CN103396725B - Emulation copper coating and production technique thereof - Google Patents
Emulation copper coating and production technique thereof Download PDFInfo
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- CN103396725B CN103396725B CN201310338660.6A CN201310338660A CN103396725B CN 103396725 B CN103396725 B CN 103396725B CN 201310338660 A CN201310338660 A CN 201310338660A CN 103396725 B CN103396725 B CN 103396725B
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Abstract
The present invention relates to building and ornament materials and applied technical field.The invention provides emulation copper coating, by weight, be made up of following raw materials according: mixed solvent 670-700 part, cellulose acetate butyrate 60-70 part, vibrin 60-70 part, nitro-cotton 40-50 part, aminoresin 30-40 part, flow agent 2-5 part, anti-settling agent 25-35 part, pearly pigment 55-75 part, toner pigment 10-30 part.The present invention also provides the production technique preparing above-mentioned emulation copper coating simultaneously, step is as follows: add in cylinder by mixed solvent, cellulose acetate butyrate, vibrin, nitro-cotton, aminoresin, flow agent, anti-settling agent, pearly pigment and toner pigment successively, mixing and stirring.The present invention by introducing the directed auxiliary agent of high glass transition temperature, and selects multiple pearly pigment, is mixed, make its film reach the object of perfect reproduction copper material effect and metal-like by certain proportion.
Description
Technical field
The present invention relates to building and ornament materials and applied technical field, be specifically related to a kind of emulation copper coating and production technique thereof.
Background technology
Since ancient times, brass work gives the sensation of noble air, and in China, brass work is as symbol that is rich and honour and power, be subject to liking of people always, and some brass works also tinkling of jadesly to meet the eye on every side with it, of all shapes and colors and colourful feature, there is higher artistic view, be applicable to appreciation and the collection of people.But copper product itself gets rusty easily, be difficult to safeguard, starting material and cost of manufacture price higher, this decorative effect cannot be popularized.Although coating industry in succession develops various coventional type bronze-like coating and attempts to address this problem in recent years, be difficult to the metal-like imitating copper material, effect is always barely satisfactory.
Summary of the invention
Solve the problems of the technologies described above, the invention provides emulation copper coating and production technique thereof, the metal-like of the true copper of reproduction that can be true to nature, imitative copper effect is more fine and smooth graceful, and has the weather-proof effect in good open air, thus the use of Some substitute copper material.Both solve the problem that copper material gets rusty easily, again reduce the trimming cost of copper effect, applied range.
In order to achieve the above object, the technical solution adopted in the present invention is, emulation copper coating, by weight, be made up of following raw materials according: mixed solvent 670-700 part, cellulose acetate butyrate 60-70 part, vibrin 60-70 part, nitro-cotton 40-50 part, aminoresin 30-40 part, flow agent 2-5 part, anti-settling agent 25-35 part, pearly pigment 55-75 part, toner pigment 10-30 part.
Further, described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.
Further, described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate and CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.
Further, described vibrin is the wherein a kind of of saturated polyester and unsaturated polyester or their arbitrary combination.
Further, described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton and 1/16 " nitro-cotton or their arbitrary combination.
Further, described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of propyl carbinol etherificate, the terpolycyantoamino-formaldehyde resin of isopropylcarbinol etherificate, the terpolycyantoamino-formaldehyde resin of methanol etherification and complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.
Further, described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution and polyacrylate(s) flow agent or their arbitrary combination.
Further, described anti-settling agent is a kind of in polyethylene wax and polyamide wax or their arbitrary combination.
Further, described pearly pigment is the combination of the mica-iron oxide pigment of coated by titanium dioxide or the synthetic chip glass of coated by titanium dioxide and pearl white pearl cream.
Further, described toner pigment is a kind of in look essence, the blue or green pigment of transparent iron oxide pigment and phthalein or their arbitrary combination.
The present invention also provides the production technique having used preparation above-mentioned emulation copper coating simultaneously, comprises the following steps:
Step 1: added successively in a mixing bowl by mixed solvent, stirring at low speed is even;
Cellulose acetate butyrate is added, until dissolve completely under step 2:400 rev/min of agitation condition;
Nitro-cotton is added, until dissolve completely under step 3:400 rev/min of agitation condition;
Step 4: add vibrin, aminoresin, flow agent, anti-settling agent successively, with the rotating speed of 600 revs/min, stirs 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 revs/min stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
The present invention is by adopting technique scheme, and compared with prior art, tool has the following advantages:
1, the present invention is using vibrin and aminoresin as main body filmogen, and under the hot conditions more than 130 DEG C, both crosslinking reaction can occur, thus form uniform film, pearly pigment is played to the effect of the fixing and protection of bonding.The Synolac used from coventional type bronze-like coating of the prior art is different, vibrin has better protects light unfading, and better shock resistance, weathering resistance aspect will be much better than Synolac out of doors, can provide better long-lasting protection to film.
2, cellulose acetate butyrate (CAB) is added in the present invention's formula, this material has very high second-order transition temperature, can quick surface drying at normal temperatures, the pearly pigment making to be wrapped in wherein can be directed at short notice, reduce the irregular alignment that its unordered flowing causes, thus decrease the scattering of light, allow whole film have stronger metal-like.
3, in the present invention, nitro-cotton is used as auxiliary film forming matter and auxiliary directional agent, can play matrix resin and cellulose acetate butyrate and accept auxiliary effect, thus corresponding formula adjustment can be done for different execution conditions more easily.As one of main film forming substance of nitro paint the while of nitro-cotton, have the feature of quick surface drying, therefore it has two large characteristics of filmogen and directing agent concurrently.Although it has certain high temperature xanthochromia, as long as control at certain addition, affect very little.
4, present invention employs two kinds of pearly pigments, a kind of is the mica-iron oxide pigment of coated by titanium dioxide, or the synthetic chip glass of coated by titanium dioxide, by controlling the thickness of coated titanium dioxide, form different refraction effects, thus form different interference color, finally form pearl effect, this pigment is referred to as pearlescence usually; Another kind is pearl white, is a kind of translucent white pearlescent pigment, and be added in the middle of film and can form fine and smooth metal-like, this pigment is commonly referred to pearl cream.By the collocation of two kinds of pearly pigments, copper sheet material effect true to nature can be made.
Embodiment
Preferred embodiment 1:
Emulation copper coating, by weight, be made up of following raw materials according: mixed solvent 670 parts, cellulose acetate butyrate 60 parts, 60 parts, vibrin, nitro-cotton 40 parts, 30 parts, aminoresin, flow agent 2 parts, anti-settling agent 25 parts, pearly pigment 55 parts, toner pigment 10 parts.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is the wherein a kind of of saturated polyester and unsaturated polyester or their arbitrary combination.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of propyl carbinol etherificate, the terpolycyantoamino-formaldehyde resin of isopropylcarbinol etherificate, the terpolycyantoamino-formaldehyde resin of methanol etherification, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is the combination of the mica-iron oxide pigment of coated by titanium dioxide or the synthetic chip glass of coated by titanium dioxide and pearl white pearl cream.Described toner pigment is a kind of in look essence, transparent iron oxide pigment, the blue or green pigment of phthalein or their arbitrary combination.
The production technique preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: added successively in a mixing bowl by mixed solvent, stirring at low speed is even;
Cellulose acetate butyrate is added, until dissolve completely under step 2:400 rev/min of agitation condition;
Nitro-cotton is added, until dissolve completely under step 3:400 rev/min of agitation condition;
Step 4: add vibrin, aminoresin, flow agent, anti-settling agent successively, with the rotating speed of 600 revs/min, stirs 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 revs/min stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Preferred embodiment 2:
Emulation copper coating, by weight, be made up of following raw materials according: mixed solvent 700 parts, cellulose acetate butyrate 70 parts, 70 parts, vibrin, nitro-cotton 50 parts, 40 parts, aminoresin, flow agent 5 parts, anti-settling agent 35 parts, pearly pigment 75 parts, toner pigment 30 parts.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is the wherein a kind of of saturated polyester and unsaturated polyester or their arbitrary combination.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of propyl carbinol etherificate, the terpolycyantoamino-formaldehyde resin of isopropylcarbinol etherificate, the terpolycyantoamino-formaldehyde resin of methanol etherification, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is the combination of the mica-iron oxide pigment of coated by titanium dioxide or the synthetic chip glass of coated by titanium dioxide and pearl white pearl cream.Described toner pigment is a kind of in look essence, transparent iron oxide pigment, the blue or green pigment of phthalein or their arbitrary combination.
The production technique preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: added successively in a mixing bowl by mixed solvent, stirring at low speed is even;
Cellulose acetate butyrate is added, until dissolve completely under step 2:400 rev/min of agitation condition;
Nitro-cotton is added, until dissolve completely under step 3:400 rev/min of agitation condition;
Step 4: add vibrin, aminoresin, flow agent, anti-settling agent successively, with the rotating speed of 600 revs/min, stirs 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 revs/min stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Preferred embodiment 3:
Emulation copper coating, by weight, be made up of following raw materials according: mixed solvent 685 parts, cellulose acetate butyrate 65 parts, 65 parts, vibrin, nitro-cotton 45 parts, 35 parts, aminoresin, flow agent 3 parts, anti-settling agent 30 parts, pearly pigment 65 parts, toner pigment 20 parts.
Described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.Described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate, CAB381-20 cellulose acetate butyrate or their arbitrary combination.Described vibrin is the wherein a kind of of saturated polyester and unsaturated polyester or their arbitrary combination.Described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton, 1/16 " nitro-cotton or their arbitrary combination.Described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of propyl carbinol etherificate, the terpolycyantoamino-formaldehyde resin of isopropylcarbinol etherificate, the terpolycyantoamino-formaldehyde resin of methanol etherification, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.Described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution, polyacrylate(s) flow agent or their arbitrary combination.Described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.Described pearly pigment is the combination of the mica-iron oxide pigment of coated by titanium dioxide or the synthetic chip glass of coated by titanium dioxide and pearl white pearl cream.Described toner pigment is a kind of in look essence, transparent iron oxide pigment, the blue or green pigment of phthalein or their arbitrary combination.
The production technique preparing above-mentioned emulation copper coating comprises the following steps:
Step 1: added successively in a mixing bowl by mixed solvent, stirring at low speed is even;
Cellulose acetate butyrate is added, until dissolve completely under step 2:400 rev/min of agitation condition;
Nitro-cotton is added, until dissolve completely under step 3:400 rev/min of agitation condition;
Step 4: add vibrin, aminoresin, flow agent, anti-settling agent successively, with the rotating speed of 600 revs/min, stirs 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 revs/min stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
Table 1: the chemical analysis results of emulation copper coating of the present invention and common bronze-like coating
| Analysis project | Embodiment 1,2,3 emulation copper coating | Common bronze-like coating |
| Metal-like | Strong metal-like | Lower metal-like or without metal-like |
| Unfading (Q-SUN) | 1 grade of variable color in 1000 hours | 1 grade of variable color in 1000 hours |
| Paint film flexibility | 1mm-1.2mm | 1mm-3mm |
| Paint film shock resistance | 50cm-55cm | 40cm-50cm |
| Paint film adhesion | 1 grade | 1 grade |
Although specifically show in conjunction with preferred embodiment and describe the present invention; but those skilled in the art should be understood that; not departing from the spirit and scope of the present invention that appended claims limits; can make a variety of changes the present invention in the form and details, be protection scope of the present invention.
Claims (9)
1. emulate copper coating, it is characterized in that: by weight, be made up of following raw materials according: mixed solvent 670-700 part, cellulose acetate butyrate 60-70 part, vibrin 60-70 part, nitro-cotton 40-50 part, aminoresin 30-40 part, flow agent 2-5 part, anti-settling agent 25-35 part, pearly pigment 55-75 part, toner pigment 10-30 part, described pearly pigment is the mica-iron oxide pigment of coated by titanium dioxide and the combination of pearl white pearl cream, or is the synthetic chip glass of coated by titanium dioxide and the combination of pearl white pearl cream.
2. emulation copper coating according to claim 1, is characterized in that: described mixed solvent is a kind of in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, butyl glycol ether and No. 1000 solvent oils or their arbitrary combination.
3. emulation copper coating according to claim 1, is characterized in that: described cellulose acetate butyrate is a kind of in CAB381-0.2 cellulose acetate butyrate, CAB381-0.5 cellulose acetate butyrate, CAB381-2 cellulose acetate butyrate and CAB381-20 cellulose acetate butyrate or their arbitrary combination.
4. emulation copper coating according to claim 1, is characterized in that: described vibrin is the wherein a kind of of saturated polyester and unsaturated polyester or their arbitrary combination.
5. emulation copper coating according to claim 1, is characterized in that: described nitro-cotton is a kind of in 1/2 " nitro-cotton, 1/4 " nitro-cotton, 1/8 " nitro-cotton and 1/16 " nitro-cotton or their arbitrary combination.
6. emulation copper coating according to claim 1, is characterized in that: described aminoresin is a kind of in the terpolycyantoamino-formaldehyde resin of propyl carbinol etherificate, the terpolycyantoamino-formaldehyde resin of isopropylcarbinol etherificate, the terpolycyantoamino-formaldehyde resin of methanol etherification, complex etherified terpolycyantoamino-formaldehyde resin or their arbitrary combination.
7. emulation copper coating according to claim 1, is characterized in that: described flow agent is a kind of in many methyl-silicone oils, polyester modification siloxane solution, polyether modified siloxane solution and polyacrylate(s) flow agent or their arbitrary combination.
8. emulation copper coating according to claim 1, is characterized in that: described anti-settling agent is a kind of in polyethylene wax, polyamide wax or their arbitrary combination.
9. prepare a production technique for the emulation copper coating as described in any one of claim 1 to 8, it is characterized in that: comprise the following steps:
Step 1: added successively in a mixing bowl by mixed solvent, stirring at low speed is even;
Cellulose acetate butyrate is added, until dissolve completely under step 2:400 rev/min of agitation condition;
Nitro-cotton is added, until dissolve completely under step 3:400 rev/min of agitation condition;
Step 4: add vibrin, aminoresin, flow agent, anti-settling agent successively, with the rotating speed of 600 revs/min, stirs 15 minutes, even to mixing of materials;
Under step 5:400 rev/min of agitation condition, pearly pigment and toner pigment are added in cylinder and mix colours;
Step 6: add a small amount of mixed solvent adjusting viscosity to 65 ± 5KU, 600 revs/min stir 5 minutes even to mixing of materials;
Step 7: be cooled to room temperature, after the assay was approved, 80 orders filter and package.
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| MX356701B (en) | 2012-03-14 | 2018-06-11 | Basf Coatings Gmbh | Metal pigment- and solvent-containing pigment pastes, and use thereof for producing effect-producing solvent-containing coating materials. |
| CN103665973A (en) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | Preparation process of inorganic copper imitation coating and process for replacing protective and decorative copper layer of metal surface with inorganic copper imitation coating |
| CN104530872A (en) * | 2014-12-30 | 2015-04-22 | 佛山金智节能膜有限公司 | Intelligent temperature controlling coating with oriented structure and preparation method thereof |
| CN104877491B (en) * | 2015-06-02 | 2017-12-19 | 柳州龙溪化工有限公司 | A kind of anti-hot heat insulation type automobile paint gloss oil and metallized finish |
| CN104893488B (en) * | 2015-06-12 | 2017-04-05 | 漳州鑫展旺化工有限公司 | It is a kind of to reduce vehicle body repair aberration Rapid-Repair paint and preparation method thereof |
| CN106883764B (en) * | 2017-04-14 | 2019-08-23 | 浙江喜泽荣制漆有限公司 | Aluminum profile emulation copper coating and preparation method thereof |
| CN107284066A (en) * | 2017-06-29 | 2017-10-24 | 缪秉强 | A kind of multi-sheet printed technique and its pigment for the technique |
| CN107216748B (en) * | 2017-08-04 | 2019-03-29 | 浙江喜泽荣制漆有限公司 | Aqueous emulation copper coating of one kind and preparation method thereof |
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Inventor after: Wang Shirong Inventor after: Zhao Xianglong Inventor after: Wang Shirong, Zhao Xianglong, Zheng Dalin Inventor before: Wang Shirong Inventor before: Zhang Xianglong Inventor before: Wang Shirong, Zhang Xianglong, Zheng Dalin |
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