CN105802415A - Reflective heat-insulating coating - Google Patents

Reflective heat-insulating coating Download PDF

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Publication number
CN105802415A
CN105802415A CN201610247983.8A CN201610247983A CN105802415A CN 105802415 A CN105802415 A CN 105802415A CN 201610247983 A CN201610247983 A CN 201610247983A CN 105802415 A CN105802415 A CN 105802415A
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CN
China
Prior art keywords
water
coating
heat
agent
reflective heat
Prior art date
Application number
CN201610247983.8A
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Chinese (zh)
Inventor
刘齐
沈明
刘川
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安徽巨力新型环保材料有限公司
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Priority to CN201610247983.8A priority Critical patent/CN105802415A/en
Publication of CN105802415A publication Critical patent/CN105802415A/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • C08K7/18Solid spheres inorganic
    • C08K7/20Glass
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses a reflective heat-insulating coating. The reflective heat-insulating coating is characterized by being mainly prepared from, by mass, water 20-21.5%, a functional additive 3-4.5%, glass beads 9-11%, a packing 7.5-8.5%, elastic silicon-acrylate emulsion 33-37%, an anti-freezing agent 1-2% and titanium dioxide 20-21.5%. The reflective heat-insulating coating has the advantages of having good elasticity, strength and stain-resistant performance, improving the stain-resistant self-cleaning performance of the heat-insulating coating, also improving the light and head reflectivity of the coating, meanwhile having a low heat-insulating coefficient, enhancing the heat radiation performance, having a dense surface, meeting the superior product requirements on the aspects of leveling properties, covering properties and ageing resistance, having good construction performance, improving the waterproofness and water resistance of the coating by the added water-based and non-soluble siloxane modified organic silicone emulsion and keeping good air permeability to make the coating denser, flatter and smoother.

Description

A kind of reflective heat-insulation paint
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of reflective heat-insulation paint.
Background technology
China is energy resource consumption big country, and along with the economic sustained and rapid development of China, building energy consumption accounts for the 30% of Chinese society total energy consumption, and building energy conservation form is urgent.The insulation of architectural exterior-protecting construction is one of key technology realizing building energy conservation, the heat insulation measure of architectural exterior-protecting construction is essentially divided into several aspects such as external wall outer insulation, exterior wall insulating gentleness wall self-insulation, and current China takes as the leading factor with External Thermal Insulation Technology for External.The external wall heat insulation system being widely used at present is mainly external application warming plate thin-coat plaster mode, insulation material I be styrofoam and rock cotton board, although having good heat insulation effect, but there is the shortcomings such as complicated construction technique, integrated cost is high, surface material construction quality is difficult to ensure that in it.
China's each department climate difference is bigger, the energy-saving design in construction of different regions requires difference, GB50176-1993 " code for thermal design of civil buildings " explicitly points out, designing requirement to hot summer and warm winter region is " must fully meet anti-heat request in summer; generally can be left out Winter protection ", in the industry " north is in that insulation, south emphasis are heat insulation " is built consensus.In southern area, the ratio that indoor/outdoor temperature-difference heat transfer accounts in whole heat transfer is little, and the heat effect that solar radiation produces is to cause the main cause of Summer Indoor Thermal.Insulating moulding coating can reflected solar radiation heat, thus reducing the heat of indoor, effectively reduce air conditioner refrigerating energy consumption, numerous research confirms the insulating moulding coating facilitation to building energy conservation.
Building system, as the important component part of building energy conservation system, is of great importance by insulating moulding coating.Insulating mechanism according to insulating moulding coating is different with heat insulation mode, is classified as isolation-type, reflection-type, Radiation Heat-insulated Paint, and the Insulating mechanism of this three classes insulating moulding coating is different, and application scenario and obtained effect are also different.Relatively good many organic exterior wall heat-preserving systems that China does these years, but along with No. 49 civilian appearance of the Ministry of Public Security, prohibitting the use of the organic insulation materials such as various inflammable styrofoam, nearly one or two years is all finding the external-wall heat-insulation material substituting organic heat-insulating researching and developing various high-qualitys.
Summary of the invention
The invention aims to the shortcoming solving exist in prior art, and a kind of reflective heat-insulation paint proposed.
To achieve these goals, present invention employs following technical scheme:
A kind of reflective heat-insulation paint, it is characterized in that, by weight/mass percentage composition, it specifically includes that water 20~21.5%, function additive 3~4.5%, glass microballoon 9~11%, filler 7.5~8.5%, silicon acrylate elastic emulsion 33~37%, antifreezing agent 1~2%, titanium dioxide 20~21.5%;
Described function additive includes dispersant 19~20%, defoamer 4.5~5.5%, thickening agent 14~15%, antifungus agent 4.5~5.5%, coalescents 36~37%, water-repelling agent 19~20%;
Described filler includes cordierite powder 35.5~37.5%, sericite in powder 31~32.5%, triple superphosphate 31~32.5%.
Preferably, described coating includes by weight/mass percentage composition: water 20.8%, function additive 3.1%, glass microballoon 10%, filler 7.7%, silicon acrylate elastic emulsion 36%, antifreezing agent 1.6%, titanium dioxide 20.8%.
Preferably, described coating includes by weight/mass percentage composition: water 21%, function additive 4.3%, glass microballoon 10%, filler 8%, silicon acrylate elastic emulsion 34%, antifreezing agent 1.7%, titanium dioxide 21%.
Preferably, described function additive includes dispersant 19.5%, defoamer 4.9%, thickening agent 14.6%, antifungus agent 4.9%, coalescents 36.6%, water-repelling agent 19.5% by mass percentage.
Preferably, described filler includes cordierite powder 36.8%, sericite in powder 31.6%, triple superphosphate 31.6% by mass percentage.
Preferably, described water-repelling agent adopts water nano water-repelling agent.
It is an advantage of the current invention that: a kind of reflective heat-insulation paint provided by the present invention, not only there is good elasticity, the performance of intensity and stain resistant, improve the stain resistant self-cleaning property of insulating moulding coating, and improve the photothermal reflectance rate of coating, there is low thermal conductivity simultaneously and enhance heat-radiating properties, the surface compact of this insulating moulding coating, coating levelability, opacifying property, resistance to ag(e)ing is attained by high-class product requirement, there is workability good, the aqueous increased in this coating, silicone-modified organic silicon emulsion without dissolubility, strengthen the water proofing property of coating, resistance to water, and keep good breathability, make film finer and close, smooth, smooth.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearly understand, the present invention is further elaborated.Should be appreciated that specific embodiment described herein is only in order to explain the present invention, is not intended to limit the present invention.
Embodiment one, a kind of reflective heat-insulation paint provided by the invention, it is characterized in that, by weight/mass percentage composition, it specifically includes that water 20~21.5%, function additive 3~4.5%, glass microballoon 9~11%, filler 7.5~8.5%, silicon acrylate elastic emulsion 33~37%, antifreezing agent 1~2%, titanium dioxide 20~21.5%.
Described function additive includes dispersant 19~20%, defoamer 4.5~5.5%, thickening agent 14~15%, antifungus agent 4.5~5.5%, coalescents 36~37%, water-repelling agent 19~20%, and described water-repelling agent adopts water nano water-repelling agent.
Described filler includes cordierite powder 35.5~37.5%, sericite in powder 31~32.5%, triple superphosphate 31~32.5%.
Described in embodiment two, embodiment one, reflective heat-insulation paint component by weight/mass percentage composition ratio is: water 20.8%, function additive 3.1%, glass microballoon 10%, filler 7.7%, silicon acrylate elastic emulsion 36%, antifreezing agent 1.6%, titanium dioxide 20.8%.
Described function additive includes dispersant 19.5%, defoamer 4.9%, thickening agent 14.6%, antifungus agent 4.9%, coalescents 36.6%, water-repelling agent 19.5% by mass percentage.
Described in embodiment three, embodiment one, reflective heat-insulation paint component by weight/mass percentage composition ratio is: described coating includes by weight/mass percentage composition: water 21%, function additive 4.3%, glass microballoon 10%, filler 8%, silicon acrylate elastic emulsion 34%, antifreezing agent 1.7%, titanium dioxide 21%.
Described function additive includes dispersant 19.5%, defoamer 4.9%, thickening agent 14.6%, antifungus agent 4.9%, coalescents 36.6%, water-repelling agent 19.5% by mass percentage.
Described filler includes cordierite powder 36.8%, sericite in powder 31.6%, triple superphosphate 31.6% by mass percentage.
The heat insulating function of insulating moulding coating embodies mainly by the material high reflection to sunlight and radiation, and the cleannes of coating surface directly affect reflective insulation function, surface dirt etc., and pollutant increase, and reflective insulation function reduction is bigger.Therefore the research of this project adopts high-effective water-proof material technology and self-cleaning material technology, produces the hydrophobic and automatically cleaning on existing insulating moulding coating surface.
Add five quantitative aqueouss, silicone-modified organic silicon emulsion without dissolubility at formulation for coating material, strengthen the water proofing property of coating, resistance to water, and keep good breathability.
Water nano water-repelling agent is added in coating, improves the stain resistant self-cleaning property of insulating moulding coating.Its mechanism of action is: nanoparticle is after surface conditioning agent cladding, grafting, a functional group in inorganic agent and the hydroxy polymer macromolecular reaction on nanometer material for making clothes surface, grafting, nanoparticle becomes my connection center of activity, form space network, enhance the crosslink density of film and surface strength, nanometer fine particle are filled with relatively space between coarse stuff particle, make film finer and close, smooth, smooth.Above-mentioned film feature obtains the Fundamentals of stain resistant film just, key factor then: parent-offspring's group of nanoparticle surface gives film coated surface hydrophilic.Hydrophilic group is because having low electric charge, and the charged electrostatic attraction swum between granule is little, make it be difficult to be attached to coating surface, hydrophilic film has oil repellency, some lipophile pollutant are difficult to attachment, even if attachment is also sticked loosely, easily it is blown away or is fallen by rain-out, thus keeping film self-cleaning.It has been experienced that, when the addition of nano-sized hydrophobic agent reaches 0.8%-1%, the stain resistance of film can be made to be reduced to 12% by 26%.
Described in embodiment one, reflective heat-insulation paint construction technology is:
The construction method of water-thinned heat reflecting and isolating paint can adopt brushing, roller coat or blade coating, the temperature of construction is at 5 DEG C-50 DEG C, it is preferably 45 DEG C, the metope of construction requires to ask cleaning, smooth, dry, moisture content less than 10% for surface of wall, basal plane intensity need to reach first one layer of priming paint of brush during more than 5kgf/ construction, one layer of intermediate layer paint of brush again, finally brush one aspect paint, the construction diluent of above-mentioned three road paints is all water, dilution factor≤15%, and 20 DEG C of surface drying times 1-2 hour, repainting time was be more than or equal to 3 hours.

Claims (6)

1. a reflective heat-insulation paint, it is characterized in that, by weight/mass percentage composition, it specifically includes that water 20~21.5%, function additive 3~4.5%, glass microballoon 9~11%, filler 7.5~8.5%, silicon acrylate elastic emulsion 33~37%, antifreezing agent 1~2%, titanium dioxide 20~21.5%;
Described function additive includes dispersant 19~20%, defoamer 4.5~5.5%, thickening agent 14~15%, antifungus agent 4.5~5.5%, coalescents 36~37%, water-repelling agent 19~20%;
Described filler includes cordierite powder 35.5~37.5%, sericite in powder 31~32.5%, triple superphosphate 31~32.5%.
2. a kind of reflective heat-insulation paint according to claim 1, it is characterised in that described coating includes by weight/mass percentage composition: water 20.8%, function additive 3.1%, glass microballoon 10%, filler 7.7%, silicon acrylate elastic emulsion 36%, antifreezing agent 1.6%, titanium dioxide 20.8%.
3. a kind of reflective heat-insulation paint according to claim 1, it is characterised in that described coating includes by weight/mass percentage composition: water 21%, function additive 4.3%, glass microballoon 10%, filler 8%, silicon acrylate elastic emulsion 34%, antifreezing agent 1.7%, titanium dioxide 21%.
4. a kind of reflective heat-insulation paint according to claim 1, it is characterised in that: described function additive includes dispersant 19.5%, defoamer 4.9%, thickening agent 14.6%, antifungus agent 4.9%, coalescents 36.6%, water-repelling agent 19.5% by mass percentage.
5. a kind of reflective heat-insulation paint according to claim 1, it is characterised in that: described filler includes cordierite powder 36.8%, sericite in powder 31.6%, triple superphosphate 31.6% by mass percentage.
6. a kind of reflective heat-insulation paint according to claim 1, it is characterised in that: described water-repelling agent adopts water nano water-repelling agent.
CN201610247983.8A 2016-04-20 2016-04-20 Reflective heat-insulating coating CN105802415A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147413A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 The sprayable water-repellent paint of a kind of reflection and heat insulation
CN106147452A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 A kind of reflection and heat insulation colour acrylic acid superlastic water-repellent paint
CN106189547A (en) * 2016-07-29 2016-12-07 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106243845A (en) * 2016-07-29 2016-12-21 浙江春明防水建材有限公司 A kind of transparent rapid hardening environment-friendly type building water-repellent paint
CN106316240A (en) * 2016-07-29 2017-01-11 浙江春明防水建材有限公司 Reinforced light-reflecting heat-insulating polymer cement waterproof paint
CN108753083A (en) * 2018-06-26 2018-11-06 阜南县腾博工艺品有限公司 A kind of wicker plaiting article stain resistant imitation stone lacquer
CN109251619A (en) * 2018-09-17 2019-01-22 浙江纺织服装职业技术学院 Water-thinned wall paint and preparation method thereof
CN109266082A (en) * 2018-09-07 2019-01-25 广东为民实业有限公司 A kind of reflective insulation water-repellent paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965669A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne fluorocarbon paint
CN103965758A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne wood lacquer
CN104250498A (en) * 2014-10-08 2014-12-31 中钢集团马鞍山矿山研究院有限公司 Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof
CN104762017A (en) * 2014-01-05 2015-07-08 漳州水之采环保科技有限公司 Water-based self-cleaning glaze coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965669A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne fluorocarbon paint
CN103965758A (en) * 2013-01-29 2014-08-06 惠州市华昱美实业有限公司 Waterborne wood lacquer
CN104762017A (en) * 2014-01-05 2015-07-08 漳州水之采环保科技有限公司 Water-based self-cleaning glaze coating
CN104250498A (en) * 2014-10-08 2014-12-31 中钢集团马鞍山矿山研究院有限公司 Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106147413A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 The sprayable water-repellent paint of a kind of reflection and heat insulation
CN106147452A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 A kind of reflection and heat insulation colour acrylic acid superlastic water-repellent paint
CN106189547A (en) * 2016-07-29 2016-12-07 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106243845A (en) * 2016-07-29 2016-12-21 浙江春明防水建材有限公司 A kind of transparent rapid hardening environment-friendly type building water-repellent paint
CN106316240A (en) * 2016-07-29 2017-01-11 浙江春明防水建材有限公司 Reinforced light-reflecting heat-insulating polymer cement waterproof paint
CN106147452B (en) * 2016-07-29 2018-08-03 浙江春明防水建材有限公司 A kind of reflection and heat insulation colour acrylic acid superlastic water-repellent paint
CN106189547B (en) * 2016-07-29 2018-09-25 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106147413B (en) * 2016-07-29 2018-10-09 浙江春明防水建材有限公司 A kind of water-repellent paint that reflection and heat insulation is sprayable
CN106316240B (en) * 2016-07-29 2018-10-16 浙江春明防水建材有限公司 A kind of enhanced reflection and heat insulation polymer cement waterproof paint
CN108753083A (en) * 2018-06-26 2018-11-06 阜南县腾博工艺品有限公司 A kind of wicker plaiting article stain resistant imitation stone lacquer
CN109266082A (en) * 2018-09-07 2019-01-25 广东为民实业有限公司 A kind of reflective insulation water-repellent paint and preparation method thereof
CN109251619A (en) * 2018-09-17 2019-01-22 浙江纺织服装职业技术学院 Water-thinned wall paint and preparation method thereof

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Application publication date: 20160727