CN112778806A - Environment-friendly quick-drying building material coating - Google Patents

Environment-friendly quick-drying building material coating Download PDF

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Publication number
CN112778806A
CN112778806A CN201911066863.8A CN201911066863A CN112778806A CN 112778806 A CN112778806 A CN 112778806A CN 201911066863 A CN201911066863 A CN 201911066863A CN 112778806 A CN112778806 A CN 112778806A
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CN
China
Prior art keywords
parts
mixture
building material
environment
rare earth
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Pending
Application number
CN201911066863.8A
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Chinese (zh)
Inventor
张萍
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Guangdong Wanai Construction Technology Co ltd
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Guangdong Wanai Construction Technology Co ltd
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Priority to CN201911066863.8A priority Critical patent/CN112778806A/en
Publication of CN112778806A publication Critical patent/CN112778806A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an environment-friendly quick-drying building material coating which comprises nano titanium dioxide, an A3 type molecular sieve, methacrylic acid stearate, tributyl phosphate, ferric chloride, calcium oxide, potassium/zinc salt, graphene, chlorinated paraffin, absolute ethyl alcohol, activated carbon, glacial acetic acid, a composite rare earth drier and resin. In the environment-friendly quick-drying building material coating provided by the invention, substances without harmful components are adopted, and the nano titanium dioxide has the anti-ultraviolet and antibacterial effects, so that the coating is more durable; the chlorinated paraffin is a chlorinated derivative of paraffin, has the advantages of low volatility, flame retardance, low price and the like, and improves the comprehensive performance of the coating; compared with the traditional drier, the rare earth drier has less pollution and low price.

Description

Environment-friendly quick-drying building material coating
Technical Field
The invention relates to the field of building material coatings, in particular to an environment-friendly quick-drying building material coating.
Background
With the rapid development of social production, energy and environment become two major problems of increasing attention of the society, and therefore higher requirements on energy conservation and environmental protection are provided. However, the world is generally in the crisis of increasing shortage of energy, and people put higher demands on the use efficiency of energy in terms of social production and life in order to reduce energy consumption. In the field of buildings, energy-saving buildings are effective ways for improving the use efficiency of building energy.
As a coating product for house decoration, some buildings have special requirements on mildew resistance, fire resistance and the like, some buildings have special requirements on water resistance, freezing resistance and crack resistance, and some buildings have special requirements on decoration. The habitability improvement function is mainly for indoor painting, and is a function contributing to improvement of the habitability, such as sound insulation, sound absorption, dew condensation prevention, and the like. The liquid or solid materials are collectively called as a group which can form a solid coating film having a protective decorative or special property when applied to the surface of an object. The coating has various types and extremely wide application, plays an important role in national economy and people's life, and the amount of the coating used by people every year is an important index of national living standard.
Coatings are required in many industries, and the construction industry is one of the industries that consumes large amounts of coatings. The construction industry is the sector of production dedicated to civil engineering, building construction and equipment installation and engineering exploration and design, the products of which are buildings, structures and facilities of various factories, mines, railways, bridges, ports, roads, pipelines, houses and public facilities.
China has vast land and a large number of people, different construction projects are carried out at every moment, and if the drying speed of the coating is low, the project efficiency is influenced; meanwhile, with the continuous development of society, the environmental protection consciousness of people is improved, and the environmental protection performance of the coating is required to be improved continuously, so that the environment-friendly quick-drying building material coating is an urgent need of the market.
Disclosure of Invention
The present invention aims to overcome the above-mentioned shortcomings and provide a technical solution to solve the above-mentioned problems.
An environment-friendly quick-drying building material coating is characterized by comprising 10-20 parts of nano titanium dioxide, 15-20 parts of A3 type molecular sieve, 13-18 parts of methacrylic acid stearate, 1.5-5 parts of tributyl phosphate, 10-22 parts of ferric chloride, 8-15 parts of calcium oxide, 8-15 parts of potassium/zinc salt, 2-5 parts of graphene, 9-14 parts of chlorinated paraffin, 20-25 parts of absolute ethyl alcohol, 3-9 parts of activated carbon, 5-9 parts of glacial acetic acid, 3-6 parts of a composite rare earth drier and 10-14 parts of resin.
Preferably, the composite rare earth drier is prepared from liquid fusidic acid and rare earth chloride.
A preparation method of an environment-friendly quick-drying building material coating comprises the following steps:
(1) uniformly mixing the nano titanium dioxide, calcium oxide, an A3 type molecular sieve and graphene according to a proportion, and grinding the mixture in grinding equipment for 50-60 minutes to obtain a uniform and fine first mixture;
(2) putting the resin, the methacrylic acid stearate, the tributyl phosphate and the active carbon into a planetary ball mill for milling treatment, grinding for 30-40 minutes, and then screening by using a 600-800-mesh screen to obtain a second mixture;
(3) respectively adding ferric chloride and potassium salt into water to form an aqueous solution, introducing absolute ethyl alcohol into the aqueous solution until solids are separated out, and then heating the aqueous solution by a heating instrument until the solids are completely dissolved to obtain a third mixture;
(4) adding the first mixture into the third mixture, and premixing the third mixture for 10-20 minutes by using a stirrer at the stirring speed of 140-240rpm to obtain a fourth mixture;
(5) and adding the second mixture, the fourth mixture, the chlorinated paraffin and the composite rare earth drier into a constant-temperature stirring barrel, setting the temperature at 50-70 ℃, then stirring at a high speed of 800rpm for 60-70 minutes at 600-70 rpm, and slowly adding glacial acetic acid into the constant-temperature stirring barrel after 10-15 minutes of stirring time to finally form the colloid coating.
(6) And finally, cooling, inspecting, subpackaging, sealing and storing the coating.
Compared with the prior art, the invention has the beneficial effects that: the building material coating does not contain harmful substances, has a quick drying effect, can improve the engineering construction efficiency, and has the following advantages: the nano titanium dioxide is called nano titanium dioxide for short, also called nano titanium dioxide, has the effects of ultraviolet resistance, antibiosis, self-cleaning and ageing resistance, and can be used in the fields of cosmetics, functional fibers, plastics, printing ink, coating, paint, fine ceramics, antibacterial agents and the like; the chlorinated paraffin is a chlorinated derivative of paraffin, and has the advantages of low volatility, flame retardance, good electrical insulation, low price and the like; compared with the traditional drier prepared by metals such as cobalt, manganese, lead, zinc, calcium and the like, the rare earth drier has the advantages of less pollution and low price.
Detailed Description
Example one
An environment-friendly quick-drying building material coating comprises 10 parts of nano titanium dioxide, 15 parts of A3 type molecular sieve, 13 parts of methacrylic stearate, 1.5 parts of tributyl phosphate, 10 parts of ferric chloride, 8 parts of calcium oxide, 8 parts of potassium salt, 2 parts of graphene, 9 parts of chlorinated paraffin, 20 parts of absolute ethyl alcohol, 3 parts of activated carbon, 5 parts of glacial acetic acid, 3 parts of a composite rare earth drier and 10 parts of resin.
A preparation method of an environment-friendly quick-drying building material coating comprises the following steps:
uniformly mixing the nano titanium dioxide, calcium oxide, an A3 type molecular sieve and graphene according to a proportion, and grinding the mixture in grinding equipment for 50-60 minutes to obtain a uniform and fine first mixture;
putting the resin, the methacrylic acid stearate, the tributyl phosphate and the active carbon into a planetary ball mill for milling treatment, grinding for 30-40 minutes, and then screening by using a 600-800-mesh screen to obtain a second mixture;
respectively adding ferric chloride and potassium salt into water to form an aqueous solution, introducing absolute ethyl alcohol into the aqueous solution until solids are separated out, and then heating the aqueous solution by a heating instrument until the solids are completely dissolved to obtain a third mixture;
adding the first mixture into the third mixture, and premixing the third mixture for 10-20 minutes by using a stirrer at the stirring speed of 140-240rpm to obtain a fourth mixture;
adding the second mixture, the fourth mixture, the chlorinated paraffin and the composite rare earth drier into a constant-temperature stirring barrel, setting the temperature at 50-70 ℃, then stirring at a high speed of 800rpm for 60-70 minutes at 600-70 rpm, and slowly adding glacial acetic acid into the constant-temperature stirring barrel for the remaining 10-15 minutes of the stirring time to finally form the colloid coating;
and finally, cooling, inspecting, subpackaging, sealing and storing the coating.
Example two
An environment-friendly quick-drying building material coating comprises 15 parts of nano titanium dioxide, 18 parts of A3 type molecular sieve, 15 parts of methacrylic stearate, 3 parts of tributyl phosphate, 17 parts of ferric chloride, 12 parts of calcium oxide, 12 parts of potassium salt, 3 parts of graphene, 12 parts of chlorinated paraffin, 13 parts of absolute ethyl alcohol, 6 parts of activated carbon, 7 parts of glacial acetic acid, 4 parts of a composite rare earth drier and 12 parts of resin.
EXAMPLE III
An environment-friendly quick-drying building material coating comprises 20 parts of nano titanium dioxide, 20 parts of A3 type molecular sieve, 18 parts of methacrylic stearate, 5 parts of tributyl phosphate, 22 parts of ferric chloride, 15 parts of calcium oxide, 15 parts of potassium salt, 5 parts of graphene, 14 parts of chlorinated paraffin, 25 parts of absolute ethyl alcohol, 9 parts of activated carbon, 9 parts of glacial acetic acid, 6 parts of a composite rare earth drier and 14 parts of resin.
The building material coating does not contain harmful substances, has a quick drying effect, can improve the engineering construction efficiency, and has the following advantages: the nano titanium dioxide is called nano titanium dioxide for short, also called nano titanium dioxide, has the effects of ultraviolet resistance, antibiosis, self-cleaning and ageing resistance, and can be used in the fields of cosmetics, functional fibers, plastics, printing ink, coating, paint, fine ceramics, antibacterial agents and the like; the chlorinated paraffin is a chlorinated derivative of paraffin, and has the advantages of low volatility, flame retardance, good electrical insulation, low price and the like; compared with the traditional drier prepared by metals such as cobalt, manganese, lead, zinc, calcium and the like, the rare earth drier has the advantages of less pollution and low price.

Claims (6)

1. An environment-friendly quick-drying building material coating is characterized by comprising 10-20 parts of nano titanium dioxide, 15-20 parts of A3 type molecular sieve, 13-18 parts of methacrylic acid stearate, 1.5-5 parts of tributyl phosphate, 10-22 parts of ferric chloride, 8-15 parts of calcium oxide, 8-15 parts of potassium/zinc salt, 2-5 parts of graphene, 9-14 parts of chlorinated paraffin, 20-25 parts of absolute ethyl alcohol, 3-9 parts of activated carbon, 5-9 parts of glacial acetic acid, 3-6 parts of a composite rare earth drier and 10-14 parts of resin.
2. An environment-friendly quick-drying building material coating as claimed in claim 1, wherein the coating comprises 10 parts of nano titanium dioxide, 15 parts of A3 type molecular sieve, 13 parts of methacrylic acid stearate, 1.5 parts of tributyl phosphate, 10 parts of ferric chloride, 8 parts of calcium oxide, 8 parts of potassium salt, 2 parts of graphene, 9 parts of chlorinated paraffin, 20 parts of absolute ethyl alcohol, 3 parts of activated carbon, 5 parts of glacial acetic acid, 3 parts of composite rare earth drier and 10 parts of resin.
3. An environment-friendly quick-drying building material coating as claimed in claim 1, wherein the coating comprises 15 parts of nano titanium dioxide, 18 parts of A3 type molecular sieve, 15 parts of methacrylic acid stearate, 3 parts of tributyl phosphate, 17 parts of ferric chloride, 12 parts of calcium oxide, 12 parts of potassium salt, 3 parts of graphene, 12 parts of chlorinated paraffin, 13 parts of absolute ethyl alcohol, 6 parts of activated carbon, 7 parts of glacial acetic acid, 4 parts of composite rare earth drier and 12 parts of resin.
4. An environment-friendly quick-drying building material coating as claimed in claim 1, wherein the coating comprises 20 parts of nano titanium dioxide, 20 parts of A3 type molecular sieve, 18 parts of methacrylic acid stearate, 5 parts of tributyl phosphate, 22 parts of ferric chloride, 15 parts of calcium oxide, 15 parts of potassium salt, 5 parts of graphene, 14 parts of chlorinated paraffin, 25 parts of absolute ethyl alcohol, 9 parts of activated carbon, 9 parts of glacial acetic acid, 6 parts of composite rare earth drier and 14 parts of resin.
5. An environment-friendly quick-drying building material coating as claimed in claim 1, wherein the composite rare earth drier is prepared from liquid fusidic acid and rare earth chloride.
6. The preparation method of the environment-friendly quick-drying building material coating is characterized by comprising the following steps of:
(1) uniformly mixing the nano titanium dioxide, calcium oxide, an A3 type molecular sieve and graphene according to a proportion, and grinding the mixture in grinding equipment for 50-60 minutes to obtain a uniform and fine first mixture;
(2) putting the resin, the methacrylic acid stearate, the tributyl phosphate and the active carbon into a planetary ball mill for milling treatment, grinding for 30-40 minutes, and then screening by using a 600-800-mesh screen to obtain a second mixture;
(3) respectively adding ferric chloride and potassium salt into water to form an aqueous solution, introducing absolute ethyl alcohol into the aqueous solution until solids are separated out, and then heating the aqueous solution by a heating instrument until the solids are completely dissolved to obtain a third mixture;
(4) adding the first mixture into the third mixture, and premixing the third mixture for 10-20 minutes by using a stirrer at the stirring speed of 140-240rpm to obtain a fourth mixture;
(5) adding the second mixture, the fourth mixture, the chlorinated paraffin and the composite rare earth drier into a constant-temperature stirring barrel, setting the temperature at 50-70 ℃, then stirring at a high speed of 800rpm for 60-70 minutes at 600-70 rpm, and slowly adding glacial acetic acid into the constant-temperature stirring barrel for the remaining 10-15 minutes of the stirring time to finally form the colloid coating;
(6) and finally, cooling, inspecting, subpackaging, sealing and storing the coating.
CN201911066863.8A 2019-11-04 2019-11-04 Environment-friendly quick-drying building material coating Pending CN112778806A (en)

Priority Applications (1)

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CN201911066863.8A CN112778806A (en) 2019-11-04 2019-11-04 Environment-friendly quick-drying building material coating

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Application Number Priority Date Filing Date Title
CN201911066863.8A CN112778806A (en) 2019-11-04 2019-11-04 Environment-friendly quick-drying building material coating

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CN112778806A true CN112778806A (en) 2021-05-11

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057429A (en) * 2017-03-02 2017-08-18 福州外语外贸学院 A kind of environmentally friendly rapid-curing cutback coating and preparation method thereof
CN107163842A (en) * 2017-07-12 2017-09-15 河南西超实业有限公司 A kind of environmental protection building material coating and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057429A (en) * 2017-03-02 2017-08-18 福州外语外贸学院 A kind of environmentally friendly rapid-curing cutback coating and preparation method thereof
CN107163842A (en) * 2017-07-12 2017-09-15 河南西超实业有限公司 A kind of environmental protection building material coating and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
任友直: "《涂料工业用原材料技术标准手册》", 30 April 1992, 化学工业出版社 *
汪多仁: "《绿色有机中间体》", 30 April 2007, 科学技术文献出版社 *

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Application publication date: 20210511