CN105086746A - Weather-resistance paint special for scaffold - Google Patents

Weather-resistance paint special for scaffold Download PDF

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Publication number
CN105086746A
CN105086746A CN201510465768.0A CN201510465768A CN105086746A CN 105086746 A CN105086746 A CN 105086746A CN 201510465768 A CN201510465768 A CN 201510465768A CN 105086746 A CN105086746 A CN 105086746A
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China
Prior art keywords
parts
scaffolding
nano
resin
weather
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Pending
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CN201510465768.0A
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Chinese (zh)
Inventor
许盟凯
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Anhui Pengfeng New Building Material Science & Technology Co Ltd
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Anhui Pengfeng New Building Material Science & Technology Co Ltd
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Priority to CN201510465768.0A priority Critical patent/CN105086746A/en
Publication of CN105086746A publication Critical patent/CN105086746A/en
Pending legal-status Critical Current

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Abstract

The invention discloses weather-resistance paint special for a scaffold. The weather-resistance paint special for the scaffold comprises, by weight, 20-40 parts of epoxy resin, 15-30 parts of phenolic resin, 5-20 parts of acrylic resin, 3-15 parts of acidic nano-silicon sol, 10-15 parts of diphenyldimethoxysilane, 2-10 parts of a silane coupling agent KH560, 3-15 parts of polyhydroxy styrene resin, 4-10 parts of hexafluorobutyl methacrylate, 2-10 parts of carboxyl-terminated butadiene acrylonitrile rubber, 15-25 parts of compound stuffing, 15-30 parts of solvent, 2-8 parts of amino resin and 3-8 parts of auxiliaries. The weather-resistance paint special for the scaffold is good in corrosion resistance and excellent in water resistance and weathering resistance.

Description

A kind of scaffolding dedicated weather-proof paint
Technical field
The present invention relates to paint technology field, particularly relate to a kind of scaffolding dedicated weather-proof paint.
Background technology
Scaffolding refers to that working-yard is the various supports that operative also solves vertically and horizontal transport is set up, in building, circle refers to construction site is used in the higher place that cannot directly construct of exterior wall, inside fitting or floor height, works up and down or perimeter security net is gone along with sb. to guard him and high-altitude installation component etc. mainly for workmen.Existing scaffolding develops into metal products from wood, bamboo.Metal scaffolding, can leak in outdoor for a long time cruelly in the process used, and under wind, Exposure to Sunlight, the effect that drenches with rain, is easily corroded, shortens its work-ing life, while also there is potential safety hazard.
Paint coating is due to the chemical physical property of its uniqueness, have a wide range of applications in industrial and agricultural production and daily life, such as: the door and window in the epidermis of the outer wall of various pipeline, the shell of mining machinery, vehicle, everyday home and building material surface can see various paint coating.Paint coating also plays the protective effect even more important to various surface except the effect playing decoration.At metal scaffolding surface-coated paint coating, protective effect can be played to the surface of metal scaffolding, extend the work-ing life of scaffolding.Along with the development of society, the performance of people to scaffolding and paint used is had higher requirement, and its water tolerance of existing paint and erosion resistance are not very desirable, not good enough for its weather resistance in scaffolding, needs to carry out modification.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of scaffolding dedicated weather-proof paint, its good corrosion resistance, water tolerance and weather resistance excellence.
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: epoxy resin 20-40 part, resol 15-30 part, acrylic resin 5-20 part, acidity nanometer silicon sol 3-15 part, dimethoxydiphenylsilane 10-15 part, silane coupling agent KH5602-10 part, polyhydroxy styrene resin 3-15 part, Hexafluorobutyl mathacrylate 4-10 part, nbr carboxyl terminal 2-10 part, compounded mix 15-25 part, solvent 15-30 part, aminoresin 2-8 part, auxiliary agent 3-8 part.
Preferably, its raw material comprises following component by weight: epoxy resin 28-35 part, resol 22-25 part, acrylic resin 13-16 part, acidity nanometer silicon sol 9-12 part, dimethoxydiphenylsilane 12-15 part, silane coupling agent KH5607-8 part, polyhydroxy styrene resin 12-13 part, Hexafluorobutyl mathacrylate 7-9 part, nbr carboxyl terminal 7-8 part, compounded mix 20-25 part, solvent 20-25 part, aminoresin 5-7 part, auxiliary agent 5-7 part.
Preferably, its raw material comprises following component by weight: epoxy resin 30 parts, 20 parts, resol, acrylic resin 15 parts, acidity nanometer silicon sol 10 parts, dimethoxydiphenylsilane 12 parts, silane coupling agent KH5607.5 part, polyhydroxy styrene resin 12.3 parts, Hexafluorobutyl mathacrylate 8 parts, nbr carboxyl terminal 7.6 parts, compounded mix 22 parts, solvent 23 parts, 5.8 parts, aminoresin, auxiliary agent 6.2 parts.
Preferably, described epoxy resin is one or more the combination in bisphenol A epoxide resin, bisphenol-s epoxy resin, hydrogenated bisphenol A epoxy resin.
Preferably, described compounded mix is mixed by 8-10 part polyaniline, 3-15 part Graphene, 2-8 part mica powder, 2-10 part nano-calcium carbonate, 2-10 part nano zine oxide, 1-5 part nano titanium oxide, 2-5 part nano-cerium oxide, 1-2.5 part Sodium dodecylbenzene sulfonate, 2-5 part sorbitan carboxylic esters by weight.
Preferably, described compounded mix is mixed by 8.5 parts of polyanilines, 12 parts of Graphenes, 5 parts of mica powders, 8 parts of nano-calcium carbonates, 6 parts of nano zine oxides, 3 parts of nano titanium oxides, 4 parts of nano-cerium oxides, 1.8 parts of Sodium dodecylbenzene sulfonatees, 3.4 parts of sorbitan carboxylic esterses by weight.
In compounded mix, the polyaniline added and Graphene are uniformly dispersed in system, after both coordinate, on the one hand by the dual function of filling and lamella intercepts, hinder water molecules and immerse metallic matrix, serve good physical isolation effect, and, in system, both can form the conductive network of continous-stable, can, by transfer transport to coating surface, make cathodic reaction occur in coatingsurface, the corrosion product avoiding generation is deposited in paint film and metallic surface, improves the shielding effect of paint film, improve water tolerance and the erosion resistance of paint film, improve the weathering resistance of paint film, in addition, Graphene has sheet structure, join after coordinating with mica powder in system, uniform sealing coat can be formed under the effect of Sodium dodecylbenzene sulfonate and sorbitan carboxylic esters, prevent entering of water molecules, improve water tolerance and the weathering resistance of paint film, and nano-calcium carbonate, nano zine oxide, nano titanium oxide, nano-cerium oxide adds in system as Nano filling, there is small-size effect, be filled with the space between paint film and defect further, improve the water tolerance of paint film, erosion resistance and weathering resistance.
Preferably, described solvent is one or more the combination in ethylene glycol ether acetate, methyl iso-butyl ketone (MIBK), epoxy propane butyl ether, butyl, Virahol, trolamine, glycerol, ethylene glycol.
Preferably, described auxiliary agent is one or more the combination in antioxidant 4010NA, antioxidant MB, cobalt naphthenate, cobalt iso-octoate, silicone antifoam agent, carboxymethyl cellulose, dicumyl peroxide, Sodium Benzoate, chitosan.
Scaffolding dedicated weather-proof paint of the present invention can paint preparation technology conveniently be prepared from.
Scaffolding dedicated weather-proof paint of the present invention, take epoxy resin as main film forming substance, and cooperation with the addition of resol, both can react, aminoresin auxiliary under, improve the character of epoxy resin while making epoxy resin cure, the paint obtained is made to have the character that powerful oxidation corrosion resistance is sour, heat-resisting and weather resistance is excellent, in the process used, not easily degrade, not easily yellowing; The acrylic resin added coordinates with epoxy resin, further improves the weathering resistance of system; The acidity nanometer silicon sol added, dimethoxydiphenylsilane and silane coupling agent KH560 can react, form continuous print reticulated structure, join in system, epoxy resin, resol and Aqueous Acrylate Resin Filling are between reticulated structure, because of the existence of silane coupling agent KH560 epoxy group, improve the consistency of reticulated structure and epoxy resin, give weathering resistance and the water tolerance of paint film excellence, and because the existence of phenyl ring adds the snappiness of paint film, rigidity and erosion resistance in dimethoxydiphenylsilane, improve its package stability; Polyhydroxy styrene resin joins in system, by the phenyl ring introducing system of rigidity, after coordinating, further improves thermotolerance and the water tolerance of system with dimethoxydiphenylsilane; Hexafluorobutyl mathacrylate joins in system, and fluorine wherein in coating surface enrichment, can prevent the wetting of corrosive medium and infiltrate, improving the water tolerance of paint film, weathering resistance and erosion resistance.
Embodiment
In a particular embodiment, a kind of scaffolding dedicated weather-proof paint that the present invention proposes, in its raw material, the weight part of epoxy resin can be 20,22,23,24,25,26.4,28,29,32,34,36,38,39.4,40 parts; The weight part of resol can be 15,16,17,18,19.3,21,23,25,26,27,27.5,28,28.5,29,29.3,30 parts; The weight part of acrylic resin can be 5,6,7,8,9,10,12,13,14,15,15.6,17,18,18.6,19,19.3,20 parts; The weight part of acidity nanometer silicon sol can be 3,4,5,6,6.4,7,8,8.5,9,10,11,11.4,12,13.5,14,14.6,15 parts; The weight part of dimethoxydiphenylsilane can be 10,10.3,10.8,11,11.4,12,12.6,13,13.6,14,14.5,15 parts; The weight part of silane coupling agent KH560 can be 2,3,4,5,5.6,6,6.5,7,8,8.6,9,9.3,10 parts; The weight part of polyhydroxy styrene resin can be 3,4,5,6,7,7.8,8,8.7,9,10,11,11.5,12,13,13.6,15 parts; The weight part of Hexafluorobutyl mathacrylate can be 4,5,6,7,8,8.6,9,9.3,10 parts; The weight part of nbr carboxyl terminal can be 2,3,4,5,5.6,6,6.4,7,8,8.5,9,9.3,10 parts; The weight part of compounded mix can be 15,16,17,17.5,18,18.6,19,19.4,21,23,23.5,24,24.6,25 parts; The weight part of solvent can be 15,16,17,18,18.5,19,21,23,25,26.4,28,28.6,29,29.4,30 parts; The weight part of aminoresin can be 2,3,4,5,5.4,6,7,7.5,8 parts; The weight part of auxiliary agent can be 3,4,5,5.5,6,6.4,7,7.5,8 parts.
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: bisphenol A epoxide resin 20 parts, 30 parts, resol, acrylic resin 5 parts, acidity nanometer silicon sol 15 parts, dimethoxydiphenylsilane 10 parts, silane coupling agent KH56010 part, polyhydroxy styrene resin 3 parts, Hexafluorobutyl mathacrylate 10 parts, nbr carboxyl terminal 2 parts, compounded mix 25 parts, solvent 15 parts, 8 parts, aminoresin, auxiliary agent 3 parts.
Embodiment 2
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: bisphenol-s epoxy resin 30 parts, hydrogenated bisphenol A epoxy resin 10 parts, 15 parts, resol, acrylic resin 20 parts, acidity nanometer silicon sol 3 parts, dimethoxydiphenylsilane 15 parts, silane coupling agent KH5602 part, polyhydroxy styrene resin 15 parts, Hexafluorobutyl mathacrylate 4 parts, nbr carboxyl terminal 10 parts, compounded mix 15 parts, solvent 30 parts, 2 parts, aminoresin, antioxidant 4010NA 8 parts;
Wherein, described solvent is that ethylene glycol ether acetate, methyl iso-butyl ketone (MIBK), epoxy propane butyl ether, butyl, Virahol, trolamine, glycerol, ethylene glycol are by the combination of the ratio of any weight.
Embodiment 3
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: bisphenol-s epoxy resin 28 parts, 25 parts, resol, acrylic resin 13 parts, acidity nanometer silicon sol 9 parts, dimethoxydiphenylsilane 15 parts, silane coupling agent KH5607 part, polyhydroxy styrene resin 13 parts, Hexafluorobutyl mathacrylate 7 parts, nbr carboxyl terminal 8 parts, compounded mix 20 parts, Virahol 12 parts, trolamine 13 parts, 5 parts, aminoresin, antioxidant MB 3 parts, cobalt naphthenate 4 parts;
Wherein, described compounded mix is mixed by 8 parts of polyanilines, 15 parts of Graphenes, 2 parts of mica powders, 10 parts of nano-calcium carbonates, 2 parts of nano zine oxides, 5 parts of nano titanium oxides, 2 parts of nano-cerium oxides, 2.5 parts of Sodium dodecylbenzene sulfonatees, 2 parts of sorbitan carboxylic esterses by weight.
Embodiment 4
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: hydrogenated bisphenol A epoxy resin 35 parts, 22 parts, resol, acrylic resin 16 parts, acidity nanometer silicon sol 12 parts, dimethoxydiphenylsilane 12 parts, silane coupling agent KH5608 part, polyhydroxy styrene resin 12 parts, Hexafluorobutyl mathacrylate 9 parts, nbr carboxyl terminal 7 parts, compounded mix 25 parts, methyl iso-butyl ketone (MIBK) 10 parts, epoxy propane butyl ether 3 parts, butyl 7 parts, 7 parts, aminoresin, dicumyl peroxide 2 parts, Sodium Benzoate 1 part, chitosan 2 parts,
Wherein, described compounded mix is mixed by 10 parts of polyanilines, 3 parts of Graphenes, 8 parts of mica powders, 2 parts of nano-calcium carbonates, 10 parts of nano zine oxides, 1 part of nano titanium oxide, 5 parts of nano-cerium oxides, 1 part of Sodium dodecylbenzene sulfonate, 5 parts of sorbitan carboxylic esterses by weight.
Embodiment 5
A kind of scaffolding dedicated weather-proof paint that the present invention proposes, its raw material comprises following component by weight: bisphenol A epoxide resin 20 parts, bisphenol-s epoxy resin 8 parts, hydrogenated bisphenol A epoxy resin 2 parts, 20 parts, resol, acrylic resin 15 parts, acidity nanometer silicon sol 10 parts, dimethoxydiphenylsilane 12 parts, silane coupling agent KH5607.5 part, polyhydroxy styrene resin 12.3 parts, Hexafluorobutyl mathacrylate 8 parts, nbr carboxyl terminal 7.6 parts, compounded mix 22 parts, ethylene glycol ether acetate 23 parts, 5.8 parts, aminoresin, auxiliary agent 6.2 parts,
Wherein, described compounded mix is mixed by 8.5 parts of polyanilines, 12 parts of Graphenes, 5 parts of mica powders, 8 parts of nano-calcium carbonates, 6 parts of nano zine oxides, 3 parts of nano titanium oxides, 4 parts of nano-cerium oxides, 1.8 parts of Sodium dodecylbenzene sulfonatees, 3.4 parts of sorbitan carboxylic esterses by weight; Described auxiliary agent is that antioxidant 4010NA, antioxidant MB, cobalt naphthenate, cobalt iso-octoate, silicone antifoam agent, carboxymethyl cellulose, dicumyl peroxide, Sodium Benzoate, chitosan are by the combination of the ratio of any weight.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (8)

1. a scaffolding dedicated weather-proof paint, it is characterized in that, its raw material comprises following component by weight: epoxy resin 20-40 part, resol 15-30 part, acrylic resin 5-20 part, acidity nanometer silicon sol 3-15 part, dimethoxydiphenylsilane 10-15 part, silane coupling agent KH5602-10 part, polyhydroxy styrene resin 3-15 part, Hexafluorobutyl mathacrylate 4-10 part, nbr carboxyl terminal 2-10 part, compounded mix 15-25 part, solvent 15-30 part, aminoresin 2-8 part, auxiliary agent 3-8 part.
2. scaffolding dedicated weather-proof paints according to claim 1, it is characterized in that, its raw material comprises following component by weight: epoxy resin 28-35 part, resol 22-25 part, acrylic resin 13-16 part, acidity nanometer silicon sol 9-12 part, dimethoxydiphenylsilane 12-15 part, silane coupling agent KH5607-8 part, polyhydroxy styrene resin 12-13 part, Hexafluorobutyl mathacrylate 7-9 part, nbr carboxyl terminal 7-8 part, compounded mix 20-25 part, solvent 20-25 part, aminoresin 5-7 part, auxiliary agent 5-7 part.
3. scaffolding dedicated weather-proof paint according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: epoxy resin 30 parts, 20 parts, resol, acrylic resin 15 parts, acidity nanometer silicon sol 10 parts, dimethoxydiphenylsilane 12 parts, silane coupling agent KH5607.5 part, polyhydroxy styrene resin 12.3 parts, Hexafluorobutyl mathacrylate 8 parts, nbr carboxyl terminal 7.6 parts, compounded mix 22 parts, solvent 23 parts, 5.8 parts, aminoresin, auxiliary agent 6.2 parts.
4. scaffolding dedicated weather-proof paint according to any one of claim 1-3, it is characterized in that, described epoxy resin is one or more the combination in bisphenol A epoxide resin, bisphenol-s epoxy resin, hydrogenated bisphenol A epoxy resin.
5. scaffolding dedicated weather-proof paint according to any one of claim 1-4, it is characterized in that, described compounded mix is mixed by 8-10 part polyaniline, 3-15 part Graphene, 2-8 part mica powder, 2-10 part nano-calcium carbonate, 2-10 part nano zine oxide, 1-5 part nano titanium oxide, 2-5 part nano-cerium oxide, 1-2.5 part Sodium dodecylbenzene sulfonate, 2-5 part sorbitan carboxylic esters by weight.
6. scaffolding dedicated weather-proof paint according to any one of claim 1-5, it is characterized in that, described compounded mix is mixed by 8.5 parts of polyanilines, 12 parts of Graphenes, 5 parts of mica powders, 8 parts of nano-calcium carbonates, 6 parts of nano zine oxides, 3 parts of nano titanium oxides, 4 parts of nano-cerium oxides, 1.8 parts of Sodium dodecylbenzene sulfonatees, 3.4 parts of sorbitan carboxylic esterses by weight.
7. scaffolding dedicated weather-proof paint according to any one of claim 1-6, it is characterized in that, described solvent is one or more the combination in ethylene glycol ether acetate, methyl iso-butyl ketone (MIBK), epoxy propane butyl ether, butyl, Virahol, trolamine, glycerol, ethylene glycol.
8. scaffolding dedicated weather-proof paint according to any one of claim 1-7, it is characterized in that, described auxiliary agent is one or more the combination in antioxidant 4010NA, antioxidant MB, cobalt naphthenate, cobalt iso-octoate, silicone antifoam agent, carboxymethyl cellulose, dicumyl peroxide, Sodium Benzoate, chitosan.
CN201510465768.0A 2015-07-29 2015-07-29 Weather-resistance paint special for scaffold Pending CN105086746A (en)

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Cited By (11)

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Publication number Priority date Publication date Assignee Title
CN105505095A (en) * 2016-01-28 2016-04-20 赵栋 Cold zinc-sprayed anticorrosion coating doped with modified graphene
CN107057430A (en) * 2017-06-07 2017-08-18 南通加隆塑胶有限公司 It is a kind of applied to weather resistant paints of automobile rearview mirror and preparation method thereof
CN107746660A (en) * 2017-11-24 2018-03-02 南宁可煜能源科技有限公司 A kind of outrigger special anti-corrosion erosion paint
CN107974112A (en) * 2017-11-29 2018-05-01 马鞍山市恒特重工科技有限公司 A kind of mining machinery surface weather-resistant coating
CN108864819A (en) * 2018-07-11 2018-11-23 徐冬 A kind of preparation method of the hydrophobic ink adhesive of chemical corrosion resistance
CN108912853A (en) * 2018-06-01 2018-11-30 唐水生 A kind of weatherability coating and preparation method thereof for exterior building
CN109251631A (en) * 2018-09-10 2019-01-22 江苏叙然信息科技有限公司 A kind of high temperature resistant cleaning shaft and coating process
CN109294404A (en) * 2018-10-31 2019-02-01 陈赞 A kind of preparation method of novel plastering coating
CN109988483A (en) * 2019-03-26 2019-07-09 安徽省欣雨环卫机械有限公司 A kind of electronic automobile-used low temperature resistant crack resisting coating of environmental sanitation and preparation method thereof
CN110982351A (en) * 2019-12-18 2020-04-10 江阴宏江锻造有限公司 High-wear-resistance antioxidant and preparation method thereof
CN111017935A (en) * 2019-12-18 2020-04-17 上海新安纳电子科技有限公司 Preparation method of silica sol and application of silica sol in ceramic coating

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CN101407655A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505095A (en) * 2016-01-28 2016-04-20 赵栋 Cold zinc-sprayed anticorrosion coating doped with modified graphene
CN107057430A (en) * 2017-06-07 2017-08-18 南通加隆塑胶有限公司 It is a kind of applied to weather resistant paints of automobile rearview mirror and preparation method thereof
CN107746660A (en) * 2017-11-24 2018-03-02 南宁可煜能源科技有限公司 A kind of outrigger special anti-corrosion erosion paint
CN107974112A (en) * 2017-11-29 2018-05-01 马鞍山市恒特重工科技有限公司 A kind of mining machinery surface weather-resistant coating
CN108912853A (en) * 2018-06-01 2018-11-30 唐水生 A kind of weatherability coating and preparation method thereof for exterior building
CN108864819A (en) * 2018-07-11 2018-11-23 徐冬 A kind of preparation method of the hydrophobic ink adhesive of chemical corrosion resistance
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CN109294404A (en) * 2018-10-31 2019-02-01 陈赞 A kind of preparation method of novel plastering coating
CN109988483A (en) * 2019-03-26 2019-07-09 安徽省欣雨环卫机械有限公司 A kind of electronic automobile-used low temperature resistant crack resisting coating of environmental sanitation and preparation method thereof
CN110982351A (en) * 2019-12-18 2020-04-10 江阴宏江锻造有限公司 High-wear-resistance antioxidant and preparation method thereof
CN111017935A (en) * 2019-12-18 2020-04-17 上海新安纳电子科技有限公司 Preparation method of silica sol and application of silica sol in ceramic coating

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Application publication date: 20151125