CN102358811A - Multifunctional environment-friendly color paste - Google Patents
Multifunctional environment-friendly color paste Download PDFInfo
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- CN102358811A CN102358811A CN2011102072903A CN201110207290A CN102358811A CN 102358811 A CN102358811 A CN 102358811A CN 2011102072903 A CN2011102072903 A CN 2011102072903A CN 201110207290 A CN201110207290 A CN 201110207290A CN 102358811 A CN102358811 A CN 102358811A
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- mill base
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Abstract
The invention discloses a multifunctional environment-friendly color paste which is prepared by the following components by weight: a wetting agent 2 to 20%, a dispersing agent 1 to 20%, a stabilizing agent 1 to 10%, organic pigments 30 to 50%, and the balance being water, wherein, the wetting agent is dihydric alcohol, or trihydric alcohol or a composition of dihydric alcohol or trihydric alcohol and a polyhydroxy-carboxyl copolymer with a molecular weight of 8000 to 10000 or a sodium salt thereof, the dispersing agent is one selected from the group consisting of sodium methylnaphthalene sulfonate, ammonium methylnaphthalene sulfonate, sodium lignosulfonate, sulfonic acid sodium salt of melamine-formaldehyde resin copolymer and sodium salt or ammonium salt of acrylic acid-itaconic acid copolymer or a composition of two or more selected from the group, and the stabilizing agent is a silane coupling agent or a titanate coupling agent. The multifunctional environment-friendly color paste provided in the invention is applicable to coloring of aqueous building coatings and pigment printing and pulp coloring of cotton, polyester cotton and blended fabrics, has a wide application scope, enables a paint film to have high water resistance, and has a high degree of dyeing.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to a kind of multi-functional environment-protection mill base.
Background technology
In the production of pigment printing paste and using, traditional method is to be carrier with non-ionics, wetting agent, water etc., and pigment dyestuff is dispersed in the system, and processing fineness through physical grinding is the floating thing of pulpous state below the 5 μ m.
There is following shortcoming in existing pigment printing paste: 1) non-ionics can produce significant foam when numerous areas is used; 2) existence of nonionogenic tenside declines to a great extent the paint film water tolerance in the coating products; 3) this pigment printing paste narrow in application range can not be to cotton fibre, paper fiber staining (dye uptake is extremely low).Therefore can produce the general multifunctional mill base is the present task of top priority with the use problem that solves multiple field.
Summary of the invention
The present invention provides a kind of painted and textile, the polyester-cotton blend of aqueous architectural coating, the pigment printing and painted multifunction environment-protection type mill base of paper pulp of BLENDED FABRIC of being applicable to.
For this reason, this bright technical scheme is following:
A kind of multi-functional environment-protection mill base is characterized in that being prepared from following components in weight percentage:
Said wetting agent is divalent alcohol or trivalent alcohol; Or divalent alcohol or trivalent alcohol and molecular weight be the combination of poly-hydroxy-carboxyl copolymer (perhaps its sodium salt) of 8000～10000, and wherein the weight ratio of divalent alcohol or trivalent alcohol and said poly-hydroxy-carboxyl copolymer (or its sodium salt) is 1.5～5: 1.Preferably, said divalent alcohol is a Ucar 35, and said trivalent alcohol is a USP Kosher.The structural formula of this poly-hydroxy-carboxyl copolymer is following:
Said dispersion agent is sodium salt or one or more the combination in the ammonium salt of sulfonate sodium, the vinylformic acid-itaconic acid copolymer of methyl naphthalene sulfonic acid sodium, methyl naphthalene sulfonic acid ammonium, sodium lignosulfonate, melamine formaldehyde resin multipolymer.
Said stablizer is silane coupling agent or titanate coupling agent, and said titanate coupling agent is titanic acid ester TC-2, TC-3, TC-4 or TSC, and said silane coupling agent is JS-D858 or JS-D758.
Tinting pigment is the pigment dyestuff of market sale, buys easily.Kind has permanent yellow C1.12, C1.14, C1.83 etc., solid forever orange C1.13, C1.16, permanent bordeaux F4R, permanent bordeaux C1.22, Phthalocyanine Blue BGS, Phthalocyanine Green G, permanent violet RL, carbon black C-219, C-330 etc.
Multifunction environment-protection type mill base of the present invention is applicable to that the pigment printing and the paper pulp of painted and textile, polyester-cotton blend, BLENDED FABRIC of aqueous architectural coating is painted, and applied range, paint film water tolerance height and dye uptake are high.
Embodiment
Below in conjunction with concrete embodiment multifunction environment-protection type mill base of the present invention is elaborated.The sodium salt of poly-hydroxy-carboxyl copolymer shown in " (1) " the representative formula (1) in the wetting agent wherein.
By above embodiment, each material and glass microballon are put into the high-speed horizontal sand mill grind dispersion, through and filtering high-performance mill base of the present invention, carry out performance test, method is following:
One, the stamp cloth specimen is used prescription:
Mill base (embodiment 3) 5 grams
Screen printing binding agent 15 grams
Acrapon A paste 80 grams
Be coated with the screen printing method and scrape in cloth specimen in the above ratio back of sizing mixing, dried 5 minutes in 130 ℃, it is following to record the result:
| Coloured light | Look power | Washing fastness | Dry fastness | The wet fastness of rubbing | Thermotolerance | Level-dyeing property |
| Approximate | ?100％ | 4 grades | The 3-4 level | 4 grades | 160℃ | Good |
Above test result is higher than former printing paste each item index.
Two, coloration of building coating:
Mill base (embodiment 1) 0.5 gram
White slurry 99.5 grams of coating
Above gained coating is applied to cement plate, and test result is following:
| Coloured light | Soak test | Fast light | Aberration | Stability |
| Approximate | 48 hours | The 7-8 level | 0.2 | Excellent |
Above test result is superior to or reaches the requirement of coating to mill base.
Three, aquosity metallic protective paint is painted
The metal protection lacquer of above preparation is sprayed on the iron plate,, draws following detected result 130 ℃ of oven dry 1 hour:
Above test result shows that natural color pulp is outstanding water-miscible paint tinting material, and the lacquer performance is not had influence.
Four, paper applications (making plain color paper):
Size mixing, stir by above prescription, add retention aid (Al then
2(SO4)
3) 3 grams, copy paper after 2 minutes.Copy as clear as crystal, the noresidue pigment of waste water behind the paper, can be recycled, or allow compliance with emission standards, through fish-culture test, have no effect.Paper pulp obtains bright-coloured plain shade decorating and uses paper after oven dry.
Claims (6)
1. multi-functional environment-protection mill base is characterized in that being prepared from following components in weight percentage:
2. multi-functional environment-protection mill base according to claim 1; It is characterized in that: said wetting agent is divalent alcohol or trivalent alcohol; Or divalent alcohol or trivalent alcohol and molecular weight be the combination of poly-hydroxy-carboxyl copolymer of 8000～10000, and wherein the weight ratio of divalent alcohol or trivalent alcohol and described poly-hydroxy-carboxyl copolymer is 1.5～5: 1.
3. multi-functional environment-protection mill base according to claim 2 is characterized in that: said divalent alcohol is a Ucar 35, and said trivalent alcohol is a USP Kosher.
4. multi-functional environment-protection mill base according to claim 1 is characterized in that: said dispersion agent is sodium salt or one or more the combination in the ammonium salt of sulfonate sodium, the vinylformic acid-itaconic acid copolymer of methyl naphthalene sulfonic acid sodium, methyl naphthalene sulfonic acid ammonium, sodium lignosulfonate, melamine formaldehyde resin multipolymer.
5. multi-functional environment-protection mill base according to claim 1 is characterized in that: said stablizer is silane coupling agent or titanate coupling agent.
6. multi-functional environment-protection mill base according to claim 1 is characterized in that: said titanate coupling agent is titanic acid ester TC-2, TC-3, TC-4 or TSC, and said silane coupling agent is JS-D858 or JS-D758.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102072903A CN102358811A (en) | 2011-07-26 | 2011-07-26 | Multifunctional environment-friendly color paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102072903A CN102358811A (en) | 2011-07-26 | 2011-07-26 | Multifunctional environment-friendly color paste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102358811A true CN102358811A (en) | 2012-02-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102072903A Pending CN102358811A (en) | 2011-07-26 | 2011-07-26 | Multifunctional environment-friendly color paste |
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| CN (1) | CN102358811A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103572619A (en) * | 2013-11-19 | 2014-02-12 | 湖南新力华纳米科技有限公司 | Water-based resin-free pigment printing paste |
| CN103572617A (en) * | 2013-11-19 | 2014-02-12 | 湖南新力华纳米科技有限公司 | Water-based anti-settling non-laminated fluorescent pigment paste |
| CN105368159A (en) * | 2015-12-17 | 2016-03-02 | 苏州奥莱鑫建材有限公司 | Environment-friendly nano color paste |
| CN105860645A (en) * | 2016-04-14 | 2016-08-17 | 镇江恒昌塑料彩艺有限公司 | Environment-friendly printing ink composition for PVC intaglio |
| CN106854396A (en) * | 2016-12-31 | 2017-06-16 | 李勇军 | Aqueous mill base and color and manufacture method |
| CN107165000A (en) * | 2017-06-09 | 2017-09-15 | 封开县嘉诚纸业有限公司 | A kind of paper organic pigment mill base and preparation method and application |
| CN107200807A (en) * | 2017-06-09 | 2017-09-26 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersant and preparation method and application |
| CN111484773A (en) * | 2020-05-07 | 2020-08-04 | 杭州华大海天科技有限公司 | Pigment yellow dispersion containing anionic dispersant and preparation method thereof |
Citations (4)
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| WO2003006556A1 (en) * | 2001-07-11 | 2003-01-23 | Clariant Gmbh | Water-based pigment dispersions, the production thereof and the use of the same |
| WO2007141089A1 (en) * | 2006-06-09 | 2007-12-13 | Evonik Degussa Gmbh | Universal pigment compounds, their production process, and their application |
| CN101709185A (en) * | 2009-12-17 | 2010-05-19 | 浙江瑞克涂饰材料有限公司 | Waterborne general color paste and preparation method thereof |
| CN101914326A (en) * | 2010-09-17 | 2010-12-15 | 天津市海山化工科技开发有限公司 | Aqueous pigment dispersion color paste composition and preparation method thereof |
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2011
- 2011-07-26 CN CN2011102072903A patent/CN102358811A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003006556A1 (en) * | 2001-07-11 | 2003-01-23 | Clariant Gmbh | Water-based pigment dispersions, the production thereof and the use of the same |
| WO2007141089A1 (en) * | 2006-06-09 | 2007-12-13 | Evonik Degussa Gmbh | Universal pigment compounds, their production process, and their application |
| CN101709185A (en) * | 2009-12-17 | 2010-05-19 | 浙江瑞克涂饰材料有限公司 | Waterborne general color paste and preparation method thereof |
| CN101914326A (en) * | 2010-09-17 | 2010-12-15 | 天津市海山化工科技开发有限公司 | Aqueous pigment dispersion color paste composition and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103572619A (en) * | 2013-11-19 | 2014-02-12 | 湖南新力华纳米科技有限公司 | Water-based resin-free pigment printing paste |
| CN103572617A (en) * | 2013-11-19 | 2014-02-12 | 湖南新力华纳米科技有限公司 | Water-based anti-settling non-laminated fluorescent pigment paste |
| CN105368159A (en) * | 2015-12-17 | 2016-03-02 | 苏州奥莱鑫建材有限公司 | Environment-friendly nano color paste |
| CN105860645A (en) * | 2016-04-14 | 2016-08-17 | 镇江恒昌塑料彩艺有限公司 | Environment-friendly printing ink composition for PVC intaglio |
| CN105860645B (en) * | 2016-04-14 | 2018-05-29 | 镇江恒昌彩艺科技有限公司 | One kind is used for PVC intaglio plate environment-friendly ink compositions |
| CN106854396A (en) * | 2016-12-31 | 2017-06-16 | 李勇军 | Aqueous mill base and color and manufacture method |
| CN107165000A (en) * | 2017-06-09 | 2017-09-15 | 封开县嘉诚纸业有限公司 | A kind of paper organic pigment mill base and preparation method and application |
| CN107200807A (en) * | 2017-06-09 | 2017-09-26 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersant and preparation method and application |
| CN107200807B (en) * | 2017-06-09 | 2019-08-06 | 封开县嘉诚纸业有限公司 | A kind of paper nano color paste dispersing agent and preparation method and application |
| CN111484773A (en) * | 2020-05-07 | 2020-08-04 | 杭州华大海天科技有限公司 | Pigment yellow dispersion containing anionic dispersant and preparation method thereof |
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Application publication date: 20120222 |
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