CN108504199A - Insulation stone-like coating - Google Patents

Insulation stone-like coating Download PDF

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Publication number
CN108504199A
CN108504199A CN201810248881.7A CN201810248881A CN108504199A CN 108504199 A CN108504199 A CN 108504199A CN 201810248881 A CN201810248881 A CN 201810248881A CN 108504199 A CN108504199 A CN 108504199A
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China
Prior art keywords
parts
sodium
coating
acrylic emulsion
mixing speed
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Pending
Application number
CN201810248881.7A
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Chinese (zh)
Inventor
尹东林
马克军
吴祖青
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Anhui Dongtai Architectural Decoration Material Co Ltd
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Anhui Dongtai Architectural Decoration Material Co Ltd
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Priority to CN201810248881.7A priority Critical patent/CN108504199A/en
Publication of CN108504199A publication Critical patent/CN108504199A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/324Alkali metal phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of insulation stone-like coatings, include the raw material of following parts by weight:30 40 parts of styrene-acrylic emulsion, 25 35 parts of neat silicone lotion, 25 35 parts of sodium polycarboxylate, yttrium oxide 15 25,13 15 parts of zinc flake, 13 15 parts of titanium dioxide, 8 10 parts of bentonite, 8 10 parts of talcum powder, 8 10 parts of mica powder, 8 10 parts of sodium tripolyphosphate, 79 parts of Sodium Polyacrylate, 79 parts of aluminium hydroxide, 57 parts of alumina silicate, 57 parts of tricresyl phosphate, 46 parts of propylene glycol, 46 parts of terpinol, 30 40 parts of deionized water;Include the following steps:S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender.The present invention has excellent insulation, temperature-change resistance and inoxidizability, and has high tensile and good flexibility, and preparation process is simple, easy to use, at low cost.

Description

Insulation stone-like coating
Technical field
The present invention relates to stone-like coating technical field more particularly to a kind of insulation stone-like coatings.
Background technology
Building coating have the function of decoration, protection building etc., cover with paint, lacquer, colour wash, etc. material surface, can change its color, decorative pattern, gloss, Texture etc. improves the aesthetic value of object, can protect prevented by the surface of painting jewelry from extraneous light, oxygen, chemical substance, The erosions such as solvent improve the service life for being coated object.With the improvement of living standards, people require to get over to the diversification of coating Come higher, stone-like coating receives the pro-gaze of people as a kind of new coating, and being widely used for stone-like coating is general, it Decorative effect is more suitable for than stone material moulding various designs comparable to stone material.Stone-like coating can be used as exterior wall and embossment, beam column Deng special-shaped wall decoration;It applies also for doing exterior wall mural painting;In addition to this, it may also be used for interior decoration, have granite, marble, Color and luster fruit as numb stone, in particular on the decorations such as indoor cylinder, FRP Columns, can get the effect mixed the spurious with the genuine;In trip The wayside pavilion etc. at the scenic spots such as urticaria scenic spot, sacred Buddhist site is had a rest a little, is decorated using stone-like coating, not only beautiful and generous, Er Qiezeng Natural temperament and interest is added, has brought out the best in each other with sight spot.
Existing stone-like coating heat insulating effect is poor, and does not have temperature variation resistant and antioxygenic property, use scope Limited, cost is higher, and yield rate is low, and more serious to the pollution of environment, therefore, imitates stone we have proposed a kind of insulation and applies Material is for solving the above problems.
Invention content
Technical problems based on background technology, the present invention propose a kind of insulation stone-like coating.
Insulation stone-like coating proposed by the present invention, includes the raw material of following parts by weight:30-40 parts of styrene-acrylic emulsion is pure 25-35 parts of resin emulsion, 25-35 parts, yttrium oxide 15-25 of sodium polycarboxylate, 13-15 parts of zinc flake, 13-15 parts of titanium dioxide, 8-10 parts of bentonite, 8-10 parts of talcum powder, 8-10 parts of mica powder, 8-10 parts of sodium tripolyphosphate, 7-9 parts of Sodium Polyacrylate, hydrogen-oxygen Change 7-9 parts of aluminium, 5-7 parts of alumina silicate, 5-7 parts of tricresyl phosphate, 4-6 parts of propylene glycol, 4-6 parts of terpinol, deionized water 30-40 Part;
Preparation method includes the following steps:
S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender, at 40-50 DEG C 20-30min is stirred with the mixing speed of 60-70rpm;
S2:Yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate is added, 10- is stirred with the mixing speed of 120-140rpm 20min;
S3:Titanium dioxide, bentonite, talcum powder, mica powder is added, 15-25min is stirred with the mixing speed of 60-80rpm, adds Sodium tripolyphosphate, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, at 120-160 DEG C It after lower baking 20-30min, is ground, insulation stone-like coating is made.
Preferably, include the raw material of following parts by weight:32-38 parts of styrene-acrylic emulsion, 27-33 parts of neat silicone lotion, poly- carboxylic Sour sodium 27-33 parts, yttrium oxide 17-23,13.5-14.5 parts of zinc flake, 13.5-14.5 parts of titanium dioxide, bentonite 8.5-9.5 Part, 8.5-9.5 parts of talcum powder, 8.5-9.5 parts of mica powder, 8.5-9.5 parts of sodium tripolyphosphate, 7.5-8.5 parts of Sodium Polyacrylate, hydrogen 7.5-8.5 parts of aluminium oxide, 5.5-6.5 parts of alumina silicate, 5.5-6.5 parts of tricresyl phosphate, 4.5-5.5 parts of propylene glycol, terpinol 4.5-5.5 part, 32-38 parts of deionized water.
Preferably, the styrene-acrylic emulsion, neat silicone lotion and sodium polycarboxylate weight ratio are 1.2-1.6:1:1.
Preferably, in the S1, styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added and is stirred It mixes in machine, 22-28min is stirred with the mixing speed of 62-68rpm at 42-48 DEG C.
Preferably, in the S2, yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate stirring with 125-135rpm is added Mix speed stirring 12-18min.
Preferably, in the S3, titanium dioxide, bentonite, talcum powder, mica powder is added and is stirred with the mixing speed of 65-75rpm 17-23min is mixed, sodium tripolyphosphate, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol are added, is then placed in baking It in case, after toasting 22-28min at 130-150 DEG C, is ground, insulation stone-like coating is made.
In the present invention, insulation stone-like coating adds using styrene-acrylic emulsion and neat silicone lotion as base-material in coating Entering yttrium oxide keeps stone-like coating insulation obtained preferable, and with high tensile and good flexible performance, has Good temperature-change resistance and inoxidizability can improve the temperature-change resistance of stone-like coating by the way that zinc flake is added, pass through addition Aluminium hydroxide and alumina silicate can improve the inoxidizability of coating, be made by the way that bentonite, talcum powder, mica powder, titanium dioxide is added The mobility of coating can be enhanced for filler, and cost can be reduced, being used as dispersant by addition sodium tripolyphosphate makes What granules of pigments was stablized is dispersed in coating, and is used as thickener by the way that Sodium Polyacrylate is added and can enhance the apparent of coating Viscosity, and coating is assigned with thixotropy, the present invention has excellent insulation, temperature-change resistance and inoxidizability, and has height Tensile strength and good flexibility, preparation process is simple, easy to use, at low cost.
Specific implementation mode
The present invention is made further to explain with reference to specific embodiment.
Embodiment one
The present embodiment proposes insulation stone-like coating, includes the raw material of following parts by weight:30 parts of styrene-acrylic emulsion, neat silicone 25 parts of lotion, 25 parts of sodium polycarboxylate, yttrium oxide 15,13 parts of zinc flake, 13 parts of titanium dioxide, 8 parts of bentonite, 8 parts of talcum powder, cloud 8 parts of female powder, 8 parts of sodium tripolyphosphate, 7 parts of Sodium Polyacrylate, 7 parts of aluminium hydroxide, 5 parts of alumina silicate, 5 parts of tricresyl phosphate, third 4 parts of glycol, 4 parts of terpinol, 30 parts of deionized water;
Preparation method includes the following steps:
S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender, at 40 DEG C with The mixing speed of 60rpm stirs 20min;
S2:Yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate is added, 10min is stirred with the mixing speed of 120rpm;
S3:Titanium dioxide, bentonite, talcum powder, mica powder is added, 15min is stirred with the mixing speed of 60rpm, adds trimerization phosphorus Sour sodium, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, and 20min is toasted at 120 DEG C Afterwards, it is ground, insulation stone-like coating is made.
Embodiment two
The present embodiment proposes insulation stone-like coating, includes the raw material of following parts by weight:35 parts of styrene-acrylic emulsion, neat silicone 30 parts of lotion, 30 parts of sodium polycarboxylate, yttrium oxide 20,14 parts of zinc flake, 14 parts of titanium dioxide, 9 parts of bentonite, 9 parts of talcum powder, cloud 9 parts of female powder, 9 parts of sodium tripolyphosphate, 8 parts of Sodium Polyacrylate, 8 parts of aluminium hydroxide, 6 parts of alumina silicate, 6 parts of tricresyl phosphate, third 5 parts of glycol, 5 parts of terpinol, 35 parts of deionized water;
Preparation method includes the following steps:
S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender, at 45 DEG C with The mixing speed of 65rpm stirs 25min;
S2:Yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate is added, 15min is stirred with the mixing speed of 130rpm;
S3:Titanium dioxide, bentonite, talcum powder, mica powder is added, 20min is stirred with the mixing speed of 70rpm, adds trimerization phosphorus Sour sodium, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, and 25min is toasted at 140 DEG C Afterwards, it is ground, insulation stone-like coating is made.
Embodiment three
The present embodiment proposes insulation stone-like coating, includes the raw material of following parts by weight:40 parts of phenylpropyl alcohol breast, neat silicone breast 35 parts of liquid, 35 parts of sodium polycarboxylate, yttrium oxide 25,15 parts of zinc flake, 15 parts of titanium dioxide, 10 parts of bentonite, 10 parts of talcum powder, cloud It is 10 parts female, 10 parts of sodium tripolyphosphate, 9 parts of Sodium Polyacrylate, 9 parts of aluminium hydroxide, 7 parts of alumina silicate, 7 parts of tricresyl phosphate, third 6 parts of glycol, 6 parts of terpinol, 40 parts of deionized water;
Preparation method includes the following steps:
S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender, at 50 DEG C with The mixing speed of 70rpm stirs 30min;
S2:Yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate is added, 20min is stirred with the mixing speed of 140rpm;
S3:Titanium dioxide, bentonite, talcum powder, mica powder is added, 25min is stirred with the mixing speed of 80rpm, adds trimerization phosphorus Sour sodium, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, and 30min is toasted at 160 DEG C Afterwards, it is ground, insulation stone-like coating is made.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. insulation stone-like coating, which is characterized in that include the raw material of following parts by weight:30-40 parts of styrene-acrylic emulsion, pure silicon tree 25-35 parts of fat liquor, 25-35 parts, yttrium oxide 15-25 of sodium polycarboxylate, 13-15 parts of zinc flake, 13-15 parts of titanium dioxide, swelling It is 8-10 parts native, 8-10 parts of talcum powder, 8-10 parts of mica powder, 8-10 parts of sodium tripolyphosphate, 7-9 parts of Sodium Polyacrylate, aluminium hydroxide 7-9 parts, 5-7 parts of alumina silicate, 5-7 parts of tricresyl phosphate, 4-6 parts of propylene glycol, 4-6 parts of terpinol, 30-40 parts of deionized water;
Preparation method includes the following steps:
S1:Styrene-acrylic emulsion, neat silicone lotion, sodium polycarboxylate and deionized water are sequentially added in blender, at 40-50 DEG C 20-30min is stirred with the mixing speed of 60-70rpm;
S2:Yttrium oxide, zinc flake, aluminium hydroxide and alumina silicate is added, 10- is stirred with the mixing speed of 120-140rpm 20min;
S3:Titanium dioxide, bentonite, talcum powder, mica powder is added, 15-25min is stirred with the mixing speed of 60-80rpm, adds Sodium tripolyphosphate, Sodium Polyacrylate, tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, at 120-160 DEG C It after lower baking 20-30min, is ground, insulation stone-like coating is made.
2. insulation stone-like coating according to claim 1, which is characterized in that include the raw material of following parts by weight:Benzene 32-38 parts of acrylic emulsion, 27-33 parts of neat silicone lotion, 27-33 parts, yttrium oxide 17-23, zinc flake 13.5- of sodium polycarboxylate 14.5 parts, 13.5-14.5 parts of titanium dioxide, 8.5-9.5 parts of bentonite, 8.5-9.5 parts of talcum powder, 8.5-9.5 parts of mica powder, trimerization 8.5-9.5 parts of sodium phosphate, 7.5-8.5 parts of Sodium Polyacrylate, 7.5-8.5 parts of aluminium hydroxide, 5.5-6.5 parts of alumina silicate, tricresyl phosphate 5.5-6.5 parts of toluene ester, 4.5-5.5 parts of propylene glycol, 4.5-5.5 parts of terpinol, 32-38 parts of deionized water.
3. insulation stone-like coating according to claim 1, which is characterized in that the styrene-acrylic emulsion, neat silicone breast Liquid and sodium polycarboxylate weight ratio are 1.2-1.6:1:1.
4. insulation stone-like coating according to claim 1, which is characterized in that in the S1, by styrene-acrylic emulsion, pure silicon Resin emulsion, sodium polycarboxylate and deionized water sequentially add in blender, are stirred with the mixing speed of 62-68rpm at 42-48 DEG C Mix 22-28min.
5. insulation stone-like coating according to claim 1, which is characterized in that in the S2, yttrium oxide, sheet is added Zinc powder, aluminium hydroxide and alumina silicate stir 12-18min with the mixing speed of 125-135rpm.
6. insulation stone-like coating according to claim 1, which is characterized in that in the S3, titanium dioxide, swelling is added Soil, talcum powder, mica powder stir 17-23min with the mixing speed of 65-75rpm, add sodium tripolyphosphate, Sodium Polyacrylate, Tricresyl phosphate, ethylene glycol and terpinol, are then placed in baking oven, after toasting 22-28min at 130-150 DEG C, are ground Insulation stone-like coating is made in mill.
CN201810248881.7A 2018-03-25 2018-03-25 Insulation stone-like coating Pending CN108504199A (en)

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CN201810248881.7A CN108504199A (en) 2018-03-25 2018-03-25 Insulation stone-like coating

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602179A (en) * 2013-10-14 2014-02-26 南宁丽康涂料有限公司 Thermal insulation coating
CN105273620A (en) * 2015-11-05 2016-01-27 苏州明轩地坪涂料有限公司 Pure silicon resin composite paint
CN105419505A (en) * 2015-12-18 2016-03-23 天津盛同科技有限公司 Heat preserving and insulating coating material
CN106381045A (en) * 2016-10-16 2017-02-08 成都蒲江珂贤科技有限公司 Building external wall temperature-change-resistant anti-oxidative color coating
CN107353802A (en) * 2016-05-10 2017-11-17 天津市金三鑫水性涂料科技有限公司 A kind of water-based paint compositions used for building exterior wall and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602179A (en) * 2013-10-14 2014-02-26 南宁丽康涂料有限公司 Thermal insulation coating
CN105273620A (en) * 2015-11-05 2016-01-27 苏州明轩地坪涂料有限公司 Pure silicon resin composite paint
CN105419505A (en) * 2015-12-18 2016-03-23 天津盛同科技有限公司 Heat preserving and insulating coating material
CN107353802A (en) * 2016-05-10 2017-11-17 天津市金三鑫水性涂料科技有限公司 A kind of water-based paint compositions used for building exterior wall and preparation method thereof
CN106381045A (en) * 2016-10-16 2017-02-08 成都蒲江珂贤科技有限公司 Building external wall temperature-change-resistant anti-oxidative color coating

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Application publication date: 20180907

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