CN106221287A - Disperse dye composition and disperse brilliant blue dyestuff - Google Patents

Disperse dye composition and disperse brilliant blue dyestuff Download PDF

Info

Publication number
CN106221287A
CN106221287A CN201610581855.7A CN201610581855A CN106221287A CN 106221287 A CN106221287 A CN 106221287A CN 201610581855 A CN201610581855 A CN 201610581855A CN 106221287 A CN106221287 A CN 106221287A
Authority
CN
China
Prior art keywords
component
disperse
dispersant
brilliant blue
blue dyestuff
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610581855.7A
Other languages
Chinese (zh)
Inventor
王震
卜广玖
李柏毅
刘坤玲
杨娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Original Assignee
FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd filed Critical FILO DYESTUFFS CHEMICAL (WUXI) Co Ltd
Priority to CN201610581855.7A priority Critical patent/CN106221287A/en
Publication of CN106221287A publication Critical patent/CN106221287A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/008—Preparations of disperse dyes or solvent dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/18—Azo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to a kind of disperse dye composition and disperse brilliant blue dyestuff, described disperse brilliant blue dyestuff, it is characterized in that: be made up of disperse dye composition and auxiliary agent, disperse dye composition includes component A, component B and component C；The weight/mass percentage composition of described component A is 10～40%, and the weight/mass percentage composition of component B is 5～40%, and the weight/mass percentage composition of component C is 0～5%, and the weight/mass percentage composition of auxiliary agent is 15～85%.When using dye polyester fiber and blend fabric thereof on the disperse brilliant blue dyestuff of present invention offer, can obtain coloured light gorgeous, enhancing is good, the blue fabric of wash resistant, rub resistance and fastness to perspiration function admirable；After dyeing, fabric is through Intertek detection without disabling aromatic amine, and heavy metal and chlorophenol content all meet Oeko Tex Standard 100 environmental protection index.

Description

Disperse dye composition and disperse brilliant blue dyestuff
Technical field
The present invention relates to a kind of disperse dye composition and disperse brilliant blue dyestuff, especially one be applicable to polyester fiber and The disperse dyes of its blended fabric dyeing, belong to fine chemistry technical field.
Background technology
Recent domestic polyester fiber and blend fabric thereof are fast-developing, and textile is required constantly to carry by people Height, and then the dyeability with disperse dyes has higher requirement.Disperse Blue-56 is blue with its bright HONGGUANG Feature and as one of important blue disperse dye, but its tinctorial strength and color improving performance are bad, sublimation reliability The best so that when upper dye polyester fiber and blend fabric thereof, dye loss is serious, pollutes big, and production cost is high.
At present the new structure exploitation of relevant disperse dyes is less, the work of main research between the dyes and dyestuff with Compound synergic between auxiliary agent.Therefore to overcome the deficiency of anthraquinone type dispersed blue dye, can blue disperse dye gorgeous with azo and Bright blue disperse dyes carry out compounding blending, make mixing disperse dyes have lovely luster, spreadability, level-dyeing property, migration property, lifting concurrently Excellent dyeability and wash resistant color fastness, colour fastness to rubbing, the fastnesss to sublimation etc. such as property take fastness.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of disperse dye composition and disperse gorgeous Blue dyestuff, enhancing is good, and sublimation reliability is high, tint applications performance and to take color fastness good, be widely portable to polyester fiber and The dyeing of its blend fabric.
The technical scheme provided according to the present invention, described disperse dye composition, including component A shown in formula I, formula (II) component B shown in and component C shown in formula III, the mass ratio of component A, component B and component C is 10～40:5～40:0 ～5；
(I), in formula I: X1For-H ,-Br ,-CH3、-OCH3Or-C6H5OH；X2For-H Or-OH；X3For-H or-NH2；X4For-OH or-NHCH3；R1For-H or-CH3；
(II), in formula II: X5 For-Cl ,-Br ,-NO2Or-CN, X6For-CH3、-NHCOCH3Or-NHCOC2H5, R2For-H ,-CH3Or-OCH3, R3For-H ,-CH3 Or-CH (OCH3)CH3；
(III), in formula III: X7For=O or=NH, R4For-C3H6OCH3 Or-C2H4OC4H9。
In a detailed description of the invention, described component A is one of following or two or more mixing:
In a detailed description of the invention, described component B is one of following or two or more mixing:
In a detailed description of the invention, described component C is one of following or two or more mixing:
Described disperse brilliant blue dyestuff, is characterized in that: be made up of disperse dye composition and auxiliary agent, disperse dye composition bag Include component A, component B and component C；The weight/mass percentage composition of described component A is 10～40%, and the weight/mass percentage composition of component B is 5 ～40%, the weight/mass percentage composition of component C is 0～5%, and the weight/mass percentage composition of auxiliary agent is 15～85%.
In a detailed description of the invention, described auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product, lignin type, polycarboxylic acids One or more in class dispersant.
In a detailed description of the invention, described naphthalene sulfonic acid-formaldehyde condensation product is dispersant NNO, dispersing agent C NF or dispersion Agent MF, lignin type is dispersant 85A, dispersant 83A, dispersant S-33 or dispersant S-28, and polycarboxylic acid disperses Agent is dispersant 550S, dispersant Sokalan HP or dispersant Tersperse 2735.
The preparation method of described disperse brilliant blue dyestuff, is characterized in that, comprise the following steps: by disperse dye composition and Auxiliary agent stirs in water to be trembled uniformly, uses sanding-pan sand milling to reach requirement to dispersibility, then filters and be spray-dried.
The preparation method of described disperse brilliant blue dyestuff, is characterized in that, comprise the following steps: by component A, component B, component C and auxiliary agent are individually milled to dispersibility at water medium sand and reach requirement, then by the liquid mixing after sand milling, then carry out filter and It is spray-dried.
The preparation method of described disperse brilliant blue dyestuff, is characterized in that, comprise the following steps: by component A, component B, component The commercial goods powder of C and auxiliary agent, carry out powdery blending, stirs and carries out dust-proof process.
Environment-friendly type disperse brilliant blue dyestuff of the present invention, can be used for the dyeing of polyester fiber and blend fabric thereof, after dyeing Fabric coloured light is gorgeous, and enhancing is good, wash resistant, rub resistance and fastness to sublimation function admirable, and without disabling aromatic amine composition, Heavy metal and chlorophenol content reach Oeko-Tex Standard 100 environmental protection index.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
Disperse dye composition of the present invention, including component A, component B and component C；Described component A be one of following or Two or more mixing:
Described component B is one of following or two or more mixing:
Described component C is one of following or two or more mixing:
Embodiment 1:
By 35 grams of formulas (I-1) and component A of 2.5 grams of formulas (I-4), component B of 3 grams of formulas (II-6), 1.4 grams of formulas (III-1) Component C, 20 grams of dispersant 85A and 38.1 grams of Dispersant MFs, add water and stir, and reaches to want with sanding-pan sand milling to dispersibility Ask, then through filtering and being spray-dried, obtain dyestuff finished product.
Embodiment 2:
By 27 grams of formulas (I-1) and component A of 2.8 grams of formulas (I-4), component B of 8.6 grams of formulas (II-2), 3.5 grams of formulas (III-1) Component C, 25 grams of dispersant 85A and 33.1 grams of Dispersant MFs, add water and stir, with sanding-pan sand milling to dispersibility reach want Ask, then through filtering and being spray-dried, obtain dyestuff finished product.
Embodiment 3～10:
According to the data shown in table 1, by component A, component B, component C and auxiliary agent, add water and stir, use sanding-pan sand milling Reach requirement to dispersibility, then through filtering and being spray-dried, obtain dyestuff finished product.
Table 1
Embodiment 11: the application of disperse brilliant blue dyestuff
Weighing the disperse brilliant blue dyestuff that embodiment 1～10 prepares respectively, dyeing concentration is the 2% of fabric weight, bath raio 20: 1, dyed fabric is resistance polyester fiber knitting fabric, and it is 4～5 that acetic acid adjusts dye bath pH, is warming up to 130 DEG C by 70 DEG C in 50 minutes, insulation 30 minutes, after being cooled to 70 DEG C, washing, reduction was washed, and washes, and dries, and observes stained clot-h planar condition.
Using AATCC 61-2010, AATCC 6-2011, AATCC 15-2009, test obtains its wash resistant color jail respectively Spend >=4 grades, colour fastness to rubbing >=4～5 grades, colour fastness to perspiration >=4 grade.Expect after dyeing to examine through Intertek third party Surveying, without disabling aromatic amine, heavy metal and chlorophenol content all meet Oeko-Tex Standard 100 environmental protection index.

Claims (10)

1. a disperse dye composition, including shown in component B shown in component A shown in formula I, formula II and formula III Component C, the mass ratio of component A, component B and component C is 10～40:5～40:0～5；
In formula I: X1For-H ,-Br ,-CH3、-OCH3Or-C6H5OH；X2For-H Or-OH；X3For-H or-NH2；X4For-OH or-NHCH3；R1For-H or-CH3；
In formula II: X5For- Cl、-Br、-NO2Or-CN, X6For-CH3、-NHCOCH3Or-NHCOC2H5, R2For-H ,-CH3Or-OCH3, R3For-H ,-CH3Or-CH (OCH3)CH3；
In formula III: X7For=O or=NH, R4For-C3H6OCH3 Or-C2H4OC4H9。
2. disperse dye composition as claimed in claim 1, is characterized in that: described component A is one of following or two kinds or two The mixing that kind is above:
3. disperse dye composition as claimed in claim 1, is characterized in that: described component B is one of following or two kinds or two The mixing that kind is above:
4. disperse dye composition as claimed in claim 1, is characterized in that: described component C is one of following or two kinds or two The mixing that kind is above:
5. a disperse brilliant blue dyestuff, is characterized in that: being made up of disperse dye composition and auxiliary agent, disperse dye composition includes Component A, component B and component C；The weight/mass percentage composition of described component A is 10～40%, the weight/mass percentage composition of component B be 5～ 40%, the weight/mass percentage composition of component C is 0～5%, and the weight/mass percentage composition of auxiliary agent is 15～85%.
6. disperse brilliant blue dyestuff as claimed in claim 5, is characterized in that: described auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product, wooden One or more in element class dispersant, polycarboxylic acid dispersant.
7. disperse brilliant blue dyestuff as claimed in claim 6, is characterized in that: described naphthalene sulfonic acid-formaldehyde condensation product be dispersant NNO, Dispersing agent C NF or Dispersant MF, lignin type is dispersant 85A, dispersant 83A, dispersant S-33 or dispersant S- 28, polycarboxylic acid dispersant is dispersant 550S, dispersant Sokalan HP or dispersant Tersperse 2735.
8. the preparation method of disperse brilliant blue dyestuff as claimed in claim 5, is characterized in that, comprise the following steps: dispersion contaminated Feed composition and auxiliary agent stir in water to be trembled uniformly, uses sanding-pan sand milling to reach requirement to dispersibility, then filters and spray Mist is dried.
9. the preparation method of disperse brilliant blue dyestuff as claimed in claim 5, is characterized in that, comprise the following steps: by component A, Component B, component C and auxiliary agent are individually milled to dispersibility at water medium sand and reach requirement, then by the liquid mixing after sand milling, then Filter and be spray-dried.
10. the preparation method of disperse brilliant blue dyestuff as claimed in claim 5, is characterized in that, comprise the following steps: by component A, Component B, the commercial goods powder of component C and auxiliary agent, carry out powdery blending, stirs and carries out dust-proof process.
CN201610581855.7A 2016-07-21 2016-07-21 Disperse dye composition and disperse brilliant blue dyestuff Pending CN106221287A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610581855.7A CN106221287A (en) 2016-07-21 2016-07-21 Disperse dye composition and disperse brilliant blue dyestuff

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610581855.7A CN106221287A (en) 2016-07-21 2016-07-21 Disperse dye composition and disperse brilliant blue dyestuff

Publications (1)

Publication Number Publication Date
CN106221287A true CN106221287A (en) 2016-12-14

Family

ID=57532378

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610581855.7A Pending CN106221287A (en) 2016-07-21 2016-07-21 Disperse dye composition and disperse brilliant blue dyestuff

Country Status (1)

Country Link
CN (1) CN106221287A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867276A (en) * 2017-01-23 2017-06-20 浙江博澳染料工业有限公司 A kind of blue composite disperse dye and its application
CN108264780A (en) * 2017-12-31 2018-07-10 浙江龙盛化工研究有限公司 A kind of disperse dye composition and dye preparations
CN108425251A (en) * 2017-02-15 2018-08-21 上海汇友精密化学品有限公司 A kind of environment-friendly degradable dye composite containing polylactic acid microsphere
CN112341840A (en) * 2020-11-12 2021-02-09 菲诺染料化工(无锡)有限公司 Disperse dye composition and disperse brilliant blue dye

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09176509A (en) * 1995-12-25 1997-07-08 Sumitomo Chem Co Ltd Colored composition high in light resistance and coloring of hydrophobic material using the same
EP0621318B1 (en) * 1993-04-19 1998-09-30 DyStar Textilfarben GmbH & Co. Deutschland KG Disperse dye composition and dyeing method employing it
JPH11158402A (en) * 1997-11-28 1999-06-15 Sumitomo Chem Co Ltd Disperse dye composition and method for coloring hydrophobic material therewith
CN1640944A (en) * 2004-12-16 2005-07-20 浙江龙盛集团股份有限公司 Dispersed blue dye composition
JP2006193574A (en) * 2005-01-12 2006-07-27 Sumitomo Chemical Co Ltd Disperse dye composition, and application to hydrophobic fiber material
CN101983999A (en) * 2010-07-30 2011-03-09 江苏亚邦染料股份有限公司 Compound disperse blue dye for direct printing
CN102585551A (en) * 2011-12-31 2012-07-18 浙江博澳染料工业有限公司 Composite disperse dye
CN103554990A (en) * 2013-10-30 2014-02-05 江苏亚邦染料股份有限公司 Blue disperse dye composition with high washing fastness and high light fastness
CN104263013A (en) * 2014-08-30 2015-01-07 浙江花蝶化学股份有限公司 High-light-fastness disperse black dye composition
CN104448928A (en) * 2014-12-01 2015-03-25 浙江长征化工有限公司 Disperse blue dye composition, disperse dye, preparation method and application

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0621318B1 (en) * 1993-04-19 1998-09-30 DyStar Textilfarben GmbH & Co. Deutschland KG Disperse dye composition and dyeing method employing it
JPH09176509A (en) * 1995-12-25 1997-07-08 Sumitomo Chem Co Ltd Colored composition high in light resistance and coloring of hydrophobic material using the same
JPH11158402A (en) * 1997-11-28 1999-06-15 Sumitomo Chem Co Ltd Disperse dye composition and method for coloring hydrophobic material therewith
CN1640944A (en) * 2004-12-16 2005-07-20 浙江龙盛集团股份有限公司 Dispersed blue dye composition
JP2006193574A (en) * 2005-01-12 2006-07-27 Sumitomo Chemical Co Ltd Disperse dye composition, and application to hydrophobic fiber material
CN101983999A (en) * 2010-07-30 2011-03-09 江苏亚邦染料股份有限公司 Compound disperse blue dye for direct printing
CN102585551A (en) * 2011-12-31 2012-07-18 浙江博澳染料工业有限公司 Composite disperse dye
CN103554990A (en) * 2013-10-30 2014-02-05 江苏亚邦染料股份有限公司 Blue disperse dye composition with high washing fastness and high light fastness
CN104263013A (en) * 2014-08-30 2015-01-07 浙江花蝶化学股份有限公司 High-light-fastness disperse black dye composition
CN104448928A (en) * 2014-12-01 2015-03-25 浙江长征化工有限公司 Disperse blue dye composition, disperse dye, preparation method and application

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867276A (en) * 2017-01-23 2017-06-20 浙江博澳染料工业有限公司 A kind of blue composite disperse dye and its application
CN108425251A (en) * 2017-02-15 2018-08-21 上海汇友精密化学品有限公司 A kind of environment-friendly degradable dye composite containing polylactic acid microsphere
CN108264780A (en) * 2017-12-31 2018-07-10 浙江龙盛化工研究有限公司 A kind of disperse dye composition and dye preparations
CN112341840A (en) * 2020-11-12 2021-02-09 菲诺染料化工(无锡)有限公司 Disperse dye composition and disperse brilliant blue dye

Similar Documents

Publication Publication Date Title
CN101338081B (en) Dispersed deep blue dye composition
CN102746711B (en) Disperse dye composition, dye product and application thereof
CN106189360B (en) Environment-friendly type dispersed ruby blending ingredients and disperse dyes
CN100503740C (en) Dispersed black dye composition
CN102153890B (en) Disperse dye composition
CN101323712B (en) Dispersed black dye composition
CN102516811B (en) Disperse black dye composition
CN101092525A (en) Ccomposition of dispersed yellow dye
CN105566948A (en) Disperse dye composite and environment-friendly disperse yellowish-brown dye
CN103613953B (en) Disperse blue dye composition, disperse dye, and preparation method and application of disperse dye
CN106221287A (en) Disperse dye composition and disperse brilliant blue dyestuff
CN103740136A (en) High-fastness turquoise blue disperse dye composition
CN106752086A (en) Disperse bright blue dye composite and disperse bright blue dyestuff
CN110922786B (en) Black disperse dye composition, disperse dye, preparation method and application thereof
CN106833018B (en) A kind of dispersed black dye mixture and its dye preparations
CN107418249A (en) A kind of economy composite type disperses bright blue dyestuff
CN101275039B (en) Disperse orange dye composition
CN100415835C (en) Dispersion blue dye composition
CN114106585A (en) Blue-to-black disperse dye composition and dye product
CN102443280B (en) Dispersed blue-to-black dye composition
CN111925667A (en) Dacron washing-free dye composition and preparation process and dyeing process thereof
CN106700648A (en) Black disperse dye composition
CN112574594B (en) Disperse yellow-orange dye composition and product thereof
CN106833020B (en) Disperse dye composition and application thereof
CN110204922B (en) Black disperse dye composition, disperse dye, preparation method and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161214

RJ01 Rejection of invention patent application after publication