CN106978044B - A kind of production method of waterproof art painting - Google Patents
A kind of production method of waterproof art painting Download PDFInfo
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- CN106978044B CN106978044B CN201710276698.3A CN201710276698A CN106978044B CN 106978044 B CN106978044 B CN 106978044B CN 201710276698 A CN201710276698 A CN 201710276698A CN 106978044 B CN106978044 B CN 106978044B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of production method of waterproof art painting proposed by the present invention, comprising the following steps: S1: epoxy resin is placed in pulverizer and is crushed, then is placed in 2~5min of melting in melting machine, obtains resin liquid；S2: the neopentyl polyol ester of corresponding parts by weight, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol are dissolved in ethanol solution, and stir 5~10min with the speed of 200~300r/min, obtain mixed liquor A；S3: the resin liquid made in S1 step is added into mixed liquor A, and 10~20min is stirred with the speed of 200~300r/min, sequentially add phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent, sagging inhibitor and corresponding parts by weight water, continue 20~30min of stirring, obtains mixed liquid B.The present invention proposes art painting production method, and formula is rationally, quality is fine and smooth, color keeps lasting, cheap, waterproofness, stability and good in oxidation resistance, and long service life, method is simple, easy to industrialized production.
Description
Technical field
The present invention relates to painting supply technical field more particularly to a kind of production methods of waterproof art painting.
Background technique
Diversified paint can be seen in our daily life, the visual impact brought is
What other articles cannot compare.Wall is depicted as a kind of fashion trend in recent years, and family can ask special draw in finishing
Painter draws a picture on the wall of child room, keeps room more child's simplicity, children's interesting, color varied；It is drawn a picture using wall to replace glue
Viscous wall, to have the function that decoration；It draws a picture to decorate campus on the wall on playground in the public places such as kindergarten, school；
Corresponding mural painting etc. is done on the enclosure wall in city in order to publicize knowledge, culture, activity, policy etc., these are all that we are daily
Common scene in life.Why these mural paintings can show the color of riot of color, are mainly attributed to the fact that draw a picture and are used
Art painting.However these beautiful mural paintings through after a period of time wind, solarization, drench with rain after we also usually can be appreciated that
The place of some shortcoming, for example pigment can trickle to elsewhere, after being exposed to the sun with rainwater and can fade after drenching with rain
Pigment can be adhered on clothes etc. when the phenomenon that with discoloration, clothes touch wall painting surface.The main reason for leading to these shortcoming
It is used art painting when drawing a picture.And these shortcoming also further expose existing art painting there are the problem of.It removes
Except this, existing pigment be easy after a long time placement it is dry and hard, it is dry and hard after pigment cracking or graininess can be presented, hinder tune
Color is drawn a picture.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of waterproof art painting proposed
Production method.
The present invention using following technical scheme in order to solve the above technical problems, realized: a kind of system of waterproof art painting
Make method, comprising the following steps: S1: epoxy resin being placed in pulverizer and is crushed, then is placed in 2~5min of melting in melting machine, is obtained
Resin liquid, wherein 30~60 parts of epoxy resin, 20~30 parts of mica powder, 5~10 parts of nano silica；S2: by corresponding weight
The neopentyl polyol ester, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol of part are dissolved in ethanol solution, and with 200
The speed of~300r/min stirs 5~10min, obtains mixed liquor A, wherein 5~10 parts of neopentyl polyol ester, and 3~6 parts of glycerol,
4~8 parts of silicone oil, 2~8 parts of dibutyl phthalate, 2~6 parts of polyethylene glycol；S3: it is added in S1 step and makes into mixed liquor A
Standby resin liquid, and 10~20min is stirred with the speed of 200~300r/min, sequentially add (2, the 4- bis- tertiary fourths of phosphorous acid three
Base phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent, sagging inhibitor and corresponding parts by weight water, continue to stir
20~30min obtains mixed liquid B, 0.5~1.5 part of ester of phosphorous acid three (2,4- di-tert-butyl-phenyl), di-t-butyl hydroxyl first
1~3 part of benzene, 10~15 parts of pigment powder, 2~4 parts of dispersing agent, 1~3 part of sagging inhibitor, 10~20 parts of ethyl alcohol, 20~40 parts of water；
S4: the static 30~60min of mixed liquid B, then it is sieved through filter, collecting filtrate is waterproof art painting semi-finished product, then is through filling
Obtain finished product.
Preferably, the raw material including following parts by weight: 45 parts of epoxy resin, 25 parts of mica powder, 7 parts of nano silica,
8 parts of neopentyl polyol ester, 5 parts of glycerol, 5 parts of silicone oil, 5 parts of dibutyl phthalate, 4 parts of polyethylene glycol, phosphorous acid three (2,
4- di-tert-butyl-phenyl) 1 part of ester, 2 parts of di-tert-butyl hydroxy toluene, 12 parts of pigment powder, 3 parts of dispersing agent, 2 parts of sagging inhibitor, second
15 parts of alcohol, 30 parts of water.
Preferably, the mica powder and the weight part ratio of nano silica are 2~6:1.
Preferably, the weight part ratio of three (2, the 4- di-tert-butyl-phenyl) ester of phosphorous acid and di-tert-butyl hydroxy toluene is
1:1~3.
Preferably, the weight part ratio of the ethyl alcohol and water is 1~2:2~4.
Preferably, the screen mesh size used when filtering in the S4 step is not less than 50 mesh.
Waterproof art painting proposed by the present invention, formula is reasonable, quality is fine and smooth, color keeps lasting, cheap, waterproof
Property, stability and good in oxidation resistance, long service life make the resistance to of pigment mainly using the epoxy resin of excellent water resistance as filler
It is aqueous can be good, the phenomenon that avoiding rain erosion that pigment is caused to decolourize, while be dispersed in epoxy resin both can be effective for mica powder
The wear-resistant strength of pigment is improved, while dibutyl phthalate and polyethylene glycol is added to significantly improve the attachment of pigment
Pigment and wall is firmly combined in power, makes pigment that should not fall off in external force contact；Phosphorous acid three (2,4- di-tert-butyl-phenyl)
Ester and di-tert-butyl hydroxy toluene can effectively improve the antioxygenic property of pigment, make as the mutual compatible use of antioxidant
It still keeps original color under the adverse circumstances of solar exposure；The addition of neopentyl polyol ester, glycerol and silicone oil can be with
The wettability for persistently keeping pigment makes the placement of pigment through a long time also be not susceptible to dry and hard, blocking phenomenon；The present invention also proposes
A kind of method of production art painting easy to operate, it is easy to industrialized production.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
A kind of production method of waterproof art painting proposed by the present invention, comprising the following steps:
S1: epoxy resin is placed in pulverizer and is crushed, then is placed in melting 4min in melting machine, obtains resin liquid, wherein epoxy
50 parts of resin, 25 parts of mica powder, 8 parts of nano silica；
S2: by the neopentyl polyol ester of corresponding parts by weight, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol
It is dissolved in ethanol solution, and 5min is stirred with the speed of 300r/min, obtain mixed liquor A, wherein 7 parts of neopentyl polyol ester, sweet
4 parts, 6 parts of silicone oil, 4 parts of dibutyl phthalate, 4 parts of polyethylene glycol of oil；
S3: the resin liquid prepared in S1 step being added into mixed liquor A, and stirs 10min with the speed of 300r/min, then
Sequentially add phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent, sagging inhibitor
And the water of corresponding parts by weight, continue to stir 20min, obtains mixed liquid B, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester 1
Part, 2 parts of di-tert-butyl hydroxy toluene, 13 parts of pigment powder, 3 parts of dispersing agent, 2 parts of sagging inhibitor, 15 parts of ethyl alcohol, 30 parts of water；
S4: the static 60min of mixed liquid B, then it is sieved through filter, collecting filtrate is waterproof art painting semi-finished product, then through filling
Dress is got product.
Embodiment two
A kind of production method of waterproof art painting proposed by the present invention, comprising the following steps:
S1: epoxy resin is placed in pulverizer and is crushed, then is placed in melting 5min in melting machine, obtains resin liquid, wherein epoxy
60 parts of resin, 30 parts of mica powder, 5 parts of nano silica；
S2: by the neopentyl polyol ester of corresponding parts by weight, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol
It is dissolved in ethanol solution, and 10min is stirred with the speed of 200r/min, obtain mixed liquor A, wherein 10 parts of neopentyl polyol ester,
6 parts of glycerol, 6 parts of silicone oil, 2 parts of dibutyl phthalate, 4 parts of polyethylene glycol；
S3: the resin liquid prepared in S1 step being added into mixed liquor A, and stirs 20min with the speed of 200r/min, then
Sequentially add phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent, sagging inhibitor
And the water of corresponding parts by weight, continue to stir 30min, obtains mixed liquid B, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester
1.5 parts, 3 parts of di-tert-butyl hydroxy toluene, 15 parts of pigment powder, 3 parts of dispersing agent, 3 parts of sagging inhibitor, 10 parts of ethyl alcohol, 30 parts of water；
S4: the static 30min of mixed liquid B, then it is sieved through filter, collecting filtrate is waterproof art painting semi-finished product, then through filling
Dress is got product.
Embodiment three
A kind of production method of waterproof art painting proposed by the present invention, comprising the following steps:
S1: epoxy resin is placed in pulverizer and is crushed, then is placed in melting 4min in melting machine, obtains resin liquid, wherein epoxy
30 parts of resin, 30 parts of mica powder, 8 parts of nano silica；
S2: by the neopentyl polyol ester of corresponding parts by weight, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol
It is dissolved in ethanol solution, and 10min is stirred with the speed of 300r/min, obtain mixed liquor A, wherein 10 parts of neopentyl polyol ester,
4 parts of glycerol, 4 parts of silicone oil, 8 parts of dibutyl phthalate, 6 parts of polyethylene glycol；
S3: the resin liquid prepared in S1 step being added into mixed liquor A, and stirs 20min with the speed of 300r/min, then
Sequentially add phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent, sagging inhibitor
And the water of corresponding parts by weight, continue to stir 20min, obtains mixed liquid B, phosphorous acid three (2,4- di-tert-butyl-phenyl) ester
1.5 parts, 2 parts of di-tert-butyl hydroxy toluene, 15 parts of pigment powder, 4 parts of dispersing agent, 1 part of sagging inhibitor, 15 parts of ethyl alcohol, 40 parts of water；
S4: the static 30min of mixed liquid B, then it is sieved through filter, collecting filtrate is waterproof art painting semi-finished product, then through filling
Dress is got product.
It is the art painting and commercially available art paintings progress water resistance that prepared to above-described embodiment one~tri-, resistance to optical activity, resistance to
Hot, water resistance reference standard GB/T5211.5-85, the reference standard of resistance to optical activity ISO787/15-1986, heat resistance is referring to mark
Quasi- GB/T1711-89, as a result as follows:
| Embodiment one | Embodiment two | Embodiment three | Commercially available pigment | |
| Water resistance | 4-5 grades | 4-5 grades | 4-5 grades | 3 grades |
| Heat resistance | Less than standard specimen | Less than standard specimen | Less than standard specimen | Greater than standard specimen |
| Resistance to optical activity | Nothing | Nothing | Nothing | Have |
Testing result is shown, through water resistance test, art painting prepared by embodiment one~tri- is carrying out water resistance detection
When, obtained filtrate staining degree is significantly less than commercially available pigment, and can reach 4 grades or more, and commercially available pigment is water-fast
Property detection in colour filter staining rank be 3 grades, show that the water resistance for being formulated the pigment of preparation according to the present invention is good；Heat resistance and resistance to
Optical activity testing result is shown, in fine arts face prepared by artificial ageing light irradiation and baking box high-temperature baking, embodiment one~tri-
Material color still keeps original color, and the color of commercially available pigment obviously declines, and shows the pigment for being formulated preparation according to the present invention
Ageing-resistant performance it is strong, glossiness can be kept for a long time, not fugitive color, discoloration, long service life.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of production method of waterproof art painting, which comprises the following steps:
S1: epoxy resin is placed in pulverizer and is crushed, then is placed in 2~5min of melting in melting machine, obtains resin liquid, wherein asphalt mixtures modified by epoxy resin
30~60 parts of rouge, 20~30 parts of mica powder, 5~10 parts of nano silica；
S2: the neopentyl polyol ester of corresponding parts by weight, glycerol, silicone oil, dibutyl phthalate and polyethylene glycol are dissolved in
In ethanol solution, and 5~10min is stirred with the speed of 200~300r/min, obtains mixed liquor A, wherein neopentyl polyol ester 5
~10 parts, 3~6 parts of glycerol, 4~8 parts of silicone oil, 2~8 parts of dibutyl phthalate, 2~6 parts of polyethylene glycol；
S3: being added the resin liquid for preparing in S1 step into mixed liquor A, and with the speed of 200~300r/min stirring 10~
20min, sequentially add phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, di-tert-butyl hydroxy toluene, pigment powder, dispersing agent,
The water of sagging inhibitor and corresponding parts by weight continues 20~30min of stirring, obtains mixed liquid B, (2,4- bis- uncles of phosphorous acid three
Butyl phenyl) 0.5~1.5 part of ester, it is 1~3 part of di-tert-butyl hydroxy toluene, 10~15 parts of pigment powder, 2~4 parts of dispersing agent, anti-settling
1~3 part of depressant prescription, 10~20 parts of ethyl alcohol, 20~40 parts of water；
S4: the static 30~60min of mixed liquid B, then it is sieved through filter, collecting filtrate is waterproof art painting semi-finished product, then through filling
Dress is got product.
2. a kind of production method of waterproof art painting according to claim 1, which is characterized in that including following parts by weight
Raw material: 45 parts of epoxy resin, 25 parts of mica powder, 7 parts of nano silica, 8 parts of neopentyl polyol ester, 5 parts of glycerol, silicone oil
5 parts, 5 parts of dibutyl phthalate, 4 parts of polyethylene glycol, 1 part of ester of phosphorous acid three (2,4- di-tert-butyl-phenyl), di-t-butyl
2 parts of hydroxy-methylbenzene, 12 parts of pigment powder, 3 parts of dispersing agent, 2 parts of sagging inhibitor, 15 parts of ethyl alcohol, 30 parts of water.
3. a kind of production method of waterproof art painting according to claim 1, which is characterized in that the mica powder with receive
The weight part ratio of rice silica is 2~6:1.
4. a kind of production method of waterproof art painting according to claim 1, which is characterized in that the phosphorous acid three
The weight part ratio of (2,4- di-tert-butyl-phenyl) ester and di-tert-butyl hydroxy toluene is 1:1~3.
5. a kind of production method of waterproof art painting according to claim 1, which is characterized in that the ethyl alcohol and water
Weight part ratio is 1~2:2~4.
6. a kind of production method of waterproof art painting according to claim 1, which is characterized in that mistake in the S4 step
The screen mesh size used when filter is not less than 50 mesh.
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108359301A (en) * | 2018-02-12 | 2018-08-03 | 平顶山学院 | A kind of waterproof art painting and preparation method thereof |
| CN112608633A (en) * | 2020-12-29 | 2021-04-06 | 盐城工业职业技术学院 | Waterproof antioxidant art pigment and preparation method thereof |
| CN115725193A (en) * | 2021-08-30 | 2023-03-03 | 福建波普画材科技有限公司 | Oil painting pigment for art and preparation method thereof |
| CN115044235A (en) * | 2022-02-15 | 2022-09-13 | 九江学院 | Formaldehyde-free art painting pigment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069991A (en) * | 1992-07-18 | 1993-03-17 | 熊春宁 | Waterproof art painting of dilutable water and preparation method thereof |
| CN105086554A (en) * | 2014-05-23 | 2015-11-25 | 淄博职业学院 | Artistic pigment and preparation method thereof |
| CN105647262A (en) * | 2016-03-03 | 2016-06-08 | 安徽三联学院 | Colorfast mineral pigment for painting |
| JP2016204497A (en) * | 2015-04-21 | 2016-12-08 | 鳴海製陶株式会社 | Ceramic pigment, transfer sheet and production method of colored ceramic |
-
2017
- 2017-04-25 CN CN201710276698.3A patent/CN106978044B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069991A (en) * | 1992-07-18 | 1993-03-17 | 熊春宁 | Waterproof art painting of dilutable water and preparation method thereof |
| CN105086554A (en) * | 2014-05-23 | 2015-11-25 | 淄博职业学院 | Artistic pigment and preparation method thereof |
| JP2016204497A (en) * | 2015-04-21 | 2016-12-08 | 鳴海製陶株式会社 | Ceramic pigment, transfer sheet and production method of colored ceramic |
| CN105647262A (en) * | 2016-03-03 | 2016-06-08 | 安徽三联学院 | Colorfast mineral pigment for painting |
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