CN104231759A - Colorful quick-drying nitrocellulose paint - Google Patents
Colorful quick-drying nitrocellulose paint Download PDFInfo
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- CN104231759A CN104231759A CN201410482343.6A CN201410482343A CN104231759A CN 104231759 A CN104231759 A CN 104231759A CN 201410482343 A CN201410482343 A CN 201410482343A CN 104231759 A CN104231759 A CN 104231759A
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Abstract
Colorful quick-drying nitrocellulose paint comprises raw materials in parts by weight as follows: 100 parts of nitrocellulose, 5-15 parts of ethylene glycol monoethyl ether, 10-20 parts of methoxy methylpentanone, 20-30 parts of rutile type titanium dioxide, 1-10 parts of ethylene glycol monobutyl ether, 5-25 parts of polysiloxane, 80-90 parts of deionized water, 15-25 parts of hydroxyethyl methylacrylate, 10-20 parts of pigment, 15-35 parts of isobutyl acetate, 25-35 parts of methyl isobutyl carbinol, 10-30 parts of methyl amylketone, 5-10 parts of a plasticizer, 35-45 parts of cellulose acetate butyrate, 20-40 parts of naphtha and 20-30 parts of benzophenone; the pH value of a product is 7-9, and surface dry is performed for 30-60 minutes; the adhesive force is 100%, and the paint doesn't bubble and come off after soaked in water for 10-20 days; hard dry is performed for 6-10 hours, and the loss is 0.004-0.006g/cm<2> after the paint is tested by a reciprocating tester for 1,000 times; and the paint can be washed for 300-500 times, can be widely produced and can continuously replace a conventional material.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of quick-drying soluble cotton multicolor finish.
Background technology
Coating, is called paint in Chinese tradition name.So-called coating is coated in protected or decorated body surface; and the continuous film of firm attachment can be formed with coated article; normally based on resin or oily or emulsion; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of ethylene glycol monobutyl ether.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating." paint finishing can bond very well with body material in body surface and form the material of complete and tough and tensile protective membrane, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, after introducing China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to and is applied to body surface and the general name forming the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, ceiling, ground, and the coating of toilet is called building coating.Nitrocotton have dual-use two large Application Areass.Military part mainly concentrates on weapons explosive wastewater industry production, carries out military products management.Civilian part is used for the multiple fields such as coating, zylonite, regenerated fiber, cinefilm ink, makeup.
So-called quick-drying soluble cotton multicolor finish is made up of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, that quick-drying soluble cotton is colorful pattern.Soluble cotton has another name called nitro-cotton, cotton body pyroxylin (e) cement etc., belongs to nitrate esters.For the product of Mierocrystalline cellulose and nitric acid esterification.Nitrocellulose uses purified cotton and concentrated nitric acid and vitriol oil esterification and obtains.Grasp nitration mixture ratio, temperature can obtain the different kind of nitrogen content.And popularizing along with humanity concept, and the formation of novel harmonious society, the quick-drying soluble cotton multicolor finish designing a kind of water tolerance, scrub resistance and excellent in abrasion resistance is very important.
Summary of the invention
The technical problem solved:
The application, for above-mentioned technical problem, provides a kind of quick-drying soluble cotton multicolor finish, solve existing quick-drying soluble cotton multicolor finish water tolerance and scrub resistance is poor, drying slowly, the not technical problem such as rub resistance.
Technical scheme:
A kind of quick-drying soluble cotton multicolor finish, the raw materials by weight portion proportioning of described quick-drying soluble cotton multicolor finish is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 5-15 part; Methoxymethyl pentanone 10-20 part; Rutile titanium dioxide 20-30 part; Ethylene glycol monobutyl ether 1-10 part; Polysiloxane 5-25 part; Deionized water 80-90 part; Poly hydroxy ethyl acrylate 15-25 part; Pigment 10-20 part; Isobutyl acetate 15-35 part; Methyl isobutyl carbinol 25-35 part; Methyl amylketone 10-30 part; Softening agent 5-10 part; Cellulose acetate butyrate 35-45 part; Petroleum naphtha 20-40 part; Benzophenone 20-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described quick-drying soluble cotton multicolor finish is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 10 parts; Methoxymethyl pentanone 15 parts; Rutile titanium dioxide 25 parts; Ethylene glycol monobutyl ether 5 parts; Polysiloxane 15 parts; Deionized water 85 parts; Poly hydroxy ethyl acrylate 20 parts; Pigment 15 parts; Isobutyl acetate 25 parts; Methyl isobutyl carbinol 30 parts; Methyl amylketone 20 parts; 8 parts, softening agent; Cellulose acetate butyrate 40 parts; Petroleum naphtha 30 parts; Benzophenone 25 parts.
As a preferred technical solution of the present invention: described pigment adopts molybdate Exocarpium Citri Rubrum pigment, chromoxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of quick-drying soluble cotton multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product pH value 7-9, surface drying 30-60min; 2, sticking power 100%, non-foaming soak 10-20d in water after, not dry linting; 3,6-10h is done solid work, reciprocating trier 1000 loss 0.004-0.006g/cm2; 4, scrub resistance 300-500 time, the widespread production not division of history into periods can replace current material.
Embodiment
Embodiment 1:
A kind of quick-drying soluble cotton multicolor finish, its raw materials by weight portion proportioning is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 5 parts; Methoxymethyl pentanone 10 parts; Rutile titanium dioxide 20 parts; Ethylene glycol monobutyl ether 1 part; Polysiloxane 5 parts; Deionized water 80 parts; Poly hydroxy ethyl acrylate 15 parts; Molybdate Exocarpium Citri Rubrum pigment 10 parts; Isobutyl acetate 15 parts; Methyl isobutyl carbinol 25 parts; Methyl amylketone 10 parts; Dibutyl phthalate 5 parts; Cellulose acetate butyrate 35 parts; Petroleum naphtha 20 parts; Benzophenone 20 parts.Soluble cotton, methoxymethyl pentanone, rutile titanium dioxide, ethylene glycol monobutyl ether and polysiloxane are added in deionized water, be heated to 40 DEG C and stir 3h, add poly hydroxy ethyl acrylate, isobutyl acetate, methyl isobutyl carbinol, methyl amylketone, petroleum naphtha and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add ethylene glycol monoethyl ether and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product pH value 7, surface drying 60min; Sticking power 100%, non-foaming soak 10d in water after, not dry linting; Do solid work 10h, reciprocating trier 1000 loss 0.006g/cm2; Scrub resistance 300 times.
Embodiment 2:
A kind of quick-drying soluble cotton multicolor finish, its raw materials by weight portion proportioning is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 15 parts; Methoxymethyl pentanone 20 parts; Rutile titanium dioxide 30 parts; Ethylene glycol monobutyl ether 10 parts; Polysiloxane 25 parts; Deionized water 90 parts; Poly hydroxy ethyl acrylate 25 parts; Chromoxide green 20 parts; Isobutyl acetate 35 parts; Methyl isobutyl carbinol 35 parts; Methyl amylketone 30 parts; Dibutyl phthalate 10 parts; Cellulose acetate butyrate 45 parts; Petroleum naphtha 40 parts; Benzophenone 30 parts.
Soluble cotton, methoxymethyl pentanone, rutile titanium dioxide, ethylene glycol monobutyl ether and polysiloxane are added in deionized water, be heated to 40 DEG C and stir 3h, add poly hydroxy ethyl acrylate, isobutyl acetate, methyl isobutyl carbinol, methyl amylketone, petroleum naphtha and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add ethylene glycol monoethyl ether and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product pH value 8, surface drying 45min; Sticking power 100%, non-foaming soak 15d in water after, not dry linting; Do solid work 8h, reciprocating trier 1000 loss 0.005g/cm2; Scrub resistance 400 times.
Embodiment 3:
A kind of quick-drying soluble cotton multicolor finish, its raw materials by weight portion proportioning is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 10 parts; Methoxymethyl pentanone 15 parts; Rutile titanium dioxide 25 parts; Ethylene glycol monobutyl ether 5 parts; Polysiloxane 15 parts; Deionized water 85 parts; Poly hydroxy ethyl acrylate 20 parts; Iron oxide yellow 15 parts; Isobutyl acetate 25 parts; Methyl isobutyl carbinol 30 parts; Methyl amylketone 20 parts; Dibutyl phthalate 8 parts; Cellulose acetate butyrate 40 parts; Petroleum naphtha 30 parts; Benzophenone 25 parts.
Soluble cotton, methoxymethyl pentanone, rutile titanium dioxide, ethylene glycol monobutyl ether and polysiloxane are added in deionized water, be heated to 40 DEG C and stir 3h, add poly hydroxy ethyl acrylate, isobutyl acetate, methyl isobutyl carbinol, methyl amylketone, petroleum naphtha and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add ethylene glycol monoethyl ether and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product pH value 9, surface drying 30min; Sticking power 100%, non-foaming soak 20d in water after, not dry linting; Do solid work 6h, reciprocating trier 1000 loss 0.004g/cm2; Scrub resistance 500 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.
Claims (4)
1. a quick-drying soluble cotton multicolor finish, is characterized in that the raw materials by weight portion proportioning of described quick-drying soluble cotton multicolor finish is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 5-15 part; Methoxymethyl pentanone 10-20 part; Rutile titanium dioxide 20-30 part; Ethylene glycol monobutyl ether 1-10 part; Polysiloxane 5-25 part; Deionized water 80-90 part; Poly hydroxy ethyl acrylate 15-25 part; Pigment 10-20 part; Isobutyl acetate 15-35 part; Methyl isobutyl carbinol 25-35 part; Methyl amylketone 10-30 part; Softening agent 5-10 part; Cellulose acetate butyrate 35-45 part; Petroleum naphtha 20-40 part; Benzophenone 20-30 part.
2. a kind of quick-drying soluble cotton multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described quick-drying soluble cotton multicolor finish is as follows: soluble cotton 100 parts; Ethylene glycol monoethyl ether 10 parts; Methoxymethyl pentanone 15 parts; Rutile titanium dioxide 25 parts; Ethylene glycol monobutyl ether 5 parts; Polysiloxane 15 parts; Deionized water 85 parts; Poly hydroxy ethyl acrylate 20 parts; Pigment 15 parts; Isobutyl acetate 25 parts; Methyl isobutyl carbinol 30 parts; Methyl amylketone 20 parts; 8 parts, softening agent; Cellulose acetate butyrate 40 parts; Petroleum naphtha 30 parts; Benzophenone 25 parts.
3. a kind of quick-drying soluble cotton multicolor finish according to claim 1, is characterized in that: described pigment adopts molybdate Exocarpium Citri Rubrum pigment, chromoxide green or iron oxide yellow.
4. a kind of quick-drying soluble cotton multicolor finish according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
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CN201410482343.6A CN104231759B (en) | 2014-09-19 | 2014-09-19 | A kind of quick-drying nitrocellulose multicolor finish |
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CN201410482343.6A CN104231759B (en) | 2014-09-19 | 2014-09-19 | A kind of quick-drying nitrocellulose multicolor finish |
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CN104231759B CN104231759B (en) | 2016-06-29 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105086545A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Quick-drying multi-color patterned coating |
CN105086647A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Polystyrene multi-color coating |
CN105623494A (en) * | 2016-03-24 | 2016-06-01 | 叶青 | Quick-dry deep red paint for metal |
CN116814148A (en) * | 2023-06-14 | 2023-09-29 | 恩平万达福化工有限公司 | Quick-drying type nitrocellulose coating and preparation method thereof |
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CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
CN103589261A (en) * | 2012-08-16 | 2014-02-19 | 上海韩彩实业有限公司 | Weather-resistant water-based multielement multicolour paint used for building exterior walls |
CN103642344A (en) * | 2013-12-30 | 2014-03-19 | 宁波新安涂料有限公司 | Texture multicolor coating and preparation method thereof |
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2014
- 2014-09-19 CN CN201410482343.6A patent/CN104231759B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103589261A (en) * | 2012-08-16 | 2014-02-19 | 上海韩彩实业有限公司 | Weather-resistant water-based multielement multicolour paint used for building exterior walls |
CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
CN103642344A (en) * | 2013-12-30 | 2014-03-19 | 宁波新安涂料有限公司 | Texture multicolor coating and preparation method thereof |
Non-Patent Citations (1)
Title |
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周学良等: "《精细化工产品手册-涂料》", 31 May 2002, 化学工业出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105086545A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Quick-drying multi-color patterned coating |
CN105086647A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Polystyrene multi-color coating |
CN105623494A (en) * | 2016-03-24 | 2016-06-01 | 叶青 | Quick-dry deep red paint for metal |
CN116814148A (en) * | 2023-06-14 | 2023-09-29 | 恩平万达福化工有限公司 | Quick-drying type nitrocellulose coating and preparation method thereof |
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CN104231759B (en) | 2016-06-29 |
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Effective date of registration: 20201221 Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee after: Yancheng Yanlong water Co., Ltd Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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