CN104119754B - A kind of acrylic ester multicolor finish - Google Patents

A kind of acrylic ester multicolor finish Download PDF

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CN104119754B
CN104119754B CN201410374549.7A CN201410374549A CN104119754B CN 104119754 B CN104119754 B CN 104119754B CN 201410374549 A CN201410374549 A CN 201410374549A CN 104119754 B CN104119754 B CN 104119754B
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acrylic ester
multicolor finish
barite
nitrocotton
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CN104119754A (en
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费金华
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

A kind of acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: acrylic emulsion 100 parts; Nitrocotton 5-15 part; Methacrylic resin 20-30 part; Toluene 40-60 part; Polyoxyethylenealkylphenol ether 1-10 part; Hydroxyethyl cellulose 10-20 part; Deionized water 80-90 part; Dimethyl aminomethyl propanol 5-25 part; Pigment 10-20 part; Barite 10-30 part; Titanium dioxide 15-25 part; Paraffin 15-35 part; Plasticizer 4-10 part; Butanol 35-45 part; Butyl acetate 20-40 part; Dimethylbenzene 30-40 part; During Product mix, colors are uniformly, film scrub resistance 3000-5000 time; Cohesive force 100%, soaks non-foaming after 40-60d, not dry linting in 20 DEG C of water; Surface drying 30-50min, soaks 20-30d unchanged in aqueous alkali; Film is bright in luster, good decorating effect, it is possible to current material is replaced in the widespread production not division of history into periods.

Description

A kind of acrylic ester multicolor finish
Technical field
The application belongs to paint field, particularly relates to a kind of acrylic ester multicolor finish.
Background technology
Coating, is called paint in Chinese tradition name. So-called coating is to be coated in protected or decorated body surface; and the continuous film of firm attachment can be formed with coated article; usually based on resin or oily or emulsion; add or without pigment, filler; add corresponding additive, with the formulated thick liquid of organic solvent or polyoxyethylenealkylphenol ether. China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, and this material can be coated in object surface by different construction technologies, is formed and adheres to firmly, has some strength, continuous print solid film. The film common name film so formed, also known as paint film or coating. " paint finishing can bond and be formed the material of complete and tough and tensile protecting film very well in body surface with matrix material, is called coating. Coating and paint are the identicals concept. Paint is people's custom titles used for a long time, after introducing China, just utilizes in building trade always. The effect of coating may be summarized to be three aspects: protective effect, decoration function, specific function effect. The general composition of coating: comprise film forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to and is applied to body surface and can form the general name of the material of tough and tensile protecting film, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, ceiling, ground, and the coating of toilet is called building coating. The general name of the esters of acrylic acid and homologue thereof. Important has acrylic acid methyl ester., ethyl acrylate, 2-methyl methacrylate and ethyl 2-methacrylate etc. Can autohemagglutination or and other monomer copolymerizations, be the monomer manufacturing adhesive, synthetic resin, specific rubber and plastics.
So-called multicolor finish is made up of inconsistent two phase constituents, and wherein a phase disperse medium is continuous phase, and another phase is dispersion phase, during application, by disposable spray finishing, just can obtain pattern luxurious, attractive in appearance, that acrylic ester is colorful. And popularizing along with humanity concept, and the composition of novel harmonious society, the acrylic ester multicolor finish designing a kind of resistance to water, scrub resistance and alkali resistance excellent is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of acrylic ester multicolor finish, solves existing acrylic ester multicolor finish resistance to water and scrub resistance is poor, decorative effect is poor, the not technical problem such as alkali corrosion resistance.
Technical scheme:
A kind of acrylic ester multicolor finish, the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: acrylic emulsion 100 parts; Nitrocotton 5-15 part; Methacrylic resin 20-30 part; Toluene 40-60 part; Polyoxyethylenealkylphenol ether 1-10 part; Hydroxyethyl cellulose 10-20 part; Deionized water 80-90 part; Dimethyl aminomethyl propanol 5-25 part; Pigment 10-20 part; Barite 10-30 part; Titanium dioxide 15-25 part; Paraffin 15-35 part; Plasticizer 4-10 part; Butanol 35-45 part; Butyl acetate 20-40 part; Dimethylbenzene 30-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: acrylic emulsion 100 parts; Nitrocotton 10 parts; Methacrylic resin 25 parts; Toluene 50 parts; Polyoxyethylenealkylphenol ether 5 parts; Hydroxyethyl cellulose 15 parts; Deionized water 85 parts; Dimethyl aminomethyl propanol 15 parts; Pigment 15 parts; 20 parts of barite; Titanium dioxide 20 parts; 25 parts of paraffin; Plasticizer 7 parts; 40 parts of butanol; Butyl acetate 30 parts; Dimethylbenzene 35 parts.
As a preferred technical solution of the present invention: described pigment adopts iron oxide red, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described plasticizer adopts dibutyl phthalate.
Beneficial effect:
A kind of acrylic ester multicolor finish of the present invention adopts above technical scheme compared with prior art, have following technical effect that 1, Product mix time assorted uniformly, film scrub resistance 3000-5000 time; 2, cohesive force 100%, soaks non-foaming after 40-60d, not dry linting in 20 DEG C of water; 3, surface drying 30-50min, soaks 20-30d unchanged in aqueous alkali; 4, film is bright in luster, good decorating effect, it is possible to current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Embodiment 1:
A kind of acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: acrylic emulsion 100 parts; Nitrocotton 5 parts; Methacrylic resin 20 parts; Toluene 40 parts; Polyoxyethylenealkylphenol ether 1 part; Hydroxyethyl cellulose 10 parts; Deionized water 80 parts; Dimethyl aminomethyl propanol 5 parts; Iron oxide red 10 parts; 10 parts of barite; Titanium dioxide 15 parts; 15 parts of paraffin; Dibutyl phthalate 4 parts; 35 parts of butanol; Butyl acetate 20 parts; Dimethylbenzene 30 parts.
Acrylic emulsion, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and hydroxyethyl cellulose are added in deionized water, heat to 40 DEG C of stirring 3h, add dimethyl aminomethyl propanol, barite, titanium dioxide, paraffin, butyl acetate and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add nitrocotton and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Film scrub resistance 3000 times, cohesive force 100%, 20 DEG C of water soaks non-foaming after 40d, not dry linting; Surface drying 50min, soaks 20d unchanged in aqueous alkali.
Embodiment 2:
A kind of acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: acrylic emulsion 100 parts; Nitrocotton 15 parts; Methacrylic resin 30 parts; Toluene 60 parts; Polyoxyethylenealkylphenol ether 10 parts; Hydroxyethyl cellulose 20 parts; Deionized water 90 parts; Dimethyl aminomethyl propanol 25 parts; Iron oxide yellow 20 parts; 30 parts of barite; Titanium dioxide 25 parts; 35 parts of paraffin;Dibutyl phthalate 10 parts; 45 parts of butanol; Butyl acetate 40 parts; Dimethylbenzene 40 parts.
Acrylic emulsion, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and hydroxyethyl cellulose are added in deionized water, heat to 40 DEG C of stirring 3h, add dimethyl aminomethyl propanol, barite, titanium dioxide, paraffin, butyl acetate and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add nitrocotton and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Film scrub resistance 4000 times, cohesive force 100%, 20 DEG C of water soaks non-foaming after 50d, not dry linting; Surface drying 40min, soaks 25d unchanged in aqueous alkali.
Embodiment 3:
A kind of acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: acrylic emulsion 100 parts; Nitrocotton 10 parts; Methacrylic resin 25 parts; Toluene 50 parts; Polyoxyethylenealkylphenol ether 5 parts; Hydroxyethyl cellulose 15 parts; Deionized water 85 parts; Dimethyl aminomethyl propanol 15 parts; Iron oxide green 15 parts; 20 parts of barite; Titanium dioxide 20 parts; 25 parts of paraffin; Dibutyl phthalate 7 parts; 40 parts of butanol; Butyl acetate 30 parts; Dimethylbenzene 35 parts.
Acrylic emulsion, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and hydroxyethyl cellulose are added in deionized water, heat to 40 DEG C of stirring 3h, add dimethyl aminomethyl propanol, barite, titanium dioxide, paraffin, butyl acetate and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add nitrocotton and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Film scrub resistance 5000 times, cohesive force 100%, 20 DEG C of water soaks non-foaming after 60d, not dry linting; Surface drying 30min, soaks 30d unchanged in aqueous alkali.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to present disclosure is illustrated, rather than restriction, and the therefore any change in the implication suitable with claims of the present invention and scope, all it is believed that be included in the scope of claims.

Claims (2)

1. an acrylic ester multicolor finish, it is characterised in that the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: acrylic emulsion 100 parts; Nitrocotton 5-15 part; Methacrylic resin 20-30 part; Toluene 40-60 part; Polyoxyethylenealkylphenol ether 1-10 part; Hydroxyethyl cellulose 10-20 part; Deionized water 80-90 part; Dimethyl aminomethyl propanol 5-25 part; Pigment 10-20 part; Barite 10-30 part; Titanium dioxide 15-25 part; Paraffin 15-35 part; Plasticizer 4-10 part; Butanol 35-45 part; Butyl acetate 20-40 part; Dimethylbenzene 30-40 part;
Described pigment adopts iron oxide red, iron oxide green or iron oxide yellow;
Described plasticizer adopts dibutyl phthalate.
2. a kind of acrylic ester multicolor finish according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: acrylic emulsion 100 parts; Nitrocotton 10 parts; Methacrylic resin 25 parts; Toluene 50 parts; Polyoxyethylenealkylphenol ether 5 parts; Hydroxyethyl cellulose 15 parts; Deionized water 85 parts; Dimethyl aminomethyl propanol 15 parts; Pigment 15 parts; 20 parts of barite; Titanium dioxide 20 parts; 25 parts of paraffin; Plasticizer 7 parts; 40 parts of butanol; Butyl acetate 30 parts;Dimethylbenzene 35 parts.
CN201410374549.7A 2014-08-01 2014-08-01 A kind of acrylic ester multicolor finish Active CN104119754B (en)

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Publication number Priority date Publication date Assignee Title
CN105062165A (en) * 2015-08-03 2015-11-18 苏州舒而适纺织新材料科技有限公司 Acrylic acid multi-color pattern coating material
CN107793860A (en) * 2017-09-28 2018-03-13 马鞍山松鹤信息科技有限公司 A kind of acrylic acid composite coating and preparation method thereof
CN108034316A (en) * 2017-12-19 2018-05-15 中山市雅乐思商住电器有限公司 Nitro transparent primer and application thereof
CN109763352B (en) * 2019-01-10 2021-07-27 南方科技大学 Dyeing liquid for nylon parts and surface coloring treatment method for nylon parts
CN114804787B (en) * 2022-06-09 2023-07-25 新化县天马建筑新材料科技有限公司 High-adhesion high-weather-resistance ceramic tile adhesive mortar and preparation method thereof

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Publication number Priority date Publication date Assignee Title
US5340389A (en) * 1993-06-18 1994-08-23 Brymore Enterprises S.A. Water based multicolor coating compositions and process for their preparation
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1580139A (en) * 2003-08-07 2005-02-16 王光胜 Natural multi-colour mineral decorative coating (true-stone paint)

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Effective date of registration: 20180905

Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: 215200 Lao Wu Tong Highway, Songling Town, Wujiang District, Suzhou, Jiangsu

Patentee before: Wujiang Huacheng Composite Technology Co., Ltd.

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Address after: 072550 No.53, zone 1, Shenjiazhuang village, Gaolin village, Xushui District, Baoding City, Hebei Province

Patentee after: Wang Shuai

Address before: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1

Patentee before: HEBEI CHENYANG INDUSTRY & TRADE GROUP., Ltd.

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