CN103396725A - Simulated copper coating and production process thereof - Google Patents
Simulated copper coating and production process thereof Download PDFInfo
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- CN103396725A CN103396725A CN2013103386606A CN201310338660A CN103396725A CN 103396725 A CN103396725 A CN 103396725A CN 2013103386606 A CN2013103386606 A CN 2013103386606A CN 201310338660 A CN201310338660 A CN 201310338660A CN 103396725 A CN103396725 A CN 103396725A
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Abstract
The invention relates to the technical field of architectural decoration materials and application. The invention provides a simulated copper coating, and the simulated copper coating is prepared from the following raw materials: by weight, 670-700 parts of a mixed solvent, 60-70 parts of cellulose acetate butyrate, 60-70 parts of polyester resin, 40-50 parts of nitrocotton, 30-40 parts of amino resin, 2-5 parts of a leveling agent, 25-35 parts of an anti-settling agent, 55-75 parts of pearlescent pigments and 10-30 parts of a color pigment. The invention also provides a production process of the simulated copper coating, and the production process comprises the following steps: successively adding the mixed solvent, the cellulose acetate butyrate, the polyester resin, the nitrocotton, the amino resin, the leveling agent, the anti-settling agent, the pearlescent pigments and the color pigment into a vat, stirring and mixing evenly. During the production process of the simulated copper coating, a directional assistant with high glass transition temperature is introduced, various pearlescent pigments are selected and used, and through mixing in a certain proportion, a coating film can perfectly reproduce copper material effects and metal texture.
Description
Technical field
The present invention relates to building and ornament materials and applied technical field, be specifically related to a kind of emulation copper coating and production technique thereof.
Background technology
Since ancient times, brass work gives the sensation of noble atmosphere, and in China, brass work is as the symbol of rich and honour and power, be subject to liking of people always, and some brass works also with its tinkling of jadesly meet the eye on every side, of all shapes and colors and colourful characteristics, have higher artistic view, be fit to people's appreciation and collection.Yet itself gets rusty easily copper product, is difficult to safeguard, starting material and cost of manufacture price are higher, make this decorative effect to popularize.Although coating industry has in succession been developed various coventional type bronze-like coatings and attempted to address this problem in recent years, is difficult to imitate the metal-like of copper material, effect is always barely satisfactory.
Summary of the invention
Solve the problems of the technologies described above, the invention provides emulation copper coating and production technique thereof, the metal-like of the true copper of reproduction that can be true to nature, imitative copper effect is more fine and smooth graceful, and has good outdoor weather-proof effect, thus part substitutes the use of copper material.Both solve the problem that copper material gets rusty easily, reduced again the trimming cost of copper effect, applied range.
In order to achieve the above object, the technical solution adopted in the present invention is, emulation copper coating, by weight, made by following raw materials according: mixed solvent 670-700 part, cellulose acetate butyrate 60-70 part, vibrin 60-70 part, nitro-cotton 40-50 part, aminoresin 30-40 part, flow agent 2-5 part, anti-settling agent 25-35 part, pearly pigment 55-75 part, toner pigment 10-30 part.
Further, described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.
Further, described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate and CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.
Further, described vibrin is wherein a kind of or their arbitrary combination of saturated polyester and unsaturated polyester.
Further, described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton and 1/16 " nitro-cotton or their arbitrary combination.
Further, described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of terpolycyantoamino-formaldehyde resin, methanol etherification of terpolycyantoamino-formaldehyde resin, the isopropylcarbinol etherificate of propyl carbinol etherificate and complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.
Further, described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution and polyacrylate(s) flow agent or their arbitrary combination.
Further, described anti-settling agent is a kind of in polyethylene wax and polyamide wax or their arbitrary combination.
Further, described pearly pigment is mica-iron oxide pigment or the synthetic chip glass of coated by titanium dioxide and the combination of pearl white pearl cream of coated by titanium dioxide.
Further, described toner pigment is a kind of in the blue or green pigment of look essence, transparent iron oxide pigment and phthalein or their arbitrary combination.
The present invention also provides simultaneously and has used the production technique for preparing above-mentioned emulation copper coating, comprises the following steps:
Step 1: mixed solvent is added in a mixing bowl successively, and stirring at low speed is even;
Add cellulose acetate butyrate under step 2:400 rev/min of agitation condition, until dissolve fully;
Add nitro-cotton under step 3:400 rev/min of agitation condition, until dissolve fully;
Step 4: add successively vibrin, aminoresin, flow agent, anti-settling agent,, with the rotating speed of 600 rev/mins, stirred 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 rev/mins stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
The present invention, by adopting technique scheme, compared with prior art, has following advantage:
1, the present invention is used vibrin and aminoresin as the main body filmogen, and under the hot conditions more than 130 ℃, crosslinking reaction can occur for both, thereby form, films uniformly, pearly pigment is played the effect of the fixing and protection of bonding.Different from the Synolac that coventional type bronze-like coating of the prior art is used, vibrin has better guarantor's light unfading, and better shock resistance, the weathering resistance aspect will be much better than Synolac out of doors, and better long-lasting protection can be provided filming.
2, added cellulose acetate butyrate (CAB) in the present invention's formula, this material has very high second-order transition temperature, can be at normal temperatures surface drying fast, make the pearly pigment that is wrapped in wherein can be directed at short notice, reduce its unordered irregular alignment of flowing and causing, thereby reduced the scattering of light, allowed whole filming have stronger metal-like.
3, in the present invention, nitro-cotton is used as auxiliary film forming matter and auxiliary directional agent, can play the auxiliary effect of accepting to matrix resin and cellulose acetate butyrate, thereby can do corresponding formula adjustment for different execution conditions more easily.Nitro-cotton simultaneously, as one of main film forming substance of nitro paint, have the characteristics of quick surface drying, so it has two large characteristics of filmogen and directing agent concurrently., although it has certain high temperature xanthochromia,, as long as be controlled at certain addition, affect very little.
4, the present invention has adopted two kinds of pearly pigments, a kind of is the mica-iron oxide pigment of coated by titanium dioxide, or the synthetic chip glass of coated by titanium dioxide, the thickness of the titanium dioxide that coats by control, form different refraction effects, thereby form different interference color, finally form pearl effect, this pigment is referred to as pearlescence usually; Another kind is pearl white, is a kind of translucent white pearlescent pigment, is added in the middle of filming and can forms fine and smooth metal-like, and this pigment is commonly referred to pearl cream., by the collocation of two kinds of pearly pigments, can make copper sheet material effect true to nature.
Embodiment
Preferred embodiment 1:
Emulation copper coating, by weight, made by following raw materials according: 670 parts of mixed solvents, 60 parts of cellulose acetate butyrates, 60 parts, vibrin, 40 parts of nitro-cottons, 30 parts, aminoresin, 2 parts of flow agents, 25 parts of anti-settling agents, 55 parts of pearly pigments, 10 parts of toner pigments.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is wherein a kind of or their arbitrary combination of saturated polyester and unsaturated polyester.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of terpolycyantoamino-formaldehyde resin, the methanol etherification of terpolycyantoamino-formaldehyde resin, the isopropylcarbinol etherificate of propyl carbinol etherificate, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is mica-iron oxide pigment or the synthetic chip glass of coated by titanium dioxide and the combination of pearl white pearl cream of coated by titanium dioxide.Described toner pigment is a kind of in the blue or green pigment of look essence, transparent iron oxide pigment, phthalein or their arbitrary combination.
The production technique for preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: mixed solvent is added in a mixing bowl successively, and stirring at low speed is even;
Add cellulose acetate butyrate under step 2:400 rev/min of agitation condition, until dissolve fully;
Add nitro-cotton under step 3:400 rev/min of agitation condition, until dissolve fully;
Step 4: add successively vibrin, aminoresin, flow agent, anti-settling agent,, with the rotating speed of 600 rev/mins, stirred 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 rev/mins stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Preferred embodiment 2:
Emulation copper coating, by weight, made by following raw materials according: 700 parts of mixed solvents, 70 parts of cellulose acetate butyrates, 70 parts, vibrin, 50 parts of nitro-cottons, 40 parts, aminoresin, 5 parts of flow agents, 35 parts of anti-settling agents, 75 parts of pearly pigments, 30 parts of toner pigments.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is wherein a kind of or their arbitrary combination of saturated polyester and unsaturated polyester.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of terpolycyantoamino-formaldehyde resin, the methanol etherification of terpolycyantoamino-formaldehyde resin, the isopropylcarbinol etherificate of propyl carbinol etherificate, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is mica-iron oxide pigment or the synthetic chip glass of coated by titanium dioxide and the combination of pearl white pearl cream of coated by titanium dioxide.Described toner pigment is a kind of in the blue or green pigment of look essence, transparent iron oxide pigment, phthalein or their arbitrary combination.
The production technique for preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: mixed solvent is added in a mixing bowl successively, and stirring at low speed is even;
Add cellulose acetate butyrate under step 2:400 rev/min of agitation condition, until dissolve fully;
Add nitro-cotton under step 3:400 rev/min of agitation condition, until dissolve fully;
Step 4: add successively vibrin, aminoresin, flow agent, anti-settling agent,, with the rotating speed of 600 rev/mins, stirred 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 rev/mins stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Preferred embodiment 3:
Emulation copper coating, by weight, made by following raw materials according: 685 parts of mixed solvents, 65 parts of cellulose acetate butyrates, 65 parts, vibrin, 45 parts of nitro-cottons, 35 parts, aminoresin, 3 parts of flow agents, 30 parts of anti-settling agents, 65 parts of pearly pigments, 20 parts of toner pigments.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is wherein a kind of or their arbitrary combination of saturated polyester and unsaturated polyester.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of terpolycyantoamino-formaldehyde resin, the methanol etherification of terpolycyantoamino-formaldehyde resin, the isopropylcarbinol etherificate of propyl carbinol etherificate, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is mica-iron oxide pigment or the synthetic chip glass of coated by titanium dioxide and the combination of pearl white pearl cream of coated by titanium dioxide.Described toner pigment is a kind of in the blue or green pigment of look essence, transparent iron oxide pigment, phthalein or their arbitrary combination.
The production technique for preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: mixed solvent is added in a mixing bowl successively, and stirring at low speed is even;
Add cellulose acetate butyrate under step 2:400 rev/min of agitation condition, until dissolve fully;
Add nitro-cotton under step 3:400 rev/min of agitation condition, until dissolve fully;
Step 4: add successively vibrin, aminoresin, flow agent, anti-settling agent,, with the rotating speed of 600 rev/mins, stirred 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 rev/mins stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Table 1: the chemical analysis results of emulation copper coating of the present invention and common bronze-like coating
| Analysis project | Embodiment 1,2,3 emulation copper coating | Common bronze-like coating |
| Metal-like | Strong metal-like | Low metal-like or without metal-like |
| Unfading (Q-SUN) | 1 grade of variable color in 1000 hours | 1 grade of variable color in 1000 hours |
| Paint film flexibility | 1mm-1.2mm | 1mm-3mm |
| The paint film shock resistance | 50cm-55cm | 40cm-50cm |
| Paint film adhesion | 1 grade | 1 grade |
Although in conjunction with preferred embodiment, specifically show and introduced the present invention; but the those skilled in the art should be understood that; within not breaking away from the spirit and scope of the present invention that appended claims limits; can make a variety of changes the present invention in the form and details, be protection scope of the present invention.
Claims (10)
1. emulation copper coating, it is characterized in that: by weight, by following raw materials according, made: mixed solvent 670-700 part, cellulose acetate butyrate 60-70 part, vibrin 60-70 part, nitro-cotton 40-50 part, aminoresin 30-40 part, flow agent 2-5 part, anti-settling agent 25-35 part, pearly pigment 55-75 part, toner pigment 10-30 part.
2. emulation copper coating according to claim 1 is characterized in that: described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.
3. emulation copper coating according to claim 1 is characterized in that: described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate and CAB381-20 cellulose acetate butyrate or their arbitrary combination.
4. emulation copper coating according to claim 1 is characterized in that: described vibrin is wherein a kind of or their arbitrary combination of saturated polyester and unsaturated polyester.
5. emulation copper coating according to claim 1 is characterized in that: described nitro-cotton be 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton and 1/16 " nitro-cotton in a kind of or their arbitrary combination.
6. emulation copper coating according to claim 1 is characterized in that: described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of terpolycyantoamino-formaldehyde resin, the methanol etherification of terpolycyantoamino-formaldehyde resin, the isopropylcarbinol etherificate of propyl carbinol etherificate, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.
7. emulation copper coating according to claim 1 is characterized in that: described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution and polyacrylate(s) flow agent or their arbitrary combination.
8. emulation copper coating according to claim 1 is characterized in that: described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.
9. emulation copper coating according to claim 1, it is characterized in that: described pearly pigment is the combination of mica-iron oxide pigment and the pearl white pearl cream of coated by titanium dioxide, or is the combination of synthetic chip glass and the pearl white pearl cream of coated by titanium dioxide.
10. production technique for preparing emulation copper coating as described in claim 1 to 9 any one is characterized in that: comprise the following steps:
Step 1: mixed solvent is added in a mixing bowl successively, and stirring at low speed is even;
Add cellulose acetate butyrate under step 2:400 rev/min of agitation condition, until dissolve fully;
Add nitro-cotton under step 3:400 rev/min of agitation condition, until dissolve fully;
Step 4: add successively vibrin, aminoresin, flow agent, anti-settling agent,, with the rotating speed of 600 rev/mins, stirred 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 rev/mins stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
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| JP2015510022A (en) * | 2012-03-14 | 2015-04-02 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | Use of the solvent-type pigment paste for producing a solvent-type pigment paste containing a metal pigment and a solvent-type coating agent for imparting effects |
| CN104530872A (en) * | 2014-12-30 | 2015-04-22 | 佛山金智节能膜有限公司 | Intelligent temperature controlling coating with oriented structure and preparation method thereof |
| CN104877491A (en) * | 2015-06-02 | 2015-09-02 | 柳州龙溪化工有限公司 | Heat reflection and insulation type car paint mixing gloss oil and metal gleam finish coating |
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| CN107216748A (en) * | 2017-08-04 | 2017-09-29 | 浙江喜泽荣制漆有限公司 | A kind of aqueous emulation copper coating and preparation method thereof |
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| JP2015510022A (en) * | 2012-03-14 | 2015-04-02 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | Use of the solvent-type pigment paste for producing a solvent-type pigment paste containing a metal pigment and a solvent-type coating agent for imparting effects |
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| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104530872A (en) * | 2014-12-30 | 2015-04-22 | 佛山金智节能膜有限公司 | Intelligent temperature controlling coating with oriented structure and preparation method thereof |
| CN104877491A (en) * | 2015-06-02 | 2015-09-02 | 柳州龙溪化工有限公司 | Heat reflection and insulation type car paint mixing gloss oil and metal gleam finish coating |
| CN104893488A (en) * | 2015-06-12 | 2015-09-09 | 漳州鑫展旺化工有限公司 | Rapid repair paint for reducing repair chromatic aberration of car body and preparation method of rapid repair paint |
| CN104893488B (en) * | 2015-06-12 | 2017-04-05 | 漳州鑫展旺化工有限公司 | It is a kind of to reduce vehicle body repair aberration Rapid-Repair paint and preparation method thereof |
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| CN106883764B (en) * | 2017-04-14 | 2019-08-23 | 浙江喜泽荣制漆有限公司 | Aluminum profile emulation copper coating and preparation method thereof |
| CN107284066A (en) * | 2017-06-29 | 2017-10-24 | 缪秉强 | A kind of multi-sheet printed technique and its pigment for the technique |
| CN107216748A (en) * | 2017-08-04 | 2017-09-29 | 浙江喜泽荣制漆有限公司 | A kind of aqueous emulation copper coating and preparation method thereof |
| CN107216748B (en) * | 2017-08-04 | 2019-03-29 | 浙江喜泽荣制漆有限公司 | Aqueous emulation copper coating of one kind and preparation method thereof |
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