CN104119748A - High-temperature resistant water-based multicolor paint - Google Patents

High-temperature resistant water-based multicolor paint Download PDF

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Publication number
CN104119748A
CN104119748A CN201410382137.8A CN201410382137A CN104119748A CN 104119748 A CN104119748 A CN 104119748A CN 201410382137 A CN201410382137 A CN 201410382137A CN 104119748 A CN104119748 A CN 104119748A
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parts
resistant water
fire resistant
based multicolor
multicolor finish
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CN201410382137.8A
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CN104119748B (en
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费金华
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Hebei Chenyang Industry and Trade Group Co Ltd
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

The invention discloses a high-temperature resistant water-based multicolor paint which comprises the following raw materials in parts by weight: 100 parts of polyvinyl acetate, 15-25 parts of pentaerythritol, 20-30 parts of oxalic acid, 10-20 parts of micalex, 25-35 parts of butyl cellosolve, 15-35 parts of ethyl acetate, 80-90 parts of deionized water, 10-30 parts of butyl acetate, 10-20 parts of pigment, 10-40 parts of cellulose nitrate, 25-45 parts of sodium hexametaphosphate, 30-40 parts of dibutyltin dilaurate, 6-10 parts of plasticizer, 35-45 parts of triethoxymethylsilane, 40-50 parts of ethylene glycol and 20-40 parts of octamethyl cyclotetrasiloxane. The product is non-toxic and has no pungent smell, and the film is resistant to 2,000-4,000 times of scrubbing; after the product is soaked for 10-30 days in water at 30 DEG C, the phenomena of blistering and falling are avoided; 0.006-0.008g/cm<2> of the film is lost by 2,000 times of testing of a reciprocating tester; and after 20-40 days of storage at 70 DEG C, the film has bright color and good decorative effect and can be widely produced to constantly replace the existing material.

Description

A kind of fire resistant water-based multicolor finish
Technical field
The application belongs to paint field, relates in particular to a kind of fire resistant water-based multicolor finish.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally take resin or oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of butyl glycol ether.China's coating circle more authoritative < < coating process > > mono-book is definition like this: " coating is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name forming is like this filmed, and claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can forms the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be for inner wall of building, and exterior wall, ceiling, ground, the coating of toilet is called building coating.Polyvinyl acetate (polyvinyl acetate), has another name called polyvinyl acetate (PVA).It is the polymkeric substance of vinyl-acetic ester (vinyl acetate).English abbreviation is PVAc.Be called for short PVAc, the polymkeric substance that vinyl acetate generates through polymerization.Be amorphous polymer, appearance transparent, be dissolved in benzene, acetone and trichloromethane equal solvent.
So-called fire resistant water-based multicolor finish is comprised of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, fire resistant water-based colorful pattern.Colourless viscous fluid or faint yellow transparent glass shape particle, odorless, tasteless, flexible and plasticity.Softening temperature is about 38 ℃.Can not dissolve each other with fat and water, can dissolve each other with ethanol, acetic acid, acetone, ethyl acetate.And universal along with humanity concept, and the formation of novel harmonious society, the fire resistant water-based multicolor finish that designs a kind of water tolerance, scrub resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of fire resistant water-based multicolor finish, solves the technical problems such as existing fire resistant water-based multicolor finish water tolerance and poor, poisonous, the irritant smell of scrub resistance, non-refractory.
Technical scheme:
A fire resistant water-based multicolor finish, the raw materials by weight portion proportioning of described fire resistant water-based multicolor finish is as follows: 100 parts of polyvinyl acetate (PVA); Tetramethylolmethane 15-25 part; Oxalic acid 20-30 part; Muscovitum 10-20 part; Butyl glycol ether 25-35 part; Ethyl acetate 15-35 part; Deionized water 80-90 part; Butylacetate 10-30 part; Pigment 10-20 part; Nitrocellulose 10-40 part; Sodium hexametaphosphate 99 25-45 part; Dibutyl tin laurate 30-40 part; Softening agent 6-10 part; Triethoxy methyl silicane 35-45 part; Ethylene glycol 40-50 part; Octamethylcyclotetrasiloxane 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described fire resistant water-based multicolor finish is as follows: 100 parts of polyvinyl acetate (PVA); 20 parts of tetramethylolmethanes; 25 parts of oxalic acids; 15 parts of Muscovitumes; 30 parts of butyl glycol ethers; 25 parts of ethyl acetate; 85 parts of deionized waters; 20 parts of butylacetates; 15 parts of pigment; 25 parts, nitrocellulose; 35 parts of Sodium hexametaphosphate 99s; 35 parts of dibutyl tin laurates; 8 parts, softening agent; 40 parts of triethoxy methyl silicanes; 45 parts of ethylene glycol; 30 parts of octamethylcyclotetrasiloxanes.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of fire resistant water-based multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is nontoxic, have no irritating odor, and the scrubbing resistance of filming 2000-4000 time; 2, non-foaming soak 10-30d in 30 ℃ of water after, dry linting not; 3,2000 the loss 0.006-0.008g/cm of reciprocating trier that film 2; 4, store 20-40d for 70 ℃, bright in luster, the good decorating effect of filming, can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
A fire resistant water-based multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl acetate (PVA); 15 parts of tetramethylolmethanes; 20 parts of oxalic acids; 10 parts of Muscovitumes; 25 parts of butyl glycol ethers; 15 parts of ethyl acetate; 80 parts of deionized waters; 10 parts of butylacetates; 10 parts of iron oxide greens; 10 parts, nitrocellulose; 25 parts of Sodium hexametaphosphate 99s; 30 parts of dibutyl tin laurates; 6 parts of dibutyl phthalates; 35 parts of triethoxy methyl silicanes; 40 parts of ethylene glycol; 20 parts of octamethylcyclotetrasiloxanes.
Polyvinyl acetate (PVA), oxalic acid, Muscovitum, butyl glycol ether and ethyl acetate are added in deionized water, be heated to 40 ℃ and stir 3h, add butylacetate, nitrocellulose, Sodium hexametaphosphate 99, dibutyl tin laurate, ethylene glycol and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add tetramethylolmethane and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
The scrubbing resistance of filming 2000 times; Non-foaming soak 10d in 30 ℃ of water after, dry linting not; 2000 loss 0.008g/cm of reciprocating trier film 2; Store 20d for 70 ℃.
Embodiment 2:
A fire resistant water-based multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl acetate (PVA); 25 parts of tetramethylolmethanes; 30 parts of oxalic acids; 20 parts of Muscovitumes; 35 parts of butyl glycol ethers; 35 parts of ethyl acetate; 90 parts of deionized waters; 30 parts of butylacetates; 20 parts of iron oxide yellow; 40 parts, nitrocellulose; 45 parts of Sodium hexametaphosphate 99s; 40 parts of dibutyl tin laurates; 10 parts of dibutyl phthalates; 45 parts of triethoxy methyl silicanes; 50 parts of ethylene glycol; 40 parts of octamethylcyclotetrasiloxanes.
Polyvinyl acetate (PVA), oxalic acid, Muscovitum, butyl glycol ether and ethyl acetate are added in deionized water, be heated to 40 ℃ and stir 3h, add butylacetate, nitrocellulose, Sodium hexametaphosphate 99, dibutyl tin laurate, ethylene glycol and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add tetramethylolmethane and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
The scrubbing resistance of filming 3000 times; Non-foaming soak 20d in 30 ℃ of water after, dry linting not; 2000 loss 0.007g/cm of reciprocating trier film 2; Store 30d for 70 ℃.
Embodiment 3:
A fire resistant water-based multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl acetate (PVA); 20 parts of tetramethylolmethanes; 25 parts of oxalic acids; 15 parts of Muscovitumes; 30 parts of butyl glycol ethers; 25 parts of ethyl acetate; 85 parts of deionized waters; 20 parts of butylacetates; 15 parts of red iron oxides; 25 parts, nitrocellulose; 35 parts of Sodium hexametaphosphate 99s; 35 parts of dibutyl tin laurates; 8 parts of dibutyl phthalates; 40 parts of triethoxy methyl silicanes; 45 parts of ethylene glycol; 30 parts of octamethylcyclotetrasiloxanes.
Polyvinyl acetate (PVA), oxalic acid, Muscovitum, butyl glycol ether and ethyl acetate are added in deionized water, be heated to 40 ℃ and stir 3h, add butylacetate, nitrocellulose, Sodium hexametaphosphate 99, dibutyl tin laurate, ethylene glycol and dibutyl phthalate, be warming up to 50 ℃ with ball mill ball milling 10min, add tetramethylolmethane and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
The scrubbing resistance of filming 4000 times; Non-foaming soak 30d in 30 ℃ of water after, dry linting not; 2000 loss 0.006g/cm of reciprocating trier film 2; Store 40d for 70 ℃.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.

Claims (4)

1. a fire resistant water-based multicolor finish, is characterized in that the raw materials by weight portion proportioning of described fire resistant water-based multicolor finish is as follows: 100 parts of polyvinyl acetate (PVA); Tetramethylolmethane 15-25 part; Oxalic acid 20-30 part; Muscovitum 10-20 part; Butyl glycol ether 25-35 part; Ethyl acetate 15-35 part; Deionized water 80-90 part; Butylacetate 10-30 part; Pigment 10-20 part; Nitrocellulose 10-40 part; Sodium hexametaphosphate 99 25-45 part; Dibutyl tin laurate 30-40 part; Softening agent 6-10 part; Triethoxy methyl silicane 35-45 part; Ethylene glycol 40-50 part; Octamethylcyclotetrasiloxane 20-40 part.
2. a kind of fire resistant water-based multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described fire resistant water-based multicolor finish is as follows: 100 parts of polyvinyl acetate (PVA); 20 parts of tetramethylolmethanes; 25 parts of oxalic acids; 15 parts of Muscovitumes; 30 parts of butyl glycol ethers; 25 parts of ethyl acetate; 85 parts of deionized waters; 20 parts of butylacetates; 15 parts of pigment; 25 parts, nitrocellulose; 35 parts of Sodium hexametaphosphate 99s; 35 parts of dibutyl tin laurates; 8 parts, softening agent; 40 parts of triethoxy methyl silicanes; 45 parts of ethylene glycol; 30 parts of octamethylcyclotetrasiloxanes.
3. a kind of fire resistant water-based multicolor finish according to claim 1, is characterized in that: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
4. a kind of fire resistant water-based multicolor finish according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410382137.8A 2014-08-06 2014-08-06 A kind of fire resistant water-based multicolor finish Active CN104119748B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086545A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Quick-drying multi-color patterned coating
CN106085040A (en) * 2016-06-12 2016-11-09 安徽快来防水防腐有限公司 A kind of high-performance double-component polyvinyl acetate polymer cement-base waterproof coating used for building exterior wall and preparation method thereof
CN108659592A (en) * 2018-04-28 2018-10-16 杨芳 A kind of environment-friendly materials and preparation method thereof
US12036513B2 (en) 2019-10-24 2024-07-16 Mitsubishi Heavy Industries, Ltd. Desalination performance restoration agent for cellulose acetate membrane and desalination performance restoration method for cellulose acetate membrane

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096528A (en) * 1993-06-16 1994-12-21 北京新型建筑材料总厂 Hydrophilic colour thick paint
CN1108675A (en) * 1994-03-18 1995-09-20 湘潭市中南化工研究所 Multi-function building coating
CN102690567A (en) * 2012-06-01 2012-09-26 安徽省金盾涂料有限责任公司 Aqueous multicolor paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096528A (en) * 1993-06-16 1994-12-21 北京新型建筑材料总厂 Hydrophilic colour thick paint
CN1108675A (en) * 1994-03-18 1995-09-20 湘潭市中南化工研究所 Multi-function building coating
CN102690567A (en) * 2012-06-01 2012-09-26 安徽省金盾涂料有限责任公司 Aqueous multicolor paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周学良等: "《精细化工产品手册(涂料)》", 31 May 2002, article "《精细化工产品手册(涂料)》", pages: 62-63 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086545A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Quick-drying multi-color patterned coating
CN106085040A (en) * 2016-06-12 2016-11-09 安徽快来防水防腐有限公司 A kind of high-performance double-component polyvinyl acetate polymer cement-base waterproof coating used for building exterior wall and preparation method thereof
CN108659592A (en) * 2018-04-28 2018-10-16 杨芳 A kind of environment-friendly materials and preparation method thereof
US12036513B2 (en) 2019-10-24 2024-07-16 Mitsubishi Heavy Industries, Ltd. Desalination performance restoration agent for cellulose acetate membrane and desalination performance restoration method for cellulose acetate membrane

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Inventor after: Liu Shanjiang

Inventor after: Liu Zhanchuan

Inventor after: Mei Shaofeng

Inventor after: Hu Zhongyuan

Inventor before: Fei Jinhua

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Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Wu highway

Patentee before: Wujiang Huacheng Composite Technology Co., Ltd.

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