CN104073091B - A kind of polyvinyl alcohol aqueous architectural coating - Google Patents

A kind of polyvinyl alcohol aqueous architectural coating Download PDF

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Publication number
CN104073091B
CN104073091B CN201410284565.7A CN201410284565A CN104073091B CN 104073091 B CN104073091 B CN 104073091B CN 201410284565 A CN201410284565 A CN 201410284565A CN 104073091 B CN104073091 B CN 104073091B
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parts
polyvinyl alcohol
alcohol aqueous
architectural coating
aqueous architectural
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Expired - Fee Related
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CN201410284565.7A
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CN104073091A (en
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钱玉珠
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Suzhou super coating Co., Ltd.
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Suzhou Jing Yu Novel Material Co Ltd
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Abstract

A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 10-20 part; Zinc sulfide white 5-15 part; Methyl phenyl ketone 15-25 part; Zinc oxide 1-10 part; Paraffin 30-40 part; Deionized water 50-60 part; Phenylformic acid 20-30 part; Pigment 15-25 part; Nitro-cotton 30-40 part; Sodium hexametaphosphate 99 25-35 part; Ethanol 35-45 part; Softening agent 5-10 part; Vinyl acetic monomer 25-35 part; Talcum powder 15-25 part; Trolamine 20-30 part; Product storage is not lumpd for 6-10 month, solid content 35-45%; Surface drying 40-50min, does solid work 20-22h; Without exception soak 10-20d in unsaturated carbonate calcium after; The film 2600-2800 of resistance to wiping time, the widespread production not division of history into periods can replace current material.

Description

A kind of polyvinyl alcohol aqueous architectural coating
Technical field
The application belongs to paint field, particularly relates to a kind of polyvinyl alcohol aqueous architectural coating.
Background technology
Coating, is be applied to body surface can be formed and have protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating." paint finishing can bond very well with body material in body surface and form the material of complete and tough and tensile protective membrane, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, after introducing China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to and is applied to body surface and the general name forming the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, ceiling, ground, and the coating of toilet is called building coating.Building coating has decoration functions, defencive function and livability and improves function.Proportion shared by various function is not quite similar because application target is different.Decoration functions is the function of beautifying the appearance value improving it by buildings.Mainly comprise the design design of plane color, pattern and gloss aspect and the design design of three-dimensional pattern.But to match with the size and shape of the moulding of buildings itself and base material itself, just can fully play out.Defencive function refers to architecture protection thing not by the impact of environment and the function of destruction.The content that different types of protected body requires defencive function is also different.As just very large in the indoor index difference with reaching required by outdoor application.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.
Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.Building coating is mainly used in the coating products of house decoration as a class, and its market development and real estate industry develop closely related.Since " in history the tightest policy of real estate " is put into effect, market of real estate development is absorbed in low ebb, and since especially entering 2012, the policy of before expecting loosens and do not occur, is that firmly the portion of building clearly represents that in the short period of time, policy of regulation and control can not change on the contrary.Some buildingss to mildew-resistant, fire prevention, heat insulating, corrosion-resistant etc. have particular requirement.Livability improves function mainly for indoor application, contributes to the function improving living environment exactly, as sound-proofing, sound absorbing, antisweat etc.And popularizing along with humanity concept, and the formation of novel harmonious society, the polyvinyl alcohol aqueous architectural coating designing a kind of good stability, fast drying, alkali resistance and resistance to wiping excellence is very important.
Summary of the invention
The technical problem solved:
The application, for above-mentioned technical problem, provides a kind of polyvinyl alcohol aqueous architectural coating, solves existing polyvinyl alcohol aqueous architectural coating poor stability, time of drying long, alkali resistance and the technical problem such as resistance to wiping difference.
Technical scheme:
A kind of polyvinyl alcohol aqueous architectural coating, the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 10-20 part; Zinc sulfide white 5-15 part; Methyl phenyl ketone 15-25 part; Zinc oxide 1-10 part; Paraffin 30-40 part; Deionized water 50-60 part; Phenylformic acid 20-30 part; Pigment 15-25 part; Nitro-cotton 30-40 part; Sodium hexametaphosphate 99 25-35 part; Ethanol 35-45 part; Softening agent 5-10 part; Vinyl acetic monomer 25-35 part; Talcum powder 15-25 part; Trolamine 20-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 15 parts; 10 parts, zinc sulfide white; Methyl phenyl ketone 20 parts; 5 parts, zinc oxide; 35 parts, paraffin; Deionized water 55 parts; 25 parts, phenylformic acid; Pigment 20 parts; Nitro-cotton 35 parts; Sodium hexametaphosphate 99 30 parts; Ethanol 40 parts; 8 parts, softening agent; Vinyl acetic monomer 30 parts; Talcum powder 20 parts; Trolamine 25 parts.
As a preferred technical solution of the present invention: described pigment adopts light calcium carbonate.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of polyvinyl alcohol aqueous architectural coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product storage is not lumpd for 6-10 month, solid content 35-45%; 2, surface drying 40-50min, does solid work 20-22h; 3, without exception after soaking 10-20d in unsaturated carbonate calcium; 4, the film 2600-2800 of resistance to wiping time, the widespread production not division of history into periods current material can be replaced.
Embodiment
Embodiment 1:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 10 parts; 5 parts, zinc sulfide white; Methyl phenyl ketone 15 parts; 1 part, zinc oxide; 30 parts, paraffin; Deionized water 50 parts; 20 parts, phenylformic acid; Light calcium carbonate 15 parts; Nitro-cotton 30 parts; Sodium hexametaphosphate 99 25 parts; Ethanol 35 parts; Dibutyl phthalate 5 parts; Vinyl acetic monomer 25 parts; Talcum powder 15 parts; Trolamine 20 parts.
Phenyl aldehyde is added after dissolving in deionized water, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min both obtained finished product.
Product is stored and is not lumpd for 6 months, solid content 35%; Surface drying 50min, does solid work 22h; Without exception soak 10d in unsaturated carbonate calcium after; The resistance to wiping of film 2600 times.
Embodiment 2:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 20 parts; 15 parts, zinc sulfide white; Methyl phenyl ketone 25 parts; 10 parts, zinc oxide; 40 parts, paraffin; Deionized water 60 parts; 30 parts, phenylformic acid; Light calcium carbonate 25 parts; Nitro-cotton 40 parts; Sodium hexametaphosphate 99 35 parts; Ethanol 45 parts; Dibutyl phthalate 10 parts; Vinyl acetic monomer 35 parts; Talcum powder 25 parts; Trolamine 30 parts.
Phenyl aldehyde is added after dissolving in deionized water, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min both obtained finished product.
Product is stored and is not lumpd for 8 months, solid content 40%; Surface drying 45min, does solid work 21h; Without exception soak 15d in unsaturated carbonate calcium after; The resistance to wiping of film 2700 times.
Embodiment 3:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 15 parts; 10 parts, zinc sulfide white; Methyl phenyl ketone 20 parts; 5 parts, zinc oxide; 35 parts, paraffin; Deionized water 55 parts; 25 parts, phenylformic acid; Light calcium carbonate 20 parts; Nitro-cotton 35 parts; Sodium hexametaphosphate 99 30 parts; Ethanol 40 parts; Dibutyl phthalate 8 parts; Vinyl acetic monomer 30 parts; Talcum powder 20 parts; Trolamine 25 parts.
Phenyl aldehyde is added after dissolving in deionized water, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min both obtained finished product.
Product is stored and is not lumpd for 10 months, solid content 45%; Surface drying 40min, does solid work 20h; Without exception soak 20d in unsaturated carbonate calcium after; The resistance to wiping of film 2800 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.

Claims (3)

1. a polyvinyl alcohol aqueous architectural coating, is characterized in that the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 10-20 part; Zinc sulfide white 5-15 part; Methyl phenyl ketone 15-25 part; Zinc oxide 1-10 part; Paraffin 30-40 part; Deionized water 50-60 part; Phenylformic acid 20-30 part; Pigment 15-25 part; Nitro-cotton 30-40 part; Sodium hexametaphosphate 99 25-35 part; Ethanol 35-45 part; Softening agent 5-10 part; Vinyl acetic monomer 25-35 part; Talcum powder 15-25 part; Trolamine 20-30 part;
Described pigment adopts light calcium carbonate.
2. a kind of polyvinyl alcohol aqueous architectural coating according to claim 1, is characterized in that the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: polyvinyl alcohol 100 parts; Phenyl aldehyde 15 parts; 10 parts, zinc sulfide white; Methyl phenyl ketone 20 parts; 5 parts, zinc oxide; 35 parts, paraffin; Deionized water 55 parts; 25 parts, phenylformic acid; Pigment 20 parts; Nitro-cotton 35 parts; Sodium hexametaphosphate 99 30 parts; Ethanol 40 parts; 8 parts, softening agent; Vinyl acetic monomer 30 parts; Talcum powder 20 parts; Trolamine 25 parts.
3. a kind of polyvinyl alcohol aqueous architectural coating according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410284565.7A 2014-06-23 2014-06-23 A kind of polyvinyl alcohol aqueous architectural coating Expired - Fee Related CN104073091B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086667A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Water-based multicolor coating
CN106833070A (en) * 2016-12-30 2017-06-13 芜湖天鸿汽车零部件有限公司 A kind of automobile sun paint and preparation method thereof
CN113278316A (en) * 2021-06-03 2021-08-20 黑龙江佰嘉生物质材料有限公司 Environment-friendly waterproof coating composition for indoor building decoration and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1182762A (en) * 1997-11-03 1998-05-27 马新刚 High hardness water-proof porcelain imitation paint
CN101768398A (en) * 2009-12-16 2010-07-07 上海维凯化学品有限公司 Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof
CN102408793A (en) * 2010-09-21 2012-04-11 苏州美亚美建筑涂料有限公司 Polyvinyl alcohol waterproof coating

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000230144A (en) * 1999-02-10 2000-08-22 Asahi Chem Ind Co Ltd Emulsion of cellulose nitric esters

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1182762A (en) * 1997-11-03 1998-05-27 马新刚 High hardness water-proof porcelain imitation paint
CN101768398A (en) * 2009-12-16 2010-07-07 上海维凯化学品有限公司 Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof
CN102408793A (en) * 2010-09-21 2012-04-11 苏州美亚美建筑涂料有限公司 Polyvinyl alcohol waterproof coating

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Inventor after: Shen Xiaolong

Inventor before: Qian Yuzhu

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Effective date of registration: 20170920

Address after: 215100 Hope Industrial Park, North Qiao Town, Suzhou, Jiangsu, Xiangcheng District

Patentee after: Suzhou super coating Co., Ltd.

Address before: Wujiang City, Suzhou City, 215299 Song Ling Zhen Wu in Jiangsu province with the side of the road

Patentee before: Suzhou Jing Yu novel material company limited

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160210

Termination date: 20190623