CN104119754A - Acrylate series colorful coating material - Google Patents

Acrylate series colorful coating material Download PDF

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Publication number
CN104119754A
CN104119754A CN201410374549.7A CN201410374549A CN104119754A CN 104119754 A CN104119754 A CN 104119754A CN 201410374549 A CN201410374549 A CN 201410374549A CN 104119754 A CN104119754 A CN 104119754A
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parts
coating material
acrylate series
acrylic ester
multicolor finish
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CN201410374549.7A
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CN104119754B (en
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费金华
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

The invention relates to an acrylate series colorful coating material. The acrylate series colorful coating material is prepared from the following raw materials in parts by weight: 100 parts of acrylic emulsion, 5-15 parts of nitro-cotton, 20-30 parts of methacrylic resin, 40-60 parts of toluene, 1-10 parts of polyoxyethylene alkylphenol ether, 10-20 parts of hydroxyethyl cellulose, 80-90 parts of deionized water, 5-25 parts of dimethylamino methyl propanol, 10-20 parts of pigment, 10-30 parts of barite, 15-25 parts of titania, 15-35 parts of paraffin, 4-10 parts of plasticizer, 35-45 parts of butanol, 20-40 parts of butyl acetate and 30-40 parts of xylene. The acrylate series colorful coating material has the advantages that all colors are uniform during mixing, and the scrub resistance of a coating film is 3,000-5,000 times; the binding power is 100%, and the acrylate series colorful coating material does not bubble and does not come off after being soaked for 40-60 days in water of 20 DEG C; the surface drying time is 30-50 minutes, and no change occurs after the acrylate series colorful coating material is soaked for 20-30 days in alkaline water; the coating film is bright in color and good in decorative effect, so that the acrylate series colorful coating material can be extensively produced to constantly replace the existing materials.

Description

A kind of acrylic ester multicolor finish
Technical field
The application belongs to paint field, relates in particular to a kind of acrylic ester multicolor finish.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally take resin or oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of polyoxyethylenealkylphenol ether.China's coating circle more authoritative < < coating process > > mono-book is definition like this: " coating is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name forming is like this filmed, and claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can forms the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be for inner wall of building, and exterior wall, ceiling, ground, the coating of toilet is called building coating.The general name of the ester class of vinylformic acid and homologue thereof.Important have methyl acrylate, ethyl propenoate, 2-methyl methacrylate and an ethyl 2-methacrylate etc.Can autohemagglutination or and other monomer copolymerizations, be the monomer of manufacturing tackiness agent, synthetic resins, specialty elastomer and plastics.
So-called multicolor finish is comprised of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain the pattern luxurious, attractive in appearance, acrylic ester is colorful.And universal along with humanity concept, and the formation of novel harmonious society, the acrylic ester multicolor finish that designs a kind of water tolerance, scrub resistance and alkali resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of acrylic ester multicolor finish, solves existing acrylic ester multicolor finish water tolerance and scrub resistance is poor, decorative effect is poor, the technical problem such as alkali corrosion resistance not.
Technical scheme:
An acrylic ester multicolor finish, the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: 100 parts of ACRYLIC EMULSION; Nitro-cotton 5-15 part; Methacrylic resin 20-30 part; Toluene 40-60 part; Polyoxyethylenealkylphenol ether 1-10 part; Natvosol 10-20 part; Deionized water 80-90 part; Dimethyl aminomethyl propyl alcohol 5-25 part; Pigment 10-20 part; Barite 10-30 part; Titanium dioxide 15-25 part; Paraffin 15-35 part; Softening agent 4-10 part; Butanols 35-45 part; N-BUTYL ACETATE 20-40 part; Dimethylbenzene 30-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: 100 parts of ACRYLIC EMULSION; 10 parts of nitro-cottons; 25 parts of methacrylic resins; 50 parts of toluene; 5 parts of polyoxyethylenealkylphenol ethers; 15 parts of Natvosols; 85 parts of deionized waters; 15 parts of dimethyl aminomethyl propyl alcohol; 15 parts of pigment; 20 parts, barite; 20 parts of titanium dioxide; 25 parts, paraffin; 7 parts, softening agent; 40 parts, butanols; 30 parts of N-BUTYL ACETATEs; 35 parts of dimethylbenzene.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of acrylic ester multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, during Product mix of all kinds evenly, scrub resistance 3000-5000 time of filming; 2, cohesive force 100%, non-foaming soak 40-60d in 20 ℃ of water after, dry linting not; 3, surface drying 30-50min, soaks 20-30d unchanged in buck; 4, bright in luster, the good decorating effect of filming, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
An acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of ACRYLIC EMULSION; 5 parts of nitro-cottons; 20 parts of methacrylic resins; 40 parts of toluene; 1 part of polyoxyethylenealkylphenol ether; 10 parts of Natvosols; 80 parts of deionized waters; 5 parts of dimethyl aminomethyl propyl alcohol; 10 parts of red iron oxides; 10 parts, barite; 15 parts of titanium dioxide; 15 parts, paraffin; 4 parts of dibutyl phthalates; 35 parts, butanols; 20 parts of N-BUTYL ACETATEs; 30 parts of dimethylbenzene.
ACRYLIC EMULSION, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and Natvosol are added in deionized water, be heated to 40 ℃ and stir 3h, add dimethyl aminomethyl propyl alcohol, barite, titanium dioxide, paraffin, N-BUTYL ACETATE and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
Film scrub resistance 3000 times, cohesive force 100%, non-foaming soak 40d in 20 ℃ of water after, dry linting not; Surface drying 50min, soaks 20d unchanged in buck.
Embodiment 2:
An acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of ACRYLIC EMULSION; 15 parts of nitro-cottons; 30 parts of methacrylic resins; 60 parts of toluene; 10 parts of polyoxyethylenealkylphenol ethers; 20 parts of Natvosols; 90 parts of deionized waters; 25 parts of dimethyl aminomethyl propyl alcohol; 20 parts of iron oxide yellow; 30 parts, barite; 25 parts of titanium dioxide; 35 parts, paraffin; 10 parts of dibutyl phthalates; 45 parts, butanols; 40 parts of N-BUTYL ACETATEs; 40 parts of dimethylbenzene.
ACRYLIC EMULSION, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and Natvosol are added in deionized water, be heated to 40 ℃ and stir 3h, add dimethyl aminomethyl propyl alcohol, barite, titanium dioxide, paraffin, N-BUTYL ACETATE and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
Film scrub resistance 4000 times, cohesive force 100%, non-foaming soak 50d in 20 ℃ of water after, dry linting not; Surface drying 40min, soaks 25d unchanged in buck.
Embodiment 3:
An acrylic ester multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of ACRYLIC EMULSION; 10 parts of nitro-cottons; 25 parts of methacrylic resins; 50 parts of toluene; 5 parts of polyoxyethylenealkylphenol ethers; 15 parts of Natvosols; 85 parts of deionized waters; 15 parts of dimethyl aminomethyl propyl alcohol; 15 parts of iron oxide greens; 20 parts, barite; 20 parts of titanium dioxide; 25 parts, paraffin; 7 parts of dibutyl phthalates; 40 parts, butanols; 30 parts of N-BUTYL ACETATEs; 35 parts of dimethylbenzene.
ACRYLIC EMULSION, methacrylic resin, toluene, polyoxyethylenealkylphenol ether and Natvosol are added in deionized water, be heated to 40 ℃ and stir 3h, add dimethyl aminomethyl propyl alcohol, barite, titanium dioxide, paraffin, N-BUTYL ACETATE and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
Film scrub resistance 5000 times, cohesive force 100%, non-foaming soak 60d in 20 ℃ of water after, dry linting not; Surface drying 30min, soaks 30d unchanged in buck.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.

Claims (4)

1. an acrylic ester multicolor finish, is characterized in that the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: 100 parts of ACRYLIC EMULSION; Nitro-cotton 5-15 part; Methacrylic resin 20-30 part; Toluene 40-60 part; Polyoxyethylenealkylphenol ether 1-10 part; Natvosol 10-20 part; Deionized water 80-90 part; Dimethyl aminomethyl propyl alcohol 5-25 part; Pigment 10-20 part; Barite 10-30 part; Titanium dioxide 15-25 part; Paraffin 15-35 part; Softening agent 4-10 part; Butanols 35-45 part; N-BUTYL ACETATE 20-40 part; Dimethylbenzene 30-40 part.
2. a kind of acrylic ester multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described acrylic ester multicolor finish is as follows: 100 parts of ACRYLIC EMULSION; 10 parts of nitro-cottons; 25 parts of methacrylic resins; 50 parts of toluene; 5 parts of polyoxyethylenealkylphenol ethers; 15 parts of Natvosols; 85 parts of deionized waters; 15 parts of dimethyl aminomethyl propyl alcohol; 15 parts of pigment; 20 parts, barite; 20 parts of titanium dioxide; 25 parts, paraffin; 7 parts, softening agent; 40 parts, butanols; 30 parts of N-BUTYL ACETATEs; 35 parts of dimethylbenzene.
3. a kind of acrylic ester multicolor finish according to claim 1, is characterized in that: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
4. a kind of acrylic ester multicolor finish according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410374549.7A 2014-08-01 2014-08-01 A kind of acrylic ester multicolor finish Active CN104119754B (en)

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CN104119754B CN104119754B (en) 2016-06-15

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062165A (en) * 2015-08-03 2015-11-18 苏州舒而适纺织新材料科技有限公司 Acrylic acid multi-color pattern coating material
CN107793860A (en) * 2017-09-28 2018-03-13 马鞍山松鹤信息科技有限公司 A kind of acrylic acid composite coating and preparation method thereof
CN108034316A (en) * 2017-12-19 2018-05-15 中山市雅乐思商住电器有限公司 Nitro transparent primer and application thereof
CN109763352A (en) * 2019-01-10 2019-05-17 南方科技大学 For the dyeing liquor of nylon products and the surface coloring processing method of nylon products
CN114804787A (en) * 2022-06-09 2022-07-29 新化县天马建筑新材料科技有限公司 High-adhesion and high-weather-resistance ceramic tile bonding mortar and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5340389A (en) * 1993-06-18 1994-08-23 Brymore Enterprises S.A. Water based multicolor coating compositions and process for their preparation
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1580139A (en) * 2003-08-07 2005-02-16 王光胜 Natural multi-colour mineral decorative coating (true-stone paint)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5340389A (en) * 1993-06-18 1994-08-23 Brymore Enterprises S.A. Water based multicolor coating compositions and process for their preparation
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1580139A (en) * 2003-08-07 2005-02-16 王光胜 Natural multi-colour mineral decorative coating (true-stone paint)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国化工协会研究组: "《油漆的生产、加工使用技术标准与质量检测检验 中》", 31 January 2004, article ""8.丙烯酸酯系多彩涂料 配方2"", pages: 723 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062165A (en) * 2015-08-03 2015-11-18 苏州舒而适纺织新材料科技有限公司 Acrylic acid multi-color pattern coating material
CN107793860A (en) * 2017-09-28 2018-03-13 马鞍山松鹤信息科技有限公司 A kind of acrylic acid composite coating and preparation method thereof
CN108034316A (en) * 2017-12-19 2018-05-15 中山市雅乐思商住电器有限公司 Nitro transparent primer and application thereof
CN109763352A (en) * 2019-01-10 2019-05-17 南方科技大学 For the dyeing liquor of nylon products and the surface coloring processing method of nylon products
CN109763352B (en) * 2019-01-10 2021-07-27 南方科技大学 Dyeing liquid for nylon parts and surface coloring treatment method for nylon parts
CN114804787A (en) * 2022-06-09 2022-07-29 新化县天马建筑新材料科技有限公司 High-adhesion and high-weather-resistance ceramic tile bonding mortar and preparation method thereof

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Effective date of registration: 20180905

Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: 215200 Lao Wu Tong Highway, Songling Town, Wujiang District, Suzhou, Jiangsu

Patentee before: Wujiang Huacheng Composite Technology Co., Ltd.

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TR01 Transfer of patent right

Effective date of registration: 20200318

Address after: 072550 No.53, zone 1, Shenjiazhuang village, Gaolin village, Xushui District, Baoding City, Hebei Province

Patentee after: Wang Shuai

Address before: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1

Patentee before: HEBEI CHENYANG INDUSTRY & TRADE GROUP., Ltd.

TR01 Transfer of patent right