CN104119709B - A kind of alkaline-resisting multicolor finish - Google Patents
A kind of alkaline-resisting multicolor finish Download PDFInfo
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- CN104119709B CN104119709B CN201410374945.XA CN201410374945A CN104119709B CN 104119709 B CN104119709 B CN 104119709B CN 201410374945 A CN201410374945 A CN 201410374945A CN 104119709 B CN104119709 B CN 104119709B
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- parts
- acetate
- resisting
- alkaline
- multicolor finish
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- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920002160 Celluloid Polymers 0.000 claims abstract description 13
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 12
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- FQENQNTWSFEDLI-UHFFFAOYSA-J Tetrasodium pyrophosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 11
- FUZZWVXGSFPDMH-UHFFFAOYSA-M caproate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 11
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 11
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 11
- YKYONYBAUNKHLG-UHFFFAOYSA-N Propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940011051 isopropyl acetate Drugs 0.000 claims abstract description 10
- GWYFCOCPABKNJV-UHFFFAOYSA-M isovalerate Chemical compound CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- WXEHBUMAEPOYKP-UHFFFAOYSA-N methylsulfanylethane Chemical compound CCSC WXEHBUMAEPOYKP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 239000004952 Polyamide Substances 0.000 claims abstract description 5
- 229920002647 polyamide Polymers 0.000 claims abstract description 5
- 239000011528 polyamide (building material) Substances 0.000 claims abstract description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910000460 iron oxide Inorganic materials 0.000 claims description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N Dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 7
- 239000007787 solid Substances 0.000 abstract description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 5
- 238000003756 stirring Methods 0.000 abstract description 5
- 239000002932 luster Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000002791 soaking Methods 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 16
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 9
- 239000003973 paint Substances 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 239000002585 base Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- LJSQFQKUNVCTIA-UHFFFAOYSA-N Diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229960004599 sodium borate Drugs 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- -1 Butyl ester Chemical class 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N Phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N Potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- ZTHYODDOHIVTJV-UHFFFAOYSA-N propyl 3,4,5-trihydroxybenzoate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Abstract
A kind of alkaline-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of celluloid；Toluene 45 55 parts；Sodium pyrophosphate 5 15 parts；Isopropyl acetate 10 20 parts；Sodium borate 15 35 parts；N-propyl acetate 15 25 parts；Deionized water 80 90 parts；N-butyl acetate 20 30 parts；Pigment 10 20 parts；N-butyl alcohol 25 35 parts；Methyl ethyl sulfide 30 40 parts；Isopropanol 10 30 parts；Plasticizer 4 10 parts；Ethyl acetate 20 40 parts；Maleic anhydride 15 35 parts；Polyamide 25 45 parts；Adhesion during product stirring, film scrub resistance 4,000 5000 times；Non-foaming, not dry linting after soaking 60 90d in 20 DEG C of water；30 60d are soaked unchanged in saturated calcium hydroxide；Surface drying 20 30min, does solid work 4 6h, and film is bright in luster, good decorating effect, can be with the widespread production not division of history into periods for current material.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of alkaline-resisting multicolor finish.
Background technology
Coating, at the entitled paint of Chinese tradition.So-called coating is to be coated in be protected or filled
The body surface of decorations, and can be with the continuous film of coated article formation firm attachment, it is common that with tree
Fat or oil or emulsion are main, add or without pigment, filler, add corresponding additive,
With the formulated thick liquid of organic solvent or sodium borate.China's coating circle is more authoritative
" coating process " book is defined such that " coating is a kind of material, and this material is permissible
Be coated in object surface by different construction technologies, formed adhere to firmly, have some strength,
Continuous print solid film.The film common name film so formed, also known as paint film or coating." coating
Cover with paint, lacquer, colour wash, etc. and can very well bond with matrix material in body surface and form complete and tough and tensile protecting film
Material, referred to as coating.Coating and paint are the identicals concept.Paint is people's habits used for a long time
Used title, after introducing China, utilizes in building trade the most always.The effect of coating can be general
Including is three aspects: protective effect, decoration function, specific function effect.General group of coating
Become: comprise film forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to be applied to body surface and can form the general name of the material of tough and tensile protecting film, builds
Building coating is an important class in coating, in China, typically will be used for inner wall of building,
Exterior wall, ceiling, ground, the coating of toilet is referred to as building coating.Celluloid is commonly called as nitre
Cellulose, for the product of cellulose Yu nitric acid esterification.Nitric acid with cotton fiber as raw material
Cellulose is referred to as nitrocotton.Celluloid is a kind of white fibrous polymer, water-fast, resistance to
Diluted acid, resistance to weak base and various oils.The degree of polymerization is different, and its intensity is the most different, but is all thermoplastic
Property material.The most easy to change, and easily burn.
So-called alkaline-resisting multicolor finish is made up of two incompatible phase constituents, and wherein a phase dispersion is situated between
Matter is continuous phase, and another phase is dispersion phase, during application, by disposable spray finishing, just can get
Colorful pattern luxurious, attractive in appearance, alkaline-resisting.And along with the universal and novel of humanity concept and
The composition of humorous society, designs the alkaline-resisting colorful of a kind of resistance to water, scrub resistance and alkali resistance excellence
Coating is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of alkaline-resisting multicolor finish, solves existing resistance to
Alkali multicolor finish resistance to water and scrub resistance is poor, decorative effect is poor, not the technology such as alkali corrosion resistance ask
Topic.
Technical scheme:
A kind of alkaline-resisting multicolor finish, the raw materials by weight portion proportioning of described alkaline-resisting multicolor finish is such as
Under: 100 parts of celluloid；Toluene 45-55 part；Sodium pyrophosphate 5-15 part；Acetic acid is different
Propyl ester 10-20 part；Sodium borate 15-35 part；N-propyl acetate 15-25 part；Deionized water
80-90 part；N-butyl acetate 20-30 part；Pigment 10-20 part；N-butyl alcohol 25-35 part；
Methyl ethyl sulfide 30-40 part；Isopropanol 10-30 part；Plasticizer 4-10 part；Acetic acid second
Ester 20-40 part；Maleic anhydride 15-35 part；Polyamide 25-45 part.
As a preferred technical solution of the present invention: the raw material of described alkaline-resisting multicolor finish is by weight
Amount number proportioning is as follows: 100 parts of celluloid；Toluene 50 parts；Sodium pyrophosphate 10 parts；
Isopropyl acetate 15 parts；Sodium borate 25 parts；N-propyl acetate 20 parts；Deionized water 85 parts；
N-butyl acetate 25 parts；Pigment 15 parts；N-butyl alcohol 30 parts；Methyl ethyl sulfide 35 parts；
Isopropanol 20 parts；Plasticizer 8 parts；Ethyl acetate 30 parts；Maleic anhydride 25 parts；
Kymene 5 parts.
As a preferred technical solution of the present invention: described pigment uses iron oxide red, oxidation
Ferrum is green or iron oxide yellow.
As a preferred technical solution of the present invention: described plasticizer uses phthalic acid two
Butyl ester.
Beneficial effect:
The alkaline-resisting multicolor finish of one of the present invention uses above technical scheme and prior art phase
Ratio, have following technical effect that 1, product stirring time adhesion, film scrub resistance
4000-5000 time；2, in 20 DEG C of water, non-foaming after 60-90d, not dry linting is soaked；3、
30-60d is soaked unchanged in saturated calcium hydroxide；4, surface drying 20-30min, does solid work 4-6h,
Film is bright in luster, good decorating effect, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
A kind of alkaline-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: celluloid
100 parts；Toluene 45 parts；Sodium pyrophosphate 5 parts；Isopropyl acetate 10 parts；Sodium borate 15
Part；N-propyl acetate 15 parts；Deionized water 80 parts；N-butyl acetate 20 parts；Ferrum oxide
Green 10 parts；N-butyl alcohol 25 parts；Methyl ethyl sulfide 30 parts；Isopropanol 10 parts；Adjacent benzene two
Formic acid dibutyl ester 4 parts；Ethyl acetate 20 parts；Maleic anhydride 15 parts；Polyamide 25
Part.
Celluloid, sodium pyrophosphate, isopropyl acetate, sodium borate and n-propyl acetate are added
Enter in deionized water, be heated to 40 DEG C of stirring 3h, add n-butyl acetate, n-butyl alcohol, first
Base ethyl thioether, isopropanol, maleic anhydride and dibutyl phthalate, be warming up to
50 DEG C, with ball mill ball milling 10min, add toluene and surplus stock, are warming up to 60 DEG C of stirrings
Both finished product had been obtained after 10h.
Film scrub resistance 4000 times；Non-foaming after 60d, not dry linting is soaked in 20 DEG C of water；
30d is soaked unchanged in saturated calcium hydroxide；Surface drying 30min, does solid work 6h.
Embodiment 2:
A kind of alkaline-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: celluloid
100 parts；Toluene 55 parts；Sodium pyrophosphate 15 parts；Isopropyl acetate 20 parts；Sodium borate 35
Part；N-propyl acetate 25 parts；Deionized water 90 parts；N-butyl acetate 30 parts；Ferrum oxide
Yellow 20 parts；N-butyl alcohol 35 parts；Methyl ethyl sulfide 40 parts；Isopropanol 30 parts；Adjacent benzene two
Formic acid dibutyl ester 10 parts；Ethyl acetate 40 parts；Maleic anhydride 35 parts；Polyamide 45
Part.
Celluloid, sodium pyrophosphate, isopropyl acetate, sodium borate and n-propyl acetate are added
Enter in deionized water, be heated to 40 DEG C of stirring 3h, add n-butyl acetate, n-butyl alcohol, first
Base ethyl thioether, isopropanol, maleic anhydride and dibutyl phthalate, be warming up to
50 DEG C, with ball mill ball milling 10min, add toluene and surplus stock, are warming up to 60 DEG C of stirrings
Both finished product had been obtained after 10h.
Film scrub resistance 4500 times；Non-foaming after 80d, not dry linting is soaked in 20 DEG C of water；
45d is soaked unchanged in saturated calcium hydroxide；Surface drying 250min, does solid work 5h.
Embodiment 3:
A kind of alkaline-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: celluloid
100 parts；Toluene 50 parts；Sodium pyrophosphate 10 parts；Isopropyl acetate 15 parts；Sodium borate 25
Part；N-propyl acetate 20 parts；Deionized water 85 parts；N-butyl acetate 25 parts；Ferrum oxide
Red 15 parts；N-butyl alcohol 30 parts；Methyl ethyl sulfide 35 parts；Isopropanol 20 parts；Adjacent benzene two
Formic acid dibutyl ester 8 parts；Ethyl acetate 30 parts；Maleic anhydride 25 parts；Kymene 5
Part.
Celluloid, sodium pyrophosphate, isopropyl acetate, sodium borate and n-propyl acetate are added
Enter in deionized water, be heated to 40 DEG C of stirring 3h, add n-butyl acetate, n-butyl alcohol, first
Base ethyl thioether, isopropanol, maleic anhydride and dibutyl phthalate, be warming up to
50 DEG C, with ball mill ball milling 10min, add toluene and surplus stock, are warming up to 60 DEG C of stirrings
Both finished product had been obtained after 10h.
Film scrub resistance 5000 times；Non-foaming after 90d, not dry linting is soaked in 20 DEG C of water；
60d is soaked unchanged in saturated calcium hydroxide；Surface drying 20min, does solid work 4h.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of
This any change in the implication suitable with claims of the present invention and scope, all should
It is considered to be included within the scope of the claims.
Claims (2)
1. an alkaline-resisting multicolor finish, it is characterised in that the raw material of described alkaline-resisting multicolor finish is pressed
Parts by weight proportioning is as follows: 100 parts of celluloid；Toluene 45-55 part；Sodium pyrophosphate
5-15 part；Isopropyl acetate 10-20 part；Sodium borate 15-35 part；N-propyl acetate 15-25
Part；Deionized water 80-90 part；N-butyl acetate 20-30 part；Pigment 10-20 part；Positive fourth
Alcohol 25-35 part；Methyl ethyl sulfide 30-40 part；Isopropanol 10-30 part；Plasticizer 4-10
Part；Ethyl acetate 20-40 part；Maleic anhydride 15-35 part；Polyamide 25-45 part；
Described pigment uses iron oxide red, iron oxide green or iron oxide yellow；
Described plasticizer uses dibutyl phthalate.
The alkaline-resisting multicolor finish of one the most according to claim 1, it is characterised in that described
The raw materials by weight portion proportioning of alkaline-resisting multicolor finish is as follows: 100 parts of celluloid；Toluene
50 parts；Sodium pyrophosphate 10 parts；Isopropyl acetate 15 parts；Sodium borate 25 parts；Acetic acid positive third
Ester 20 parts；Deionized water 85 parts；N-butyl acetate 25 parts；Pigment 15 parts；N-butyl alcohol
30 parts；Methyl ethyl sulfide 35 parts；Isopropanol 20 parts；Plasticizer 8 parts；Ethyl acetate
30 parts；Maleic anhydride 25 parts；Kymene 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410374945.XA CN104119709B (en) | 2014-08-01 | A kind of alkaline-resisting multicolor finish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410374945.XA CN104119709B (en) | 2014-08-01 | A kind of alkaline-resisting multicolor finish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119709A CN104119709A (en) | 2014-10-29 |
| CN104119709B true CN104119709B (en) | 2016-11-30 |
Family
ID=
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076466A (en) * | 1993-03-05 | 1993-09-22 | 王学铭 | A kind of pearlite plastic spraying coating and preparation method thereof |
| CN1095733A (en) * | 1993-05-21 | 1994-11-30 | 定兴县光华科技实业公司 | Multicolor finish and preparation technology thereof |
| CN101338149A (en) * | 2008-08-11 | 2009-01-07 | 常熟市蓝都弹性涂料有限公司 | Water-soluble colorful coating and preparation thereof |
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076466A (en) * | 1993-03-05 | 1993-09-22 | 王学铭 | A kind of pearlite plastic spraying coating and preparation method thereof |
| CN1095733A (en) * | 1993-05-21 | 1994-11-30 | 定兴县光华科技实业公司 | Multicolor finish and preparation technology thereof |
| CN101338149A (en) * | 2008-08-11 | 2009-01-07 | 常熟市蓝都弹性涂料有限公司 | Water-soluble colorful coating and preparation thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Fei Jinhua Inventor after: Luo Chuntao Inventor before: Fei Jinhua |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20160930 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Yukui Address before: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Wu highway Applicant before: Wujiang Huacheng Composite Technology Co., Ltd. |
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| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Shanjiang Inventor after: Liu Zhanchuan Inventor after: Mei Shaofeng Inventor after: Hu Zhongyuan Inventor after: Dong Lizhi Inventor before: Fei Jinhua Inventor before: Luo Chuntao |
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| TR01 | Transfer of patent right |
Effective date of registration: 20171016 Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1 Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Yukui |
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| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20161130 |
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| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20161130 |