CN104356804A - Flame-retardant acrylic coating - Google Patents
Flame-retardant acrylic coating Download PDFInfo
- Publication number
- CN104356804A CN104356804A CN201410570856.2A CN201410570856A CN104356804A CN 104356804 A CN104356804 A CN 104356804A CN 201410570856 A CN201410570856 A CN 201410570856A CN 104356804 A CN104356804 A CN 104356804A
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- Prior art keywords
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- flame
- epoxy
- resin
- acrylic coating
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a flame-retardant acrylic coating. The flame-retardant acrylic coating is prepared from the following raw materials in parts by weight: 50-60 parts of water-soluble acrylic resin, 12-15 parts of terpene resin, 8-11 parts of alkyd resin, 3-6 parts of polyoxyethylene laurate, 2.3-2.6 parts of hydroxymethyl cellulose, 11-14 parts of attapulgite, 9-12 parts of zeolite powder, 1-2 parts of precipitated barium sulfate, 2-3 parts of melamine, 8-9 parts of zinc borate, 10-15 parts of methylated amino resin, 4-5 parts of aluminum oleate, 0.4-0.6 part of an epoxy-silane coupling agent, 15-25 parts of a pigment, 2.1-2.4 parts of a flexibilizer, 0.5-0.8 part of a defoamer, 0.7-1 part of a smoothing agent, 0.4-0.5 part of a mildew preventive, and 50-55 parts of a solvent. The flame-retardant acrylic coating disclosed by the invention is not only excellent in flame retardant property, and but also high in curing speed.
Description
Technical field
The present invention relates to acrylic coating technical field, particularly relate to a kind of flame-proof acrylic coating.
Background technology
At present, mostly to adopt in pitch or pitch as frie retardant coating in construction industry and add emulsified rubber, although pitch is cheap, its fire resistance property is poor; The as easy as rolling off a log volatilization of softening agent in emulsified rubber asphalt, cause emulsified rubber asphalt coating aging cracking in a short time, this frie retardant coating usually occurs that big area chaps in the open, particularly at cement pre-fabricated panel seam crossing, add Earth cave and thermal expansion, there will be obvious irregular gap, thus fire protection coating was lost efficacy.The coating of a kind of excellent fireproof performance of present needs.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of flame-proof acrylic coating, not only have excellent flame retardant properties, and curing speed is fast.
A kind of flame-proof acrylic coating that the present invention proposes, its raw material comprises by weight: water soluble acrylic resin 50-60 part, terpine resin 12-15 part, Synolac 8-11 part, polyoxyethylene lauric acid ester 3-6 part, Walocel MT 20.000PV 2.3-2.6 part, attapulgite 11-14 part, zeolite powder 9-12 part, process white 1-2 part, trimeric cyanamide 2-3 part, zinc borate 8-9 part, full methyl-etherified aminoresin 10-15 part, linolic acid aluminium 4-5 part, epoxy silane coupling 0.4-0.6 part, pigment 15-25 part, toughner 2.1-2.4 part, defoamer 0.5-0.8 part, advection agent 0.7-1 part, mould inhibitor 0.4-0.5 part, solvent 50-55 part.
Preferably, solvent is one or more combinations in water, ethanol, propyl alcohol, ethylene glycol.
Preferably, the weight ratio of water soluble acrylic resin, terpine resin and Synolac is 58-59:13-14:9-10.
Preferably, its raw material comprises by weight: water soluble acrylic resin 58-59 part, terpine resin 13-14 part, Synolac 9-10 part, polyoxyethylene lauric acid ester 4-5 part, Walocel MT 20.000PV 2.4-2.5 part, attapulgite 12-13 part, zeolite powder 10-11 part, process white 1.5-1.7 part, trimeric cyanamide 2.2-2.4 part, zinc borate 8.4-8.7 part, full methyl-etherified aminoresin 12-13 part, linolic acid aluminium 4.1-4.3 part, epoxy silane coupling 0.45-0.55 part, pigment 16-20 part, toughner 2.2-2.3 part, defoamer 0.6-0.7 part, advection agent 0.8-0.9 part, mould inhibitor 0.42-0.45 part, solvent 53-54 part.
Preferably, epoxy silane coupling is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane, 2-(3,4-epoxy cyclohexane) ethyl trimethoxy silane, 2-(3,4-epoxy cyclohexane base) ethyl triethoxysilane, 3-[(2,3)-epoxy third oxygen] hydroxypropyl methyl dimethoxysilane, oxyethyl group dimethyl [3-(oxyethane oxygen base) propyl group] silane, one in trimethoxy [3-(Oxiranylmethoxy) propyl group] silane.
The chemical name of full methyl-etherified aminoresin is HMMM formaldehyde resin.
The present invention is using water soluble acrylic resin, terpine resin and Synolac as filmogen, the present invention is made to have good heat-resisting, weather-proof, wear resisting property, by the emulsifying effect of polyoxyethylene lauric acid ester, filmogen is enable to be dissolved in polarity or non-polar solvent; Walocel MT 20.000PV, attapulgite, zeolite powder, process white and zinc borate cooperatively interact as thickening material, denseness of the present invention can not only be adjusted, also substantially increase anti-thixotropy energy of the present invention, and reduce manufacturing cost, by epoxy silane coupling and filmogen grafting, substantially increase consistency of the present invention; Attapulgite, zeolite powder have etch-proof functional group, and process white coordinates, and can significantly improve corrosion resistance of the present invention; And process white, trimeric cyanamide and zinc borate cooperatively interact, not only substantially increase heat-proof combustion-resistant performance of the present invention, and the generation of smog can also be suppressed; Full methyl-etherified aminoresin and linolic acid aluminium coordinate, and improve curing speed of the present invention, can dry 15-20min get final product complete drying when 140-160 DEG C.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of flame-proof acrylic coating that the present invention proposes, its raw material comprises by weight: water soluble acrylic resin 50 parts, terpine resin 15 parts, Synolac 8 parts, polyoxyethylene lauric acid ester 6 parts, Walocel MT 20.000PV 2.3 parts, attapulgite 14 parts, zeolite powder 9 parts, process white 2 parts, trimeric cyanamide 2 parts, zinc borate 9 parts, 10 parts, full methyl-etherified aminoresin, 5 parts, linolic acid aluminium, 3-(2, 3-epoxy third oxygen) propyl trimethoxy silicane 0.4 part, pigment 25 parts, toughner 2.1 parts, defoamer 0.8 part, advection agent 0.7 part, mould inhibitor 0.5 part, 50 parts, water.
Embodiment 2
A kind of flame-proof acrylic coating that the present invention proposes, its raw material comprises by weight: water soluble acrylic resin 59 parts, terpine resin 13 parts, Synolac 10 parts, polyoxyethylene lauric acid ester 4 parts, Walocel MT 20.000PV 2.5 parts, attapulgite 12 parts, zeolite powder 11 parts, process white 1.5 parts, trimeric cyanamide 2.4 parts, zinc borate 8.4 parts, 13 parts, full methyl-etherified aminoresin, 4.1 parts, linolic acid aluminium, 2-(3, 4-epoxy cyclohexane base) ethyl triethoxysilane 0.55 part, pigment 16 parts, toughner 2.3 parts, defoamer 0.6 part, advection agent 0.9 part, mould inhibitor 0.42 part, ethanol 54 parts.
Embodiment 3
A kind of flame-proof acrylic coating that the present invention proposes, its raw material comprises by weight: water soluble acrylic resin 58 parts, terpine resin 14 parts, Synolac 9 parts, polyoxyethylene lauric acid ester 5 parts, Walocel MT 20.000PV 2.4 parts, attapulgite 13 parts, zeolite powder 10 parts, process white 1.7 parts, trimeric cyanamide 2.2 parts, zinc borate 8.7 parts, 12 parts, full methyl-etherified aminoresin, 4.3 parts, linolic acid aluminium, 3-[(2, 3)-epoxy third oxygen] hydroxypropyl methyl dimethoxysilane 0.45 part, pigment 20 parts, toughner 2.2 parts, defoamer 0.7 part, advection agent 0.8 part, mould inhibitor 0.45 part, propyl alcohol 33 parts, 20 parts, water.
Embodiment 4
A kind of flame-proof acrylic coating that the present invention proposes, its raw material comprises by weight: water soluble acrylic resin 60 parts, terpine resin 12 parts, Synolac 11 parts, polyoxyethylene lauric acid ester 3 parts, Walocel MT 20.000PV 2.6 parts, attapulgite 11 parts, zeolite powder 12 parts, process white 1 part, trimeric cyanamide 3 parts, zinc borate 8 parts, 15 parts, full methyl-etherified aminoresin, 4 parts, linolic acid aluminium, trimethoxy [3-(Oxiranylmethoxy) propyl group] 0.6 part, silane, pigment 15 parts, toughner 2.4 parts, defoamer 0.5 part, advection agent 1 part, mould inhibitor 0.4 part, ethylene glycol 11 parts, ethanol 44 parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (5)
1. a flame-proof acrylic coating, it is characterized in that, its raw material comprises by weight: water soluble acrylic resin 50-60 part, terpine resin 12-15 part, Synolac 8-11 part, polyoxyethylene lauric acid ester 3-6 part, Walocel MT 20.000PV 2.3-2.6 part, attapulgite 11-14 part, zeolite powder 9-12 part, process white 1-2 part, trimeric cyanamide 2-3 part, zinc borate 8-9 part, full methyl-etherified aminoresin 10-15 part, linolic acid aluminium 4-5 part, epoxy silane coupling 0.4-0.6 part, pigment 15-25 part, toughner 2.1-2.4 part, defoamer 0.5-0.8 part, advection agent 0.7-1 part, mould inhibitor 0.4-0.5 part, solvent 50-55 part.
2. flame-proof acrylic coating according to claim 1, is characterized in that, solvent is one or more combinations in water, ethanol, propyl alcohol, ethylene glycol.
3. flame-proof acrylic coating according to claim 1 or 2, is characterized in that, the weight ratio of water soluble acrylic resin, terpine resin and Synolac is 58-59:13-14:9-10.
4. flame-proof acrylic coating according to any one of claim 1-3, it is characterized in that, its raw material comprises by weight: water soluble acrylic resin 58-59 part, terpine resin 13-14 part, Synolac 9-10 part, polyoxyethylene lauric acid ester 4-5 part, Walocel MT 20.000PV 2.4-2.5 part, attapulgite 12-13 part, zeolite powder 10-11 part, process white 1.5-1.7 part, trimeric cyanamide 2.2-2.4 part, zinc borate 8.4-8.7 part, full methyl-etherified aminoresin 12-13 part, linolic acid aluminium 4.1-4.3 part, epoxy silane coupling 0.45-0.55 part, pigment 16-20 part, toughner 2.2-2.3 part, defoamer 0.6-0.7 part, advection agent 0.8-0.9 part, mould inhibitor 0.42-0.45 part, solvent 53-54 part.
5. water soluble acrylic acid amino-stoving varnish according to any one of claim 1-4, it is characterized in that, epoxy silane coupling is 3-(2,3-epoxy third oxygen) propyl trimethoxy silicane, 2-(3,4-epoxy cyclohexane) ethyl trimethoxy silane, 2-(3,4-epoxy cyclohexane base) ethyl triethoxysilane, 3-[(2,3)-epoxy third oxygen] hydroxypropyl methyl dimethoxysilane, oxyethyl group dimethyl [3-(oxyethane oxygen base) propyl group] silane, one in trimethoxy [3-(Oxiranylmethoxy) propyl group] silane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410570856.2A CN104356804A (en) | 2014-10-23 | 2014-10-23 | Flame-retardant acrylic coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410570856.2A CN104356804A (en) | 2014-10-23 | 2014-10-23 | Flame-retardant acrylic coating |
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| Publication Number | Publication Date |
|---|---|
| CN104356804A true CN104356804A (en) | 2015-02-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410570856.2A Pending CN104356804A (en) | 2014-10-23 | 2014-10-23 | Flame-retardant acrylic coating |
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| Country | Link |
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| CN (1) | CN104356804A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830192A (en) * | 2015-04-29 | 2015-08-12 | 广德嘉宝莉化工有限公司 | High-weatherability and high-toughness aqueous paint |
| CN108754512A (en) * | 2018-06-19 | 2018-11-06 | 界首市创新门窗有限公司 | A kind of surface treatment method of door and window making stainless steel raw material |
| CN108779347A (en) * | 2016-03-10 | 2018-11-09 | 科莱恩塑料和涂料有限公司 | The fireproof coating that can form barrier layer being halogen-free with and application thereof |
| CN108912884A (en) * | 2018-06-19 | 2018-11-30 | 界首市创新门窗有限公司 | A kind of alum gate column anticorrosive paint |
| CN109206959A (en) * | 2018-09-30 | 2019-01-15 | 安徽开林新材料股份有限公司 | A kind of acrylic resin paint |
Citations (2)
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| CN101143988A (en) * | 2006-09-14 | 2008-03-19 | 刘炳义 | Water anti-flaming carpentry paint |
| CN103382336A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Flame-retardant anti-corrosion paint |
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2014
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830192A (en) * | 2015-04-29 | 2015-08-12 | 广德嘉宝莉化工有限公司 | High-weatherability and high-toughness aqueous paint |
| CN108779347A (en) * | 2016-03-10 | 2018-11-09 | 科莱恩塑料和涂料有限公司 | The fireproof coating that can form barrier layer being halogen-free with and application thereof |
| CN108779347B (en) * | 2016-03-10 | 2021-09-21 | 科莱恩塑料和涂料有限公司 | Halogen-free fire-retardant coating capable of forming barrier layer and use thereof |
| CN108754512A (en) * | 2018-06-19 | 2018-11-06 | 界首市创新门窗有限公司 | A kind of surface treatment method of door and window making stainless steel raw material |
| CN108912884A (en) * | 2018-06-19 | 2018-11-30 | 界首市创新门窗有限公司 | A kind of alum gate column anticorrosive paint |
| CN109206959A (en) * | 2018-09-30 | 2019-01-15 | 安徽开林新材料股份有限公司 | A kind of acrylic resin paint |
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Application publication date: 20150218 |
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