CN104479525A - Water-based antirust paint for multiple device shells and preparation method thereof - Google Patents

Water-based antirust paint for multiple device shells and preparation method thereof Download PDF

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Publication number
CN104479525A
CN104479525A CN201410711563.1A CN201410711563A CN104479525A CN 104479525 A CN104479525 A CN 104479525A CN 201410711563 A CN201410711563 A CN 201410711563A CN 104479525 A CN104479525 A CN 104479525A
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Prior art keywords
parts
water
mixture
minute
antirust paint
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Pending
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CN201410711563.1A
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Chinese (zh)
Inventor
杨奎琦
陈正义
张斌
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Changli Forging Co Ltd
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Changli Forging Co Ltd
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Priority to CN201410711563.1A priority Critical patent/CN104479525A/en
Publication of CN104479525A publication Critical patent/CN104479525A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a water-based antirust paint for multiple device shells. The invention is characterized in that the water-based antirust paint is prepared from the following raw materials in parts by weight: 2-3 parts of linoleic acid, 3-5 parts of zinc yellow, 2-3 parts of sodium dihydrogen phosphate, 3-4 parts of mica ferric oxide, 0.2-0.3 part of BYK-011, 2-3 parts of paraffin emulsion, 33-36 parts of water-based alkyd resin, 0.4-0.6 part of alkylphenol polyoxyethylene, 16-20 parts of deionized water, 2-3 parts of water-based polyamide, 1-2 parts of water-based anti-skinning agent, 1-2 parts of silane coupling agent KH550, 1-2 parts of sodium dodecylsulfate, 0.3-0.4 part of polydimethylsiloxane, 25-28 parts of acrylic acid emulsion, 2-4 parts of 2,2,4-trimethyl-1,3-pentadiol monoisobutyrate and 4-7 parts of assistant. The water-based antirust paint has the advantages of low production cost, environment friendliness and high safety, is convenient for application and harmless to health of the human body, has obvious antirust effect, greatly prolongs the service life of the device shell, reduces the cost on latter maintenance, and has wide application range. The added assistants have the functions of shock absorption and noise reduction, thereby greatly reducing the hazards of noise to people.

Description

One kind of multiple apparatus casing use rust-inhibiting paints and preparation method thereof
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly one kind of multiple apparatus casing use rust-inhibiting paints and preparation method thereof.
Background technology
Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings comprises water soluble paint, water-reducible coatings, water-dispersible paint 3 kinds.Water-borne coatings, with water as solvent, saves ample resources, and fire hazard when water-borne coatings eliminates construction, reduces topsoil; Water-borne coatings only adopts a small amount of hypotoxicity alcohol ether organic solvent, improves operating environmental condition; Water-borne coatings directly can apply construction in wet structure and wet environment; It is good to material surface adaptability, strong adhesion.
The rust corrosion of metallic substance has become a catastrophe in national economy; rust corrosion causes the waste of material; not only bring serious financial loss; and also can bring great social danger as the material of apparatus casing; therefore protect the material such as metal not got rusty, making it play effect, the slow corrosion of resistance, increase the service life is an important task.Traditional solvent-borne type rust-inhibiting paint is in manufacture, construction, drying, solidification, film process, a large amount of VOC (volatile organic compounds) is distributed in air, serious pollution and threat are caused to human ecological environment, therefore aqueous antirust paint is more and more subject to the favor of people.
Summary of the invention
The object of this invention is to provide one kind of multiple apparatus casing use rust-inhibiting paints and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
One kind of multiple apparatus casing use rust-inhibiting paints, are made up of the raw material of following weight part: linolenic acid 2-3, zinc network yellow 3-5, SODIUM PHOSPHATE, MONOBASIC 2-3, iron mica 3-4, BYK-0110.2-0.3, paraffin wax emulsions 2-3, aqueous alkide resin 33-36, alkylphenol polyoxyethylene 0.4-0.6, deionized water 16-20, aqueous polyamide 2-3, water-based anti skinning agent 1-2, Silane coupling agent KH550 1-2, sodium laurylsulfonate 1-2, polydimethylsiloxane 0.3-0.4, ACRYLIC EMULSION 25-28, alcohol ester 12 2-4, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: tripoly phosphate sodium STPP 2-4, alkylphenol polyoxyethylene 1-2, polyvinyl alcohol 2-3, urea 6-8, nanometer silver 4-5, titanate coupling agent 1-2, methyl methacrylate 10-15, ethyl propenoate 3-5, Potassium Persulphate 1-2, water 8-11, hollow glass micropearl 6-8, fly ash micro-sphere 4-6, sepiolite powder 3-5,1.2% chitosan-acetic acid solution 3-5, ammonium molybdate 2-4, polyvinyl acetate emulsion 5-8; Preparation method is that methyl methacrylate, ethyl propenoate, polyvinyl acetate emulsion and water mix by (1), passes into fluidized-bed and makes its fluidisation; (2) hollow glass micropearl, fly ash micro-sphere, sepiolite powder and Potassium Persulphate are mixed, passing into fluidized-bed is boiling state; (3) mixture of step (1) is sprayed on the mixture of step (2) on the surface, under 60-80 ° of C, reacts 1-2 hour, add titanate coupling agent again and remaining surplus materials stirs after reaction terminates, then add rubber mill grinding distribution evenly.
One kind of multiple apparatus casing use rust-inhibiting paints of the present invention, be made up of following concrete steps:
(1) polydimethylsiloxane, sodium laurylsulfonate, alkylphenol polyoxyethylene, BYK-011 and deionized water are mixed, 7-9 minute is stirred under 400-600 rev/min, add zinc network Huang, SODIUM PHOSPHATE, MONOBASIC, iron mica, auxiliary agent ultrasonic disperse 15-25 minute again, obtain mixture A;
(2) be added in Scattered Kettle by aqueous alkide resin, ACRYLIC EMULSION, alcohol ester 12, aqueous polyamide, 1200-1400 rev/min of lower high-speed mixing stirs 20-40 minute, obtains mixture B;
(3) mixture A is added in mixture B, then adds all the other surplus materialss, disperse 10-20 minute under the rotating speed of 800-1000 rev/min after, forward in shredder, obtain the material of 20-40 μm, to obtain final product.
Advantage of the present invention is: aqueous antirust paint productive expense of the present invention is low, green, environmental protection, safety, application is convenient, harmless to the health of human body, rust-proof effect is remarkable, substantially prolongs the working life of apparatus casing, reduce the expense of later maintenance, and applied widely, the auxiliary agent of interpolation also has the function of damping noise reduction, substantially reduces the harm of noise to people.
specific embodiments
Below by specific examples, the present invention is described in detail.
One kind of multiple apparatus casing use rust-inhibiting paints, are made up of the raw material of following weight part (kilogram): linolenic acid 3, zinc network Huang 4, SODIUM PHOSPHATE, MONOBASIC 2, iron mica 3, BYK-0110.2, paraffin wax emulsions 2, aqueous alkide resin 35, alkylphenol polyoxyethylene 0.5, deionized water 19, aqueous polyamide 3, water-based anti skinning agent 1, Silane coupling agent KH550 1, sodium laurylsulfonate 1, polydimethylsiloxane 0.3, ACRYLIC EMULSION 27, alcohol ester 12, auxiliary agent 6;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): tripoly phosphate sodium STPP 3, alkylphenol polyoxyethylene 1, polyvinyl alcohol 3, urea 6, nanometer silver 4, titanate coupling agent 2, methyl methacrylate 13, ethyl propenoate 4, Potassium Persulphate 2, water 8, hollow glass micropearl 6, fly ash micro-sphere 5, the chitosan-acetic acid solution 4 of sepiolite powder 3,1.2%, ammonium molybdate 3, polyvinyl acetate emulsion 7; Preparation method is that methyl methacrylate, ethyl propenoate, polyvinyl acetate emulsion and water mix by (1), passes into fluidized-bed and makes its fluidisation; (2) hollow glass micropearl, fly ash micro-sphere, sepiolite powder and Potassium Persulphate are mixed, passing into fluidized-bed is boiling state; (3) mixture of step (1) is sprayed on the mixture of step (2) on the surface, under 60-80 ° of C, reacts 1-2 hour, add titanate coupling agent again and remaining surplus materials stirs after reaction terminates, then add rubber mill grinding distribution evenly.
One kind of multiple apparatus casing use rust-inhibiting paints of the present invention, be made up of following concrete steps:
(1) polydimethylsiloxane, sodium laurylsulfonate, alkylphenol polyoxyethylene, BYK-011 and deionized water are mixed, 7-9 minute is stirred under 400-600 rev/min, add zinc network Huang, SODIUM PHOSPHATE, MONOBASIC, iron mica, auxiliary agent ultrasonic disperse 15-25 minute again, obtain mixture A;
(2) be added in Scattered Kettle by aqueous alkide resin, ACRYLIC EMULSION, alcohol ester 12, aqueous polyamide, 1200-1400 rev/min of lower high-speed mixing stirs 20-40 minute, obtains mixture B;
(3) mixture A is added in mixture B, then adds all the other surplus materialss, disperse 10-20 minute under the rotating speed of 800-1000 rev/min after, forward in shredder, obtain the material of 20-40 μm, to obtain final product.
Paint flat appearance of the present invention is smooth, without lump, and snappiness mm≤2, hardness: 3H, shock-resistance: 50, water tolerance experiment (29 ± 1 ° of C, 36h): non-foaming, do not come off, thermotolerance experiment (100 ± 2 DEG C, 5h): non-foaming wrinkling, without cracking, resistance to artificial weathering experiment: by 500 hours, cold-hot is experiment (5 cycle) alternately: without bubbling, without cracking, without coming off, recombination loss Factor Experiment: 10 ° of C:0.129,30 ° of C:0.116.

Claims (2)

1. one kind of multiple apparatus casing use rust-inhibiting paints, it is characterized in that, be made up of the raw material of following weight part: linolenic acid 2-3, zinc network yellow 3-5, SODIUM PHOSPHATE, MONOBASIC 2-3, iron mica 3-4, BYK-0110.2-0.3, paraffin wax emulsions 2-3, aqueous alkide resin 33-36, alkylphenol polyoxyethylene 0.4-0.6, deionized water 16-20, aqueous polyamide 2-3, water-based anti skinning agent 1-2, Silane coupling agent KH550 1-2, sodium laurylsulfonate 1-2, polydimethylsiloxane 0.3-0.4, ACRYLIC EMULSION 25-28, alcohol ester 12 2-4, auxiliary agent 4-7;
Described auxiliary agent is made up of the raw material of following weight part: tripoly phosphate sodium STPP 2-4, alkylphenol polyoxyethylene 1-2, polyvinyl alcohol 2-3, urea 6-8, nanometer silver 4-5, titanate coupling agent 1-2, methyl methacrylate 10-15, ethyl propenoate 3-5, Potassium Persulphate 1-2, water 8-11, hollow glass micropearl 6-8, fly ash micro-sphere 4-6, sepiolite powder 3-5,1.2% chitosan-acetic acid solution 3-5, ammonium molybdate 2-4, polyvinyl acetate emulsion 5-8; Preparation method is that methyl methacrylate, ethyl propenoate, polyvinyl acetate emulsion and water mix by (1), passes into fluidized-bed and makes its fluidisation; (2) hollow glass micropearl, fly ash micro-sphere, sepiolite powder and Potassium Persulphate are mixed, passing into fluidized-bed is boiling state; (3) mixture of step (1) is sprayed on the mixture of step (2) on the surface, under 60-80 ° of C, reacts 1-2 hour, add titanate coupling agent again and remaining surplus materials stirs after reaction terminates, then add rubber mill grinding distribution evenly.
2. one kind of multiple apparatus casing use rust-inhibiting paints according to claim 1, is characterized in that, be made up of following concrete steps:
(1) polydimethylsiloxane, sodium laurylsulfonate, alkylphenol polyoxyethylene, BYK-011 and deionized water are mixed, 7-9 minute is stirred under 400-600 rev/min, add zinc network Huang, SODIUM PHOSPHATE, MONOBASIC, iron mica, auxiliary agent ultrasonic disperse 15-25 minute again, obtain mixture A;
(2) be added in Scattered Kettle by aqueous alkide resin, ACRYLIC EMULSION, alcohol ester 12, aqueous polyamide, 1200-1400 rev/min of lower high-speed mixing stirs 20-40 minute, obtains mixture B;
(3) mixture A is added in mixture B, then adds all the other surplus materialss, disperse 10-20 minute under the rotating speed of 800-1000 rev/min after, forward in shredder, obtain the material of 20-40 μm, to obtain final product.
CN201410711563.1A 2014-12-01 2014-12-01 Water-based antirust paint for multiple device shells and preparation method thereof Pending CN104479525A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047105A (en) * 2016-07-18 2016-10-26 天长市巨龙车船涂料有限公司 Alkyd resin paint special for stainless steel
CN106085015A (en) * 2016-07-18 2016-11-09 安徽朗凯奇建材有限公司 Heat-insulating waterproof coating of butadiene-styrene rubber a kind of of durable antibiotic and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1980595A2 (en) * 2007-04-05 2008-10-15 Deutsche Amphibolin-Werke Von Robert Murjahn Stiftung & Co. KG Water dilutable, alkyd resin based filling paste for substrates to be varnished
CN101659740A (en) * 2008-08-28 2010-03-03 上海涂料有限公司技术中心 Self-crosslinking sulfonate-base epoxy ester aqueous dispersion and anti-corrosive primer thereof
CN102993792A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 High-gloss metal anti-rust paint and preparation method thereof
CN103387780A (en) * 2013-07-08 2013-11-13 吴江市物华五金制品有限公司 Anti-scaling and rustproof coating for industrial pipelines and preparation method thereof
CN103409017A (en) * 2013-07-18 2013-11-27 吴江骏达电梯部件有限公司 Aqueous antirust paint with rust
CN103436120A (en) * 2013-08-07 2013-12-11 山东奔腾漆业有限公司 Water-based alkyd resin and modified acrylic emulsion metal paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1980595A2 (en) * 2007-04-05 2008-10-15 Deutsche Amphibolin-Werke Von Robert Murjahn Stiftung & Co. KG Water dilutable, alkyd resin based filling paste for substrates to be varnished
CN101659740A (en) * 2008-08-28 2010-03-03 上海涂料有限公司技术中心 Self-crosslinking sulfonate-base epoxy ester aqueous dispersion and anti-corrosive primer thereof
CN102993792A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 High-gloss metal anti-rust paint and preparation method thereof
CN103387780A (en) * 2013-07-08 2013-11-13 吴江市物华五金制品有限公司 Anti-scaling and rustproof coating for industrial pipelines and preparation method thereof
CN103409017A (en) * 2013-07-18 2013-11-27 吴江骏达电梯部件有限公司 Aqueous antirust paint with rust
CN103436120A (en) * 2013-08-07 2013-12-11 山东奔腾漆业有限公司 Water-based alkyd resin and modified acrylic emulsion metal paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047105A (en) * 2016-07-18 2016-10-26 天长市巨龙车船涂料有限公司 Alkyd resin paint special for stainless steel
CN106085015A (en) * 2016-07-18 2016-11-09 安徽朗凯奇建材有限公司 Heat-insulating waterproof coating of butadiene-styrene rubber a kind of of durable antibiotic and preparation method thereof

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Application publication date: 20150401