CN105062165A - Acrylic acid multi-color pattern coating material - Google Patents
Acrylic acid multi-color pattern coating material Download PDFInfo
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- CN105062165A CN105062165A CN201510465691.7A CN201510465691A CN105062165A CN 105062165 A CN105062165 A CN 105062165A CN 201510465691 A CN201510465691 A CN 201510465691A CN 105062165 A CN105062165 A CN 105062165A
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Abstract
The present invention discloses an acrylic acid multi-color pattern coating material, wherein the raw materials comprise distilled water, a pigment, an acrylic acid emulsion, guar gum, phosphate triester, alkyl benzene sulfonic acid, poly ethyl phenyl ether, ethyl acrylate, methyl ethyl ether and methacrylic acid. According to the present invention, the product does not produce caking, the uniform dispersion is formed after mixing, the viscosity at a temperature of 25 DEG C is 80-99, no change is changed after the product is soaked in water for 35-55 d, no change is changed after the product is soaked in an alkali liquid for 20-40 d, no change is changed after the product is scrubbed 3000-5000 times, the paint film surface drying time is 0.5-1 h, the complete drying time is 8-10 h, the storage period is 6-14 months, the solid content is 16-22%, and the coating material can be widely produced and can continuously replace existing materials.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of vinylformic acid coating of multi-colour pattern.
Background technology
Vinylformic acid is important organic synthesis raw material and synthetic resins monomer, is polymerization velocity vinyl monomer quickly.Be the simplest unsaturated carboxylic acid, be made up of a vinyl and a carboxyl.Pure vinylformic acid is achromaticity and clarification liquid, is with characteristic irritating smell.It can dissolve each other with water, alcohol, ether and chloroform, is prepared by the propylene obtained from refinery.Great majority are in order to manufacture the esters of acrylic acids such as methyl acrylate, ethyl ester, butyl ester, hydroxyl ethyl ester.Vinylformic acid and acrylate can homopolymerization and copolymerization, and its polymkeric substance is for the synthesis of industrial sectors such as resin, synthon, super absorbent resin, building materials, coating.
Multicolor finish is mainly used in copys stone material effect, so also known as liquid stone, is also local horizon exterior coating.Be made up of inconsistent two phase compositions, wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.This pattern formed by disposable spray finishing is completely different from the method being completed the multicolour pattern that could be formed by multiple working procedure successively.But along with China is more and more stricter to the protection of natural resources and national environmental protection and energy saving policy, relevant laws and regulations, make the exploitation of lithotome, processing, transportation cost constantly increase, this affects the application of lithotome in building decoration field to a certain extent.
Vinylformic acid is important organic synthesis raw material and synthetic resins monomer, is polymerization velocity vinyl monomer quickly.Be the simplest unsaturated carboxylic acid, be made up of a vinyl and a carboxyl.Pure vinylformic acid is achromaticity and clarification liquid, is with characteristic irritating smell.It can dissolve each other with water, alcohol, ether and chloroform, is prepared by the propylene obtained from refinery.Great majority are in order to manufacture the esters of acrylic acids such as methyl acrylate, ethyl ester, butyl ester, hydroxyl ethyl ester.Vinylformic acid and acrylate can homopolymerization and copolymerization, and its polymkeric substance is for the synthesis of industrial sectors such as resin, synthon, super absorbent resin, building materials, coating.
ACRYLIC EMULSION, organic compound, white plates, cotton-shaped or pulverulent solids, tasteless.Water-soluble, be insoluble to gasoline, kerosene, vegetables oil, benzene, toluene, ethylene dichloride, tetracol phenixin, acetone, vinyl acetic monomer, methyl alcohol, ethylene glycol etc.Be slightly soluble in dimethyl sulfoxide (DMSO).ACRYLIC EMULSION is important industrial chemicals, for the manufacture of ACRYLIC EMULSION acetal, resistance to gasoline pipeline and vinylon synthon, fabric-treating agent, emulsifying agent, paper coating, tackiness agent, glue etc.
After coating, due to uneven, there is dispersion and multiple color decorative pattern can be obtained, stereoscopic sensation is strong, gloss is graceful, appearance tactile impression is good relief-type coating.The characteristic such as it has acid and alkali-resistance, water-fastness, anti-pollution, wear-resisting, bonding strength is high, can be applied to plaster, cement, asbestos, brick, wood, metallic surface.Which field is does water-water multicolor finish mainly used in? its range of application that a lot of people can feel not is very wide, actually this is not so, lithotome is long at the applicating history in building decoration field, firmly getting architect and user's favor with its noble, natural, simple and unsophisticated, luxurious style, is also one of important symbol of high-end buildings external image.
Acrylicacidandesters class self or after mixing with other monomers, can generate homopolymer or multipolymer by polymerization reaction take place.Usually can with the monomer of acrylic acid copolymer comprise amides, vinyl cyanide, containing vinyl-based, vinylbenzene and divinyl etc.This base polymer can be used for producing various plastics, coating, tackiness agent, elastomerics, mop photo etching and coating.
Multicolor finish is the new decorative material for building of beautifying hotel, movie theatre, entertainment place, shop, office building, house etc.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan, therefore also known as liquid stone.The performance of ACRYLIC EMULSION rubber affects by atomic number of alkyl carbon object in its principal monomer alkyl acrylate.Rubber based on ACRYLIC EMULSION, oil resistant, thermotolerance are better; And the rubber based on butyl acrylate, because atomic number of alkyl carbon object increases, the shielding effect of ester group polar group is increased, therefore water tolerance is made to make moderate progress, simultaneously due to shielding effect, reduce power between rubber molecule, increase inner plasticity, thus temperature limit of brittleness is reduced, winter hardiness is better.If by above-mentioned two kinds of monomers and use, then can obtain the rubber between both performances.
1843, first find that acrolein oxidation generates vinylformic acid.1931, Rohm and Haas Company (US) Independenec Mall West, Philadelphia, Pennsy Lvania 1 of the U.S. succeeded in developing cyanoethanol hydrolysis acrylic acid process processed, is industrial unique production method for a long time.Nineteen thirty-nine, fritz W.J. thunder is worn and has been invented Carbonylation of Acetylene legal system vinylformic acid, within 1954, establishes full scale plant in the U.S..Meanwhile also successfully develop acrylonitrile hydrolysis acrylic acid process.Build up from U.S. combinating carbide company in 1969 with after propylene oxidation legal system vinylformic acid full scale plant, various countries adopt this method to produce in succession.In recent years, oxidation of propylene had carried out many improvement at catalyzer and process aspect, had become and had produced acrylic acid main method.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan.
Summary of the invention
The invention provides the multicolor finish that a kind of fast drying and period of storage are long, solve the technical problems such as the dry slow and period of storage of existing multicolor finish is short.
The present invention is by the following technical solutions: a kind of vinylformic acid coating of multi-colour pattern, it is as follows that mass fraction proportioning pressed by its raw material: distilled water 100 parts, pigment 1-5 part, ACRYLIC EMULSION 50-70 part, guar gum 30-50 part, phosphotriester 10-30 part, alkyl benzene sulphonate (ABS) 5-25 part, poly-ethyl group phenyl ether 8-22 part, ethyl propenoate 60-80 part, methyl ethyl ether 30-50 part, methacrylic acid 20-40 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described vinylformic acid coating of multi-colour pattern: distilled water 100 parts, pigment 2-4 part, ACRYLIC EMULSION 55-65 part, guar gum 35-45 part, phosphotriester 15-25 part, alkyl benzene sulphonate (ABS) 10-20 part, poly-ethyl group phenyl ether 12-18 part, ethyl propenoate 65-75 part, methyl ethyl ether 35-45 part, methacrylic acid 25-35 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described vinylformic acid coating of multi-colour pattern: distilled water 100 parts, pigment 3 parts, ACRYLIC EMULSION 60 parts, guar gum 40 parts, phosphotriester 20 parts, alkyl benzene sulphonate (ABS) 15 parts, poly-ethyl group phenyl ether 15 parts, ethyl propenoate 70 parts, methyl ethyl ether 40 parts, methacrylic acid 30 parts.As a preferred technical solution of the present invention: described pigment adopts red iron oxide or phthalocyanine blue.
Beneficial effect: a kind of vinylformic acid coating of multi-colour pattern of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is without caking, uniformly dispersion after mixing; 2,25 DEG C of viscosity 80-99, soak 35-55d in water unchanged, soak 20-40d in alkali lye unchanged, and resistance to shampooing 3000-5000 time is unchanged; 3, film surface drying 0.5-1h, does solid work 8-10h, 6-14 month storage period, and solid content 16-22% the widespread production not division of history into periods can replace current material.
Embodiment
Below in conjunction with example, the invention will be further described, and embodiment, only for the present invention will be described, does not form the restriction to right, and other alternative means that it may occur to persons skilled in the art that, all within the scope of the claims in the present invention.
Embodiment 1:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 1 part, ACRYLIC EMULSION 50 parts, guar gum 30 parts, phosphotriester 10 parts, alkyl benzene sulphonate (ABS) 5 parts, poly-ethyl group phenyl ether 8 parts, ethyl propenoate 60 parts, methyl ethyl ether 30 parts, methacrylic acid 20 parts, is uniformly mixed in a kettle..
Product without caking, uniformly dispersion after mixing; 25 DEG C of viscosity 80, soak 35d in water unchanged, soak 20d in alkali lye unchanged, and resistance to shampooing 3000 times is unchanged; Film surface drying 1h, does solid work 10h, 6 months storage periods, solid content 16%.
Embodiment 2:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 5 parts, ACRYLIC EMULSION 70 parts, guar gum 50 parts, phosphotriester 30 parts, alkyl benzene sulphonate (ABS) 25 parts, poly-ethyl group phenyl ether 22 parts, ethyl propenoate 80 parts, methyl ethyl ether 50 parts, methacrylic acid 40 parts, is uniformly mixed in a kettle..
Product without caking, uniformly dispersion after mixing; 25 DEG C of viscosity 85, soak 40d in water unchanged, soak 25d in alkali lye unchanged, and resistance to shampooing 3500 times is unchanged; Film surface drying 0.8h, does solid work 9.5h, 12 months storage periods, solid content 18%.
Embodiment 3:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 2 parts, ACRYLIC EMULSION 55 parts, guar gum 35 parts, phosphotriester 15 parts, alkyl benzene sulphonate (ABS) 10 parts, poly-ethyl group phenyl ether 12 parts, ethyl propenoate 65 parts, methyl ethyl ether 35 parts, methacrylic acid 25 parts, is uniformly mixed in a kettle..
Product without caking, uniformly dispersion after mixing; 25 DEG C of viscosity 90, soak 45d in water unchanged, soak 30d in alkali lye unchanged, and resistance to shampooing 5000 times is unchanged; Film surface drying 1h, does solid work 10h, 6 months storage periods, solid content 16%.
Embodiment 4:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 4 parts, ACRYLIC EMULSION 65 parts, guar gum 45 parts, phosphotriester 25 parts, alkyl benzene sulphonate (ABS) 20 parts, poly-ethyl group phenyl ether 18 parts, ethyl propenoate 75 parts, methyl ethyl ether 45 parts, methacrylic acid 35 parts, is uniformly mixed in a kettle..
Product without caking, uniformly dispersion after mixing; 25 DEG C of viscosity 95, soak 50d in water unchanged, soak 35d in alkali lye unchanged, and resistance to shampooing 4500 times is unchanged; Film surface drying 0.6h, does solid work 8.5h, 10 months storage periods, solid content 20%.
Embodiment 5:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 3 parts, ACRYLIC EMULSION 60 parts, guar gum 40 parts, phosphotriester 20 parts, alkyl benzene sulphonate (ABS) 15 parts, poly-ethyl group phenyl ether 15 parts, ethyl propenoate 70 parts, methyl ethyl ether 40 parts, methacrylic acid 30 parts, is uniformly mixed in a kettle..
Product without caking, uniformly dispersion after mixing; 25 DEG C of viscosity 99, soak 55d in water unchanged, soak 40d in alkali lye unchanged, and resistance to shampooing 5000 times is unchanged; Film surface drying 0.5h, does solid work 8h, 14 months storage periods, solid content 22%.
Claims (4)
1. a vinylformic acid coating of multi-colour pattern, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described vinylformic acid coating of multi-colour pattern: distilled water 100 parts, pigment 1-5 part, ACRYLIC EMULSION 50-70 part, guar gum 30-50 part, phosphotriester 10-30 part, alkyl benzene sulphonate (ABS) 5-25 part, poly-ethyl group phenyl ether 8-22 part, ethyl propenoate 60-80 part, methyl ethyl ether 30-50 part, methacrylic acid 20-40 part.
2. a kind of vinylformic acid coating of multi-colour pattern according to claim 1, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described vinylformic acid coating of multi-colour pattern: distilled water 100 parts, pigment 2-4 part, ACRYLIC EMULSION 55-65 part, guar gum 35-45 part, phosphotriester 15-25 part, alkyl benzene sulphonate (ABS) 10-20 part, poly-ethyl group phenyl ether 12-18 part, ethyl propenoate 65-75 part, methyl ethyl ether 35-45 part, methacrylic acid 25-35 part.
3. a kind of vinylformic acid coating of multi-colour pattern according to claim 2, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described vinylformic acid coating of multi-colour pattern: distilled water 100 parts, pigment 3 parts, ACRYLIC EMULSION 60 parts, guar gum 40 parts, phosphotriester 20 parts, alkyl benzene sulphonate (ABS) 15 parts, poly-ethyl group phenyl ether 15 parts, ethyl propenoate 70 parts, methyl ethyl ether 40 parts, methacrylic acid 30 parts.
4. a kind of vinylformic acid coating of multi-colour pattern according to claim 1, is characterized in that: described pigment adopts red iron oxide or phthalocyanine blue.
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| CN201510465691.7A CN105062165A (en) | 2015-08-03 | 2015-08-03 | Acrylic acid multi-color pattern coating material |
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Citations (5)
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|---|---|---|---|---|
| JP2005015645A (en) * | 2003-06-26 | 2005-01-20 | Sk Kaken Co Ltd | Multicolor coating composition |
| CN101338149A (en) * | 2008-08-11 | 2009-01-07 | 常熟市蓝都弹性涂料有限公司 | Water-soluble colorful coating and preparation thereof |
| CN101693800A (en) * | 2009-10-20 | 2010-04-14 | 鳄鱼制漆(上海)有限公司 | Preparation method and construction process of waterborne marble-imitated multicolor paint |
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
| CN104119754A (en) * | 2014-08-01 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Acrylate series colorful coating material |
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2015
- 2015-08-03 CN CN201510465691.7A patent/CN105062165A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005015645A (en) * | 2003-06-26 | 2005-01-20 | Sk Kaken Co Ltd | Multicolor coating composition |
| CN101338149A (en) * | 2008-08-11 | 2009-01-07 | 常熟市蓝都弹性涂料有限公司 | Water-soluble colorful coating and preparation thereof |
| CN101693800A (en) * | 2009-10-20 | 2010-04-14 | 鳄鱼制漆(上海)有限公司 | Preparation method and construction process of waterborne marble-imitated multicolor paint |
| CN104119754A (en) * | 2014-08-01 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Acrylate series colorful coating material |
| CN104119715A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | Aqueous colorful-pattern coating material |
Non-Patent Citations (1)
| Title |
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| 中国化学协会研究组: "《油漆的生产、加工使用技术标准与质量检测检验（中）》", 31 January 2004, 中国科学技术出版社 * |
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