CN108892984A - A kind of green environmental friendly coatings of highly effective flame-retardant - Google Patents

A kind of green environmental friendly coatings of highly effective flame-retardant Download PDF

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Publication number
CN108892984A
CN108892984A CN201810568619.0A CN201810568619A CN108892984A CN 108892984 A CN108892984 A CN 108892984A CN 201810568619 A CN201810568619 A CN 201810568619A CN 108892984 A CN108892984 A CN 108892984A
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China
Prior art keywords
parts
coating
agent
highly effective
environmental friendly
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Withdrawn
Application number
CN201810568619.0A
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Chinese (zh)
Inventor
孟青
李良浩
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Guangzhou City Mdt Infotech Ltd
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Guangzhou City Mdt Infotech Ltd
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Priority to CN201810568619.0A priority Critical patent/CN108892984A/en
Publication of CN108892984A publication Critical patent/CN108892984A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

Abstract

The present invention relates to chemical technology field, in particular a kind of green environmental friendly coatings of highly effective flame-retardant include the following steps:S1;It conscientiously checks and quite produces required each equipment, be allowed in intact clean state, operator wears safety protective tools S2;Fire-resistant composition is configured according to the component ratio of required coating;S3;Sand mill or ball mill grinding dispersion fire prevention raw material are carried out to required material;S4;Add mixed solvent, stirring configuration fireproof coating;S5;Molding coating is repeatedly examined;S6;Packaging is sealed to molding coating, sticks ingredient, application method, production time and effective time and points for attention.The present invention is non-toxic and tasteless, green safe by this coating of the configuration of corresponding proportion and there is good elasticity, flexibility, water resistance and the high heat-insulating, fire-preventing coating quality of waterproofness, stability to stablize, using effect is good, while with excellent flameproof effect, it is provided simultaneously with heat insulating function.

Description

A kind of green environmental friendly coatings of highly effective flame-retardant
Technical field
The present invention relates to technical field more particularly to a kind of green environmental friendly coatings of highly effective flame-retardant.
Background technique
Chinese coating industry the real estate of fast growth, automobile, ship, etc. downstream industries promotion under, to be higher than The speed of GDP5%-10% increases, and becomes the second big country of world's coating material production and consumption, generally China's coating industry in 2008 Macroeconomic running quality improves a lot, and constantly to large enterprises, brand enterprise is concentrated in market, industry profitability and anti-risk Ability enhancing, is presented benign development situation on the whole.Environmental protection coating material be it is a kind of can securely be covered on body surface, rise protection, dress The chemical mixture coating of decorations, mark and other specific uses.Paint is because of the moisture-proof defencive function of its anti-corrosion and decoration function Can, and by the favor of finishing person, but organic solvents, the harm to the human body such as addition benzene are larger mostly for existing paint, and it also can be to ring Border affects, and resistance to oxidation is not strong, and fire retardant performance is poor, and wear-resistance and oil-resistance ability is poor, as people are to environmental protection Consciousness is more and more stronger, this just needs a kind of reliable performance, to the environment protection oil paint of human body and environmental nonpollution.Heat-insulated high resistant fire prevention, The coating of water-proof environmental protection is particularly important.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of green of the highly effective flame-retardant proposed Environmental protection coating material.
To achieve the goals above, present invention employs following technical solutions:
A kind of green environmental friendly coatings of highly effective flame-retardant, include the following steps:
S1;It conscientiously checks and quite produces required each equipment, be allowed in intact clean state, operator Wear safety protective tools
S2;Fire-resistant composition is configured according to the component ratio of required coating;
S3;Sand mill or ball mill grinding dispersion fire prevention raw material are carried out to required material;
S4;Add mixed solvent, stirring configuration fireproof coating;
S5;Molding coating is repeatedly examined;
S6;Packaging is sealed to molding coating, sticks ingredient, application method, production time and effective time And points for attention.
Preferably, the component ratio of the coating configures modified acroleic acid 20-40 parts, 2-5 parts of bentonite, wollastonite 15- 25 parts, 10-18 parts of polyvinyl alcohol, 15-25 parts of light calcium carbonate powder, 3-8 parts of activating agent, 2-7 parts of toughener, 3-8 parts of hydrophobing agent, film forming help 1-3 parts of agent, 70-110 parts of china clay, 30-45 parts of titanium dioxide, 3-10 parts of perlite particle, 4-6 parts of sepiolite, water-base epoxy tree Rouge, 20-30 parts, 11-16 parts of waterglass, 11-15 parts of potassium hydroxide, 4-9 parts of sodium metasilicate, 3-8 parts of zinc chloride.
Preferably, described to pass through china clay, titanium dioxide, perlite particle, sepiolite with the requisite quality got ready respectively Ball mill is ground, and milling time will control fineness in 100um or less in 60min or more.
Preferably, the mixed solvent includes:Elastic emulsion, fungicide, film forming solvent, thickener, disappears at pigment dispersing agent Infusion and PH debug agent, and weight part ratio is as follows:Elastic emulsion:Pigment dispersing agent:Fungicide:Film forming solvent:Thickener:Defoaming Agent and:Debug agent=35:7:2:4:2.2:3:0.3.
Preferably, the ingredient of the required coating and high china clay, titanium dioxide, perlite particle, sepiolite are according to number Proportion is added to high-speed mixer stirring 30min or more, while adding water in thinning vessel, sequentially add under the low speed by Aqueous epoxy resins, waterglass, potassium hydroxide, sodium metasilicate, zinc chloride raw material according to number proportion mention after stirring 15-20min High wheel speed, with 1-2 hours formation products of high-speed stirred.
Compared with prior art, the invention proposes a kind of green environmental friendly coatings of highly effective flame-retardant, have below beneficial to effect Fruit:
1, there is excellent environmental-protecting performance by proportion coating, it is non-toxic and tasteless, it is green safe;And there is good bullet Property, flexibility, water resistance and waterproofness, the coating there is no volatile organic solvent and free formaldehyde, safety and environmental protection, without nocuousness Substance will not damage human health;Ageing resistance is strong, not easily to fall off, and stability is high.
2, to be stablized by proportion heat-insulating, fire-preventing coating quality, using effect is good, while with excellent flameproof effect, It is provided simultaneously with heat insulating function.
In the present invention, it is not directed to part in the device and is the same as those in the prior art or can be realized by using the prior art, The present invention has excellent environmental-protecting performance by proportion coating, non-toxic and tasteless, green safe;And have good elastic, soft Toughness, water resistance and waterproofness, the coating do not have volatile organic solvent and free formaldehyde, and safety and environmental protection is free of harmful substance, Human health will not be damaged;Ageing resistance is strong, not easily to fall off, and stability is high;By matching heat-insulating, fire-preventing coating quality Stablize, using effect is good, while with excellent flameproof effect, is provided simultaneously with heat insulating function.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
A kind of green environmental friendly coatings of highly effective flame-retardant, include the following steps:
S1;It conscientiously checks and quite produces required each equipment, be allowed in intact clean state, operator Wear safety protective tools
S2;Fire-resistant composition is configured according to the component ratio of required coating;
S3;Sand mill or ball mill grinding dispersion fire prevention raw material are carried out to required material;
S4;Add mixed solvent, stirring configuration fireproof coating;
S5;Molding coating is repeatedly examined;
S6;Packaging is sealed to molding coating, sticks ingredient, application method, production time and effective time And points for attention.
The component ratio of the coating configures modified acroleic acid 20-40 parts, 2-5 parts of bentonite, 15-25 parts of wollastonite, gathers 10-18 parts of vinyl alcohol, 15-25 parts of light calcium carbonate powder, 3-8 parts of activating agent, 2-7 parts of toughener, 3-8 parts of hydrophobing agent, coalescing agent 1-3 Part, 70-110 parts of china clay, 30-45 parts of titanium dioxide, 3-10 parts of perlite particle, 4-6 parts of sepiolite, aqueous epoxy resins, 20- 30 parts, 11-16 parts of waterglass, 11-15 parts of potassium hydroxide, 4-9 parts of sodium metasilicate, 3-8 parts of zinc chloride.
The china clay by with the requisite quality got ready, titanium dioxide, perlite particle, sepiolite respectively through ball mill into Row grinding, milling time will control fineness in 100um or less in 60min or more.
The mixed solvent includes:Elastic emulsion, pigment dispersing agent, fungicide, film forming solvent, thickener, defoaming agent and PH debugs agent, and weight part ratio is as follows:Elastic emulsion:Pigment dispersing agent:Fungicide:Film forming solvent:Thickener:Defoaming agent and: Debug agent=35:7:2:4:2.2:3:0.3.
The ingredient and high china clay, titanium dioxide, perlite particle, sepiolite of coating needed for described are matched according to number, are added Enter to high-speed mixer and stir 30min or more, while adding water in thinning vessel, sequentially adds match according to number under the low speed Aqueous epoxy resins, waterglass, potassium hydroxide, sodium metasilicate, the zinc chloride raw material of ratio after stirring 15-20min, improve impeller and turn Speed, with 1-2 hours formation products of high-speed stirred.
Specific embodiment 1;
According to weight, the component of the fireproof coating includes:20 parts of modified acroleic acid, 2 parts of bentonite, wollastonite 15 parts, 10 parts of polyvinyl alcohol, 15 parts of light calcium carbonate powder, 3 parts of activating agent, 2 parts of toughener, 3 parts of hydrophobing agent, 1 part of coalescing agent, china clay 70 parts, 30 parts of titanium dioxide, 3 parts of perlite particle, 4 parts of sepiolite, 20 parts of aqueous epoxy resins, 11 parts of waterglass, potassium hydroxide 11 parts, 4 parts of sodium metasilicate, 3 parts of zinc chloride, mixed solvent weight part ratio is as follows:Elastic emulsion:Pigment dispersing agent:Fungicide:Film forming Solvent:Thickener:Defoaming agent and:Debug agent=35:7:2:4:2.2:3:0.3, it is coated on corresponding object, sees after being sufficiently stirred Examine its color brightness, water-fast degree, fire resisting degree, degree of thermal insulation.
Specific embodiment 2;
According to weight, the component of the fireproof coating includes 30 parts of modified acroleic acid, 3 parts of bentonite, wollastonite 20 parts, 14 parts of polyvinyl alcohol, 20 parts of light calcium carbonate powder, 5 parts of activating agent, 4 parts of toughener, 5 parts of hydrophobing agent, 2 parts of coalescing agent, china clay 90 parts, 37 parts of titanium dioxide, 5 parts of perlite particle, sea bubble 5 parts, 25 parts of aqueous epoxy resins, 13 parts of waterglass, potassium hydroxide 13 Part, 6 parts of sodium metasilicate, 5 parts of zinc chloride, it is as follows to add mixed solvent weight part ratio:Elastic emulsion:Pigment dispersing agent:Fungicide: Film forming solvent:Thickener:Defoaming agent and:Debug agent=35:7:2:4:2.2:3:0.3, corresponding object is coated in after being sufficiently stirred On, observe its color brightness, water-fast degree, fire resisting degree, degree of thermal insulation.
Specific embodiment 3;
According to weight, the component of the fireproof coating includes 40 parts of modified acroleic acid, 5 parts of bentonite, wollastonite 25 parts, 18 parts of polyvinyl alcohol, 25 parts of light calcium carbonate powder, 8 parts of activating agent, 7 parts of toughener, 8 parts of hydrophobing agent, 3 parts of coalescing agent, china clay 110 parts, 45 parts of titanium dioxide, 10 parts of perlite particle, 6 parts of sepiolite, 30 parts of aqueous epoxy resins, 16 parts of waterglass, hydroxide 15 parts of potassium, 9 parts of sodium metasilicate, 8 parts of zinc chloride, mixed solvent weight part ratio is as follows:Elastic emulsion:Pigment dispersing agent:Fungicide:At Membrane solvent:Thickener:Defoaming agent and:Debug agent=35:7:2:4:2.2:3:0.3, it is coated in after being sufficiently stirred on corresponding object, Observe its color brightness, water-fast degree, fire resisting degree, degree of thermal insulation.
In the present invention, in use, there is excellent environmental-protecting performance by proportion coating, it is non-toxic and tasteless, it is green safe;And With good elasticity, flexibility, water resistance and waterproofness, which does not have volatile organic solvent and free formaldehyde, safety Environmental protection is free of harmful substance, will not damage to human health;Ageing resistance is strong, not easily to fall off, and stability is high;By matching Stablize than heat-insulating, fire-preventing coating quality, using effect is good, while with excellent flameproof effect, is provided simultaneously with heat-insulated function Energy.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of green environmental friendly coatings of highly effective flame-retardant, which is characterized in that include the following steps:
S1;It conscientiously checks and quite produces required each equipment, be allowed in intact clean state, operator wears Good safety protective tools
S2;Fire-resistant composition is configured according to the component ratio of required coating;
S3;Sand mill or ball mill grinding dispersion fire prevention raw material are carried out to required material;
S4;Add mixed solvent, stirring configuration fireproof coating;
S5;Molding coating is repeatedly examined;
S6;Packaging is sealed to molding coating, sticks ingredient, application method, production time and effective time and note Meaning item.
2. a kind of green environmental friendly coatings of highly effective flame-retardant according to claim 1, which is characterized in that the ingredient of the coating 20-40 parts of proportional arrangement modified acroleic acid, 2-5 parts of bentonite, 15-25 parts of wollastonite, 10-18 parts of polyvinyl alcohol, light calcium carbonate powder 15- 25 parts, 3-8 parts of activating agent, 2-7 parts of toughener, 3-8 parts of hydrophobing agent, 1-3 parts of coalescing agent, 70-110 parts of china clay, titanium dioxide 30-45 parts, 3-10 parts of perlite particle, 4-6 parts of sepiolite, 20-30 parts of aqueous epoxy resins, 11-16 parts of waterglass, hydroxide 11-15 parts of potassium, 4-9 parts of sodium metasilicate, 3-8 parts of zinc chloride.
3. a kind of green environmental friendly coatings of highly effective flame-retardant according to claim 1, which is characterized in that it is described will be with getting ready China clay, titanium dioxide, perlite particle, the sepiolite of requisite quality are ground through ball mill respectively, and milling time will be 60min or more controls fineness in 100um or less.
4. a kind of green environmental friendly coatings of highly effective flame-retardant according to claim 1, which is characterized in that the mixed solvent packet It includes:Elastic emulsion, pigment dispersing agent, fungicide, film forming solvent, thickener, defoaming agent and PH debug agent, and weight part ratio is such as Under:Elastic emulsion:Pigment dispersing agent:Fungicide:Film forming solvent:Thickener:Defoaming agent and:Debug agent=35:7:2:4:2.2: 3:0.3.
5. a kind of green environmental friendly coatings of highly effective flame-retardant according to claim 3, which is characterized in that coating needed for described Ingredient and high china clay, titanium dioxide, perlite particle, sepiolite are matched according to number, are added to high-speed mixer stirring 30min More than, while adding water in thinning vessel, the aqueous epoxy resins according to number proportion, water glass are sequentially added under the low speed Glass, potassium hydroxide, sodium metasilicate, zinc chloride raw material after stirring 15-20min, improve wheel speed, with 1-2 hours shapes of high-speed stirred At product.
CN201810568619.0A 2018-06-05 2018-06-05 A kind of green environmental friendly coatings of highly effective flame-retardant Withdrawn CN108892984A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111021652A (en) * 2019-11-25 2020-04-17 江苏柏威建设有限公司 Green energy-saving construction method for building transformation
CN117264445A (en) * 2023-06-27 2023-12-22 常德职业技术学院 Inner wall fireproof paint based on metakaolin base polymer and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104250498A (en) * 2014-10-08 2014-12-31 中钢集团马鞍山矿山研究院有限公司 Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof
CN107556884A (en) * 2017-10-18 2018-01-09 江苏建中能源科技有限公司 A kind of heat-insulating, fire-preventing coating
CN107805433A (en) * 2017-12-15 2018-03-16 安聪聪 A kind of environment-friendly type building water-repellent paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104250498A (en) * 2014-10-08 2014-12-31 中钢集团马鞍山矿山研究院有限公司 Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof
CN107556884A (en) * 2017-10-18 2018-01-09 江苏建中能源科技有限公司 A kind of heat-insulating, fire-preventing coating
CN107805433A (en) * 2017-12-15 2018-03-16 安聪聪 A kind of environment-friendly type building water-repellent paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111021652A (en) * 2019-11-25 2020-04-17 江苏柏威建设有限公司 Green energy-saving construction method for building transformation
CN117264445A (en) * 2023-06-27 2023-12-22 常德职业技术学院 Inner wall fireproof paint based on metakaolin base polymer and preparation process thereof

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Application publication date: 20181127

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