CN105482709A - Elastic contamination resisting solar heat reflection insulation coating and preparing method thereof - Google Patents
Elastic contamination resisting solar heat reflection insulation coating and preparing method thereof Download PDFInfo
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- CN105482709A CN105482709A CN201510943709.XA CN201510943709A CN105482709A CN 105482709 A CN105482709 A CN 105482709A CN 201510943709 A CN201510943709 A CN 201510943709A CN 105482709 A CN105482709 A CN 105482709A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Abstract
The invention relates to exterior architectural coatings, in particular to an elastic contamination resisting solar heat reflection insulation coating and a preparing method thereof. The elastic contamination resisting solar heat reflection insulation coating is prepared from, by weight, 1.15-19.6 parts of water, 0.2-0.4 part of hydroxyethyl cellulose, 0.15-0.2 part of PH modifier, 0.4-0.7 part of water-based dispersant, 0.3-0.5 part of water-based wetting agent, 0.2-0.3 part of sterilizing agent, 0.5-0.6 part of defoamer, 6-8 parts of ordinary titanium dioxide, 10-12 parts of infrared reflection pigment, 7-8 parts of precipitated barium sulphate, 8-10 parts of calcium carbonate, 3-6 parts of hollow microsphere, 33-35 parts of elastic emulsion, 4-5 parts of non-transparent polymer, 0.5-1 part of coalescing agent, 1.0-1.2 parts of antifreezing agent, 0.2-0.5 part of water-based contamination resisting additive, 0.2-0.3 part of preservative, 0.2-0.4 part of thickener and 0.1-0.2 part of flatting agent. By the adoption of the elastic contamination resisting solar heat reflection insulation coating and the preparing method thereof, cleanness of a wall can be maintained, the load on the wall can be reduced, and completeness of a paint film can be maintained.
Description
Technical field
The present invention relates to a kind of outer wall building coating, be in particular a kind of elasticity stain resistant solar heat reflecting and heat insulating coating and preparation method thereof.
Background technology
Along with global warming, ozonosphere is destroyed, make the irradiation of sunlight to buildings stronger, when solar irradiation is mapped to external surface of buildings, the energy of sunlight is absorbed by buildings and is transmitted to interior of building, what internal space can be made to become after the temperature of the inside is raised is uncomfortable, the burden simultaneously strengthening air-conditioning system improves energy consumption, add the quantity discharged of carbonic acid gas and greenhouse gases, cause a hidden trouble to the safety of the inhabitation of the mankind and installations and facilities, in order to prevent accident risks occur and for bring comfortable living environment to the mankind, there is reflective insulation, hide minute crack, the functional paints such as stain resistant arise at the historic moment, become human living life active demand, reflective insulation material traditional at present exists increases body of wall heavy burden, involve great expense, ornamental difference, reflective insulation persistence difference and the shortcoming such as production process is wayward, be difficult to meet the persistent requirement of energy-conserving and environment-protective.
Summary of the invention
The object of the invention is to: a kind of elasticity stain resistant solar heat reflecting and heat insulating coating and preparation method thereof is provided, the maintenance metope that it can be lasting cleans, alleviate body of wall and bear a heavy burden and under low temperature, still can keep the integrity of paint film.
The present invention is achieved through the following technical solutions: a kind of elasticity stain resistant solar heat reflecting and heat insulating coating, is characterized in that: the preparation of raw material primarily of following weight parts forms:
In order to better implement this programme, also provide following prioritization scheme:
Further, described infrared reflecting paint is the ALTIRIS800 infrared reflecting paint that Hensel steps production.Further, described tiny balloon major ingredient is silicon-dioxide, aluminum oxide, zirconium white, magnesium oxide and water glass.
A kind of elasticity stain resistant solar heat reflecting and heat insulating coating preparation method, is characterized in that: comprise following steps:
Step one: 15.15-19.6 part water is joined in dispersion cylinder, by speed adjustment to 400-800r/min, then continue in dispersion cylinder, add 0.2-0.4 part Natvosol and 0.15-0.2 part PH conditioning agent, under 400-800r/min rotating speed, disperse 3-5min;
Step 2: after the mixture thickness in dispersion cylinder, continue again in dispersion cylinder, add 0.4-0.7 part aqueous dispersant, 0.3-0.5 part aqueous wetting agent, 0.2-0.3 part sterilant and 0.5-0.6 part defoamer, under 400-800r/min rotating speed, disperse 5-10min;
Step 3: after the mixture in dispersion cylinder mixes, after continuing to add 6-8 part ordinary titanium powder, 10-12 part infrared reflecting paint, 7-8 part process white and 8-10 part Paris white again in dispersion cylinder, under this rotating speed, disperse 15-20min after rotating speed being increased to 1500-2000r/min, continue when fineness≤60 μm of mixture in dispersion cylinder to perform next step;
Step 4: by adjustment of rotational speed to 600-800r/min, after then continuing to add 3-6 part cenosphere, 4-5 part Opacifying polymers, 33-35 part elastic emulsion, 0.5-1 part film coalescence aid, 1-1.2 part frostproofer, 0.2-0.5 part aqueous contamination resistant auxiliary agent, 0.2-0.3 part sanitas, 0.2-0.4 part thickening material and 0.1-0.2 part flow agent in dispersion cylinder, the mixture obtained after disperseing 10-15min to mix under 600-800r/min rotating speed is elasticity stain resistant solar heat reflecting and heat insulating coating.
Technology comparatively, beneficial effect of the present invention is:
1. the present invention adopts the good elastic emulsion of anti-pollution characteristic to be arranged in pairs or groups by scientific and reasonable powder, promote the compactness of paint film and anti-after-tackiness, and adding water-based resistant auxiliary agent in system maintains this performance muchly simultaneously, thus the present invention is applied in, and maintenance metope that outdoor can be lasting cleans, thus make the reflective insulation effect of itself more effectively lasting;
2. have employed the excellent elastic emulsion of cryogenic stretching performance in system of the present invention, when body of wall is subject to the cold and hot impact of outside temperature, when body of wall appearance contraction and hair line, film is subject to tensile deformation, paint film also can not ftracture, thus still can completely keeps original decorative effect, gives full play to the function of its protection body of wall;
3. traditional body of wall reflective heat-insulation paint adopts sheet material, stone material and matrix material usually, the comparatively large and heavier-weight of its volume, and present invention employs the lighter tiny balloon of quality and instead of traditional material, not only reach heat insulation effect but also alleviate the heavy burden of body of wall, save cost, also utilize the efficient reflective insulation effect of infrared reflecting paint simultaneously, reach and reduce metope to the absorption of heat, reduce room temp and reduce the effect of air conditioning energy consumption, energy-conserving and environment-protective;
4. the present invention is nonpoisonous and tasteless, safety and environmental protection.
Embodiment
Below in conjunction with embodiment, the present invention is elaborated:
Embodiment 1:
The present embodiment is also prepared from as follows primarily of the raw material of following weight parts:
Step one: join in dispersion cylinder by 19.6 parts of water, by speed adjustment to 800r/min, then continues in dispersion cylinder, add 0.4 part of Natvosol and 0.2 part of PH conditioning agent, under 800r/min rotating speed, disperses 5min;
Step 2: after the mixture thickness in dispersion cylinder, then continue in dispersion cylinder, add 0.7 part of aqueous dispersant, 0.5 part of aqueous wetting agent, 0.2 part of sterilant and 0.5 part of defoamer, under 800r/min rotating speed, disperse 10min;
Step 3: after the mixture in dispersion cylinder mixes, after continuing to add 6 parts of ordinary titanium powder, 12 parts of infrared reflecting paints, 7 parts of process whites and 10 parts of Paris whites again in dispersion cylinder, under this rotating speed, disperse 20min after rotating speed being increased to 2000r/min, continue when fineness≤60 μm of mixture in dispersion cylinder to perform next step;
Step 4: by adjustment of rotational speed to 800r/min, after then continuing to add 3 parts of cenospheres, 4 parts of Opacifying polymers, 33 parts of elastic emulsions, 0.5 part of film coalescence aid, 1 part of frostproofer, 0.5 part of aqueous contamination resistant auxiliary agent, 0.3 part of sanitas, 0.4 part of thickening material and 0.2 part of flow agent in dispersion cylinder, the mixture obtained after disperseing 15min to mix under 800r/min rotating speed is elasticity stain resistant solar heat reflecting and heat insulating coating.
Embodiment 2:
The present embodiment is also prepared from as follows primarily of the raw material of following weight parts:
Step one: join in dispersion cylinder by 16.45 parts of water, by speed adjustment to 600r/min, then continues in dispersion cylinder, add 0.3 part of Natvosol and 0.2 part of PH conditioning agent, under 600r/min rotating speed, disperses 4min;
Step 2: after the mixture thickness in dispersion cylinder, then continue in dispersion cylinder, add 0.6 part of aqueous dispersant, 0.4 part of aqueous wetting agent, 0.3 part of sterilant and 0.6 part of defoamer, under 600r/min rotating speed, disperse 8min;
Step 3: after the mixture in dispersion cylinder mixes, after continuing to add 7 parts of ordinary titanium powder, 11 parts of infrared reflecting paints, 8 parts of process whites and 9 parts of Paris whites again in dispersion cylinder, under this rotating speed, disperse 18min after rotating speed being increased to 1800r/min, continue when fineness≤60 μm of mixture in dispersion cylinder to perform next step;
Step 4: by adjustment of rotational speed to 700r/min, after then continuing to add 4 parts of cenospheres, 5 parts of Opacifying polymers, 34 parts of elastic emulsions, 1 part of film coalescence aid, 1 part of frostproofer, 0.4 part of aqueous contamination resistant auxiliary agent, 0.25 part of sanitas, 0.3 part of thickening material and 0.2 part of flow agent in dispersion cylinder, the mixture obtained after disperseing 13min to mix under 700r/min rotating speed is elasticity stain resistant solar heat reflecting and heat insulating coating.
Embodiment 3:
The present embodiment is also prepared from as follows primarily of the raw material of following weight parts:
Step one: join in dispersion cylinder by 15.15 parts of water, by speed adjustment to 400r/min, then continues in dispersion cylinder, add 0.2 part of Natvosol and 0.15 part of PH conditioning agent, under 400r/min rotating speed, disperses 3min;
Step 2: after the mixture thickness in dispersion cylinder, then continue in dispersion cylinder, add 0.4 part of aqueous dispersant, 0.3 part of aqueous wetting agent, 0.3 part of sterilant and 0.6 part of defoamer, under 400r/min rotating speed, disperse 5min;
Step 3: after the mixture in dispersion cylinder mixes, after continuing to add 8 parts of ordinary titanium powder, 10 parts of infrared reflecting paints, 8 parts of process whites and 8 parts of Paris whites again in dispersion cylinder, under this rotating speed, disperse 15min after rotating speed being increased to 1500r/min, continue when fineness≤60 μm of mixture in dispersion cylinder to perform next step;
Step 4: by adjustment of rotational speed to 600r/min, after then continuing to add 6 parts of cenospheres, 5 parts of Opacifying polymers, 35 parts of elastic emulsions, 1 part of film coalescence aid, 1.2 parts of frostproofers, 0.2 part of aqueous contamination resistant auxiliary agent, 0.2 part of sanitas, 0.2 part of thickening material and 0.1 part of flow agent in dispersion cylinder, the mixture obtained after disperseing 10min to mix under 600r/min rotating speed is elasticity stain resistant solar heat reflecting and heat insulating coating.
Above in each embodiment:
Described hydromining ordinary tap water;
The 250HBR that described Natvosol adopts the sub-dragon that collapses to produce;
The AMP95 that described PH conditioning agent adopts Tao Shi to produce;
The CA-2500 that described aqueous dispersant adopts ROHM AND HAAS to produce;
The SN-WET996 that described aqueous wetting agent adopts Sheng Nuopuke to produce;
Described sterilant adopts the ZOE-T of Qi Chemical Manufacture difficult to understand;
Described defoamer adopts Spain all risk insurance chemical industry PA700 and Blackburn CF246;
Described ordinary titanium powder adopts Du Pont R706;
Described functional type titanium dioxide is the ALTIRIS800 infrared reflecting paint that Hensel steps production;
Described process white adopts the industrial 20HB of powder body;
Described calcium carbonate adopts 1083 of agriculture-countryside-farmer's production;
The 461WE20d36 that described tiny balloon adopts Akzo Nobel to produce;
Described elastic emulsion is the elastic emulsion 2468M that Tao Shi produces;
The op-62 that described Opacifying polymers adopts ROHM AND HAAS to produce;
The Texanol that described film coalescence aid adopts Yi Shiman to produce;
Described frostproofer adopts the propylene glycol of Depew, Shandong Chemical Manufacture;
Described aqueous contamination resistant auxiliary agent adopts the polydimethylsiloxane of safe rich Chemical Manufacture;
The RS that described sanitas adopts Troy to produce;
The RM8W that described thickening material adopts ROHM AND HAAS to produce;
Described flow agent adopts the RM2020 produced.
Infrared reflecting paint is by changing the crystallographic dimension of rutile titanium dioxide, and ALTIRIS infrared reflecting paint is designed to provide high infrared reflection rate, and by improved treatment and coated, makes this pigment have high weathering resistance.And selected ALTIRIS800 pigment can produce the ratio of best near infrared/visible reflectance in above each embodiment, reflecting properties of the present invention is made to reach best.
Cenosphere outward appearance is canescence, is a kind of powder body material of loose, good fluidity.Greyish white hollow glass micropearl feature is: sound-proofing, thermal insulation, and flame retardant resistance, electrical insulating property are good, and density is little, and oil absorbency is low, and intensity is high.
In each embodiment of elasticity stain resistant solar heat reflecting and heat insulating coating prepared by the present invention, measured property indices and technical indicator are as following table;
Tensile strength, elongation at tear tests data that elasticity stain resistant solar heat reflecting and heat insulating coating prepared by table one-the present invention records according to exterior coating tensile strength, elongation at tear tests method in JG/T172-2014 " elastic building paint ":
Can as apparent from table one, the exterior wall tensile strength of each embodiment of elasticity stain resistant solar heat reflecting and heat insulating coating of the present invention and elongation at break all more than the technical indicator of exterior wall tensile strength in JG/T172-2014 " elastic building paint " and elongation at break, even if hide trickle ability also remaining intact compared with paint film under low temperature environment.
The contamination resistance testing data that elasticity stain resistant solar heat reflecting and heat insulating coating prepared by table two-the present invention records according to exterior wall paint coatings contamination resistance test method in GB/T9780-2013 " building coating coating contamination resistance testing method "
Can as apparent from table two, the contaminated resistance of each embodiment of elasticity stain resistant solar heat reflecting and heat insulating coating of the present invention is all more than the salable product requirement of the national standard in GB/T9780-2013 " building coating coating contamination resistance testing method ", stain resistant is all less than 15%, make film keep lasting clean, the reflective insulation performance being more conducive to film keeps for a long time.
Elasticity stain resistant solar heat reflecting and heat insulating coating prepared by table three-the present invention is according to the testing data of aqueous coating test gained in JG/T1040-2007 " heat-reflecting insulating coating for outer surface of building "
As apparent from table three can, the heat insulating reflecting performance of each embodiment of elasticity stain resistant solar heat reflecting and heat insulating coating of the present invention fullys meet the technical indicator in JG/T1040-2007 " heat-reflecting insulating coating for outer surface of building " standard required by aqueous coating.
Although the present invention adopts specific embodiment and alternative thereof illustrate to the present invention and illustrate, only to should be appreciated that otherwise the variations and modifications deviated from scope of the present invention all can be implemented.Therefore, except being to be understood that the restriction of claim except being enclosed and condition of equivalent thereof, the present invention is not by the restriction of going up in all senses.
Claims (5)
1. an elasticity stain resistant solar heat reflecting and heat insulating coating, is characterized in that: the preparation of raw material primarily of following weight parts forms:
2. elasticity stain resistant solar heat reflecting and heat insulating coating according to claim 1, is characterized in that: described infrared reflecting paint is the ALTIRIS800 infrared reflecting paint that Hensel steps production.
3. elasticity stain resistant solar heat reflecting and heat insulating coating according to claim 1, is characterized in that: described tiny balloon major ingredient is silicon-dioxide, aluminum oxide, zirconium white, magnesium oxide and water glass.
4. elasticity stain resistant solar heat reflecting and heat insulating coating according to claim 1, is characterized in that:
Described Natvosol is the water dissolvable ether of cellulose of non-ionic type;
Described PH conditioning agent is 2-amino-2-methyl-1-propanol;
Described aqueous dispersant is hydrophobically modified ammonium polyacrylate dipersant;
Described aqueous wetting agent is poly-hydroxyalkyl ether nonionic type wetting agent;
Described sterilant is Zinc Pyrithione;
Described defoamer comprises non-ionic type mineral oil antifoam agent and silicone based defoamer;
Described ordinary titanium powder is Rutile type Titanium Dioxide;
Described process white employing average particle size range is 2.2-3.8 μm, purity is 97%, whiteness scope is 93-95, oil number scope is 9-11g/100g, and density range is the blaue fixe of 4.4-4.6g/cm3;
Described calcium carbonate is 800 object Paris whites;
Described elastic emulsion is the elastic emulsion 2468M that Tao Shi produces;
Described Opacifying polymers is the hollow beads polymkeric substance closed by vinylbenzene and acrylic ester copolymerization;
Described film coalescence aid is 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate;
Described frostproofer is 1,2-PD;
The main component of described aqueous contamination resistant auxiliary agent is polydimethylsiloxane;
Described thickening material is non-ionic type modified polyurethane RM-8W;
Described flow agent is the non-ionic type association type urethane RM-2020 of hydrophobically modified.
5. a kind of elasticity stain resistant solar heat reflecting and heat insulating coating preparation method according to claim 1-4 any one, is characterized in that: comprise following steps:
Step one: 15.15-19.6 part water is joined in dispersion cylinder, by speed adjustment to 400-800r/min, then continue in dispersion cylinder, add 0.2-0.4 part Natvosol and 0.15-0.2 part PH conditioning agent, under 400-800r/min rotating speed, disperse 3-5min;
Step 2: after the mixture thickness in dispersion cylinder, continue again in dispersion cylinder, add 0.4-0.7 part aqueous dispersant, 0.3-0.5 part aqueous wetting agent, 0.2-0.3 part sterilant and 0.5-0.6 part defoamer, under 400-800r/min rotating speed, disperse 5-10min;
Step 3: after the mixture in dispersion cylinder mixes, after continuing to add 6-8 part ordinary titanium powder, 10-12 part infrared reflecting paint, 7-8 part process white and 8-10 part Paris white again in dispersion cylinder, under this rotating speed, disperse 15-20min after rotating speed being increased to 1500-2000r/min, continue when fineness≤60 μm of mixture in dispersion cylinder to perform next step;
Step 4: by adjustment of rotational speed to 600-800r/min, after then continuing to add 3-6 part cenosphere, 4-5 part Opacifying polymers, 33-35 part elastic emulsion, 0.5-1 part film coalescence aid, 1-1.2 part frostproofer, 0.2-0.5 part aqueous contamination resistant auxiliary agent, 0.2-0.3 part sanitas, 0.2-0.4 part thickening material and 0.1-0.2 part flow agent in dispersion cylinder, the mixture obtained after disperseing 10-15min to mix under 600-800r/min rotating speed is elasticity stain resistant solar heat reflecting and heat insulating coating.
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| CN201510943709.XA CN105482709A (en) | 2015-12-16 | 2015-12-16 | Elastic contamination resisting solar heat reflection insulation coating and preparing method thereof |
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| CN201510943709.XA CN105482709A (en) | 2015-12-16 | 2015-12-16 | Elastic contamination resisting solar heat reflection insulation coating and preparing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366737A (en) * | 2016-08-26 | 2017-02-01 | 枣阳市恒泰化工有限公司 | Toxin-free micro-aroma type waterproof latex paint and preparation method |
| CN106700796A (en) * | 2016-12-29 | 2017-05-24 | 三棵树涂料股份有限公司 | High-pollution-resistance matte external-wall elastic paint and preparation method thereof |
| CN107987655A (en) * | 2017-12-23 | 2018-05-04 | 湖南辰砾新材料有限公司 | A kind of reflective heat-insulation paint |
| CN112225493A (en) * | 2020-10-15 | 2021-01-15 | 三棵树(上海)新材料研究有限公司 | Super-weather-resistant infrared reflection heat insulation inorganic coating and preparation method thereof |
| CN113185908A (en) * | 2021-06-18 | 2021-07-30 | 河北三棵树涂料有限公司 | High-performance reflective heat-insulation water-based exterior wall elastic coating and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366737A (en) * | 2016-08-26 | 2017-02-01 | 枣阳市恒泰化工有限公司 | Toxin-free micro-aroma type waterproof latex paint and preparation method |
| CN106700796A (en) * | 2016-12-29 | 2017-05-24 | 三棵树涂料股份有限公司 | High-pollution-resistance matte external-wall elastic paint and preparation method thereof |
| CN107987655A (en) * | 2017-12-23 | 2018-05-04 | 湖南辰砾新材料有限公司 | A kind of reflective heat-insulation paint |
| CN107987655B (en) * | 2017-12-23 | 2019-12-03 | 厦门卓施特建材有限公司 | A kind of reflective heat-insulation paint |
| CN112225493A (en) * | 2020-10-15 | 2021-01-15 | 三棵树(上海)新材料研究有限公司 | Super-weather-resistant infrared reflection heat insulation inorganic coating and preparation method thereof |
| CN113185908A (en) * | 2021-06-18 | 2021-07-30 | 河北三棵树涂料有限公司 | High-performance reflective heat-insulation water-based exterior wall elastic coating and preparation method thereof |
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