CN104194501A - Colorful oil-water emulsion coating - Google Patents
Colorful oil-water emulsion coating Download PDFInfo
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- CN104194501A CN104194501A CN201410483132.4A CN201410483132A CN104194501A CN 104194501 A CN104194501 A CN 104194501A CN 201410483132 A CN201410483132 A CN 201410483132A CN 104194501 A CN104194501 A CN 104194501A
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Abstract
The invention relates to a colorful oil-water emulsion coating which comprises the following raw materials in parts by weight: 100 parts of styrene-butadiene emulsion, 5-15 parts of neopentyl glycol diacrylate, 50-60 parts of titanium dioxide, 1-10 parts of trimethylolpropane triacrylate, 10-20 parts of sodium phenate, 5-25 parts of crylic acid-2-ethylhexyl acrylate, 80-90 parts of deionized water, 15-35 parts of epoxy acrylate resin, 10-20 parts of pigment, 25-35 parts of diallyl phthalate, 10-30 parts of sodium nitrite, 15-25 parts of tripropylene glycol diacrylate, 6-10 parts of plasticizer, 30-40 parts of isophorone diisocyanate, 25-45 parts of nitric acid tributyl ester and 20-40 parts of 2,6- butylated hydroxytoluene. The colorful oil-water emulsion coating has the benefits that the surface during time is 0.5-1.5 hours, the time of scrubbing resistance to the coating is 3000-5000, and the bottom is not exposed; the adhesive force is 100 percent, and no foaming and no powder falling-off occur after the colorful oil-water emulsion coating is socked in water for 40-60 days; the hard drying time is 8-10 hours, the alkali resistance time is 30-50 days, and no change occurs; the coating is bright in color, has good decorative effect and can be widely produced and constantly substitute the existing materials.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of profit latex multicolor finish.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally taking resin oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of sodium phenylate.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, and ceiling, ground, the coating of toilet is called building coating.Styrene-butadiene emulsion relative density 0.9～1.05.Combined styrene amount is 23%～85%, and mass-produced styrene-butadiene emulsion combined styrene amount is 23%～25%, and high-phenylethylene emulsion (SBR-HSL) combined styrene amount is up to 80%～85%.The styrene-butadiene emulsion total solid content that general method makes is 40%～50%, and high solid emulsion total solid content is 63%～69%.
So-called multicolor finish is made up of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, when application, by disposable spray finishing, just can obtain pattern luxurious, attractive in appearance, that profit latex is colorful.Styrene-butadiene emulsion is to be obtained by divinyl and styrene emulsion copolymerization, is called for short SBRL; The thermotolerance of styrene-butadiene emulsion is better than natural emulsion, is not clamminess after aging, softening, but hardening.And universal along with humanity concept, and the formation of novel harmonious society, the profit latex multicolor finish that designs a kind of water tolerance, scrub resistance and alkali resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of profit latex multicolor finish, solves existing profit latex multicolor finish water tolerance and scrub resistance is poor, decorative effect is poor, the technical problem such as alkaline-resisting water not.
Technical scheme:
A kind of profit latex multicolor finish, the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: 100 parts of styrene-butadiene emulsion; Neopentylglycol diacrylate 5-15 part; Titanium dioxide 50-60 part; Viscoat 295 1-10 part; Sodium phenylate 10-20 part; Ethyl acrylate 5-25 part; Deionized water 80-90 part; Epoxy acrylic resin 15-35 part; Pigment 10-20 part; PDDA 25-35 part; Sodium Nitrite 10-30 part; Tri (propylene glycol) diacrylate 15-25 part; Softening agent 6-10 part; Isophorone diisocyanate 30-40 part; Nitric acid tri-n-butyl 25-45 part; 2,6 ditertiary butyl p cresol 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: 100 parts of styrene-butadiene emulsion; 10 parts of neopentylglycol diacrylates; 55 parts of titanium dioxides; 5 parts of Viscoat 295s; 15 parts of sodium phenylates; 15 parts of ethyl acrylates; 85 parts of deionized waters; 25 parts of epoxy acrylic resins; 15 parts of pigment; 30 parts of PDDA; 20 parts of Sodium Nitrites; 20 parts of tri (propylene glycol) diacrylates; 8 parts, softening agent; 38 parts of isophorone diisocyanates; 35 parts of nitric acid tri-n-butyls; 30 parts of 2,6 ditertiary butyl p cresol.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of profit latex multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product surface drying 0.5-1.5h, and film scrubbing resistance 3000-5000 time is not show-through; 2, sticking power 100%, non-foaming soak 40-60d in 20 DEG C of water after, dry linting not; 3, do solid work 8-10h, alkali resistance 30-50d is unchanged; 4, bright in luster, the good decorating effect of film, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of styrene-butadiene emulsion; 5 parts of neopentylglycol diacrylates; 50 parts of titanium dioxides; 1 part of Viscoat 295; 10 parts of sodium phenylates; 5 parts of ethyl acrylates; 80 parts of deionized waters; 15 parts of epoxy acrylic resins; 10 parts of iron oxide yellow; 25 parts of PDDA; 10 parts of Sodium Nitrites; 15 parts of tri (propylene glycol) diacrylates; 6 parts of dibutyl phthalates; 30 parts of isophorone diisocyanates; 25 parts of nitric acid tri-n-butyls; 20 parts of 2,6 ditertiary butyl p cresol.
Styrene-butadiene emulsion, titanium dioxide, Viscoat 295, sodium phenylate and ethyl acrylate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy acrylic resin, PDDA, Sodium Nitrite, tri (propylene glycol) diacrylate, nitric acid tri-n-butyl and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Product surface drying 1.5h, does solid work 10h, sticking power 100%, and film scrubbing resistance 3000 times is not show-through; Non-foaming soak 40d in 20 DEG C of water after, dry linting not, alkali resistance 30d is unchanged.
Embodiment 2:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of styrene-butadiene emulsion; 15 parts of neopentylglycol diacrylates; 60 parts of titanium dioxides; 10 parts of Viscoat 295s; 20 parts of sodium phenylates; 25 parts of ethyl acrylates; 90 parts of deionized waters; 35 parts of epoxy acrylic resins; 20 parts of iron oxide greens; 35 parts of PDDA; 30 parts of Sodium Nitrites; 25 parts of tri (propylene glycol) diacrylates; 10 parts of dibutyl phthalates; 40 parts of isophorone diisocyanates; 45 parts of nitric acid tri-n-butyls; 40 parts of 2,6 ditertiary butyl p cresol.
Styrene-butadiene emulsion, titanium dioxide, Viscoat 295, sodium phenylate and ethyl acrylate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy acrylic resin, PDDA, Sodium Nitrite, tri (propylene glycol) diacrylate, nitric acid tri-n-butyl and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Product surface drying 1h, does solid work 9h, sticking power 100%, and film scrubbing resistance 4000 times is not show-through; Non-foaming soak 50d in 20 DEG C of water after, dry linting not, alkali resistance 40d is unchanged.
Embodiment 3:
A kind of profit latex multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of styrene-butadiene emulsion; 10 parts of neopentylglycol diacrylates; 55 parts of titanium dioxides; 5 parts of Viscoat 295s; 15 parts of sodium phenylates; 15 parts of ethyl acrylates; 85 parts of deionized waters; 25 parts of epoxy acrylic resins; 15 parts of red iron oxides; 30 parts of PDDA; 20 parts of Sodium Nitrites; 20 parts of tri (propylene glycol) diacrylates; 8 parts of dibutyl phthalates; 38 parts of isophorone diisocyanates; 35 parts of nitric acid tri-n-butyls; 30 parts of 2,6 ditertiary butyl p cresol.
Styrene-butadiene emulsion, titanium dioxide, Viscoat 295, sodium phenylate and ethyl acrylate are added in deionized water, be heated to 40 DEG C and stir 3h, add epoxy acrylic resin, PDDA, Sodium Nitrite, tri (propylene glycol) diacrylate, nitric acid tri-n-butyl and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add neopentylglycol diacrylate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Product surface drying 0.5h, does solid work 8h, sticking power 100%, and film scrubbing resistance 5000 times is not show-through; Non-foaming soak 60d in 20 DEG C of water after, dry linting not, alkali resistance 50d is unchanged.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.
Claims (4)
1. a profit latex multicolor finish, is characterized in that the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: 100 parts of styrene-butadiene emulsion; Neopentylglycol diacrylate 5-15 part; Titanium dioxide 50-60 part; Viscoat 295 1-10 part; Sodium phenylate 10-20 part; Ethyl acrylate 5-25 part; Deionized water 80-90 part; Epoxy acrylic resin 15-35 part; Pigment 10-20 part; PDDA 25-35 part; Sodium Nitrite 10-30 part; Tri (propylene glycol) diacrylate 15-25 part; Softening agent 6-10 part; Isophorone diisocyanate 30-40 part; Nitric acid tri-n-butyl 25-45 part; 2,6 ditertiary butyl p cresol 20-40 part.
2. a kind of profit latex multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described profit latex multicolor finish is as follows: 100 parts of styrene-butadiene emulsion; 10 parts of neopentylglycol diacrylates; 55 parts of titanium dioxides; 5 parts of Viscoat 295s; 15 parts of sodium phenylates; 15 parts of ethyl acrylates; 85 parts of deionized waters; 25 parts of epoxy acrylic resins; 15 parts of pigment; 30 parts of PDDA; 20 parts of Sodium Nitrites; 20 parts of tri (propylene glycol) diacrylates; 8 parts, softening agent; 38 parts of isophorone diisocyanates; 35 parts of nitric acid tri-n-butyls; 30 parts of 2,6 ditertiary butyl p cresol.
3. a kind of profit latex multicolor finish according to claim 1, is characterized in that: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
4. a kind of profit latex multicolor finish according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410483132.4A CN104194501B (en) | 2014-09-19 | 2014-09-19 | A kind of profit latex multicolor finish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410483132.4A CN104194501B (en) | 2014-09-19 | 2014-09-19 | A kind of profit latex multicolor finish |
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| Publication Number | Publication Date |
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| CN104194501A true CN104194501A (en) | 2014-12-10 |
| CN104194501B CN104194501B (en) | 2016-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410483132.4A Active CN104194501B (en) | 2014-09-19 | 2014-09-19 | A kind of profit latex multicolor finish |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629553A (en) * | 2017-09-07 | 2018-01-26 | 广州市优伟家居用品有限公司 | A kind of immiscible colored liquid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
| CN103589261A (en) * | 2012-08-16 | 2014-02-19 | 上海韩彩实业有限公司 | Weather-resistant water-based multielement multicolour paint used for building exterior walls |
| CN103642344A (en) * | 2013-12-30 | 2014-03-19 | 宁波新安涂料有限公司 | Texture multicolor coating and preparation method thereof |
-
2014
- 2014-09-19 CN CN201410483132.4A patent/CN104194501B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589261A (en) * | 2012-08-16 | 2014-02-19 | 上海韩彩实业有限公司 | Weather-resistant water-based multielement multicolour paint used for building exterior walls |
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
| CN103642344A (en) * | 2013-12-30 | 2014-03-19 | 宁波新安涂料有限公司 | Texture multicolor coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周学良等: "《精细化工产品手册-涂料》", 31 May 2002, article "03135 油水乳胶多彩涂料", pages: 68-69 - 600-601 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629553A (en) * | 2017-09-07 | 2018-01-26 | 广州市优伟家居用品有限公司 | A kind of immiscible colored liquid |
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| Publication number | Publication date |
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| CN104194501B (en) | 2016-06-29 |
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Effective date of registration: 20201224 Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee after: Yancheng Yanlong water Co., Ltd Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |