CN107163842A - A kind of environmental protection building material coating and preparation method thereof - Google Patents

A kind of environmental protection building material coating and preparation method thereof Download PDF

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Publication number
CN107163842A
CN107163842A CN201710565568.1A CN201710565568A CN107163842A CN 107163842 A CN107163842 A CN 107163842A CN 201710565568 A CN201710565568 A CN 201710565568A CN 107163842 A CN107163842 A CN 107163842A
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CN
China
Prior art keywords
parts
coating
building material
environmental protection
edible gelatin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710565568.1A
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Chinese (zh)
Inventor
张西峰
胡箐
张驰博
赵彦超
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Henan West Super Industrial Co Ltd
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Henan West Super Industrial Co Ltd
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Publication date
Application filed by Henan West Super Industrial Co Ltd filed Critical Henan West Super Industrial Co Ltd
Priority to CN201710565568.1A priority Critical patent/CN107163842A/en
Publication of CN107163842A publication Critical patent/CN107163842A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D189/00Coating compositions based on proteins; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of environmental protection building material coating and preparation method thereof, it is related to building materials technical field of paint preparation, is made up of the component of following parts by weight:20 30 parts of titanium dioxide of rutile type nano level, 20 25 parts of molecular sieve, 15 25 parts of iron chloride, 10 15 parts of calcium oxide, 10 15 parts of edible gelatin, 8 15 parts of potassium/zinc salt, 25 parts of graphene, solvent is the ethanol solution that volume fraction is 60 70%.In the environment-friendly type coating that the present invention is provided, no harmful components using coating of the present invention, will not only produce harmful substance, molecular sieve therein also has adsorption effect;Rutile type nano level titanium dioxide color and luster is good, adapts to coating aesthetic demands at this stage, it is not easy to fades or changes colour;Edible gelatin has good cementability, and coating can be bonded in building material surface without occurring peeling phenomenon, and edible gelatin can be dispersed by each component, and obtained coating is uniform in material, and using effect is good;In the method for producing coating that present invention production is used, the generation of no waste water and gas, production process is pollution-free.

Description

A kind of environmental protection building material coating and preparation method thereof
Technical field
The present invention relates to building materials technical field of paint preparation, more particularly to a kind of environmental protection building material coating and Its preparation method.
Background technology
Coating is to be coated in the body surface protected or decorated, and can be continuous thin with coated article formation firm attachment Film, is typically based on resin or oil or emulsion, to add or without pigment, filler, add corresponding additive, use organic solvent Or the thick liquid that water is formulated.Coating is general by four kinds of bases:Film forming matter (resin), pigment (including constitution face Material), solvent and additive.
According to the main film forming substance used in coating coating can be divided into oil paint, fiber coating, synthetic paint and Inorganic coating;It can divide solution, latex by coating or paint film character, colloidal sol, powder, have light, delustring and multicolor novelty coating etc..It Play protection, decoration, mark and other special role (such as electric insulation, antifouling, drag reduction, heat-insulated, radiation hardness, conduction, magnetic conductions Deng).Therefore, increasingly it is widely applied in industrial or agricultural, national defence, scientific research and people's lives.
Previous coating is all to be processed to go through to be generally termed paint with vegetable oil and natural resin.With the hair of industry Exhibition, coating variety is increasing, and quality and performance are improved constantly, the composition of many new coatings no longer containing oil.It is so oily Paint this noun and just seem not definite enough.Therefore, the various materials for application object plane are referred to as coating now, paint is only It is one kind in coating.With the reach of science, the extensive use of various high molecular synthetic resins makes coating products there occurs root This change, therefore accurately title should be " organic coating ".
With the quickening pace of modern life, people are for building up after finishing to also requiring that increasingly during moving in this It is short, but because existing building materials coating adds the organic solvents such as benzene mostly, harm to the human body is larger, also can cause certain to environment Influence, so the research and development for environment protecting building paint are increasingly urgent.
Under such circumstances, a series of environment-friendly type coatings arise at the historic moment, but substantially contain in existing environment-friendly type coating There are the noxious materials such as polyethyleneimine, acrylic resin, can human body skin, eyes be caused with certain infringement.
The content of the invention
The present invention provides a kind of environmental protection building material coating and preparation method thereof, is applied with providing a kind of novel environment friendly building materials Material, reduces the infringement to human body and environment.
To solve above-mentioned technical problem, the present invention uses following technical scheme:
A kind of environmental protection building material coating, is made up of the component of following parts by weight:Rutile type nano level titanium dioxide 20-30 Part, 20-25 parts of molecular sieve, 15-25 parts of iron chloride, 10-15 parts of calcium oxide, 10-15 parts of edible gelatin, potassium/8-15 parts of zinc salt, stone Black alkene 2-5 parts, solvent is the ethanol solution that volume fraction is 60-70%.
A kind of preparation method of environmental protection building material coating, comprises the following steps:
(1) rutile type nano level titanium dioxide, molecular sieve, graphene, calcium oxide are uniformly mixed to form silty in proportion Mixture;
(2) iron chloride, potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until starting to occur Solid-state precipitate, is warming up to solid-state precipitate and is completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir Edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) in the environment-friendly type coating that the present invention is provided, no harmful components, using coating of the present invention, will not only have been produced Evil material, molecular sieve therein also has adsorption effect;Rutile type nano level titanium dioxide color and luster is good, adapts to coating at this stage Aesthetic demands, it is not easy to fade or change colour;The edible gelatin of use has good cementability, and coating can be bonded in building materials table Face is without occurring peeling phenomenon, and edible gelatin can be dispersed by each component, and obtained coating is uniform in material, using effect Good, service life is long;The coating of product formation of the present invention also has excellent flintiness and wear-resisting intensity;
(2) in the method for producing coating that present invention production is used, the generation of no waste water and gas, production process is pollution-free;And Production process is easily formed industrialization operation.
Embodiment
Application principle, effect and effect of the present invention, is explained by the way that mode is implemented as follows.
Embodiment 1
The preparation method of environmental protection building material coating, comprises the following steps:
(1) it is 20 parts of titanium dioxide of rutile type nano level, 25 parts of molecular sieve, 2 parts of graphene, 10 parts of calcium oxide is equal in proportion It is even to be mixed to form silty mixture;
(2) 15 parts of iron chloride, 8 parts of potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until Start solid-state precipitate occur, be warming up to solid-state precipitate and be completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir 10 parts of edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
The product that the present embodiment is obtained is coated on experiment metope, under ventilation condition, is completely dried the time for 2-3 My god, coating flintiness and wear-resisting intensity are better than the coating that existing coating is formed;It is to change colour in the coating 2-3 of formation And discoloration;The present embodiment coating is coated, indoor formaldehyde and other toxic gas contents effectively reduce 2-10 percentage points.
Embodiment 2
The preparation method of environmental protection building material coating, comprises the following steps:
(1) it is 20 parts of titanium dioxide of rutile type nano level, 25 parts of molecular sieve, 3 parts of graphene, 10 parts of calcium oxide is equal in proportion It is even to be mixed to form silty mixture;
(2) 20 parts of iron chloride, 10 parts of potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until Start solid-state precipitate occur, be warming up to solid-state precipitate and be completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir 15 parts of edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
The product that the present embodiment is obtained is coated on experiment metope, under ventilation condition, is completely dried the time for 4-5 My god, coating flintiness and wear-resisting intensity are better than the coating that coating made from embodiment 1 is formed;In the coating 2-3 of formation To occur discoloration and discoloration;The present embodiment coating is coated, indoor formaldehyde and other toxic gas contents effectively reduce 2- 10 percentage points.
Embodiment 3
The preparation method of environmental protection building material coating, comprises the following steps:
(1) it is 20 parts of titanium dioxide of rutile type nano level, 25 parts of molecular sieve, 5 parts of graphene, 10 parts of calcium oxide is equal in proportion It is even to be mixed to form silty mixture;
(2) 20 parts of iron chloride, 15 parts of potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until Start solid-state precipitate occur, be warming up to solid-state precipitate and be completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir 15 parts of edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
The product that the present embodiment is obtained is coated on experiment metope, under ventilation condition, is completely dried the time for 6-7 My god, coating flintiness and wear-resisting intensity are better than the coating that coating made from embodiment 2 is formed;In the coating 2-3 of formation To occur discoloration and discoloration;The present embodiment coating is coated, indoor formaldehyde and other toxic gas contents effectively reduce 2- 10 percentage points.
Embodiment 4
The preparation method of environmental protection building material coating, comprises the following steps:
(1) it is 30 parts of titanium dioxide of rutile type nano level, 25 parts of molecular sieve, 2 parts of graphene, 10 parts of calcium oxide is equal in proportion It is even to be mixed to form silty mixture;
(2) 20 parts of iron chloride, 15 parts of potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until Start solid-state precipitate occur, be warming up to solid-state precipitate and be completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir 15 parts of edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
The product that the present embodiment is obtained is coated on experiment metope, under ventilation condition, is completely dried the time for 2-3 My god, coating flintiness and wear-resisting intensity are better than the coating that existing coating is formed, and with embodiment 1 quite, are worse than embodiment 2-3; The coating color and luster of formation is better than in embodiment 1-3, and 2-3 being to occur discoloration and discoloration;The present embodiment coating is coated, Indoor formaldehyde and other toxic gas contents effectively reduce 2-10 percentage points.
Embodiment 5
The preparation method of environmental protection building material coating, comprises the following steps:
(1) it is 30 parts of titanium dioxide of rutile type nano level, 20 parts of molecular sieve, 2 parts of graphene, 15 parts of calcium oxide is equal in proportion It is even to be mixed to form silty mixture;
(2) 20 parts of iron chloride, 15 parts of potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until Start solid-state precipitate occur, be warming up to solid-state precipitate and be completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring formed after dispersed suspension keep stir 15 parts of edible gelatin is rapidly added in the state of mixing, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
The product that the present embodiment is obtained is coated on experiment metope, under ventilation condition, is completely dried the time for 2-3 My god, coating flintiness and wear-resisting intensity are better than the coating that existing coating is formed, suitable with embodiment 1-2, are worse than embodiment 3; The coating color and luster of formation is equivalent to embodiment 4, and it is to occur discoloration and discoloration that 2-3 is interior;The present embodiment coating is coated, Indoor formaldehyde and other toxic gas contents effectively reduce 2-8 percentage points.
It is embodiments of the invention as described above.The present invention is not limited to the above-described embodiments, anyone should learn that The structure change made under the enlightenment of the present invention, the technical schemes that are same or similar to the present invention each fall within this Within the protection domain of invention.

Claims (2)

1. a kind of environmental protection building material coating, it is characterised in that be made up of the component of following parts by weight:Rutile type nano level titanium 20-30 parts of white powder, 20-25 parts of molecular sieve, 15-25 parts of iron chloride, 10-15 parts of calcium oxide, 10-15 parts of edible gelatin, potassium/zinc salt 8-15 parts, 2-5 parts of graphene, solvent is the ethanol solution that volume fraction is 60-70%.
2. a kind of preparation method of environmental protection building material coating as claimed in claim 1, it is characterised in that including following step Suddenly:
(1) rutile type nano level titanium dioxide, molecular sieve, graphene, calcium oxide are uniformly mixed to form silty and mixed in proportion Thing;
(2) iron chloride, potassium/zinc salt are dissolved in the water formation aqueous solution, and ethanol is added into the aqueous solution, until starting solid-state occur Precipitate, is warming up to solid-state precipitate and is completely dissolved;
(3) the silty mixture that step (1) is obtained is added in the solution that step (2) is obtained;
(4) heat insulation system temperature be 50-55 DEG C under conditions of, by stirring form what is be kept stirring for after dispersed suspension Edible gelatin is rapidly added under state, is formed and room temperature is cooled to after colloid coating, packing, sealing preserve.
CN201710565568.1A 2017-07-12 2017-07-12 A kind of environmental protection building material coating and preparation method thereof Pending CN107163842A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710565568.1A CN107163842A (en) 2017-07-12 2017-07-12 A kind of environmental protection building material coating and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710565568.1A CN107163842A (en) 2017-07-12 2017-07-12 A kind of environmental protection building material coating and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841247A (en) * 2017-11-21 2018-03-27 河南西超实业有限公司 A kind of environment protecting water-based paint
CN112778806A (en) * 2019-11-04 2021-05-11 广东万爱建筑科技有限公司 Environment-friendly quick-drying building material coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2466392A (en) * 2009-10-15 2010-06-23 Michael Trevor Berry Latent heat storage materials
CN103159437A (en) * 2011-12-15 2013-06-19 张国庆 Temperature adjusting humidity adjusting coating and preparation method thereof
CN104745077A (en) * 2015-03-30 2015-07-01 上海轩颂建筑装饰有限公司 External wall paint for buildings
CN104926220A (en) * 2015-06-29 2015-09-23 青岛恩高运动控制技术有限公司 Building coating
CN105567037A (en) * 2014-10-08 2016-05-11 江苏瑞丰科技实业有限公司 Efficient antibacterial formaldehyde-removing environmental protection coating material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2466392A (en) * 2009-10-15 2010-06-23 Michael Trevor Berry Latent heat storage materials
CN103159437A (en) * 2011-12-15 2013-06-19 张国庆 Temperature adjusting humidity adjusting coating and preparation method thereof
CN105567037A (en) * 2014-10-08 2016-05-11 江苏瑞丰科技实业有限公司 Efficient antibacterial formaldehyde-removing environmental protection coating material
CN104745077A (en) * 2015-03-30 2015-07-01 上海轩颂建筑装饰有限公司 External wall paint for buildings
CN104926220A (en) * 2015-06-29 2015-09-23 青岛恩高运动控制技术有限公司 Building coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841247A (en) * 2017-11-21 2018-03-27 河南西超实业有限公司 A kind of environment protecting water-based paint
CN112778806A (en) * 2019-11-04 2021-05-11 广东万爱建筑科技有限公司 Environment-friendly quick-drying building material coating

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Application publication date: 20170915