CN104073117A - Water-soluble acrylic resin coating and preparation method thereof - Google Patents
Water-soluble acrylic resin coating and preparation method thereof Download PDFInfo
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- CN104073117A CN104073117A CN201410281929.6A CN201410281929A CN104073117A CN 104073117 A CN104073117 A CN 104073117A CN 201410281929 A CN201410281929 A CN 201410281929A CN 104073117 A CN104073117 A CN 104073117A
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Abstract
The invention discloses a water-soluble acrylic resin coating and a preparation method thereof. The preparation method comprises the following steps of weighting hydroxyethyl methacrylate, chlorinated polyethylene, methyl methacrylate, butyl methacrylate, monobutyl maleate, butyl acrylate, styrene, diethylaminoethyl methacrylate, azobisisobutyronitrile, methylbenzene, a crosslinking agent, hexahydrophthalic anhydride, methanol 1 and a plasticizer; adding hydroxyethyl methacrylate, chlorinated polyethylene, methyl methacrylate and butyl methacrylate into a reaction kettle; stirring while heating; then, adding styrene, methanol and azobisisobutyronitrile; recovering methanol; adding monobutyl maleate and methylbenzene; adding the rest raw materials, and grinding to obtain the water-soluble acrylic resin coating. The water-soluble acrylic resin coating has the viscosity of 60-80s, the adhesive force of 1-2 grades and the hardness of 0.55-0.75; the impact strength is 45-65kg/cm, the tack-free time is 30-50min, and the solid drying time is 4-6h; a coated film has no bubbling and winkling phenomena after being soaked in a saturated calcium hydroxide solution for 7-14d and has no falling and bubbling phenomena after being soaked in water for 15-30d; the water-soluble acrylic resin coating has the flexibility of 2-4mm and can be widely produced and used for continuously replacing the traditional material.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of water soluble acrylic resin's coating and preparation method thereof, belong to water soluble paint technical field.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form the continuous film of firm attachment with coated article, and normally take resin or oil or emulsion as main, add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of water.China's coating circle more authoritative < < coating process > > mono-book is definition like this: " coating is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name forming is like this filmed, and claims again paint film or coating.”。Coating (paint), our usual said paint is wherein a kind of just.Refer to coat that body surface can form film under certain conditions and play protection, decorate or a class I liquid I or the solid material of other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.).Because early stage coating is main raw material mainly with vegetables oil greatly, therefore be called again paint.At synthetic resins, replaced vegetables oil, therefore be called coating.Coating is not liquid, and powder coating is the large class of coating variety one.
Water soluble paint is to take the coating that water is solvent composition dispersion media, is all called water soluble paint.Water soluble paint has formed many kinds, multi-functional, multi-usage, huge and rounded system.Water soluble paint is to take water-soluble synthetic resin as main film forming substance, and water is thinner, adds appropriate pigment, filler and subsidiary material etc., through grinding a kind of coating forming.Water soluble paint is divided into water soluble paint, water-dispersible paint; Be divided into again electrocoating paint, the water-soluble certainly dry or low temperature baking(stoving) enamel of latex coating; Classification by use can be divided into: water-soluble woodenware priming paint, ornamental water soluble paint, interior exterior wall water soluble paint for building, process water soluble paint, wherein occupy main status with water soluble paint, electrocoating paint and latex coating.
Founding of New, over 60 years, is accompanied by the development of national economy every profession and trade, as its supporting coatings industry, from an extremely unobtrusive little industry, progressively develops into the requisite important industry of all fields of national economy.Through the struggling hard, pioneer and keep forging ahead of several generations, China has become second-biggest-in-the-world coating material production Guo He country of consumption, enters into the main flow of world's coating industry development.Water-borne coatings and powder coating make good, and the water-miscible paint of especially take accounts for approximately 38% in main building coating Yi China coating total amount.Be applied to body surface and can form and there is protection, decoration or property a solid-state class I liquid I of filming of (as insulation, anticorrosion, sign etc.) or the general name of solid material.Comprise oil (property) paint, water-miscible paint, powder coating.Along with the development of social city, technicalization, hommization, design that a kind of viscosity is high, fast drying, hardness is high, shock strength is high and sticking power is excellent water soluble acrylic resin's coating and preparation method thereof, to meet the need of market, be very important.
Summary of the invention
the technical problem solving:
The application is for existing water soluble paint viscosity, sticking power, hardness and shock strength is low, the equal poor technical problem of dry slow, alkali resistance and water tolerance, and a kind of water soluble acrylic resin's of utilization coating and preparation method thereof is provided.
technical scheme:
A kind of water soluble acrylic resin's coating, raw materials by weight portion proportioning is as follows: 100 parts of hydroxyethyl methylacrylates, chlorinatedpolyethylene 35-45 part, methyl methacrylate 30-50 part, butyl methacrylate 40-50 part, butyl maleate 25-45 part, butyl acrylate 30-40 part, vinylbenzene 5-15 part, methacrylic acid diethyl amino ethyl ester 15-25 part, azobis isobutyronitrile 10-30 part, toluene 10-20 part, linking agent 25-35 part, hexahydro phthalic anhydride 1-10 part, methyl alcohol 15-35 part, softening agent 20-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described water soluble acrylic resin's coating is as follows: 100 parts of hydroxyethyl methylacrylates, chlorinatedpolyethylene 38-42 part, methyl methacrylate 35-45 part, butyl methacrylate 42-48 part, butyl maleate 30-40 part, butyl acrylate 33-37 part, vinylbenzene 8-12 part, methacrylic acid diethyl amino ethyl ester 18-22 part, azobis isobutyronitrile 15-25 part, toluene 13-17 part, linking agent 27-33 part, hexahydro phthalic anhydride 2-8 part, methyl alcohol 20-30 part, softening agent 22-28 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described water soluble acrylic resin's coating is as follows: 100 parts of hydroxyethyl methylacrylates, 40 parts of chlorinatedpolyethylenees, 40 parts of methyl methacrylates, 45 parts of butyl methacrylate, 35 parts of butyl maleates, 35 parts of butyl acrylates, 10 parts of vinylbenzene, 20 parts of methacrylic acid diethyl amino ethyl esters, 20 parts of azobis isobutyronitriles, 15 parts of toluene, 30 parts of linking agents, 5 parts of hexahydro phthalic anhydrides, 25 parts of methyl alcohol, 25 parts, softening agent.
As a preferred technical solution of the present invention: described linking agent adopts hexamethoxymethyl melamine.
As a preferred technical solution of the present invention: described softening agent adopts trioctyl trimellitate or Tetra hydro Phthalic anhydride.
As a preferred technical solution of the present invention: preparation method's step of described water soluble acrylic resin's coating is:
The first step: hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate are dropped in the reactor with agitator, thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heat while stirring;
Second step: add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 2-4h;
The 3rd step: reclaim methyl alcohol, add butyl maleate and toluene, insulation 1-2h;
The 4th step: add surplus stock, adjusting viscosity, adds grinding machine for grinding 1-2h to obtain product after being cooled to room temperature.
As a preferred technical solution of the present invention: the heating rate in the described the first step is 2 ℃/s.
As a preferred technical solution of the present invention: the adjusting viscosity in described the 4th step is at 60-80s by viscosity controller.
beneficial effect:
Compared to the prior art a kind of water soluble acrylic resin's coating of the present invention and preparation method thereof adopt above technical scheme, has following technique effect: 1, product viscosity 60-80s, sticking power 1-2 level, hardness 0.55-0.75; 2, shock strength 45-65kg/cm, surface drying time 30-50min, does solid work 4-6h; 3, film and in saturated calcium hydroxide, soak that 7-14d is non-foaming, elephant skin, in water, soak 15-30d and do not come off, bubble; 4, snappiness 2-4mm, appearance of film is smooth smooth, can the not division of history into periods of widespread production replace current material.
Embodiment
embodiment 1:
Proportioning takes 100 parts of hydroxyethyl methylacrylates by weight, 35 parts of chlorinatedpolyethylenees, 30 parts of methyl methacrylates, 40 parts of butyl methacrylate, 25 parts of butyl maleates, 30 parts of butyl acrylates, 5 parts of vinylbenzene, 15 parts of methacrylic acid diethyl amino ethyl esters, 10 parts of azobis isobutyronitriles, 10 parts of toluene, 25 parts of hexamethoxymethyl melamines, 1 part of hexahydro phthalic anhydride, 15 parts of methyl alcohol, 20 parts of trioctyl trimellitates, by hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate drop into agitator, in the reactor of thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heating rate is 2 ℃/s, heat while stirring, add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 2h, reclaim methyl alcohol, add butyl maleate and toluene, insulation 1h, add surplus stock, by viscosity controller at 60s, after being cooled to room temperature, add grinding machine for grinding 1h to obtain product.
Product viscosity 60s, 2 grades of sticking power, hardness 0.55; Shock strength 45kg/cm, snappiness 2mm, surface drying time 50min, does solid work 6h; Film and in saturated calcium hydroxide, soak that 7d is non-foaming, elephant skin, in water, soak 15d and do not come off, bubble.
embodiment 2:
Proportioning takes 100 parts of hydroxyethyl methylacrylates by weight, 45 parts of chlorinatedpolyethylenees, 50 parts of methyl methacrylates, 50 parts of butyl methacrylate, 45 parts of butyl maleates, 40 parts of butyl acrylates, 15 parts of vinylbenzene, 25 parts of methacrylic acid diethyl amino ethyl esters, 30 parts of azobis isobutyronitriles, 20 parts of toluene, 35 parts of hexamethoxymethyl melamines, 10 parts of hexahydro phthalic anhydrides, 35 parts of methyl alcohol, 30 parts of trioctyl trimellitates, by hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate drop into agitator, in the reactor of thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heating rate is 2 ℃/s, heat while stirring, add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 4h, reclaim methyl alcohol, add butyl maleate and toluene, insulation 2h, add surplus stock, by viscosity controller at 80s, after being cooled to room temperature, add grinding machine for grinding 2h to obtain product.
Product viscosity 80s, 2 grades of sticking power, hardness 0.75; Shock strength 50kg/cm, snappiness 2.5mm, surface drying time 45min, does solid work 5.5h; Film and in saturated calcium hydroxide, soak that 9d is non-foaming, elephant skin, in water, soak 20d and do not come off, bubble.
embodiment 3:
Proportioning takes 100 parts of hydroxyethyl methylacrylates by weight, 38 parts of chlorinatedpolyethylenees, 35 parts of methyl methacrylates, 42 parts of butyl methacrylate, 30 parts of butyl maleates, 33 parts of butyl acrylates, 8 parts of vinylbenzene, 18 parts of methacrylic acid diethyl amino ethyl esters, 15 parts of azobis isobutyronitriles, 13 parts of toluene, 27 parts of hexamethoxymethyl melamines, 2 parts of hexahydro phthalic anhydrides, 20 parts of methyl alcohol, 22 parts of trioctyl trimellitates, by hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate drop into agitator, in the reactor of thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heating rate is 2 ℃/s, heat while stirring, add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 2.5h, reclaim methyl alcohol, add butyl maleate and toluene, insulation 1.2h, add surplus stock, by viscosity controller at 65s, after being cooled to room temperature, add grinding machine for grinding 1.2h to obtain product.
Product viscosity 65s, 2 grades of sticking power, hardness 0.6; Shock strength 55kg/cm, snappiness 3mm, surface drying time 40min, does solid work 5h; Film and in saturated calcium hydroxide, soak that 10d is non-foaming, elephant skin, in water, soak 23d and do not come off, bubble.
embodiment 4:
Proportioning takes 100 parts of hydroxyethyl methylacrylates by weight, 42 parts of chlorinatedpolyethylenees, 45 parts of methyl methacrylates, 48 parts of butyl methacrylate, 40 parts of butyl maleates, 37 parts of butyl acrylates, 12 parts of vinylbenzene, 22 parts of methacrylic acid diethyl amino ethyl esters, 25 parts of azobis isobutyronitriles, 17 parts of toluene, 33 parts of hexamethoxymethyl melamines, 8 parts of hexahydro phthalic anhydrides, 30 parts of methyl alcohol, 28 parts of Tetra hydro Phthalic anhydrides, by hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate drop into agitator, in the reactor of thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heating rate is 2 ℃/s, heat while stirring, add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 3.5h, reclaim methyl alcohol, add butyl maleate and toluene, insulation 1.8h, add surplus stock, by viscosity controller at 75s, after being cooled to room temperature, add grinding machine for grinding 1.8h to obtain product.
Product viscosity 75s, adhesion 1 grade, hardness 0.7; Shock strength 60kg/cm, snappiness 3.5mm, surface drying time 35min, does solid work 4.5h; Film and in saturated calcium hydroxide, soak that 12d is non-foaming, elephant skin, in water, soak 27d and do not come off, bubble.
embodiment 5:
Proportioning takes 100 parts of hydroxyethyl methylacrylates by weight, 40 parts of chlorinatedpolyethylenees, 40 parts of methyl methacrylates, 45 parts of butyl methacrylate, 35 parts of butyl maleates, 35 parts of butyl acrylates, 10 parts of vinylbenzene, 20 parts of methacrylic acid diethyl amino ethyl esters, 20 parts of azobis isobutyronitriles, 15 parts of toluene, 30 parts of hexamethoxymethyl melamines, 5 parts of hexahydro phthalic anhydrides, 25 parts of methyl alcohol, 25 parts of Tetra hydro Phthalic anhydrides, by hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate drop into agitator, in the reactor of thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heating rate is 2 ℃/s, heat while stirring, add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 3h, reclaim methyl alcohol, add butyl maleate and toluene, insulation 1.5h, add surplus stock, by viscosity controller at 70s, after being cooled to room temperature, add grinding machine for grinding 1.5h to obtain product.
Product viscosity 70s, adhesion 1 grade, hardness 0.6; Shock strength 65kg/cm, snappiness 4mm, surface drying time 30min, does solid work 4h; Film and in saturated calcium hydroxide, soak that 14d is non-foaming, elephant skin, in water, soak 30d and do not come off, bubble.
All components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.
Claims (8)
1. water soluble acrylic resin's coating, it is characterized in that, the raw materials by weight portion proportioning of described water soluble acrylic resin's coating is as follows: 100 parts of hydroxyethyl methylacrylates, chlorinatedpolyethylene 35-45 part, methyl methacrylate 30-50 part, butyl methacrylate 40-50 part, butyl maleate 25-45 part, butyl acrylate 30-40 part, vinylbenzene 5-15 part, methacrylic acid diethyl amino ethyl ester 15-25 part, azobis isobutyronitrile 10-30 part, toluene 10-20 part, linking agent 25-35 part, hexahydro phthalic anhydride 1-10 part, methyl alcohol 15-35 part, softening agent 20-30 part.
2. a kind of water soluble acrylic resin's coating according to claim 1, it is characterized in that, the raw materials by weight portion proportioning of described water soluble acrylic resin's coating is as follows: 100 parts of hydroxyethyl methylacrylates, chlorinatedpolyethylene 38-42 part, methyl methacrylate 35-45 part, butyl methacrylate 42-48 part, butyl maleate 30-40 part, butyl acrylate 33-37 part, vinylbenzene 8-12 part, methacrylic acid diethyl amino ethyl ester 18-22 part, azobis isobutyronitrile 15-25 part, toluene 13-17 part, linking agent 27-33 part, hexahydro phthalic anhydride 2-8 part, methyl alcohol 20-30 part, softening agent 22-28 part.
3. a kind of water soluble acrylic resin's coating according to claim 1, it is characterized in that, the raw materials by weight portion proportioning of described water soluble acrylic resin's coating is as follows: 100 parts of hydroxyethyl methylacrylates, 40 parts of chlorinatedpolyethylenees, 40 parts of methyl methacrylates, 45 parts of butyl methacrylate, 35 parts of butyl maleates, 35 parts of butyl acrylates, 10 parts of vinylbenzene, 20 parts of methacrylic acid diethyl amino ethyl esters, 20 parts of azobis isobutyronitriles, 15 parts of toluene, 30 parts of linking agents, 5 parts of hexahydro phthalic anhydrides, 25 parts of methyl alcohol, 25 parts, softening agent.
4. a kind of water soluble acrylic resin's coating according to claim 1, is characterized in that: described linking agent adopts hexamethoxymethyl melamine.
5. a kind of water soluble acrylic resin's coating according to claim 1, is characterized in that: described softening agent adopts trioctyl trimellitate or Tetra hydro Phthalic anhydride.
6. a preparation method for water soluble acrylic resin's coating described in claim 1, is characterized in that, comprises the steps:
The first step: hydroxyethyl methylacrylate, chlorinatedpolyethylene, methyl methacrylate and butyl methacrylate are dropped in the reactor with agitator, thermometer and reflux condensing tube, be filled with nitrogen, be heated to 100 ℃, heat while stirring;
Second step: add again vinylbenzene, methyl alcohol and azobis isobutyronitrile, reaction 2-4h;
The 3rd step: reclaim methyl alcohol, add butyl maleate and toluene, insulation 1-2h;
The 4th step: add surplus stock, adjusting viscosity, adds grinding machine for grinding 1-2h to obtain product after being cooled to room temperature.
7. the preparation method of a kind of water soluble acrylic resin's coating according to claim 6, is characterized in that: the heating rate in the described the first step is 2 ℃/s.
8. the preparation method of a kind of water soluble acrylic resin's coating according to claim 6, is characterized in that: the adjusting viscosity in described the 4th step is at 60-80s by viscosity controller.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410281929.6A CN104073117A (en) | 2014-06-23 | 2014-06-23 | Water-soluble acrylic resin coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410281929.6A CN104073117A (en) | 2014-06-23 | 2014-06-23 | Water-soluble acrylic resin coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106118169A (en) * | 2016-07-20 | 2016-11-16 | 青岛华联装饰工程有限公司 | A kind of nano silicon acrylic resin paint |
| CN107629164A (en) * | 2017-09-18 | 2018-01-26 | 广州振清环保技术有限公司 | A kind of preparation method of cation type water-soluble polymer polymer |
| CN107793525A (en) * | 2017-09-18 | 2018-03-13 | 广州振清环保技术有限公司 | A kind of cation type water-soluble polymer polymer |
| CN115975435A (en) * | 2022-12-27 | 2023-04-18 | 广东英科集团股份有限公司 | High-concentration superfine color paste and preparation method thereof |
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| US20020132890A1 (en) * | 2000-12-22 | 2002-09-19 | Swaminathan Ramesh | Water-based acrylic emulsion dispersants utilized as grind resins for pigments and method of preparing the same |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118169A (en) * | 2016-07-20 | 2016-11-16 | 青岛华联装饰工程有限公司 | A kind of nano silicon acrylic resin paint |
| CN107629164A (en) * | 2017-09-18 | 2018-01-26 | 广州振清环保技术有限公司 | A kind of preparation method of cation type water-soluble polymer polymer |
| CN107793525A (en) * | 2017-09-18 | 2018-03-13 | 广州振清环保技术有限公司 | A kind of cation type water-soluble polymer polymer |
| CN107793525B (en) * | 2017-09-18 | 2019-11-08 | 广州振清环保技术有限公司 | A kind of cation type water-soluble polymer polymer |
| CN107629164B (en) * | 2017-09-18 | 2019-11-12 | 广州振清环保技术有限公司 | A kind of preparation method of cation type water-soluble polymer polymer |
| CN115975435A (en) * | 2022-12-27 | 2023-04-18 | 广东英科集团股份有限公司 | High-concentration superfine color paste and preparation method thereof |
| CN115975435B (en) * | 2022-12-27 | 2024-02-02 | 广东英科集团股份有限公司 | High-concentration superfine color paste and preparation method thereof |
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Application publication date: 20141001 |