts, methyl methacrylate 10 parts, 6 parts of acrylic acid, styrene 40 parts, 4 parts of barium sulfate, zinc phosphate 5 parts, modified aluminium triphosphate 7 parts, sodium bicarbonate 0.4 part, Ammonium persulfate. 0.3 part, Pulvis Talci 8 parts.
6. the preparation method of iron and steel antirusting paint described in a claim 1, it is characterised in that comprise the steps:
The first step: weigh epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate, acrylic acid, styrene, barium sulfate, zinc phosphate, modified aluminium triphosphate, sodium bicarbonate, Ammonium persulfate. and Pulvis Talci;
Second step: epoxy resin, isopropanol, butanol, aluminum paste, butyl acrylate, methyl methacrylate and acrylic acid being put in the reactor being provided with agitator and thermometer, stir 10-30min, mixing speed is 200-300 rev/min;
3rd step: add surplus stock, in grinding machine for grinding 15-35min.
CN201610372352.9A 2016-05-31 2016-05-31 Antirust coating used for steel, and preparation method thereof Pending CN106009818A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752630A (en) * 2016-12-16 2017-05-31 盐城工学院 A kind of steel rust prevention coating and preparation method thereof
CN107603403A (en) * 2017-10-10 2018-01-19 徐州赛欧电子科技有限公司 A kind of preparation method of novel antirust coating
CN107868593A (en) * 2017-11-28 2018-04-03 苏州卓诚钛设备有限公司 A kind of surface of metal product coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064548A (en) * 1999-08-27 2001-03-13 Kikusui Chemical Industries Co Ltd Method for forming fireproof coating layer
CN102206459A (en) * 2010-03-29 2011-10-05 中化化工科学技术研究总院 Novel solvent-free high-performance epoxy anticorrosive paint for steel surface
CN102993842A (en) * 2012-10-16 2013-03-27 益阳祥瑞科技有限公司 Styrene-acrylic emulsion aqueous rust coating and preparation method thereof
CN105255324A (en) * 2015-11-25 2016-01-20 蓬莱蔚阳新材料有限公司 Hydrophobic and oleophobic coating with super-long durable corrosion resistance and low surface energy and preparation process of hydrophobic and oleophobic coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064548A (en) * 1999-08-27 2001-03-13 Kikusui Chemical Industries Co Ltd Method for forming fireproof coating layer
CN102206459A (en) * 2010-03-29 2011-10-05 中化化工科学技术研究总院 Novel solvent-free high-performance epoxy anticorrosive paint for steel surface
CN102993842A (en) * 2012-10-16 2013-03-27 益阳祥瑞科技有限公司 Styrene-acrylic emulsion aqueous rust coating and preparation method thereof
CN105255324A (en) * 2015-11-25 2016-01-20 蓬莱蔚阳新材料有限公司 Hydrophobic and oleophobic coating with super-long durable corrosion resistance and low surface energy and preparation process of hydrophobic and oleophobic coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752630A (en) * 2016-12-16 2017-05-31 盐城工学院 A kind of steel rust prevention coating and preparation method thereof
CN107603403A (en) * 2017-10-10 2018-01-19 徐州赛欧电子科技有限公司 A kind of preparation method of novel antirust coating
CN107868593A (en) * 2017-11-28 2018-04-03 苏州卓诚钛设备有限公司 A kind of surface of metal product coating and preparation method thereof

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