CN104478258A - Preparation method of resin coated color quartz sand - Google Patents

Preparation method of resin coated color quartz sand Download PDF

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Publication number
CN104478258A
CN104478258A CN201410668156.7A CN201410668156A CN104478258A CN 104478258 A CN104478258 A CN 104478258A CN 201410668156 A CN201410668156 A CN 201410668156A CN 104478258 A CN104478258 A CN 104478258A
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Prior art keywords
resin
sand
preparation
quartz sand
color
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CN201410668156.7A
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CN104478258B (en
Inventor
王永生
单秀军
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Suzhou Mahayana environmental protection new material Co., Ltd.
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Suzhou Manayana Environmental Protection Building Material Co Ltd
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Abstract

The invention discloses a preparation method of resin coated color quartz sand. The key point of the technical scheme of the invention is as follows: the preparation method is implemented by taking quartz sand as a base material through the concrete preparation steps of the preparation of pigmental resin: mixing one or more base pigments, uniformly mixing the obtained mixture with resin in a proportion of 1:3-5, and grinding the obtained mixture into the pigmental resin for standby application; mixing and stirring the pigmental resin and the quartz sand, so that the pigmental resin is uniformly covered on the surface of the quartz sand, thereby obtaining a semi-finished product of colored sand; drying the semi-finished product of colored sand by using hot air at a temperature of 60-80 DEG C; putting the dried colored sand into a drying furnace to dry again for 0.5-1 hour at a temperature of 200-400 DEG C; and taking the re-dried colored sand from the drying furnace, putting the colored sand into a water-cooled roller to cool to 40-45 DEG C, taking out, cooling the obtained product to room temperature, and sieving the obtained product, so that a finished product is obtained. The color control difficulty of products set according to the preparation method of resin coated color quartz sand disclosed by the invention is greatly reduced, and the chromatic aberration is stable.

Description

A kind of preparation method of resin coating colorful quartz sands
Technical field
The present invention relates to a kind of manufacture craft of colorful quartz sands, in particular, it relates to a kind of preparation method of resin coating colorful quartz sands.
Background technology
Color sand, as the important aggregate of true mineral varnish, resin terrace, bituminized shingle, colored road surface etc., is widely used in architectural decoration.
Along with true mineral varnish, resin terrace, bituminized shingle, colored road surface etc. are accepted by users day by day, the consumption of color sand expands rapidly.
Color sand is divided into natural colour sand and two kinds, artificial color sand.Natural colour sand, because of variegated many, the reason such as color stability is poor, color disunity and Mineral resources are nervous, more and more cannot meet user demand in the industry.Artificial color sand is with the favor of factor is more and more the subject to user such as its rich color, consistence be strong, bright-colored.
Preparation method, artificial color sand is mainly made by three kinds of methods.
The first is pigment dyestuff staining;
The second is adhesive cures method, and be coated on sand grains top layer with binding agent as resin, silicone based etc. mixes inorganic color, then at 200-300 DEG C of temperature, baking-curing is painted;
The third is high temperature glazing method, is to stick to sand grains top layer with mineral dye, then high temperature sintering is painted at 900-1200 DEG C, and mineral dye is mainly six kinds of basic pigments: iron oxide red, iron oxide yellow, iron oxide black, titanium white, cobalt green, cobalt blue.
The not ageing-resistant also not resistance to rain-out of pigment dyestuff in first method, the stability of color is not high; In second method, the quality of color sand depends on the quality of caking agent to a great extent, but the glue caking agent that the method uses is expensive, adds the preparation cost of color sand; Although the made color sand of the third method is fast in colour, particle is little, and its color is difficult to allotment, and energy consumption is large, and complex procedures, not easily promotes.And adopt the color sand stable performance out of the color sand explained hereafter of resin coating excellent, but its color conditioning remains unchanged, stability that is more difficult and its color is difficult to control.And the color stabilities of industry to color sand such as true mineral varnish, epoxide terrace have high requirement.
Summary of the invention
For the deficiency that prior art exists, a kind of difficulty of mixing colours is the object of the present invention is to provide greatly to reduce and the preparation method of the resin coating colorful quartz sands of color stable.
For achieving the above object, the invention provides following technical scheme: a kind of preparation method of resin coating colorful quartz sands, take quartz sand as base-material, concrete making step comprises:
(1) making of pigmental resin: mix after being mixed by one or more basic pigments that to grind to form pigmental resin for subsequent use again with resin according to 1:3 ~ 5 ratio;
(2) again pigmental resin and quartz sand are passed through mix and blend, make pigmental resin uniform fold at quartz sand surface, obtain half-finished color sand;
(3) half-finished color sand is passed through 60 ~ 80 DEG C of hot-air seasonings;
(4) the color sand after drying is put into stoving oven at the temperature of 200-400 DEG C, to go through 0.5-1 hour again dry;
(5) enter after the color sand after again drying being taken out from stoving oven after being again cooled to normal temperature after water cold drum is cooled to 40-45 DEG C of taking-up and sieve and get product.
As preferably, described quartz sand is SiO 2≤ 98%, fineness is 40-80 object silica sand.
As preferably, described basic pigment comprises: iron oxide red, iron oxide yellow, iron oxide black, titanium white, cobalt green, cobalt blue, and described resin is acrylic resin.
As preferably, in described color sand, each component raw material weight proportion is:
Quartz sand 100 parts
Pigmental resin 2 ~ 6 parts.
The present invention has following advantage compared to existing technology: the present invention is by six selected large basic pigments, the first method of prefabricated pigmental resin, make basic pigment and resin completely compatible and color development is complete, fineness is even, such toning difficulty reduces, then key is half-finished color sand first through the hot-air seasoning of 60 ~ 80 DEG C, color sand after being about to oven dry through second-heating puts into stoving oven dries 0.5-1 hour again in 200-400 DEG C, pigmental resin now through the color sand surface of second-heating is attached on color sand completely, color sand like this reduces gradually because dry moisture content in the process of 0.5-1 hour at 200-400 DEG C, the colour component of pigmental resin is deposited in color sand surface, colour fastness is high, Color control is stablized, entering water cold drum after taking-up again, to be cooled to the 40-45 DEG C of thermal adaptability naturally cooling to the color of the color sand that normal temperature so just makes again strong, control look difficulty reduces greatly, product aberration is stablized, and the step making this resin coating colorful quartz sands is simple and clear, implement very convenient, operation easier reduces greatly.
Embodiment
The invention will be further described below.
Embodiment one: the making method of the color sand of a kind of Chinese red resin coating, its constituent mass ratio is:
Pure white quartz sand: 100 parts
Chinese red pigmental resin: 2 parts
Wherein pure white quartz sand is SiO2≤98%, and fineness is 40-80 object silica sand,
Chinese red pigmental resin quality group becomes:
Iron oxide red 15 parts
Iron black 5 parts
Iron oxide yellow 5 parts
Acrylic resin 75 parts
Making step is:
(1) making of pigmental resin: to grind to form pigmental resin for subsequent use by mixing with acrylic resin after iron oxide red, iron oxide black, iron oxide yellow mixing again;
(2) again the pigmental resin of (1) and quartz sand are passed through mix and blend, make pigmental resin uniform fold at quartz sand surface, obtain half-finished color sand;
(3) the half-finished color sand in (2) is passed through 60 DEG C of hot-air seasonings;
(4) the color sand after drying is put into stoving oven to go through at the temperature of 300 DEG C and again dry for 0.5 hour;
(5) enter after the color sand after again drying being taken out from stoving oven after being again cooled to normal temperature after water cold drum is cooled to 40 DEG C of taking-ups and sieve and get product.
Embodiment two: the making method of the color sand of a kind of coffee brown resin coating, its constituent mass ratio is:
Pure white quartz sand: 100 parts
Coffee brown pigmental resin: 5 parts
Wherein pure white quartz sand is SiO2≤98%, and fineness is 40-80 object silica sand,
Coffee brown pigmental resin quality group becomes:
Iron oxide red 5 parts
Iron black 15 parts
Cobalt green 5 parts
Acrylic resin 75 parts
Making step is:
(1) making of pigmental resin: to grind to form pigmental resin for subsequent use by mixing with acrylic resin after iron oxide red, iron oxide black, cobalt green mixing again;
(2) again the pigmental resin of (1) and quartz sand are passed through mix and blend, make pigmental resin uniform fold at quartz sand surface, obtain half-finished color sand;
(3) the half-finished color sand in (2) is passed through 70 DEG C of hot-air seasonings;
(4) the color sand after drying is put into stoving oven to go through at the temperature of 400 DEG C and again dry for 1 hour;
(5) enter after the color sand after again drying being taken out from stoving oven after being again cooled to normal temperature after water cold drum is cooled to 45 DEG C of taking-ups and sieve and get product.
Embodiment three: the making method of the color sand of a kind of gray jade resin coating, its constituent mass ratio is:
Pure white quartz sand: 100 parts
Gray jade pigmental resin: 6 parts
Wherein pure white quartz sand is SiO2≤98%, and fineness is 80-120 object silica sand,
Gray jade pigmental resin quality group becomes:
Cobalt blue 10 parts
Iron black 5 parts
Cobalt green 2 parts
Acrylic resin 83 parts
Making step is:
(1) making of pigmental resin: to grind to form pigmental resin for subsequent use by mixing with acrylic resin after cobalt blue, iron oxide black, cobalt green mixing again;
(2) again the pigmental resin of (1) and quartz sand are passed through mix and blend, make pigmental resin uniform fold at quartz sand surface, obtain half-finished color sand;
(3) the half-finished color sand in (2) is passed through 80 DEG C of hot-air seasonings;
(4) the color sand after drying is put into stoving oven to go through at the temperature of 200 DEG C and again dry for 0.7 hour;
(5) enter after the color sand after again drying being taken out from stoving oven after being again cooled to normal temperature after water cold drum is cooled to 43 DEG C of taking-ups and sieve and get product.
The above is only the preferred embodiment of the present invention, protection scope of the present invention be not only confined to above-described embodiment, and all technical schemes belonged under thinking of the present invention all belong to protection scope of the present invention.It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (4)

1. a preparation method for resin coating colorful quartz sands, take quartz sand as base-material, concrete making step comprises:
(1) making of pigmental resin: mix after being mixed by one or more basic pigments that to grind to form pigmental resin for subsequent use again with resin according to 1:3 ~ 5 ratio;
(2) again pigmental resin and quartz sand are passed through mix and blend, make pigmental resin uniform fold at quartz sand surface, obtain half-finished color sand;
(3) half-finished color sand is passed through 60 ~ 80 DEG C of hot-air seasonings;
(4) the color sand after drying is put into stoving oven at the temperature of 200-400 DEG C, to go through 0.5-1 hour again dry;
(5) enter after the color sand after again drying being taken out from stoving oven after being again cooled to normal temperature after water cold drum is cooled to 40-45 DEG C of taking-up and sieve and get product.
2. the preparation method of a kind of resin coating colorful quartz sands according to claim 1, is characterized in that: described quartz sand is SiO 2≤ 98%, fineness is 40-80 object silica sand.
3. the preparation method of a kind of resin coating colorful quartz sands according to claim 1, is characterized in that: described basic pigment comprises iron oxide red, iron oxide yellow, iron oxide black, titanium white, cobalt green, cobalt blue, and described resin is acrylic resin.
4. the preparation method of a kind of resin coating colorful quartz sands according to claim 1, is characterized in that: in described color sand, each component raw material weight proportion is:
Quartz sand 100 parts
Color resin 2 ~ 6 parts.
CN201410668156.7A 2014-11-21 2014-11-21 Preparation method of resin coated color quartz sand Active CN104478258B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204362A (en) * 2019-04-16 2019-09-06 开鲁县昌达矽砂有限公司 A kind of preparation facilities of resin coating colorful quartz sands
CN110877964A (en) * 2019-09-12 2020-03-13 杨国曙 Environment-friendly energy-saving coated color sand and manufacturing method thereof
CN114873940A (en) * 2022-03-26 2022-08-09 段宏均 Silica sand manufacturing and dyeing process

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1026222B1 (en) * 2018-10-19 2019-11-14 Sidec Nv Method for obtaining wear-resistant and colourfast grain for a floor application and the obtained grain

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03122075A (en) * 1989-10-03 1991-05-24 Kubota Corp Colored silica sand
CN102180609A (en) * 2011-01-28 2011-09-14 牛智勇 Preparation process of vitrified color sand
CN102180608A (en) * 2011-01-28 2011-09-14 牛智勇 Method for realizing active coloring of vitrified color sand

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03122075A (en) * 1989-10-03 1991-05-24 Kubota Corp Colored silica sand
CN102180609A (en) * 2011-01-28 2011-09-14 牛智勇 Preparation process of vitrified color sand
CN102180608A (en) * 2011-01-28 2011-09-14 牛智勇 Method for realizing active coloring of vitrified color sand

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐晓虹 等: "彩砂的研究与应用", 《佛山陶瓷》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204362A (en) * 2019-04-16 2019-09-06 开鲁县昌达矽砂有限公司 A kind of preparation facilities of resin coating colorful quartz sands
CN110877964A (en) * 2019-09-12 2020-03-13 杨国曙 Environment-friendly energy-saving coated color sand and manufacturing method thereof
CN114873940A (en) * 2022-03-26 2022-08-09 段宏均 Silica sand manufacturing and dyeing process

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Address after: Jiangsu province Suzhou City Hongxi road 215000 High-tech Zone No. 99

Patentee after: Suzhou Mahayana environmental protection new material Co., Ltd.

Address before: Jiangsu province Suzhou City Hongxi road 215000 High-tech Zone No. 99

Patentee before: Suzhou Manayana Environmental Protection Building Material Co., Ltd.