CN101818013A - Reflecting thermal insulating paint - Google Patents

Reflecting thermal insulating paint Download PDF

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Publication number
CN101818013A
CN101818013A CN200910009483A CN200910009483A CN101818013A CN 101818013 A CN101818013 A CN 101818013A CN 200910009483 A CN200910009483 A CN 200910009483A CN 200910009483 A CN200910009483 A CN 200910009483A CN 101818013 A CN101818013 A CN 101818013A
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CN
China
Prior art keywords
parts
far infrared
cenosphere
infrared ceramic
speed
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Pending
Application number
CN200910009483A
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Chinese (zh)
Inventor
田凤兰
段文锋
王会元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Dongfang Yuhong Building Materials Co., Ltd.
Xuzhou Woniushan New Waterproof Material Co., Ltd.
Beijing Oriental Yuhong Waterproof Technology Co Ltd
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Beijing Oriental Yuhong Waterproof Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Beijing Oriental Yuhong Waterproof Technology Co Ltd filed Critical Beijing Oriental Yuhong Waterproof Technology Co Ltd
Priority to CN200910009483A priority Critical patent/CN101818013A/en
Publication of CN101818013A publication Critical patent/CN101818013A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a reflecting thermal insulating paint which comprises the following components in parts by mass: 70 parts to 80 parts of water, 85 parts to 100 parts of rutile type titanium dioxide, 35 parts to 40 parts of cenosphere, 10 parts to 12 parts of far infrared ceramic powder, 6 parts to 10 parts of dispersing agent and 230 parts to 250 pars of pure elasticity acrylic emulsion. The invention also provides a preparation method of the reflecting thermal insulating paint. The reflecting thermal insulating paint belongs to water-based paints, has the advantages of safety and environment protection, has the thermal insulating temperature higher than 10 DEG C, has extensibility,crack resistance and wide application.

Description

Reflective heat-insulation paint
Technical field:
The present invention relates to technical field of coatings, specifically is a kind of used solar heat reflecting and heat insulating coating and preparation technologies such as outer surface of building (comprising body of wall and roof) and industrial storage tank that are used for.
Background technology:
Human active development sun power is to save limited resources.But the heat that intense radiation produced of the sun brings inconvenience also for people's life, and in developed country, the used energy of cooling system such as cold air unit, conditioning unit and electric fan account for more than 20% of annual total energy consumption; In China, the energy of these devices consume is then up to about 41%, and annual the trend that increases progressively arranged all.Cause the too high loss of these energy, the heat-insulation and heat-preservation measure of taking with buildings has very big relation.
In order to reduce the rising of outside atmosphere (mainly being sun power) to buildings and industrial tank inside temperature, traditional method is to consider from reducing the thermal conduction rate aspect, adopts the little lagging material of heat transfer coefficient to reduce sun power to the thermal conduction in buildings and the storage tank.This quasi-tradition lagging material is that it is main reducing thermal conductivity and heat transfer by conduction with raising gas phase voidage.The fiber-like lagging material will make transmission of heat by convection and radiative transfer reduce in environment for use, and thicker coating must be arranged; Section bar class inorganic heat insulation material is wanted assembling construction, has shortcomings such as seam is many, influence is attractive in appearance, water-repellancy is poor, work-ing life is short.And in case heat energy imports the internal space into, even outside temperature goes down, heat energy is difficult to discharge.
Reflective insulation, shielding sun heat radiation are a kind of novel heat insulation modes, can solve that many factory buildings and house roof under the solar irradiation are laid black waterproof layer and the internal high temperature brought.Especially during the broiling summer, can effectively reduce the intravital temperature of coating sealing under the solar irradiation.
Solar heat reflecting and heat insulating coating mainly be adopt good weatherability, water tolerance is strong, ageing resistance is strong, have strong cohesive force and elastic and can be with the insulation filler, reflect the good film forming material of filler intermiscibility, select light weight hollow, high temperature resistant, thermal resistance big and have the filler of good reflection and radiativity, refraction coefficient height, surface smoothness height, heat reflectivity and the high superfine powder of radiant ratio are suitable as the reflection filler, constitute low radiative transfer layer with the film forming base-material, can effectively cut off the transmission of heat.Heat reflectivity can reach 85%.This thin layer heat insulating reflecting coating and the compound use of porous material can be used for different places applications such as buildings, car and boat, petrochemical industry oil tank equipment, grain depot, freezer, freight container, pipeline.
There is following problem mostly in prior art:
1 adopts solvent based coating, unfavorable for environmental protection;
2 used vacuum micro-balls can not disperse in system fully, thickening, stratified phenomenon occur at lay up period;
Though 3 have added heat insulation material, but heat still increases in time and increases.
Summary of the invention:
The object of the present invention is to provide a kind of a kind of solar heat reflecting and heat insulating coating of being brushed at buildings and industrial storage tank outside surface.Utilize the characteristic of coating of the present invention, reduce the surface temperature of buildings or industrial storage tank, thereby and play effect of heat insulation and reduce internal temperature, further reduce the power consumption of refrigeration equipment, reach energy-conservation effect.
The invention provides a kind of reflective heat-insulation paint, wherein comprise according to the mass fraction:
70~80 parts in water;
85~100 parts of Rutile type Titanium Dioxides;
35~40 parts of cenospheres;
10~12 parts of far infrared ceramic powders;
6~10 parts of dispersion agents
230~250 parts of pure acrylate elastic emulsions.
The median size of wherein said cenosphere≤30 μ m, described far infrared ceramic powder median size≤40nm.
Wherein also comprise and be selected from following auxiliary material: antifreezing agent propylene glycol, film coalescence aid, defoamer, multifunctional assistant, thickening material, auxiliary rheological agents, mould inhibitor.
The present invention also provides the preparation technology of described reflective heat-insulation paint, comprises following processing step:
1) cenosphere pre-treatment: soak cenosphere with aluminum sulfate aqueous solution, furnishing pulpous state during immersion carries out the surface treatment of cenosphere;
2) far infrared ceramic powder is pre-dispersed: with far infrared ceramic powder, water, dispersion agent according to 10:2: 0.5 quality is mixed into slurry than high speed dispersion with far infrared ceramic powder;
3) water, dispersion agent are stirred with the speed of 200r/min, in whipping process, add titanium dioxide, speed is heightened 800r/min gradually, disperse about 10min;
4) pre-dispersed far infrared ceramic powder slurry is added stirring, speed still is 800r/min, disperses about 15min;
5) add pretreated cenosphere, speed is reduced to 400r/min, disperses about 10min;
6) emulsion is added stirring, speed is 400r/min, mixes about 5min;
7) discharging is weighed, packing.
Wherein before step 7) also in steps 6 ') add auxiliary rheological agents and regulate dope viscosity.
Also be added with antifreezing agent, defoamer in the described step 3);
Also be added with process white in the described step 4);
Also be added with film coalescence aid, mould inhibitor, multifunctional assistant, defoamer, thickening material in the described step 6).
The present invention possesses following characteristics:
1) select for use water as solvent, safety and environmental protection, and easy construction.
2) select pure acrylate elastic emulsion for use, ageing resistance is good, and it is smooth smooth to film, and the tensile strength of filming 1.4MPa films elongation at break more than 300%.The excellent extensibility of filming prevents the phenomenons such as causing cracking, disengaging of expanding with heat and contract with cold that climate change brings.
3) select outstanding Rutile type Titanium Dioxide for use, its superelevation refraction coefficient guarantees the photocatalytic coating film reflectivity more than 95%, and the heat reflectivity of filming is more than 85%.
4) select hollow tiny pearl for use, also reduce the weight of filming when guaranteeing coating thickness, its heat insulation temperature reaches more than 10 ℃.
5) select nano-scale far infrared ceramic powder for use, can the usable reflection solar infrared, and to the external irradiation heat of filming.
6) cenosphere carries out pre-treatment, guarantees better to be scattered in the water-based system, guarantees the coating package stability.
7) far infrared ceramic powder carries out pre-dispersedly, can disperse on the one hand to increase work efficiency easily in the coating preparation process, prevents the nano-powder reunion on the other hand and deposited phenomenon occurs.
Description of drawings:
Temperature before and after Fig. 1 asphalt water-proof coiled material face brushing coating of the present invention relatively
The temperature that Fig. 2 simulates before and after the storage tank brushing coating of the present invention compares
The temperature of Fig. 3 skin brushing coating of the present invention and common coating relatively
Embodiment
The present invention is further described below in conjunction with embodiment.The invention provides 3 embodiment, wherein fill a prescription and calculate with mass parts, and its action effect of description of drawings.
Embodiment 1
80 parts in water
6 parts of dispersion agent 731A
12 parts of antifreezing agent propylene glycol
100 parts of titanium dioxide r902s
30 parts in process white 800 orders
40 parts of cenosphere PQ6030
10 parts of far infrared ceramic powder 50nm
250 parts of emulsion SC138
8 parts of film coalescence aid texnol
3 parts of defoamer DF-01
4 parts of multifunctional assistant AMP-95
1.5 parts of thickening material TT-935
2.5 parts of auxiliary rheological agents RM-8W
0.5 part of mould inhibitor F-251
Preparation technology:
1) gets 40 parts of cenospheres, prepare 80 parts of 4% alum liquors, in whipping process, add cenosphere furnishing pulpous state, carry out the surface treatment of cenosphere, place stand-by after 12 hours.
2) far infrared ceramic powder, water, dispersion agent 731A are carried out high speed dispersion with the high speed sand mill with 2500r/min according to 10: 2: 0.5 mass ratio, far infrared ceramic powder is mixed into slurry.
3) water, dispersion agent, antifreezing agent, 2 parts of defoamers are joined respectively in the stirred pot, the speed stirring with 200r/min adds titanium dioxide in whipping process, speed is heightened 800r/min gradually, disperses 10min;
4) process white, far infrared ceramic powder slurry are joined respectively in the stirred pot, speed still is 800r/min, disperses 15min;
5) add the cenosphere of handling well as right descriptions 2, speed is reduced to 400r/min, disperses 10min;
6) emulsion, film coalescence aid, mould inhibitor, multifunctional assistant, residue defoamer, thickening material are joined stirred pot respectively, speed is 400r/min, mixes 5min;
7) add auxiliary rheological agents to stirred pot, regulate dope viscosity to KU value about 100.
8) discharging is weighed, packing.
Accompanying drawing 1 ground is a roof asphalt water-proof coiled material face, test period be summer from 9:30 to 16:30, the highest temperature was 37 ℃ at that time.Wherein 1 is brushing roof of the present invention, and 2 for not brushing roof of the present invention.Brush behind this coating 25 ℃ of the highest declines of roof temperature.
Embodiment 2
75 parts in water
10 parts of dispersion agent 731A
11 parts of antifreezing agent propylene glycol
85 parts of titanium dioxide r902s
40 parts in process white 800 orders
35 parts of cenosphere PQ603
12 parts of far infrared ceramic powder 50nm
230 parts of emulsion SC138
6 parts of film coalescence aid texnol
4 parts of defoamer DF-01
4 parts of multifunctional assistant AMP-95
1 part of thickening material TT-935
3 parts of auxiliary rheological agents RM-8W
1 part of mould inhibitor F-251
Preparation technology:
1) gets 35 parts of cenospheres, prepare 70 parts of 4% alum liquors, in whipping process, add cenosphere furnishing pulpous state, carry out the surface treatment of cenosphere, place stand-by after 12 hours.
2) far infrared ceramic powder, water, dispersion agent 731A are carried out high speed dispersion with the high speed sand mill with 2500r/min according to 10: 2: 0.5 mass ratio, far infrared ceramic powder is mixed into slurry.
3) water, dispersion agent, antifreezing agent, 2 parts of defoamers are joined respectively in the stirred pot, the speed stirring with 200r/min adds titanium dioxide in whipping process, speed is heightened 800r/min gradually, disperses 10min;
4) process white, far infrared ceramic powder slurry are joined respectively in the stirred pot, speed still is 800r/min, disperses 15min;
5) add the cenosphere of handling well as right descriptions 2, speed is reduced to 400r/min, disperses 10min;
6) emulsion, film coalescence aid, mould inhibitor, multifunctional assistant, residue defoamer, thickening material are joined stirred pot respectively, speed is 400r/min, mixes 5min;
7) add auxiliary rheological agents to stirred pot, regulate dope viscosity to KU value about 100.
8) discharging is weighed, packing.
Accompanying drawing 2 grounds are the simulation storage tank, and test period is 9:00 to 17:00 in summer, and the highest temperature was 37 ℃ at that time.1 is brushing storage tank internal temperature of the present invention, and 2 for not brushing storage tank internal temperature of the present invention.Two tank body temperature difference are up to 15 ℃.
Embodiment 3
70 parts in water
6 parts of dispersion agent 731A
10 parts of antifreezing agent propylene glycol
85 parts of titanium dioxide r902s
40 parts in process white 800 orders
40 parts of cenosphere PQ6030
12 parts of far infrared ceramic powder 50nm
230 parts of emulsion SC138
6 parts of film coalescence aid texnol
3 parts of defoamer DF-01
3 parts of multifunctional assistant AMP-95
1 part of thickening material TT-935
3 parts of auxiliary rheological agents RM-8W
1 part of mould inhibitor F-251
Preparation technology:
1) gets 40 parts of cenospheres, prepare 80 parts of 4% alum liquors, in whipping process, add cenosphere furnishing pulpous state, carry out the surface treatment of cenosphere, place stand-by after 12 hours.
2) far infrared ceramic powder, water, dispersion agent 731A are carried out high speed dispersion with the high speed sand mill with 2500r/min according to 10: 2: 0.5 mass ratio, far infrared ceramic powder is mixed into slurry.
3) water, dispersion agent, antifreezing agent, 2 parts of defoamers are joined respectively in the stirred pot, the speed stirring with 200r/min adds titanium dioxide in whipping process, speed is heightened 800r/min gradually, disperses 10min;
4) process white, far infrared ceramic powder slurry are joined respectively in the stirred pot, speed still is 800r/min, disperses 15min;
5) add the cenosphere of handling well as right descriptions 2, speed is reduced to 400r/min, disperses 10min;
6) emulsion, film coalescence aid, mould inhibitor, multifunctional assistant, residue defoamer, thickening material are joined stirred pot respectively, speed is 400r/min, mixes 5min;
7) add auxiliary rheological agents to stirred pot, regulate dope viscosity to KU value about 100.
8) discharging is weighed, packing.
Accompanying drawing 3 grounds are skin, and test period is 9:30 to 16:30 in summer, and the highest temperature was 37 ℃ at that time.1 is brushing exterior wall temperature of the present invention, the 2 exterior wall temperature for other coating of brushing.Two kinds of coating temperature difference are up to 12 ℃.

Claims (6)

1. reflective heat-insulation paint wherein comprises according to the mass fraction:
70~80 parts in water;
85~100 parts of Rutile type Titanium Dioxides;
35~40 parts of cenospheres;
10~12 parts of far infrared ceramic powders;
6~10 parts of dispersion agents;
230~250 parts of pure acrylate elastic emulsions.
2. reflective heat-insulation paint as claimed in claim 1, the median size of wherein said cenosphere≤30 μ m, described far infrared ceramic powder median size≤40nm.
3. reflective heat-insulation paint as claimed in claim 1 or 2 wherein also comprises being selected from following auxiliary material: antifreezing agent propylene glycol, film coalescence aid, defoamer, multifunctional assistant, thickening material, auxiliary rheological agents, mould inhibitor.
4. the preparation technology of reflective heat-insulation paint according to claim 1 comprises following processing step:
1) cenosphere pre-treatment: soak cenosphere with aluminum sulfate aqueous solution, furnishing pulpous state during immersion carries out the surface treatment of cenosphere;
2) far infrared ceramic powder is pre-dispersed: with far infrared ceramic powder, water, dispersion agent according to 10:2: 0.5 quality is mixed into slurry than high speed dispersion with far infrared ceramic powder;
3) water, dispersion agent are stirred with the speed of 200r/min, in whipping process, add titanium dioxide, speed is heightened 800r/min gradually, disperse about 10min;
4) pre-dispersed far infrared ceramic powder slurry is added stirring, speed still is 800r/min, disperses about 15min;
5) add pretreated cenosphere, speed is reduced to 400r/min, disperses about 10min;
6) emulsion is added stirring, speed is 400r/min, mixes about 5min;
7) discharging is weighed, packing.
5. preparation technology as claimed in claim 4 wherein also had step 6) to add auxiliary rheological agents before step 7) and regulates dope viscosity.
6. as claim 4 or 5 described preparation technologies, wherein:
Also be added with antifreezing agent, defoamer in the described step 3);
Also be added with process white in the described step 4);
Also be added with film coalescence aid, mould inhibitor, multifunctional assistant, defoamer, thickening material in the described step 6).
CN200910009483A 2009-02-26 2009-02-26 Reflecting thermal insulating paint Pending CN101818013A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910009483A CN101818013A (en) 2009-02-26 2009-02-26 Reflecting thermal insulating paint

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Application Number Priority Date Filing Date Title
CN200910009483A CN101818013A (en) 2009-02-26 2009-02-26 Reflecting thermal insulating paint

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CN101818013A true CN101818013A (en) 2010-09-01

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229772A (en) * 2011-06-20 2011-11-02 厦门固克涂料集团有限公司 Elastic texture coating with heat insulation function and preparation method of elastic texture coating
CN103725183A (en) * 2013-12-27 2014-04-16 三棵树涂料股份有限公司 Two-component oil-based curable coating for storage tank and preparation method thereof
CN103881501A (en) * 2014-04-08 2014-06-25 佛山市顺德区派兰涂料有限公司 Latex paint and preparation method thereof
CN104497741A (en) * 2014-11-19 2015-04-08 江苏丰彩新型建材有限公司 Building energy-saving coating and its preparation method
CN104497881A (en) * 2014-12-03 2015-04-08 江苏丽高博能建筑节能有限公司 Water-based reflective insulation stone paint and manufacturing method thereof
CN105542597A (en) * 2015-12-22 2016-05-04 三棵树涂料股份有限公司 Heat-reflection thermal-insulation high-lightness base material and preparation method thereof
CN106833227A (en) * 2017-01-20 2017-06-13 四川大学 A kind of aqueous compound insulating moulding coating and preparation method thereof
CN107216758A (en) * 2017-06-21 2017-09-29 徐州尚铭装饰材料有限公司 A kind of cross-linking reaction type water-water reflective heat-insulation paint
CN108314902A (en) * 2018-03-12 2018-07-24 黄河防水材料股份有限公司 A kind of preparation method of self-adhered polymer modified bitumen waterproofing membrane
CN108442414A (en) * 2018-03-12 2018-08-24 黄河防水材料股份有限公司 A kind of preparation method of elastomer modified asphalt waterproof roll

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229772A (en) * 2011-06-20 2011-11-02 厦门固克涂料集团有限公司 Elastic texture coating with heat insulation function and preparation method of elastic texture coating
CN103725183A (en) * 2013-12-27 2014-04-16 三棵树涂料股份有限公司 Two-component oil-based curable coating for storage tank and preparation method thereof
CN103725183B (en) * 2013-12-27 2016-08-17 三棵树涂料股份有限公司 Can be used for the bi-component oiliness of storage tank coating material solidified and preparation method thereof
CN103881501A (en) * 2014-04-08 2014-06-25 佛山市顺德区派兰涂料有限公司 Latex paint and preparation method thereof
CN104497741A (en) * 2014-11-19 2015-04-08 江苏丰彩新型建材有限公司 Building energy-saving coating and its preparation method
CN104497881A (en) * 2014-12-03 2015-04-08 江苏丽高博能建筑节能有限公司 Water-based reflective insulation stone paint and manufacturing method thereof
CN105542597A (en) * 2015-12-22 2016-05-04 三棵树涂料股份有限公司 Heat-reflection thermal-insulation high-lightness base material and preparation method thereof
CN106833227A (en) * 2017-01-20 2017-06-13 四川大学 A kind of aqueous compound insulating moulding coating and preparation method thereof
CN107216758A (en) * 2017-06-21 2017-09-29 徐州尚铭装饰材料有限公司 A kind of cross-linking reaction type water-water reflective heat-insulation paint
CN108314902A (en) * 2018-03-12 2018-07-24 黄河防水材料股份有限公司 A kind of preparation method of self-adhered polymer modified bitumen waterproofing membrane
CN108442414A (en) * 2018-03-12 2018-08-24 黄河防水材料股份有限公司 A kind of preparation method of elastomer modified asphalt waterproof roll

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: XUZHOU WONIUSHAN ADVANCED WATERPROOF MATERIALS CO.

Effective date: 20121205

C41 Transfer of patent application or patent right or utility model
C53 Correction of patent for invention or patent application
CB03 Change of inventor or designer information

Inventor after: Tian Fenglan

Inventor after: Duan Wenfeng

Inventor after: Wang Huiyuan

Inventor after: Li Wanglong

Inventor before: Tian Fenglan

Inventor before: Duan Wenfeng

Inventor before: Wang Huiyuan

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: TIAN FENGLAN DUAN WENFENG WANG HUIYUAN TO: TIAN FENGLAN DUAN WENFENG WANG HUIYUAN LI WANGLONG

Free format text: CORRECT: ADDRESS; FROM: 100025 CHAOYANG, BEIJING TO: 100123 CHAOYANG, BEIJING

TA01 Transfer of patent application right

Effective date of registration: 20121205

Address after: 100123 Beijing, Gaobeidian, Kang Kang home district, building 4, building No.

Applicant after: Beijing Oriental Yuhong Waterproof Technology Co., Ltd.

Applicant after: Xuzhou Woniushan New Waterproof Material Co., Ltd.

Applicant after: Huizhou Dongfang Yuhong Building Materials Co., Ltd.

Address before: 100025, Beijing, Chaoyang District Gaobeidian Kang homes District No. 4 Building

Applicant before: Beijing Oriental Yuhong Waterproof Technology Co., Ltd.

C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20100901