CN105086545A - Quick-drying multi-color patterned coating - Google Patents

Quick-drying multi-color patterned coating Download PDF

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Publication number
CN105086545A
CN105086545A CN201510465857.5A CN201510465857A CN105086545A CN 105086545 A CN105086545 A CN 105086545A CN 201510465857 A CN201510465857 A CN 201510465857A CN 105086545 A CN105086545 A CN 105086545A
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China
Prior art keywords
parts
quick
drying
patterned coating
water
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Pending
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CN201510465857.5A
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Chinese (zh)
Inventor
卢业虎
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Relax And Suitable New Textile Material Science And Technology Ltd In Suzhou
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Relax And Suitable New Textile Material Science And Technology Ltd In Suzhou
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Priority to CN201510465857.5A priority Critical patent/CN105086545A/en
Publication of CN105086545A publication Critical patent/CN105086545A/en
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Abstract

The invention discloses a quick-drying multi-color patterned coating. The quick-drying multi-color patterned coating is made from distilled water, pigment, sodium alkyl benzene sulfonate, polyoxyethylene alkylbenzene ether, ethyl acrylate, methyl methacrylate, oxalic acid, butyl cellosolve, pentaerythritol and micalex. The quick-drying multi-color patterned coating ranges from 85 to 95 in viscosity at the temperature of 25 DEG C and is free of agglomeration and forms uniform dispersoid after being mixed; the quick-drying multi-color patterned coating is free of change after being soaked in water for 35 days to 45 days, free of change after being soaked in alkali liquor for 20 days to 30 days and free of change after being scrubbed 3000 times to 5000 times; the surface drying time ranges from 1 hour to 1.5 hours, the hard drying time ranges from 16 hours to 20 hours, the storage life ranges from 9 months to 12 months, the solid content ranges from 18% to 28%, and the quick-drying multi-color patterned coating can be produced widely and replace existing materials continuously.

Description

A kind of quick-drying coating of multi-colour pattern
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of quick-drying coating of multi-colour pattern.
Background technology
Water-water colorful marble paint rich color is colorful, and special color can be provided on request and emulation property high, it is unrestricted in designer, can change shape arbitrarily according to the intention of Designers.The general name of the ester class of vinylformic acid and homologue thereof.Important has methyl acrylate, sodium alkyl benzene sulfonate, 2-methyl methacrylate and 2-methyl alkyl benzene sulfonic acid sodium salt etc.Can autohemagglutination or and other monomer copolymerizations, be manufacture the monomer of tackiness agent, synthetic resins, specialty elastomer and plastics.
Multicolor finish is mainly used in copys stone material effect, so also known as liquid stone, is also local horizon exterior coating.Be made up of inconsistent two phase compositions, wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.This pattern formed by disposable spray finishing is completely different from the method being completed the multicolour pattern that could be formed by multiple working procedure successively.But along with China is more and more stricter to the protection of natural resources and national environmental protection and energy saving policy, relevant laws and regulations, make the exploitation of lithotome, processing, transportation cost constantly increase, this affects the application of lithotome in building decoration field to a certain extent.
Vinylformic acid is important organic synthesis raw material and synthetic resins monomer, is polymerization velocity vinyl monomer quickly.Be the simplest unsaturated carboxylic acid, be made up of a vinyl and a carboxyl.Pure vinylformic acid is achromaticity and clarification liquid, is with characteristic irritating smell.It can dissolve each other with water, alcohol, ether and chloroform, is prepared by the propylene obtained from refinery.Great majority are in order to manufacture the esters of acrylic acids such as methyl acrylate, ethyl ester, butyl ester, hydroxyl ethyl ester.Vinylformic acid and acrylate can homopolymerization and copolymerization, and its polymkeric substance is for the synthesis of industrial sectors such as resin, synthon, super absorbent resin, building materials, coating.
Sodium alkyl benzene sulfonate, organic compound, white plates, cotton-shaped or pulverulent solids, tasteless.Water-soluble, be insoluble to gasoline, kerosene, vegetables oil, benzene, toluene, ethylene dichloride, tetracol phenixin, acetone, vinyl acetic monomer, methyl alcohol, ethylene glycol etc.Be slightly soluble in dimethyl sulfoxide (DMSO).Sodium alkyl benzene sulfonate is important industrial chemicals, for the manufacture of sodium alkyl benzene sulfonate acetal, resistance to gasoline pipeline and vinylon synthon, fabric-treating agent, emulsifying agent, paper coating, tackiness agent, glue etc.After coating, due to uneven, there is dispersion and multiple color decorative pattern can be obtained, stereoscopic sensation is strong, gloss is graceful, appearance tactile impression is good relief-type coating.The characteristic such as it has acid and alkali-resistance, water-fastness, anti-pollution, wear-resisting, bonding strength is high, can be applied to plaster, cement, asbestos, brick, wood, metallic surface.Which field is does water-water multicolor finish mainly used in? its range of application that a lot of people can feel not is very wide, actually this is not so, lithotome is long at the applicating history in building decoration field, firmly getting architect and user's favor with its noble, natural, simple and unsophisticated, luxurious style, is also one of important symbol of high-end buildings external image.
Oil-in-water-type, oily bag vinylformic acid, oily oil-in and water bag vinylformic acid four class can be divided into by its medium condition, best with oily bag vinylformic acid package stability, and most widely used, water bag vinylformic acid environmental protection multicolor finish is being developed in practicality.The colorful marble paint of water-water is water-based coating, meet environmental requirement, non-harmful product during construction, because containing supra polymer element, construct after complete drying, have wear-resistant, wash away the characteristic changed with uviolizing, antistatic, high temperature resistant, acid rain resistant, waterproof, anti-be full of cracks, high strength, resistance to long-term multiple weather condition, property retention is constant, is easy to maintenance and cleaning, self-cleaning is excellent, multicolour once sprays, constructs easily, is a kind of excellent water tolerance, weathering resistance, a coating material.
Multicolor finish is the new decorative material for building of beautifying hotel, movie theatre, entertainment place, shop, office building, house etc.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan, therefore also known as liquid stone.The performance of alkyl benzene sulphonate (ABS) sodium rubber affects by atomic number of alkyl carbon object in its principal monomer alkyl acrylate.Rubber based on sodium alkyl benzene sulfonate, oil resistant, thermotolerance are better; And the rubber based on butyl acrylate, because atomic number of alkyl carbon object increases, the shielding effect of ester group polar group is increased, therefore water tolerance is made to make moderate progress, simultaneously due to shielding effect, reduce power between rubber molecule, increase inner plasticity, thus temperature limit of brittleness is reduced, winter hardiness is better.If by above-mentioned two kinds of monomers and use, then can obtain the rubber between both performances.
1843, first find that acrolein oxidation generates vinylformic acid.1931, Rohm and Haas Company (US) Independenec Mall West, Philadelphia, Pennsy Lvania 1 of the U.S. succeeded in developing cyanoethanol hydrolysis acrylic acid process processed, is industrial unique production method for a long time.Nineteen thirty-nine, fritz W.J. thunder is worn and has been invented Carbonylation of Acetylene legal system vinylformic acid, within 1954, establishes full scale plant in the U.S..Meanwhile also successfully develop acrylonitrile hydrolysis acrylic acid process.Build up from U.S. combinating carbide company in 1969 with after propylene oxidation legal system vinylformic acid full scale plant, various countries adopt this method to produce in succession.In recent years, oxidation of propylene had carried out many improvement at catalyzer and process aspect, had become and had produced acrylic acid main method.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan.
Summary of the invention
The invention provides the multicolor finish that a kind of fast drying and period of storage are long, solve the technical problems such as the dry slow and period of storage of existing multicolor finish is short.
The present invention is by the following technical solutions: a kind of quick-drying coating of multi-colour pattern, it is as follows that mass fraction proportioning pressed by its raw material: distilled water 100 parts, pigment 1-5 part, sodium alkyl benzene sulfonate 10-30 part, polyoxyethylene alkyl phenylate 5-25 part, ethyl propenoate 60-80 part, methyl methacrylate 30-50 part, oxalic acid 1-10 part, butyl glycol ether 5-10 part, tetramethylolmethane 3-7 part, Muscovitum 4-16 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described quick-drying coating of multi-colour pattern: distilled water 100 parts, pigment 2-4 part, sodium alkyl benzene sulfonate 15-25 part, polyoxyethylene alkyl phenylate 10-20 part, ethyl propenoate 65-75 part, methyl methacrylate 35-45 part, oxalic acid 3-7 part, butyl glycol ether 7-9 part, tetramethylolmethane 4-6 part, Muscovitum 7-13 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described quick-drying coating of multi-colour pattern: distilled water 100 parts, pigment 3 parts, sodium alkyl benzene sulfonate 20 parts, polyoxyethylene alkyl phenylate 15 parts, ethyl propenoate 70 parts, methyl methacrylate 40 parts, oxalic acid 5 parts, butyl glycol ether 8 parts, tetramethylolmethane 5 parts, Muscovitum 10 parts.As a preferred technical solution of the present invention: described pigment adopts red iron oxide or phthalocyanine blue.
Beneficial effect: a kind of quick-drying coating of multi-colour pattern of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is without caking, uniformly dispersion after mixing; 2,25 DEG C of viscosity 85-95, soak 35-45d in water unchanged, soak 20-30d in alkali lye unchanged, and resistance to shampooing 3000-5000 time is unchanged; 3, film surface drying 1-1.5h, does solid work 16-20h, 9-12 month storage period, and solid content 18-28% the widespread production not division of history into periods can replace current material.
Embodiment
Below in conjunction with example, the invention will be further described, and embodiment, only for the present invention will be described, does not form the restriction to right, and other alternative means that it may occur to persons skilled in the art that, all within the scope of the claims in the present invention.
Embodiment 1:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 1 part, sodium alkyl benzene sulfonate 10 parts, polyoxyethylene alkyl phenylate 5 parts, ethyl propenoate 60 parts, methyl methacrylate 30 parts, oxalic acid 1 part, butyl glycol ether 5 parts, tetramethylolmethane 3 parts, Muscovitum 4 parts, is uniformly mixed in a kettle..
25 DEG C of viscosity 85, soak 35d in water unchanged, soak 20d in alkali lye unchanged, and resistance to shampooing 3000 times is unchanged; Film surface drying 1.5h, does solid work 20h, 12 months storage periods, solid content 28%.
Embodiment 2:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 5 parts, sodium alkyl benzene sulfonate 30 parts, polyoxyethylene alkyl phenylate 25 parts, ethyl propenoate 80 parts, methyl methacrylate 50 parts, oxalic acid 10 parts, butyl glycol ether 10 parts, tetramethylolmethane 7 parts, Muscovitum 16 parts, is uniformly mixed in a kettle..
25 DEG C of viscosity 88, soak 38d in water unchanged, soak 22d in alkali lye unchanged, and resistance to shampooing 3500 times is unchanged; Film surface drying 1.4h, does solid work 19h, 10 months storage periods, solid content 20%.
Embodiment 3:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 2 parts, sodium alkyl benzene sulfonate 15 parts, polyoxyethylene alkyl phenylate 10 parts, ethyl propenoate 65 parts, methyl methacrylate 35 parts, oxalic acid 3 parts, butyl glycol ether 7 parts, tetramethylolmethane 4 parts, Muscovitum 7 parts, is uniformly mixed in a kettle..
25 DEG C of viscosity 90, soak 40d in water unchanged, soak 25d in alkali lye unchanged, and resistance to shampooing 4000 times is unchanged; Film surface drying 1h, does solid work 18h, 10 months storage periods, solid content 18%.
Embodiment 4:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 4 parts, sodium alkyl benzene sulfonate 25 parts, polyoxyethylene alkyl phenylate 20 parts, ethyl propenoate 75 parts, methyl methacrylate 45 parts, oxalic acid 7 parts, butyl glycol ether 9 parts, tetramethylolmethane 6 parts, Muscovitum 13 parts, is uniformly mixed in a kettle..
25 DEG C of viscosity 93, soak 42d in water unchanged, soak 28d in alkali lye unchanged, and resistance to shampooing 4500 times is unchanged; Film surface drying 1.1h, does solid work 17h, 11 months storage periods, solid content 25%.
Embodiment 5:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 3 parts, sodium alkyl benzene sulfonate 20 parts, polyoxyethylene alkyl phenylate 15 parts, ethyl propenoate 70 parts, methyl methacrylate 40 parts, oxalic acid 5 parts, butyl glycol ether 8 parts, tetramethylolmethane 5 parts, Muscovitum 10 parts, is uniformly mixed in a kettle..
25 DEG C of viscosity 95, soak 45d in water unchanged, soak 30d in alkali lye unchanged, and resistance to shampooing 5000 times is unchanged; Film surface drying 1h, does solid work 16h, 12 months storage periods, solid content 28%.

Claims (4)

1. a quick-drying coating of multi-colour pattern, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described quick-drying coating of multi-colour pattern: distilled water 100 parts, pigment 1-5 part, sodium alkyl benzene sulfonate 10-30 part, polyoxyethylene alkyl phenylate 5-25 part, ethyl propenoate 60-80 part, methyl methacrylate 30-50 part, oxalic acid 1-10 part, butyl glycol ether 5-10 part, tetramethylolmethane 3-7 part, Muscovitum 4-16 part.
2. a kind of quick-drying coating of multi-colour pattern according to claim 1, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described quick-drying coating of multi-colour pattern: distilled water 100 parts, pigment 2-4 part, sodium alkyl benzene sulfonate 15-25 part, polyoxyethylene alkyl phenylate 10-20 part, ethyl propenoate 65-75 part, methyl methacrylate 35-45 part, oxalic acid 3-7 part, butyl glycol ether 7-9 part, tetramethylolmethane 4-6 part, Muscovitum 7-13 part.
3. a kind of quick-drying coating of multi-colour pattern according to claim 2, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described quick-drying coating of multi-colour pattern: distilled water 100 parts, pigment 3 parts, sodium alkyl benzene sulfonate 20 parts, polyoxyethylene alkyl phenylate 15 parts, ethyl propenoate 70 parts, methyl methacrylate 40 parts, oxalic acid 5 parts, butyl glycol ether 8 parts, tetramethylolmethane 5 parts, Muscovitum 10 parts.
4. a kind of quick-drying coating of multi-colour pattern according to claim 1, is characterized in that: described pigment adopts red iron oxide or phthalocyanine blue.
CN201510465857.5A 2015-08-03 2015-08-03 Quick-drying multi-color patterned coating Pending CN105086545A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005015645A (en) * 2003-06-26 2005-01-20 Sk Kaken Co Ltd Multicolor coating composition
CN104073079A (en) * 2014-06-20 2014-10-01 吴江华诚复合材料科技有限公司 Quick-drying multicolor paint
CN104098975A (en) * 2014-07-15 2014-10-15 杭州宁致合成材料有限公司 Water-in-water multi-color coating synthetized by multi-color ultra-thin slices and production process
CN104119748A (en) * 2014-08-06 2014-10-29 吴江华诚复合材料科技有限公司 High-temperature resistant water-based multicolor paint
CN104231759A (en) * 2014-09-19 2014-12-24 苏州洛特兰新材料科技有限公司 Colorful quick-drying nitrocellulose paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005015645A (en) * 2003-06-26 2005-01-20 Sk Kaken Co Ltd Multicolor coating composition
CN104073079A (en) * 2014-06-20 2014-10-01 吴江华诚复合材料科技有限公司 Quick-drying multicolor paint
CN104098975A (en) * 2014-07-15 2014-10-15 杭州宁致合成材料有限公司 Water-in-water multi-color coating synthetized by multi-color ultra-thin slices and production process
CN104119748A (en) * 2014-08-06 2014-10-29 吴江华诚复合材料科技有限公司 High-temperature resistant water-based multicolor paint
CN104231759A (en) * 2014-09-19 2014-12-24 苏州洛特兰新材料科技有限公司 Colorful quick-drying nitrocellulose paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国化学协会研究组: "《油漆的生产、加工使用技术标准与质量检测检验(中)》", 31 January 2004, 中国科学技术出版社 *

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Application publication date: 20151125