CN104073065A - Multicolor sodium carboxymethylcellulose paint - Google Patents

Multicolor sodium carboxymethylcellulose paint Download PDF

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Publication number
CN104073065A
CN104073065A CN201410277445.4A CN201410277445A CN104073065A CN 104073065 A CN104073065 A CN 104073065A CN 201410277445 A CN201410277445 A CN 201410277445A CN 104073065 A CN104073065 A CN 104073065A
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parts
xylo
paint
mucine
multicolor finish
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CN201410277445.4A
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CN104073065B (en
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费金华
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Wujiang Huacheng Composite Technology Co Ltd
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

The invention relates to a multicolor sodium carboxymethylcellulose paint which is prepared from the following raw materials in parts by weight: 100 parts of sodium carboxymethylcellulose, 10 to 20 parts of cyclohexanone, 20 to 30 parts of calcium carbonate, 40 to 50 parts of talcum powder, 10 to 30 parts of polyethylene glycol, 15 to 25 parts of aluminium stearate, 80 to 90 parts of deionized water, 25 to 35 parts of epoxidized soybean oil, 10 to 20 parts of pigment, 25 to 35 parts of castor oil, 5 to 25 parts of ammonium hydroxide, 10 to 30 parts of rosin water, 4 to 10 parts of plasticizer, 35 to 45 parts of paraffin, 30 to 40 parts of naphthalene sulfonic acid sodium salt and 45 to 55 parts of chlorinated rubber. The paint has the good dispersibility; a painting film is resistant to scrubbing, namely the painting film cannot be threadbare even after being scrubbed for 11500 to 12500 times; the solid content of the paint is between 30% and 40%; the painting film cannot be blistered and desquamated after being soaked in water at 20 DEG C for 8 to 10 weeks; the surface of the paint is dried within 20 to 30 minutes; the loss of the paint is within 0.004g/cm<2> to 0.006g/cm<2> after being tested by a reciprocating-type tester for 1000 times; and the painting film is bright in color and good in decorative effect. Thus, the paint can be widely produced and continuously used for replacing the existing material.

Description

A kind of Xylo-Mucine multicolor finish
Technical field
The application belongs to paint field, relates in particular to a kind of Xylo-Mucine multicolor finish.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally taking resin oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of polyethylene glycol.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, and ceiling, ground, the coating of toilet is called building coating.Xylo-Mucine this product is the sodium salt of carboxymethyl cellulose ether, belongs to anionic ether of cellulose, is white or oyster white fibrous powder or particle, density 0.5-0.7 gram/cc, almost odorless, tasteless, tool water absorbability.Be easy to be dispersed in water into transparent colloidal solution, insoluble in the organic solvents such as ethanol.1% aqueous solution pH is 6.5~8.5, and in the time of pH>10 or <5, rubber cement viscosity significantly reduces, performance the best in the time of pH=7.To thermally-stabilised, rise rapidly 20 DEG C of following viscosity, 45 DEG C time, change slowlyer, more than 80 DEG C long-time heating can make its colloid sex change and viscosity and performance obviously decline.Soluble in water, solution is transparent; Very stable in basic solution, meet acid facile hydrolysis, pH value there will be precipitation during for 2-3, meets polyvalent metal salt and also can react appearance and precipitate.
So-called multicolor finish is made up of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, when application, by disposable spray finishing, just can obtain the pattern luxurious, attractive in appearance, Xylo-Mucine is colorful.And universal along with humanity concept, and the formation of novel harmonious society, the Xylo-Mucine multicolor finish that designs a kind of water tolerance, scrub resistance and excellent in abrasion resistance is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of Xylo-Mucine multicolor finish, solves existing Xylo-Mucine multicolor finish water tolerance and scrub resistance is poor, decorative effect is poor, the technical problem such as rub resistance not.
Technical scheme:
A kind of Xylo-Mucine multicolor finish, the raw materials by weight portion proportioning of described Xylo-Mucine multicolor finish is as follows: 100 parts of Xylo-Mucines; Pimelinketone 10-20 part; Calcium carbonate 20-30 part; Talcum powder 40-50 part; Polyethylene glycol 10-30 part; Aluminum stearate 15-25 part; Deionized water 80-90 part; Epoxy soybean oil 25-35 part; Pigment 10-20 part; Viscotrol C 25-35 part; Ammonium hydroxide 5-25 part; Rosin 10-30 part; Softening agent 4-10 part; Paraffin 35-45 part; Sodium naphthalene sulfonate 30-40 part; Chlorinated rubber 45-55 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described Xylo-Mucine multicolor finish is as follows: 100 parts of Xylo-Mucines; 15 parts of pimelinketone; 25 parts, calcium carbonate; 45 parts of talcum powder; 20 parts of polyethylene glycols; 20 parts of aluminum stearates; 85 parts of deionized waters; 30 parts of epoxy soybean oils; 15 parts of pigment; 30 parts of Viscotrol C; 15 parts, ammonium hydroxide; 20 parts, rosin; 7 parts, softening agent; 40 parts, paraffin; 35 parts of sodium naphthalene sulfonates; 50 parts of chlorinated rubbers.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of Xylo-Mucine multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, good product dispersibility, and film scrubbing resistance 11500-12500 time is not show-through; 2, solid content 30-40%, non-foaming soak 8-10 week in 20 DEG C of water after, dry linting not; 3, surface drying 20-30min, 1000 loss 0.004-0.006g/cm of reciprocating trier 2; 4, bright in luster, the good decorating effect of film, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
A kind of Xylo-Mucine multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of Xylo-Mucines; 10 parts of pimelinketone; 20 parts, calcium carbonate; 40 parts of talcum powder; 10 parts of polyethylene glycols; 15 parts of aluminum stearates; 80 parts of deionized waters; 25 parts of epoxy soybean oils; 10 parts of iron oxide greens; 25 parts of Viscotrol C; 5 parts, ammonium hydroxide; 10 parts, rosin; 4 parts of dibutyl phthalates; 35 parts, paraffin; 30 parts of sodium naphthalene sulfonates; 45 parts of chlorinated rubbers.
Xylo-Mucine, calcium carbonate, talcum powder, polyethylene glycol and aluminum stearate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy soybean oil, Viscotrol C, ammonium hydroxide, rosin, sodium naphthalene sulfonate and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add pimelinketone and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 11500 times is not show-through; Solid content 30% soaks non-foaming after 8 weeks, dry linting not in 20 DEG C of water; Surface drying 30min, 1000 loss 0.006g/cm of reciprocating trier 2.
Embodiment 2:
A kind of Xylo-Mucine multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of Xylo-Mucines; 20 parts of pimelinketone; 30 parts, calcium carbonate; 50 parts of talcum powder; 30 parts of polyethylene glycols; 25 parts of aluminum stearates; 90 parts of deionized waters; 35 parts of epoxy soybean oils; 20 parts of iron oxide yellow; 35 parts of Viscotrol C; 25 parts, ammonium hydroxide; 30 parts, rosin; 10 parts of dibutyl phthalates; 45 parts, paraffin; 40 parts of sodium naphthalene sulfonates; 55 parts of chlorinated rubbers.
Xylo-Mucine, calcium carbonate, talcum powder, polyethylene glycol and aluminum stearate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy soybean oil, Viscotrol C, ammonium hydroxide, rosin, sodium naphthalene sulfonate and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add pimelinketone and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 12000 times is not show-through; Solid content 35% soaks non-foaming after 9 weeks, dry linting not in 20 DEG C of water; Surface drying 25min, 1000 loss 0.005g/cm of reciprocating trier 2.
Embodiment 3:
A kind of Xylo-Mucine multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of Xylo-Mucines; 15 parts of pimelinketone; 25 parts, calcium carbonate; 45 parts of talcum powder; 20 parts of polyethylene glycols; 20 parts of aluminum stearates; 85 parts of deionized waters; 30 parts of epoxy soybean oils; 15 parts of red iron oxides; 30 parts of Viscotrol C; 15 parts, ammonium hydroxide; 20 parts, rosin; 7 parts of dibutyl phthalates; 40 parts, paraffin; 35 parts of sodium naphthalene sulfonates; 50 parts of chlorinated rubbers.
Xylo-Mucine, calcium carbonate, talcum powder, polyethylene glycol and aluminum stearate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy soybean oil, Viscotrol C, ammonium hydroxide, rosin, sodium naphthalene sulfonate and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add pimelinketone and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 12500 times is not show-through; Solid content 40% soaks non-foaming after 10 weeks, dry linting not in 20 DEG C of water; Surface drying 20min, 1000 loss 0.004g/cm of reciprocating trier 2.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.

Claims (4)

1. an Xylo-Mucine multicolor finish, is characterized in that the raw materials by weight portion proportioning of described Xylo-Mucine multicolor finish is as follows: 100 parts of Xylo-Mucines; Pimelinketone 10-20 part; Calcium carbonate 20-30 part; Talcum powder 40-50 part; Polyethylene glycol 10-30 part; Aluminum stearate 15-25 part; Deionized water 80-90 part; Epoxy soybean oil 25-35 part; Pigment 10-20 part; Viscotrol C 25-35 part; Ammonium hydroxide 5-25 part; Rosin 10-30 part; Softening agent 4-10 part; Paraffin 35-45 part; Sodium naphthalene sulfonate 30-40 part; Chlorinated rubber 45-55 part.
2. a kind of Xylo-Mucine multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described Xylo-Mucine multicolor finish is as follows: 100 parts of Xylo-Mucines; 15 parts of pimelinketone; 25 parts, calcium carbonate; 45 parts of talcum powder; 20 parts of polyethylene glycols; 20 parts of aluminum stearates; 85 parts of deionized waters; 30 parts of epoxy soybean oils; 15 parts of pigment; 30 parts of Viscotrol C; 15 parts, ammonium hydroxide; 20 parts, rosin; 7 parts, softening agent; 40 parts, paraffin; 35 parts of sodium naphthalene sulfonates; 50 parts of chlorinated rubbers.
3. a kind of Xylo-Mucine multicolor finish according to claim 1, is characterized in that: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
4. a kind of Xylo-Mucine multicolor finish according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410277445.4A 2014-06-20 2014-06-20 A kind of Xylo-Mucine multicolor finish Active CN104073065B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831550A (en) * 2015-05-05 2015-08-12 湖州哲豪丝绸有限公司 Novel moisture-proof pigment for linen
CN105462492A (en) * 2015-12-31 2016-04-06 文登蓝岛建筑工程有限公司 Environment-friendly paint and preparation method thereof
CN107201072A (en) * 2017-06-17 2017-09-26 常州新区金利宝塑料制品有限公司 A kind of powder of lacquer putty for use on and preparation method thereof
CN115058138A (en) * 2022-08-01 2022-09-16 佛山市高明大都化工有限公司 Water-based rubber treating agent

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Publication number Priority date Publication date Assignee Title
CN101429368A (en) * 2008-12-06 2009-05-13 王月琴 Method for producing water type multicolor paint for water drum
CN101838489A (en) * 2010-05-31 2010-09-22 刘昆虎 Undersurface syncretic anti-corrosion paint
CN102850877A (en) * 2012-08-30 2013-01-02 青岛保利康新材料有限公司 Preparation method for water-based damping paint with high solid content and high damping performance
CN102993791A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Metal paint and preparation method thereof
CN102993832A (en) * 2012-10-16 2013-03-27 益阳祥瑞科技有限公司 Chlorinated rubber iron oxide red primer

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Publication number Priority date Publication date Assignee Title
CN101429368A (en) * 2008-12-06 2009-05-13 王月琴 Method for producing water type multicolor paint for water drum
CN101838489A (en) * 2010-05-31 2010-09-22 刘昆虎 Undersurface syncretic anti-corrosion paint
CN102850877A (en) * 2012-08-30 2013-01-02 青岛保利康新材料有限公司 Preparation method for water-based damping paint with high solid content and high damping performance
CN102993791A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Metal paint and preparation method thereof
CN102993832A (en) * 2012-10-16 2013-03-27 益阳祥瑞科技有限公司 Chlorinated rubber iron oxide red primer

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831550A (en) * 2015-05-05 2015-08-12 湖州哲豪丝绸有限公司 Novel moisture-proof pigment for linen
CN105462492A (en) * 2015-12-31 2016-04-06 文登蓝岛建筑工程有限公司 Environment-friendly paint and preparation method thereof
CN107201072A (en) * 2017-06-17 2017-09-26 常州新区金利宝塑料制品有限公司 A kind of powder of lacquer putty for use on and preparation method thereof
CN115058138A (en) * 2022-08-01 2022-09-16 佛山市高明大都化工有限公司 Water-based rubber treating agent
CN115058138B (en) * 2022-08-01 2023-03-14 佛山市高明大都化工有限公司 Water-based rubber treating agent

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