CN111087872A - Preparation method of low-volatile water-based purifying artistic coating - Google Patents
Preparation method of low-volatile water-based purifying artistic coating Download PDFInfo
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- CN111087872A CN111087872A CN201911359548.4A CN201911359548A CN111087872A CN 111087872 A CN111087872 A CN 111087872A CN 201911359548 A CN201911359548 A CN 201911359548A CN 111087872 A CN111087872 A CN 111087872A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a preparation method of a low-volatile water-based purifying artistic coating, and relates to the technical field of preparation of artistic coatings. The preparation method of the low-volatile water-based purifying artistic coating comprises the following preparation steps: s1, firstly, preparing raw materials for preparing the artistic paint; s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, and starting the stirring kettle to stir the added mixed materials in the stirring kettle; s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, and then continuing stirring. According to the invention, the artistic paint is prepared by selecting proper raw materials, so that the performance of the produced artistic paint is greatly improved, particularly the volatility of the artistic paint is extremely low, volatile substances generated in the painting process of the artistic paint are greatly reduced, the body health of users of the artistic paint is benefited, and the artistic paint can be used in a large scale.
Description
Technical Field
The invention relates to the technical field of art paint preparation, in particular to a preparation method of a low-volatile water-based purifying art paint.
Background
The art paint is originally originated in Europe, advanced technology is spread from Europe, the earliest art paint can be traced back to wall paintings, rock paintings, lacquer paintings and various dyed and colored decorative articles which are known to be early by human beings almost, 20 th century, and after the paint enters the domestic market, the paint is popular and advocated by people with novel decorative style and unusual decorative effect.
With the improvement of the quality of life of people, the requirements of people on art coatings are stricter and stricter, at present, the application range of the art coatings relates to a plurality of small and large fields, the use amount of the art coatings is increased every year, and although the art coatings have obvious advantages compared with the traditional emulsion paint, a plurality of existing art coatings still have some defects, such as the volatility of a plurality of existing art coatings and the environmental protection problem of the art coatings, so that the serious obstruction is brought to the use of the art coatings, and the great limitation is existed.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation method of a low-volatile water-based purifying artistic coating, which solves the defects and shortcomings of the prior art.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a preparation method of a low-volatile water-based purifying artistic coating comprises the following preparation steps:
s1, firstly, preparing raw materials for preparing the art paint, wherein the raw materials comprise water-based acrylic resin, hydroxyethyl cellulose, deionized water, diatom ooze, modified titanium dioxide, calcium carbonate, pigment, mica sand powder, a dispersing agent, a leveling agent, a wetting agent, a flame retardant, an antibacterial agent, an antioxidant, a surfactant and a film-forming aid;
s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, starting the stirring kettle to stir the added mixed materials in the stirring kettle, and obtaining a mixture A after the stirring is finished, wherein the stirring time is 5-10min, and the stirring speed is 300-500 r/min;
s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, then continuing stirring to obtain a mixture B after stirring is finished, wherein the stirring time is 10-20min, and the stirring speed is 500-600 r/min;
s4, continuously adding the pigment, the mica sand powder, the dispersing agent, the flatting agent and the wetting agent into the mixture B in the stirring kettle, then continuously stirring to obtain a mixture C after stirring is finished, wherein the stirring time is 25-30min, and the stirring speed is 600-1000 r/min;
s5, finally adding the flame retardant, the antibacterial agent, the antioxidant, the surfactant and the film forming aid into the mixture C in the stirring kettle, and stirring to obtain the final artistic paint, wherein the stirring time is 8-10min, and the stirring speed is 600-800 r/min.
Preferably, the art coating is prepared from the following raw materials in parts by weight: 70-90 parts of water-based acrylic resin, 30-40 parts of hydroxyethyl cellulose, 50-60 parts of deionized water, 15-25 parts of diatom ooze, 8-10 parts of modified titanium dioxide, 6-8 parts of calcium carbonate, 10-12 parts of pigment, 5-7 parts of mica sand powder, 7-8 parts of dispersing agent, 5-6 parts of flatting agent, 6-7 parts of wetting agent, 4-6 parts of flame retardant, 3-5 parts of antibacterial agent, 3-4 parts of antioxidant, 5-6 parts of surfactant and 7-8 parts of film-forming assistant.
Preferably, the preparation steps of the modified titanium dioxide are as follows:
1) preparing kaolin, silicon dioxide and a surface modifier, and fully mixing the three together;
2) pulping and ball-milling the obtained mixed material;
3) roasting the material for 1-3 hours, cooling the material under natural conditions, and crushing the material by a crusher, wherein the granularity after crushing is controlled to be 100-300 meshes.
Preferably, the mass ratio of the kaolin, the silicon dioxide and the surface modifier is 5:2:1, wherein the roasting temperature is 700-900 ℃.
Preferably, the art coating is prepared from the following raw materials in parts by weight: 80 parts of water-based acrylic resin, 35 parts of hydroxyethyl cellulose, 55 parts of deionized water, 20 parts of diatom ooze, 9 parts of modified titanium dioxide, 7 parts of calcium carbonate, 11 parts of pigment, 6 parts of mica sand powder, 7.5 parts of dispersing agent, 5.5 parts of flatting agent, 6.5 parts of wetting agent, 5 parts of flame retardant, 4 parts of antibacterial agent, 3.5 parts of antioxidant, 5.5 parts of surfactant and 7.5 parts of film-forming assistant.
(III) advantageous effects
The invention provides a preparation method of a low-volatile water-based purifying artistic coating. The method has the following beneficial effects:
1. according to the preparation method of the low-volatility water-based purification art coating, the art coating is prepared by selecting proper raw materials, the performance of the produced art coating is greatly improved, particularly the volatility of the art coating is extremely low, volatile substances generated in the painting process of the art coating are greatly reduced, the body health of users of the art coating is benefited, and the art coating can be used in a large scale.
2. According to the preparation method of the low-volatile water-based purification art coating, the modified titanium dioxide is added into the raw materials, so that the performance of the art coating is improved, materials are saved to a certain extent, the preparation cost is reduced, and meanwhile, the prepared art coating is environment-friendly and economical and has popularization significance.
Detailed Description
The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides a preparation method of a low-volatile water-based purifying artistic coating, which comprises the following preparation steps:
s1, firstly, preparing raw materials for preparing the art paint, wherein the raw materials comprise water-based acrylic resin, hydroxyethyl cellulose, deionized water, diatom ooze, modified titanium dioxide, calcium carbonate, pigment, mica sand powder, a dispersing agent, a leveling agent, a wetting agent, a flame retardant, an antibacterial agent, an antioxidant, a surfactant and a film-forming aid;
s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, starting the stirring kettle to stir the added mixed materials in the stirring kettle, and obtaining a mixture A after the stirring is finished, wherein the stirring time is 5-10min, and the stirring speed is 300-500 r/min;
s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, then continuing stirring to obtain a mixture B after stirring is finished, wherein the stirring time is 10-20min, and the stirring speed is 500-600 r/min;
s4, continuously adding the pigment, the mica sand powder, the dispersing agent, the flatting agent and the wetting agent into the mixture B in the stirring kettle, then continuously stirring to obtain a mixture C after stirring is finished, wherein the stirring time is 25-30min, and the stirring speed is 600-1000 r/min;
s5, finally adding the flame retardant, the antibacterial agent, the antioxidant, the surfactant and the film forming aid into the mixture C in the stirring kettle, and stirring to obtain the final artistic paint, wherein the stirring time is 8-10min, and the stirring speed is 600-800 r/min.
The artistic coating comprises the following raw materials in parts by weight: 70 parts of water-based acrylic resin, 30 parts of hydroxyethyl cellulose, 50 parts of deionized water, 15 parts of diatom ooze, 8 parts of modified titanium dioxide, 6 parts of calcium carbonate, 10 parts of pigment, 5 parts of mica sand powder, 7 parts of dispersing agent, 5 parts of flatting agent, 6 parts of wetting agent, 4 parts of flame retardant, 3 parts of antibacterial agent, 3 parts of antioxidant, 5 parts of surfactant and 7 parts of film-forming assistant.
The preparation steps of the modified titanium dioxide are as follows:
1) preparing kaolin, silicon dioxide and a surface modifier, and fully mixing the kaolin, the silicon dioxide and the surface modifier together, wherein the mass ratio of the kaolin, the silicon dioxide and the surface modifier is 5:2: 1;
2) pulping and ball-milling the obtained mixed material;
3) roasting the material for 1-3 hours at the roasting temperature of 700-900 ℃, then cooling the material under natural conditions, and then crushing the material by a crusher, wherein the granularity after crushing is controlled to be 100-300 meshes.
Example two:
the embodiment of the invention provides a preparation method of a low-volatile water-based purifying artistic coating, which comprises the following preparation steps:
s1, firstly, preparing raw materials for preparing the art paint, wherein the raw materials comprise water-based acrylic resin, hydroxyethyl cellulose, deionized water, diatom ooze, modified titanium dioxide, calcium carbonate, pigment, mica sand powder, a dispersing agent, a leveling agent, a wetting agent, a flame retardant, an antibacterial agent, an antioxidant, a surfactant and a film-forming aid;
s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, starting the stirring kettle to stir the added mixed materials in the stirring kettle, and obtaining a mixture A after the stirring is finished, wherein the stirring time is 5-10min, and the stirring speed is 300-500 r/min;
s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, then continuing stirring to obtain a mixture B after stirring is finished, wherein the stirring time is 10-20min, and the stirring speed is 500-600 r/min;
s4, continuously adding the pigment, the mica sand powder, the dispersing agent, the flatting agent and the wetting agent into the mixture B in the stirring kettle, then continuously stirring to obtain a mixture C after stirring is finished, wherein the stirring time is 25-30min, and the stirring speed is 600-1000 r/min;
s5, finally adding the flame retardant, the antibacterial agent, the antioxidant, the surfactant and the film forming aid into the mixture C in the stirring kettle, and stirring to obtain the final artistic paint, wherein the stirring time is 8-10min, and the stirring speed is 600-800 r/min.
The artistic coating comprises the following raw materials in parts by weight: 80 parts of water-based acrylic resin, 35 parts of hydroxyethyl cellulose, 55 parts of deionized water, 20 parts of diatom ooze, 9 parts of modified titanium dioxide, 7 parts of calcium carbonate, 11 parts of pigment, 6 parts of mica sand powder, 7.5 parts of dispersing agent, 5.5 parts of flatting agent, 6.5 parts of wetting agent, 5 parts of flame retardant, 4 parts of antibacterial agent, 3.5 parts of antioxidant, 5.5 parts of surfactant and 7.5 parts of film-forming assistant.
The preparation steps of the modified titanium dioxide are as follows:
1) preparing kaolin, silicon dioxide and a surface modifier, and fully mixing the kaolin, the silicon dioxide and the surface modifier together, wherein the mass ratio of the kaolin, the silicon dioxide and the surface modifier is 5:2: 1;
2) pulping and ball-milling the obtained mixed material;
3) roasting the material for 1-3 hours at the roasting temperature of 700-900 ℃, then cooling the material under natural conditions, and then crushing the material by a crusher, wherein the granularity after crushing is controlled to be 100-300 meshes.
Example three:
the embodiment of the invention provides a preparation method of a low-volatile water-based purifying artistic coating, which comprises the following preparation steps:
s1, firstly, preparing raw materials for preparing the art paint, wherein the raw materials comprise water-based acrylic resin, hydroxyethyl cellulose, deionized water, diatom ooze, modified titanium dioxide, calcium carbonate, pigment, mica sand powder, a dispersing agent, a leveling agent, a wetting agent, a flame retardant, an antibacterial agent, an antioxidant, a surfactant and a film-forming aid;
s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, starting the stirring kettle to stir the added mixed materials in the stirring kettle, and obtaining a mixture A after the stirring is finished, wherein the stirring time is 5-10min, and the stirring speed is 300-500 r/min;
s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, then continuing stirring to obtain a mixture B after stirring is finished, wherein the stirring time is 10-20min, and the stirring speed is 500-600 r/min;
s4, continuously adding the pigment, the mica sand powder, the dispersing agent, the flatting agent and the wetting agent into the mixture B in the stirring kettle, then continuously stirring to obtain a mixture C after stirring is finished, wherein the stirring time is 25-30min, and the stirring speed is 600-1000 r/min;
s5, finally adding the flame retardant, the antibacterial agent, the antioxidant, the surfactant and the film forming aid into the mixture C in the stirring kettle, and stirring to obtain the final artistic paint, wherein the stirring time is 8-10min, and the stirring speed is 600-800 r/min.
The artistic coating comprises the following raw materials in parts by weight: 90 parts of water-based acrylic resin, 40 parts of hydroxyethyl cellulose, 60 parts of deionized water, 25 parts of diatom ooze, 10 parts of modified titanium dioxide, 8 parts of calcium carbonate, 12 parts of pigment, 7 parts of mica sand powder, 8 parts of dispersing agent, 6 parts of flatting agent, 7 parts of wetting agent, 6 parts of flame retardant, 5 parts of antibacterial agent, 4 parts of antioxidant, 6 parts of surfactant and 8 parts of film-forming assistant.
The preparation steps of the modified titanium dioxide are as follows:
1) preparing kaolin, silicon dioxide and a surface modifier, and fully mixing the kaolin, the silicon dioxide and the surface modifier together, wherein the mass ratio of the kaolin, the silicon dioxide and the surface modifier is 5:2: 1;
2) pulping and ball-milling the obtained mixed material;
3) roasting the material for 1-3 hours at the roasting temperature of 700-900 ℃, then cooling the material under natural conditions, and then crushing the material by a crusher, wherein the granularity after crushing is controlled to be 100-300 meshes.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (5)
1. A preparation method of low-volatile water-based purifying artistic paint is characterized by comprising the following steps: the preparation method comprises the following preparation steps:
s1, firstly, preparing raw materials for preparing the art paint, wherein the raw materials comprise water-based acrylic resin, hydroxyethyl cellulose, deionized water, diatom ooze, modified titanium dioxide, calcium carbonate, pigment, mica sand powder, a dispersing agent, a leveling agent, a wetting agent, a flame retardant, an antibacterial agent, an antioxidant, a surfactant and a film-forming aid;
s2, taking the water acrylic resin, the hydroxyethyl cellulose and the deionized water into a stirring kettle, starting the stirring kettle to stir the added mixed materials in the stirring kettle, and obtaining a mixture A after the stirring is finished, wherein the stirring time is 5-10min, and the stirring speed is 300-500 r/min;
s3, adding diatom ooze, modified titanium dioxide and calcium carbonate into the mixture A in the stirring kettle, then continuing stirring to obtain a mixture B after stirring is finished, wherein the stirring time is 10-20min, and the stirring speed is 500-600 r/min;
s4, continuously adding the pigment, the mica sand powder, the dispersing agent, the flatting agent and the wetting agent into the mixture B in the stirring kettle, then continuously stirring to obtain a mixture C after stirring is finished, wherein the stirring time is 25-30min, and the stirring speed is 600-1000 r/min;
s5, finally adding the flame retardant, the antibacterial agent, the antioxidant, the surfactant and the film forming aid into the mixture C in the stirring kettle, and stirring to obtain the final artistic paint, wherein the stirring time is 8-10min, and the stirring speed is 600-800 r/min.
2. The method for preparing a low-volatile water-based purifying artistic coating as claimed in claim 1, wherein the method comprises the following steps: the artistic coating is prepared from the following raw materials in parts by weight: 70-90 parts of water-based acrylic resin, 30-40 parts of hydroxyethyl cellulose, 50-60 parts of deionized water, 15-25 parts of diatom ooze, 8-10 parts of modified titanium dioxide, 6-8 parts of calcium carbonate, 10-12 parts of pigment, 5-7 parts of mica sand powder, 7-8 parts of dispersing agent, 5-6 parts of flatting agent, 6-7 parts of wetting agent, 4-6 parts of flame retardant, 3-5 parts of antibacterial agent, 3-4 parts of antioxidant, 5-6 parts of surfactant and 7-8 parts of film-forming assistant.
3. The method for preparing a low-volatile water-based purifying artistic coating as claimed in claim 1, wherein the method comprises the following steps: the preparation steps of the modified titanium dioxide are as follows:
1) preparing kaolin, silicon dioxide and a surface modifier, and fully mixing the three together;
2) pulping and ball-milling the obtained mixed material;
3) roasting the material for 1-3 hours to cool the material under natural conditions, and then crushing the material by a crusher, wherein the granularity after crushing is controlled to be 100-300 meshes.
4. The method for preparing a low-volatile water-based purifying artistic coating as claimed in claim 3, wherein the method comprises the following steps: the mass ratio of the kaolin to the silicon dioxide to the surface modifier is 5:2:1, wherein the roasting temperature is 700-900 ℃.
5. The method for preparing a low-volatile water-based purifying artistic coating as claimed in claim 2, wherein: the artistic coating is prepared from the following raw materials in parts by weight: 80 parts of water-based acrylic resin, 35 parts of hydroxyethyl cellulose, 55 parts of deionized water, 20 parts of diatom ooze, 9 parts of modified titanium dioxide, 7 parts of calcium carbonate, 11 parts of pigment, 6 parts of mica sand powder, 7.5 parts of dispersing agent, 5.5 parts of flatting agent, 6.5 parts of wetting agent, 5 parts of flame retardant, 4 parts of antibacterial agent, 3.5 parts of antioxidant, 5.5 parts of surfactant and 7.5 parts of film-forming assistant.
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| CN201911359548.4A CN111087872A (en) | 2019-12-25 | 2019-12-25 | Preparation method of low-volatile water-based purifying artistic coating |
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| CN201911359548.4A CN111087872A (en) | 2019-12-25 | 2019-12-25 | Preparation method of low-volatile water-based purifying artistic coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085614A (en) * | 2021-12-11 | 2022-02-25 | 广东金涂宝新材料股份有限公司 | Preparation method of low-volatility water-based odor-free artistic coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102031024A (en) * | 2010-11-19 | 2011-04-27 | 杭州腾石科技有限公司 | Kaolin-based compound titanium dioxide and preparation method thereof |
| KR101100283B1 (en) * | 2011-03-23 | 2011-12-28 | 주식회사 에스앤씨 | Anti-pollutant and dewing-protective bio silk paint and application method thereof |
| CN102676013A (en) * | 2012-05-25 | 2012-09-19 | 广东花王涂料有限公司 | Low-VOC (volatile organic compounds) odorless stain-resistant emulsion paint for interior walls and method for preparing low-VOC odorless stain-resistant emulsion paint |
-
2019
- 2019-12-25 CN CN201911359548.4A patent/CN111087872A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102031024A (en) * | 2010-11-19 | 2011-04-27 | 杭州腾石科技有限公司 | Kaolin-based compound titanium dioxide and preparation method thereof |
| KR101100283B1 (en) * | 2011-03-23 | 2011-12-28 | 주식회사 에스앤씨 | Anti-pollutant and dewing-protective bio silk paint and application method thereof |
| CN102676013A (en) * | 2012-05-25 | 2012-09-19 | 广东花王涂料有限公司 | Low-VOC (volatile organic compounds) odorless stain-resistant emulsion paint for interior walls and method for preparing low-VOC odorless stain-resistant emulsion paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114085614A (en) * | 2021-12-11 | 2022-02-25 | 广东金涂宝新材料股份有限公司 | Preparation method of low-volatility water-based odor-free artistic coating |
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