CN104194501B - A kind of profit latex multicolor finish - Google Patents

A kind of profit latex multicolor finish Download PDF

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Publication number
CN104194501B
CN104194501B CN201410483132.4A CN201410483132A CN104194501B CN 104194501 B CN104194501 B CN 104194501B CN 201410483132 A CN201410483132 A CN 201410483132A CN 104194501 B CN104194501 B CN 104194501B
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parts
latex
profit
diacrylate
multicolor finish
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CN104194501A (en
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马志明
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Yancheng Yanlong water Co., Ltd
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Suzhou Luotelan New Material Technology Co Ltd
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Abstract

A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 5-15 part;Titanium dioxide 50-60 part;Trimethylolpropane trimethacrylate 1-10 part;Sodium phenate 10-20 part;Acrylic acid-2-ethyl caproite 5-25 part;Deionized water 80-90 part;Epoxy acrylic resin 15-35 part;Pigment 10-20 part;PDDA 25-35 part;Sodium nitrite 10-30 part;Tri (propylene glycol) diacrylate 15-25 part;Plasticizer 6-10 part;Isophorone diisocyanate 30-40 part;Nitric acid tributyl 25-45 part;DBPC 2,6 ditertiary butyl p cresol 20-40 part;Product surface drying 0.5-1.5h, film scrubbing resistance 3000-5000 time is not show-through;Adhesive force 100%, soaks non-foaming after 40-60d, not dry linting in 20 DEG C of water;Doing solid work 8-10h, alkali resistance 30-50d is unchanged;Film is bright in luster, good decorating effect, it is possible to current material is replaced in the widespread production not division of history into periods.

Description

A kind of profit latex multicolor finish
Technical field
The application belongs to paint field, particularly relates to a kind of profit latex multicolor finish.
Background technology
Coating, is called paint in Chinese tradition name.So-called coating is to be coated in protected or decorated body surface; and the continuous film of firm attachment can be formed with coated article, it is common that based on resin or oil or emulsion, add or without pigment, filler; add corresponding additive, with the formulated thick liquid of organic solvent or sodium phenate.China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, and this material can be coated in object surface by different construction technologies, is formed and adheres to firmly, has some strength, continuous print solid film.The film common name film so formed, also known as paint film or coating." paint finishing can bond and be formed the material of complete and tough and tensile protecting film very well in body surface with matrix material, is called coating.Coating and paint are the identicals concept.Paint is people's custom titles used for a long time, after introducing China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: protective effect, decoration function, specific function effect.The general composition of coating: comprise film forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to and is applied to body surface and can form the general name of the material of tough and tensile protecting film, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, ceiling, ground, and the coating of toilet is called building coating.Styrene-butadiene emulsion relative density 0.9~1.05.Combinated styrene content amount is 23%~85%, and mass-produced styrene-butadiene emulsion combinated styrene content amount is 23%~25%, and high-phenylethylene emulsion (SBR-HSL) combinated styrene content amount is then up to 80%~85%.The styrene-butadiene emulsion total solid content that conventional method prepares is 40%~50%, and high solid emulsion total solid content is then 63%~69%.
So-called multicolor finish is made up of inconsistent two phase constituents, and wherein a phase disperse medium is continuous phase, and another phase is dispersion phase, during application, by disposable spray finishing, just can obtain pattern luxurious, attractive in appearance, that profit latex is colorful.Styrene-butadiene emulsion is to be obtained by butadiene and styrene emulsion copolymerization, is called for short SBRL;The thermostability of styrene-butadiene emulsion is not better than natural emulsion, tacky after aging, do not soften, but hardening.And popularizing along with humanity concept, and the composition of novel harmonious society, the profit latex multicolor finish designing a kind of resistance to water, scrub resistance and alkali resistance excellent is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of profit latex multicolor finish, solve existing profit latex multicolor finish resistance to water and scrub resistance is poor, decorative effect is poor, weak to technical problems such as aqueous alkalis.
Technical scheme:
A kind of profit latex multicolor finish, the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 5-15 part;Titanium dioxide 50-60 part;Trimethylolpropane trimethacrylate 1-10 part;Sodium phenate 10-20 part;Acrylic acid-2-ethyl caproite 5-25 part;Deionized water 80-90 part;Epoxy acrylic resin 15-35 part;Pigment 10-20 part;PDDA 25-35 part;Sodium nitrite 10-30 part;Tri (propylene glycol) diacrylate 15-25 part;Plasticizer 6-10 part;Isophorone diisocyanate 30-40 part;Nitric acid tributyl 25-45 part;DBPC 2,6 ditertiary butyl p cresol 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 10 parts;Titanium dioxide 55 parts;Trimethylolpropane trimethacrylate 5 parts;Sodium phenate 15 parts;Acrylic acid-2-ethyl caproite 15 parts;Deionized water 85 parts;Epoxy acrylic resin 25 parts;Pigment 15 parts;PDDA 30 parts;Sodium nitrite 20 parts;Tri (propylene glycol) diacrylate 20 parts;Plasticizer 8 parts;Isophorone diisocyanate 38 parts;Nitric acid tributyl 35 parts;DBPC 2,6 ditertiary butyl p cresol 30 parts.
As a preferred technical solution of the present invention: described pigment adopts iron oxide red, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described plasticizer adopts dibutyl phthalate.
Beneficial effect:
A kind of profit latex multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technical effect that 1, product surface drying 0.5-1.5h, and film scrubbing resistance 3000-5000 time is not show-through;2, adhesive force 100%, soaks non-foaming after 40-60d, not dry linting in 20 DEG C of water;3, doing solid work 8-10h, alkali resistance 30-50d is unchanged;4, film is bright in luster, good decorating effect, it is possible to current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Embodiment 1:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 5 parts;Titanium dioxide 50 parts;Trimethylolpropane trimethacrylate 1 part;Sodium phenate 10 parts;Acrylic acid-2-ethyl caproite 5 parts;Deionized water 80 parts;Epoxy acrylic resin 15 parts;Iron oxide yellow 10 parts;PDDA 25 parts;Sodium nitrite 10 parts;Tri (propylene glycol) diacrylate 15 parts;Dibutyl phthalate 6 parts;Isophorone diisocyanate 30 parts;Nitric acid tributyl 25 parts;DBPC 2,6 ditertiary butyl p cresol 20 parts.
Styrene-butadiene emulsion, titanium dioxide, trimethylolpropane trimethacrylate, sodium phenate and acrylic acid-2-ethyl caproite are added in deionized water, heat to 40 DEG C of stirring 3h, add epoxy acrylic resin, PDDA, sodium nitrite, tri (propylene glycol) diacrylate, nitric acid tributyl and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product surface drying 1.5h, does solid work 10h, adhesive force 100%, and film scrubbing resistance 3000 times is not show-through;Soaking non-foaming after 40d, not dry linting in 20 DEG C of water, alkali resistance 30d is unchanged.
Embodiment 2:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 15 parts;Titanium dioxide 60 parts;Trimethylolpropane trimethacrylate 10 parts;Sodium phenate 20 parts;Acrylic acid-2-ethyl caproite 25 parts;Deionized water 90 parts;Epoxy acrylic resin 35 parts;Iron oxide green 20 parts;PDDA 35 parts;Sodium nitrite 30 parts;Tri (propylene glycol) diacrylate 25 parts;Dibutyl phthalate 10 parts;Isophorone diisocyanate 40 parts;Nitric acid tributyl 45 parts;DBPC 2,6 ditertiary butyl p cresol 40 parts.
Styrene-butadiene emulsion, titanium dioxide, trimethylolpropane trimethacrylate, sodium phenate and acrylic acid-2-ethyl caproite are added in deionized water, heat to 40 DEG C of stirring 3h, add epoxy acrylic resin, PDDA, sodium nitrite, tri (propylene glycol) diacrylate, nitric acid tributyl and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product surface drying 1h, does solid work 9h, adhesive force 100%, and film scrubbing resistance 4000 times is not show-through;Soaking non-foaming after 50d, not dry linting in 20 DEG C of water, alkali resistance 40d is unchanged.
Embodiment 3:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 10 parts;Titanium dioxide 55 parts;Trimethylolpropane trimethacrylate 5 parts;Sodium phenate 15 parts;Acrylic acid-2-ethyl caproite 15 parts;Deionized water 85 parts;Epoxy acrylic resin 25 parts;Iron oxide red 15 parts;PDDA 30 parts;Sodium nitrite 20 parts;Tri (propylene glycol) diacrylate 20 parts;Dibutyl phthalate 8 parts;Isophorone diisocyanate 38 parts;Nitric acid tributyl 35 parts;DBPC 2,6 ditertiary butyl p cresol 30 parts.
Styrene-butadiene emulsion, titanium dioxide, trimethylolpropane trimethacrylate, sodium phenate and acrylic acid-2-ethyl caproite are added in deionized water, heat to 40 DEG C of stirring 3h, add epoxy acrylic resin, PDDA, sodium nitrite, tri (propylene glycol) diacrylate, nitric acid tributyl and dibutyl phthalate, it is warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, after being warming up to 60 DEG C of stirring 10h, both obtain finished product.
Product surface drying 0.5h, does solid work 8h, adhesive force 100%, and film scrubbing resistance 5000 times is not show-through;Soaking non-foaming after 60d, not dry linting in 20 DEG C of water, alkali resistance 50d is unchanged.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to present disclosure is illustrated, rather than restriction, and the therefore any change in the implication suitable with claims of the present invention and scope, all it is believed that be included in the scope of claims.

Claims (1)

1. a profit latex multicolor finish, it is characterised in that the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: styrene-butadiene emulsion 100 parts;Neopentylglycol diacrylate 10 parts;Titanium dioxide 55 parts;Trimethylolpropane trimethacrylate 5 parts;Sodium phenate 15 parts;Acrylic acid-2-ethyl caproite 15 parts;Deionized water 85 parts;Epoxy acrylic resin 25 parts;Pigment 15 parts;PDDA 30 parts;Sodium nitrite 20 parts;Tri (propylene glycol) diacrylate 20 parts;Plasticizer 8 parts;Isophorone diisocyanate 38 parts;Nitric acid tributyl 35 parts;DBPC 2,6 ditertiary butyl p cresol 30 parts;
Described pigment adopts iron oxide red, iron oxide green or iron oxide yellow;
Described plasticizer adopts dibutyl phthalate.
CN201410483132.4A 2014-09-19 2014-09-19 A kind of profit latex multicolor finish Active CN104194501B (en)

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CN104194501B true CN104194501B (en) 2016-06-29

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629553B (en) * 2017-09-07 2021-05-14 广州市优伟家居用品有限公司 Immiscible color liquid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254709A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Two-component emulsion water-in-water multi-color paint and preparation method thereof
CN103589261A (en) * 2012-08-16 2014-02-19 上海韩彩实业有限公司 Weather-resistant water-based multielement multicolour paint used for building exterior walls
CN103642344A (en) * 2013-12-30 2014-03-19 宁波新安涂料有限公司 Texture multicolor coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103589261A (en) * 2012-08-16 2014-02-19 上海韩彩实业有限公司 Weather-resistant water-based multielement multicolour paint used for building exterior walls
CN103254709A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Two-component emulsion water-in-water multi-color paint and preparation method thereof
CN103642344A (en) * 2013-12-30 2014-03-19 宁波新安涂料有限公司 Texture multicolor coating and preparation method thereof

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Effective date of registration: 20201224

Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province

Patentee after: Yancheng Yanlong water Co., Ltd

Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province

Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd.