CN105482531A - Solid instant transparent watercolor and preparation method thereof - Google Patents
Solid instant transparent watercolor and preparation method thereof Download PDFInfo
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- CN105482531A CN105482531A CN201511017365.6A CN201511017365A CN105482531A CN 105482531 A CN105482531 A CN 105482531A CN 201511017365 A CN201511017365 A CN 201511017365A CN 105482531 A CN105482531 A CN 105482531A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a solid instant transparent watercolor which comprises a nano pigment paste, pigment powder, cyclodextrin, carrageenin, Kathon, alkylphenol polyoxyethylene, a humectant, sodium polypropionate, vapor-phase silicon dioxide and deionized water. A small amount of nano pigment is added into the formula to substitute part of the common pigment raw material, so that the prepared product has improved service performance and effect without obviously increasing the economic cost of the product. The solid instant transparent watercolor has the advantages of favorable usability, bright color, excellent weather resistance and high chemical stability. The watercolor has the characteristics of favorable solubility, high fineness, smooth painting, high water resistance and the like, and the painting does not fade after the watercolor becomes dry.
Description
Technical field
The present invention relates to a kind of watercolors, in particular, the present invention relates to a kind of solid-state instant transparent water color painting and preparation method thereof.
Background technology
The difference of watercolor painting and oil painting, gouache is that it has two essential characteristics: one is that picture has penetrating visual sense feeling mostly; Two is the mobility of water in painting process, cause watercolor painting thus and be different from the difference that other draw appearance style and features and the creating technique of planting, watercolor presents transparent, slim and graceful, beautiful and moistening smoothness, no matter be warm gorgeous sunlight or deep vast ocean, it is no matter the cloud of bright and beautiful bright-colored flowers and trees or chilly haze, invariably arouse color impulsion and the performance desire of watercolor painting artist heart, usually can draw fantasy magnificent picture.So watercolors are the important factors being related to watercolor painting, it requires that watercolors look grain is very thin, very well water-soluble, the state of its crystal clear can be shown, it is coated on blank sheet of paper from level to level, just as the effect that transparent glass Paper Diego falls, watercolor light color can not cover background color, do not resemble oil painting, gouache pigment has stronger hiding power, pigment and prime cement all require very exquisite, the mineral pigment too easily precipitated and the bad batching of the transparency all should not be used for moist colours, at present superior in quality moist colours on the market all transparent and water-soluble in all fine, the picture of the watercolor painting doing out is had and infuses clearly transparent impression, mix colours with water, play the effect of moisture, flexible nature, moisten smooth, to one's great satisfaction dripping, charm is endless.But also have some moist colours water-soluble poor, its major cause is that pigment and prime cement are selected and arrange in pairs or groups bad, result in the sensation that work picture does not out have moistening smoothness, crystal clear.
Summary of the invention
The object of this invention is to provide a kind of solubility property good, and have exquisiteness, drawing is smooth, water resisting property is strong, draw dry after the moist colours and preparation method thereof of the feature such as colour-fast.
The technical solution used in the present invention is: a kind of instant solid transparent water color painting, comprises the component of following weight part:
Nano dye is starched: 5 ~ 15 parts; Pigment powder: 5 ~ 15 parts; Cyclodextrin: 0.2 ~ 0.5 part;
Carrageenin: 1 ~ 5 part; Kathon CG: 7 ~ 12 parts; Alkylphenol polyoxyethylene: 6 ~ 15 parts;
Wetting Agent for Printing Inks: 2 ~ 12 parts; Poly-Sodium Propionate: 3 ~ 8 parts; Aerosil: 0.1 ~ 3 part;
Deionized water: 5 ~ 20 parts.
Preferably, what described nano dye slurry was one or more in nano titanium oxide, nano-calcium carbonate, nano-sized iron oxide is composite, and the particle diameter of described nano dye is 20 ~ 100 nanometers.
Preferably, described wetting Agent for Printing Inks is the one in polyoxyethylene glycol, polypropylene glycol, glycerine, Tetraglycol 99, BT, diethylene glycol dibutyl ether, triglycol one ether, tetraethylene glycol dimethyl ether, 31 hydramine and diethanolamine.
Preferably, described pigment powder be selected from titanium white, carbon black, phthalocyanine blue, phthalein is dark green, sun-proof is red and the toner of organic yellow.
Preferably, also comprise the auxiliary agent of 0.1 part ~ 0.5 part, described auxiliary agent is sanitas, mould inhibitor or their mixture.
Preferably, the molecular weight of described poly-Sodium Propionate is 3000000 ~ 6000000.
Another object of the present invention is to provide a kind of preparation method of instant solid transparent water color painting, comprises the steps:
Step 1): first deionized water is heated, after boiling 10 minutes microbicidels, stop heating, add the cyclodextrin of described parts by weight, carrageenin, Kathon CG, wetting Agent for Printing Inks, poly-Sodium Propionate stirring and dissolving, obtain mixture;
Step 2): in above-mentioned mixed solution, add alkylphenol polyoxyethylene be stirred into viscose;
Step 3): add nano dye oar and pigment powder at described viscose and to stir to obtain coarse particles;
Step 4): above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3 times for mill base feed liquid through three-roll grinder; Three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (rpm).By the width in handwheel adjusting roller gap, stand-off distance between adjusting roller during grinding, first time grinding adjustment two roller gap distance is 45 μm; Second time grinding adjustment two roller gap distance is 20 μm; Third time grinding adjustment two roller gap distance is 10 μm; The fineness of the mill base feed liquid after grinding is below 15 μm;
Step 5 :) ground mill base feed liquid is put into baking oven to toast, the water content controlling material is take out between 4.5% ~ 5%, is pulverized by baked material again, finally powder stamping machine is carried out being washed into cake or sheet, inspection, packaging, obtains solid water color paint product.
The present invention at least comprises following beneficial effect:
(1) use a small amount of nano dye to replace part common pigments raw material in the present invention's formula, the product made reaches and improves use properties and effect, but the Financial cost of not obvious increase product; Possess excellent high-weatherability and chemical stability while not only having possessed excellent usability and bright-coloured bright color;
(2) the present invention is by adding sodium polyacrylate, and it is except having adhesive property, also utilizes its film-forming properties, and its film formed covers the surface of pigment, has the performances such as good elasticity, tenacity, the transparency, gloss, nondiscoloration.
Embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technique means adopted in embodiment is well known to those skilled in the art, the raw material adopted also be can business obtain.The various process do not described in detail and method are ordinary methods as known in the art.
A kind of instant solid transparent water color painting, comprises the component of following weight part:
Nano dye is starched: 5 ~ 15 parts; Pigment powder: 5 ~ 15 parts; Cyclodextrin: 0.2 ~ 0.5 part;
Carrageenin: 1 ~ 5 part; Kathon CG: 7 ~ 12 parts; Alkylphenol polyoxyethylene: 6 ~ 15 parts;
Wetting Agent for Printing Inks: 2 ~ 12 parts; Poly-Sodium Propionate: 3 ~ 8 parts; Aerosil: 0.1 ~ 3 part;
Deionized water: 5 ~ 20 parts.
Improve further as the present invention, what described nano dye slurry was one or more in nano titanium oxide, nano-calcium carbonate, nano-sized iron oxide is composite, and the particle diameter of described nano dye is 20 ~ 100 nanometers.
Improve further as the present invention, described wetting Agent for Printing Inks is the one in polyoxyethylene glycol, polypropylene glycol, glycerine, Tetraglycol 99, BT, diethylene glycol dibutyl ether, triglycol one ether, tetraethylene glycol dimethyl ether, 31 hydramine and diethanolamine.
Improve further as the present invention, described pigment powder be selected from titanium white, carbon black, phthalocyanine blue, phthalein is dark green, sun-proof is red and the toner of organic yellow.
Improve further as the present invention, also comprise the auxiliary agent of 0.1 part ~ 0.5 part, described auxiliary agent is sanitas, mould inhibitor or their mixture.
Improve further as the present invention, the molecular weight of described poly-Sodium Propionate is 3000000 ~ 6000000.
Another object of the present invention is to provide a kind of preparation method of instant solid transparent water color painting, comprises the steps:
Step 1): first deionized water is heated, after boiling 10 minutes microbicidels, stop heating, add the cyclodextrin of described parts by weight, carrageenin, Kathon CG, wetting Agent for Printing Inks, poly-Sodium Propionate stirring and dissolving, obtain mixture;
Step 2): in above-mentioned mixed solution, add alkylphenol polyoxyethylene be stirred into viscose;
Step 3): add nano dye oar and pigment powder at described viscose and to stir to obtain coarse particles;
Step 4): above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3 times for mill base feed liquid through three-roll grinder; Three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (rpm).By the width in handwheel adjusting roller gap, stand-off distance between adjusting roller during grinding, first time grinding adjustment two roller gap distance is 45 μm; Second time grinding adjustment two roller gap distance is 20 μm; Third time grinding adjustment two roller gap distance is 10 μm; The fineness of the mill base feed liquid after grinding is below 15 μm;
Step 5 :) ground mill base feed liquid is put into baking oven to toast, the water content controlling material is take out between 4.5%-5%, is pulverized by baked material again, finally powder stamping machine is carried out being washed into cake or sheet, inspection, packaging, obtains solid water color paint product.
Use nano dye raw material for commercial goods in formula of the present invention, and starch can be directly used in formula for scattered nano dye colorant.The particle diameter of nano dye is 20-100 nanometer.This ultrafine particle is due to the increase greatly of surface-area, and surface atom chemical bond is unsettled and exist in special surface effects and volume effect.These effects cause the change of superfine pigment particles physicals and surface chemistry.Nano dye particle embodies outstanding quality of colour, and bright in colour bright, color is saturated strong, and tinting strength is extremely strong, and remains water-fast, fast light, the weather-proof characteristic of common pigments.Its surface-area increases greatly, and surface energy increases greatly, sterically hindered increase.Sterically hindered increase can make all particulates in matrix comprise pigment suspension itself, so the physical stability of product increases.
Alkylphenol polyoxyethylene is an ionogenic surfactant containing hydrophilic radical and lipophilic group, and it makes pigment-dispersing good, and it makes two kinds of different pigment obtain uniform dispersion system, improves chroma-luminance.
Carrageenin is nontoxic, has good security.Carrageenin has typical volume rheological characteristics.Along with shearing rate increases, because gel-like network is destroyed, viscosity is caused to reduce, glue is thinning, but once shearing force disappears, viscosity can be recovered again, thus carrageenin is made to have the performance well controlling the finished product rheological, product has good pumping and processing characteristics, this feature is utilized to add xanthan gum in the liquid needing to add thickening material, not only liquid easily flows in course of conveying, and can return to required viscosity again after leaving standstill, and has consistency with most synthesis, natural thickener etc.
Cyclodextrin is a kind of cyclic oligomer sugar compounds, be ring dextrin glucosyl transferase act on starch and 7 glucose generated with α-1, the cyclic oligosaccharide that 4-glycosidic link combines, because it has special circular hollow cylinder type, therefore can with some chromogenesis inclusion compound, and under certain temperature condition, pigment molecular again can from stripping in inclusion compound, therefore it can be used to the solubleness, the stability that increase pigment, can also reduce pungency and the toxicity of pigment.
Table 1 lists concrete component and the content thereof of different embodiment and comparative example.
Table 1 embodiment 1 ~ 3 and the concrete component of comparative example 1 ~ 4
Table 2 lists the test result of embodiment 1 ~ 3 and comparative example 1 ~ 4.
The test result of table 2 embodiment 1 ~ 3 and comparative example 1 ~ 4
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (7)
1. a solid-state instant transparent water color painting, is characterized in that, comprises the component of following weight part:
Nano dye is starched: 5 ~ 15 parts; Pigment powder: 5 ~ 15 parts; Cyclodextrin: 0.2 ~ 0.5 part;
Carrageenin: 1 ~ 5 part; Kathon CG: 7 ~ 12 parts; Alkylphenol polyoxyethylene: 6 ~ 15 parts;
Wetting Agent for Printing Inks: 2 ~ 12 parts; Poly-Sodium Propionate: 3 ~ 8 parts; Aerosil: 0.1 ~ 3 part;
Deionized water: 5 ~ 20 parts.
2. solid-state instant transparent water color painting as claimed in claim 1, is characterized in that, described nano dye slurry is one or more in nano titanium oxide, nano-calcium carbonate, nano-sized iron oxide, and the particle diameter of described nano dye is 20 ~ 100 nanometers.
3. solid-state instant transparent water color painting as claimed in claim 1, it is characterized in that, described wetting Agent for Printing Inks is polyoxyethylene glycol, polypropylene glycol, glycerine, Tetraglycol 99,1, one in 2,4-trihydroxybutane, diethylene glycol dibutyl ether, triglycol one ether, tetraethylene glycol dimethyl ether, 31 hydramine and diethanolamine.
4. solid-state instant transparent water color painting as claimed in claim 1, is characterized in that, described pigment powder be selected from titanium white, carbon black, phthalocyanine blue, phthalein is dark green, sun-proof is red and the toner of organic yellow.
5. solid-state instant transparent water color painting as claimed in claim 1, it is characterized in that, also comprise the auxiliary agent of 0.1 part ~ 0.5 part, described auxiliary agent is sanitas, mould inhibitor or their mixture.
6. solid-state instant transparent water color painting as claimed in claim 1, it is characterized in that, the molecular weight of described poly-Sodium Propionate is 3000000 ~ 6000000.
7., as a preparation method for solid-state instant transparent water color painting as claimed in claim 1, it is characterized in that, comprise the steps:
Step 1): first deionized water is heated, after boiling 10 minutes microbicidels, stop heating, add the cyclodextrin of described parts by weight, carrageenin, Kathon CG, wetting Agent for Printing Inks, poly-Sodium Propionate stirring and dissolving, obtain mixed solution;
Step 2): in above-mentioned mixed solution, add alkylphenol polyoxyethylene be stirred into viscose;
Step 3): add nano dye oar and pigment powder at described viscose and to stir to obtain coarse particles;
Step 4): above-mentioned coarse particles is added in the hopper of three-roll grinder, grinds 3 times for mill base feed liquid through three-roll grinder; Three-roll grinder roller diameter 650mm, three roller speed are 26: 70: 145 (rpm).By the width in handwheel adjusting roller gap, stand-off distance between adjusting roller during grinding, first time grinding adjustment two roller gap distance is 45 μm; Second time grinding adjustment two roller gap distance is 20 μm; Third time grinding adjustment two roller gap distance is 10 μm; The fineness of the mill base feed liquid after grinding is below 15 μm;
Step 5 :) ground mill base feed liquid is put into baking oven to toast, the water content controlling material is take out between 4.5% ~ 5%, is pulverized by baked material again, finally powder stamping machine is carried out being washed into cake or sheet, inspection, packaging, obtains solid water color paint product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201511017365.6A CN105482531A (en) | 2015-12-31 | 2015-12-31 | Solid instant transparent watercolor and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201511017365.6A CN105482531A (en) | 2015-12-31 | 2015-12-31 | Solid instant transparent watercolor and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221341A (en) * | 2016-08-05 | 2016-12-14 | 陈毅忠 | A kind of preparation method of weather resistant non-toxic pigment |
| CN106479237A (en) * | 2016-11-02 | 2017-03-08 | 常州创索新材料科技有限公司 | A kind of method that utilization pitaya peel prepares aubergine child's pigment |
| CN107033680A (en) * | 2017-06-15 | 2017-08-11 | 南昌蓝珀笔业画材有限公司 | A kind of preparation method of solid water color |
| CN107325645A (en) * | 2017-07-04 | 2017-11-07 | 真彩文具股份有限公司 | Colour rod containing nano dye and preparation method thereof |
| CN108410236A (en) * | 2017-02-09 | 2018-08-17 | 株式会社樱花彩色笔 | Solid water color color compositions |
| CN112029364A (en) * | 2020-04-17 | 2020-12-04 | 苏州冰心文化用品有限公司 | Weather-resistant surface modified nano gouache pigment and preparation method thereof |
| CN113831778A (en) * | 2021-09-24 | 2021-12-24 | 上海马利画材股份有限公司 | Solid pigment composition and preparation method and application thereof |
| CN113980517A (en) * | 2021-09-29 | 2022-01-28 | 宁波康大美术画材集团股份有限公司 | Solid watercolour paint and its preparing process |
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| CN101186782A (en) * | 2007-12-26 | 2008-05-28 | 宋健 | Water pigment containing nano pigment for fine arts and manufacturing method thereof |
| CN101225252A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Art watercolour containing nano-pigment and method for manufacturing same |
| CN101565571A (en) * | 2008-09-27 | 2009-10-28 | 深圳云之彩美术工艺用品有限公司 | Instant watercolor pigment and production method thereof |
| CN102101993A (en) * | 2010-12-29 | 2011-06-22 | 上海乐美文具有限公司 | Water-based pseudoplastic sealant |
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| CN101186782A (en) * | 2007-12-26 | 2008-05-28 | 宋健 | Water pigment containing nano pigment for fine arts and manufacturing method thereof |
| CN101225252A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Art watercolour containing nano-pigment and method for manufacturing same |
| CN101565571A (en) * | 2008-09-27 | 2009-10-28 | 深圳云之彩美术工艺用品有限公司 | Instant watercolor pigment and production method thereof |
| CN102101993A (en) * | 2010-12-29 | 2011-06-22 | 上海乐美文具有限公司 | Water-based pseudoplastic sealant |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221341A (en) * | 2016-08-05 | 2016-12-14 | 陈毅忠 | A kind of preparation method of weather resistant non-toxic pigment |
| CN106479237A (en) * | 2016-11-02 | 2017-03-08 | 常州创索新材料科技有限公司 | A kind of method that utilization pitaya peel prepares aubergine child's pigment |
| CN108410236A (en) * | 2017-02-09 | 2018-08-17 | 株式会社樱花彩色笔 | Solid water color color compositions |
| CN108410236B (en) * | 2017-02-09 | 2020-06-09 | 株式会社樱花彩色笔 | Solid watercolor pigment composition |
| CN107033680A (en) * | 2017-06-15 | 2017-08-11 | 南昌蓝珀笔业画材有限公司 | A kind of preparation method of solid water color |
| CN107325645A (en) * | 2017-07-04 | 2017-11-07 | 真彩文具股份有限公司 | Colour rod containing nano dye and preparation method thereof |
| CN112029364A (en) * | 2020-04-17 | 2020-12-04 | 苏州冰心文化用品有限公司 | Weather-resistant surface modified nano gouache pigment and preparation method thereof |
| CN113831778A (en) * | 2021-09-24 | 2021-12-24 | 上海马利画材股份有限公司 | Solid pigment composition and preparation method and application thereof |
| CN113980517A (en) * | 2021-09-29 | 2022-01-28 | 宁波康大美术画材集团股份有限公司 | Solid watercolour paint and its preparing process |
| CN113980517B (en) * | 2021-09-29 | 2022-10-14 | 宁波康大美术画材集团股份有限公司 | Preparation method of solid watercolor paint |
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Application publication date: 20160413 |