CN108659592A - A kind of environment-friendly materials and preparation method thereof - Google Patents
A kind of environment-friendly materials and preparation method thereof Download PDFInfo
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- CN108659592A CN108659592A CN201810398346.XA CN201810398346A CN108659592A CN 108659592 A CN108659592 A CN 108659592A CN 201810398346 A CN201810398346 A CN 201810398346A CN 108659592 A CN108659592 A CN 108659592A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to environment-friendly materials technical fields, more particularly to a kind of environment-friendly materials and preparation method thereof, mainly by the raw materials such as 10 20 parts of 20 30 parts of polyvinyl acetate, 5 10 parts of vinyl formate, 15 20 parts of water-soluble epoxy resin, 10 15 parts of n-butyl acetate, 57 parts of anti-settling agent and pigment through ultrasonic disperse, allotment and etc. be made；Pigment mainly takes through boiling, finally by raw materials such as 15 20 parts of 10 15 parts of beet, 10 20 parts of crab apple bark, 10 20 parts of Cortex Phellodendri, 10 20 parts of Flos Hibisci Mutabilis, 10 15 parts of St. john's wort, 10 12 parts of rose, 10 20 parts of Su Make fruits, 20 30 parts of madder and safflowers, filtered, clarified, homogeneous and ultrafiltration and etc. be made.The coating film performance and mobile performance are excellent, bright in colour, and anti-sedimentation function improves, and service life extends, asepsis environment-protecting, and preparation method is simple, and production cost is low.
Description
Technical field
The present invention relates to environment-friendly materials technical fields, and in particular to a kind of environment-friendly materials and preparation method thereof.
Background technology
Currently, interior wall for building is generally used paint spraying, paint finishing can be fine with basis material in body surface
Complete and tough and tensile protective film is bonded and is formed, building coating has the function of that decoration functions, defencive function and livability are improved.Respectively
Proportion shared by kind function is not quite similar because using purpose different.Building coating color is varied, very gorgeous, but big
The color of part coatings is not only polluted the environment, and cost is higher made of addition chemical pigment.And about utilization
Colored paint is made in pigment made of plant extraction liquid, is not used widely but.
Invention content
The goal of the invention of the present invention is：In view of the above problems, a kind of environment-friendly materials and preparation method thereof are provided,
The film performance and mobile performance of coating are excellent, bright in colour, and anti-sedimentation function improves, and service life extends, nontoxic, ring
It protects, and preparation method is simple, production cost is low.
To achieve the goals above, the technical solution adopted by the present invention is as follows：
A kind of environment-friendly materials are mainly made of following raw material：20-30 parts of polyvinyl acetate, vinyl formate
5-10 parts, epoxy resin 15-20 parts water-soluble, 10-15 parts of n-butyl acetate, 5-7 parts of anti-settling agent, 10-20 parts of pigment, other auxiliary agents
1-2 parts and 30-60 parts of deionized water；
Wherein, the pigment is mainly made of following raw material：10-15 parts of beet, 10-20 parts of crab apple bark,
10-20 parts of Cortex Phellodendri, 10-20 parts of Flos Hibisci Mutabilis, 10-15 parts of St. john's wort, 10-12 parts of rose, 10-20 parts of Su Make fruits,
10-20 parts of 20-30 parts of madder, 15-20 parts of safflower, 10-30 parts of red yeast rice and pimiento.
Preferably, it is mainly made of following raw material：25 parts of polyvinyl acetate, 7 parts of vinyl formate, water-soluble ring
45 parts of 17 parts of oxygen resin, 13 parts of n-butyl acetate, 6 parts of anti-settling agent, 15 parts of pigment, 1.5 parts of other auxiliary agents and deionized water；
Wherein, the pigment is mainly made of following raw material：13 parts of beet, 15 parts of crab apple bark, cork tree tree
15 parts of skin, 15 parts of Flos Hibisci Mutabilis, 13 parts of St. john's wort, 11 parts of rose, 15 parts of Su Make fruits, 25 parts of madder, 17 parts of safflower, red yeast rice
20 parts and 15 parts of pimiento.
Preferably, the anti-settling agent be by organobentonite, castor oil, polyvinyl alcohol wax and polyamide wax one kind or
A variety of compositions.
Preferably, other described auxiliary agents are mixed by curing agent, thickener, antifoaming agent and coalescents.
Preferably, the preparation method of the pigment is：
S1：It crushes, is boiled in water to 1-2h, filtering obtains mixed liquor after Cortex Phellodendri and crab apple bark are cleaned
A, it is spare；
S2：Beet, Flos Hibisci Mutabilis, St. john's wort, rose, Su Make fruits, madder, safflower, red yeast rice and pimiento are cleaned
After rub, impregnate 1-2 day in water, filtering, vegetation lime juice is added is stirred evenly in filter residue and is placed at 30-40 DEG C ultrasound finally
1-2h is taken, mixed liquid B is obtained after filtering, it is spare；
S3：Mixed liquor A and mixed liquid B are uniformly mixed, acid-base modifier is added and is adjusted to pH value 6-7, after clarified, homogeneous
The pigment is made in ultrafiltration.
The preparation method of environment-friendly materials as described above, specifically includes following steps：
(1) water-soluble epoxy resin, n-butyl acetate and deionized water are mixed, the ultrasonic disperse 30- at 40-60 DEG C
40min obtains the first mixed liquor, spare；
(2) polyvinyl acetate, vinyl formate, anti-settling agent and other auxiliary agents are added to above-mentioned first after mixing
In mixed liquor, 40-60min is stirred, the second mixed liquor is obtained, it is spare；
(3) pigment is added in above-mentioned second mixed liquor, stirs 20-40min, the environment-friendly materials are made.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1, the present invention uses organic solvent vinyl formate and n-butyl acetate, effectively increases the dissolubility of coating, makes
Reaction is come into full contact between major raw material, improves the mobile performance and film performance of coating, while vinyl formate also has one
Fixed sterilization and disinsection effect, effectively extends the service life of coating.
2, present invention addition anti-settling agent reduces coating precipitation, improves stability and paint viscosity.
3, the present invention, not only so that coating is bright in colour, also has certain antibacterial desinsection by using vegetalitas pigment
Effect, effectively improves the antiseptic property of coating, prolongs the service life.
4, preparation method for coating of the invention is simple, easy to produce and nontoxic, environmental protection, and production cost is low.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is only
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
The every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention
The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the Listed Items of pass.
Embodiment 1
A kind of environment-friendly materials are mainly made of following raw material：20 parts of polyvinyl acetate, 5 parts of vinyl formate,
30 parts of 15 parts of water-soluble epoxy resin, 10 parts of n-butyl acetate, 5 parts of anti-settling agent, 10 parts of pigment, 1 part of other auxiliary agents and deionized water；
Wherein, anti-settling agent is made of organobentonite and castor oil；
Other auxiliary agents are mixed by curing agent, thickener, antifoaming agent and coalescents；
Pigment is mainly made of following raw material：10 parts of beet, 10 parts of crab apple bark, 10 parts of Cortex Phellodendri, cottonrose hibiscus
Rong spend 10 parts, 10 parts of St. john's wort, 10 parts of rose, 10 parts of Su Make fruits, 20 parts of madder, 15 parts of safflower, 10 parts of red yeast rice and red
10 parts of capsicum；Preparation method is：
S1：It crushing, boils in water to 1h after Cortex Phellodendri and crab apple bark are cleaned, filtering obtains mixed liquor A,
It is spare；
S2：Beet, Flos Hibisci Mutabilis, St. john's wort, rose, Su Make fruits, madder, safflower, red yeast rice and pimiento are cleaned
After rub, impregnate 1 in water, filtering, vegetation lime juice is added is stirred evenly in filter residue and be placed at 30 DEG C ultrasound soldier and take 1h,
Mixed liquid B is obtained after filtering, it is spare；
S3：Mixed liquor A and mixed liquid B are uniformly mixed, acid-base modifier is added and is adjusted to pH value 6, surpasses after clarified, homogeneous
The pigment is made in filter.
The expectation of said ratio is prepared into environment-friendly materials using following methods, specifically includes following steps：
(1) water-soluble epoxy resin, n-butyl acetate and deionized water are mixed, ultrasonic disperse 30min, obtains at 40 DEG C
First mixed liquor, it is spare；
(2) polyvinyl acetate, vinyl formate, anti-settling agent and other auxiliary agents are added to above-mentioned first after mixing
In mixed liquor, 40min is stirred, the second mixed liquor is obtained, it is spare；
(3) pigment is added in above-mentioned second mixed liquor, stirs 20min, the environment-friendly materials are made.
Embodiment 2
A kind of environment-friendly materials are mainly made of following raw material：25 parts of polyvinyl acetate, 7 parts of vinyl formate,
17 parts of water-soluble epoxy resin, 13 parts of n-butyl acetate, 6 parts of anti-settling agent, 15 parts of pigment, 1.5 parts of other auxiliary agents and deionized water 45
Part；
Wherein, anti-settling agent is made of polyvinyl alcohol wax and polyamide wax；
Other auxiliary agents are mixed by curing agent, thickener, antifoaming agent and coalescents；
Pigment is mainly made of following raw material：13 parts of beet, 15 parts of crab apple bark, 15 parts of Cortex Phellodendri, cottonrose hibiscus
Rong spend 15 parts, 13 parts of St. john's wort, 11 parts of rose, 15 parts of Su Make fruits, 25 parts of madder, 17 parts of safflower, 20 parts of red yeast rice and red
15 parts of capsicum；Preparation method is：
S1：It crushes, is boiled in water to 1.5h, filtering obtains mixed liquor after Cortex Phellodendri and crab apple bark are cleaned
A, it is spare；
S2：Beet, Flos Hibisci Mutabilis, St. john's wort, rose, Su Make fruits, madder, safflower, red yeast rice and pimiento are cleaned
After rub, impregnate 1.5 in water, filtering, vegetation lime juice is added is stirred evenly in filter residue and be placed at 35 DEG C ultrasound soldier and take
1.5h obtains mixed liquid B after filtering, spare；
S3：Mixed liquor A and mixed liquid B are uniformly mixed, acid-base modifier is added and is adjusted to pH value 6.5, after clarified, homogeneous
The pigment is made in ultrafiltration.
The expectation of said ratio is prepared into environment-friendly materials using following methods, specifically includes following steps：
(1) water-soluble epoxy resin, n-butyl acetate and deionized water are mixed, ultrasonic disperse 35min, obtains at 50 DEG C
First mixed liquor, it is spare；
(2) polyvinyl acetate, vinyl formate, anti-settling agent and other auxiliary agents are added to above-mentioned first after mixing
In mixed liquor, 50min is stirred, the second mixed liquor is obtained, it is spare；
(3) pigment is added in above-mentioned second mixed liquor, stirs 30min, the environment-friendly materials are made.
Embodiment 3
A kind of environment-friendly materials are mainly made of following raw material：30 parts of polyvinyl acetate, vinyl formate 10
Part, 20 parts of water-soluble epoxy resin, 15 parts of n-butyl acetate, 7 parts of anti-settling agent, 20 parts of pigment, 2 parts of other auxiliary agents and deionized water 60
Part；
Wherein, anti-settling agent is made of organobentonite, castor oil, polyvinyl alcohol wax and polyamide wax；
Other auxiliary agents are mixed by curing agent, thickener, antifoaming agent and coalescents；
Pigment is mainly made of following raw material：15 parts of beet, 20 parts of crab apple bark, 20 parts of Cortex Phellodendri, cottonrose hibiscus
Rong spend 20 parts, 15 parts of St. john's wort, 12 parts of rose, 20 parts of Su Make fruits, 30 parts of madder, 20 parts of safflower, 30 parts of red yeast rice and red
20 parts of capsicum；Preparation method is：
S1：It crushing, boils in water to 2h after Cortex Phellodendri and crab apple bark are cleaned, filtering obtains mixed liquor A,
It is spare；
S2：Beet, Flos Hibisci Mutabilis, St. john's wort, rose, Su Make fruits, madder, safflower, red yeast rice and pimiento are cleaned
After rub, impregnate 2 in water, filtering, vegetation lime juice is added is stirred evenly in filter residue and be placed at 40 DEG C ultrasound soldier and take 2h,
Mixed liquid B is obtained after filtering, it is spare；
S3：Mixed liquor A and mixed liquid B are uniformly mixed, acid-base modifier is added and is adjusted to pH value 7, surpasses after clarified, homogeneous
The pigment is made in filter.
The expectation of said ratio is prepared into environment-friendly materials using following methods, specifically includes following steps：
(1) water-soluble epoxy resin, n-butyl acetate and deionized water are mixed, ultrasonic disperse 40min, obtains at 60 DEG C
First mixed liquor, it is spare；
(2) polyvinyl acetate, vinyl formate, anti-settling agent and other auxiliary agents are added to above-mentioned first after mixing
In mixed liquor, 60min is stirred, the second mixed liquor is obtained, it is spare；
(3) pigment is added in above-mentioned second mixed liquor, stirs 40min, the environment-friendly materials are made.
Applicant carried out contrast experiments once, and carry out correlated performance test, and test method is as follows：By comparative example 1-5
And coating made from embodiment 1-3 is contained with bucket, seals In Shade standing half a year, the precipitation feelings of coating are detected after half a year
Condition, color and luster and deterioration, and precipitation reduction percentage when service life extension percentage is calculated, the results are shown in Table 1.
Comparative example 1：Decorate common coating.
Comparative example 2：The raw material of decorative paint is polyvinyl acetate, vinyl formate, water-soluble epoxy resin, the positive fourth of acetic acid
Ester, other auxiliary agents and deionized water are other identical as the embodiment of the present invention 1.
Comparative example 3：The raw material of decorative paint be polyvinyl acetate, vinyl formate, water-soluble epoxy resin, acetic acid just
Butyl ester, anti-settling agent, other auxiliary agents and deionized water are other identical as the embodiment of the present invention 1.
Comparative example 4：The raw material of decorative paint be polyvinyl acetate, vinyl formate, water-soluble epoxy resin, acetic acid just
The raw material of butyl ester, anti-settling agent, pigment, other auxiliary agents and deionized water, pigment is beet, crab apple bark, Cortex Phellodendri, lotus
Flower and rose, it is other identical as the embodiment of the present invention 1.
Comparative example 5：The raw material of decorative paint be polyvinyl acetate, vinyl formate, water-soluble epoxy resin, acetic acid just
Butyl ester, anti-settling agent, pigment, other auxiliary agents and deionized water, the raw material of pigment be St. john's wort, Su Make fruits, madder, safflower,
Red yeast rice and pimiento, it is other identical as the embodiment of the present invention 1.
1 coating test result of table
Such as table 1 the results show that the coating obtained by 1-3 of the embodiment of the present invention is bright in colour, glossy, anti-sedimentation function carries
Height, service life extend, and precipitation reduces percentage, and when service life extends about 2.3 times and 28 that percentage is comparative example 1 respectively
Times, reduce cost.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the claims of the present invention.
Claims (6)
1. a kind of environment-friendly materials, which is characterized in that be mainly made of following raw material：20-30 parts of polyvinyl acetate, first
5-10 parts of vinyl acetate, epoxy resin 15-20 parts water-soluble, 10-15 parts of n-butyl acetate, 5-7 parts of anti-settling agent, 10-20 parts of pigment,
30-60 parts of 1-2 parts of other auxiliary agents and deionized water；
Wherein, the pigment is mainly made of following raw material：10-15 parts of beet, 10-20 parts of crab apple bark, cork tree
10-20 parts of bark, 10-20 parts of Flos Hibisci Mutabilis, 10-15 parts of St. john's wort, 10-12 parts of rose, 10-20 parts of Su Make fruits, madder
10-20 parts of 20-30 parts, 15-20 parts of safflower, 10-30 parts of red yeast rice and pimiento.
2. environment-friendly materials according to claim 1, which is characterized in that be mainly made of following raw material：Poly- acetic acid
25 parts of vinyl acetate, 7 parts of vinyl formate, 17 parts of water-soluble epoxy resin, 13 parts of n-butyl acetate, 6 parts of anti-settling agent, 15 parts of pigment,
45 parts of 1.5 parts of other auxiliary agents and deionized water；
Wherein, the pigment is mainly made of following raw material：13 parts of beet, 15 parts of crab apple bark, Cortex Phellodendri 15
Part, 15 parts of Flos Hibisci Mutabilis, 13 parts of St. john's wort, 11 parts of rose, 15 parts of Su Make fruits, 25 parts of madder, 17 parts of safflower, 20 parts of red yeast rice
And 15 parts of pimiento.
3. environment-friendly materials according to claim 1 or 2, it is characterised in that：The anti-settling agent is by organobentonite, castor-oil plant
One or more compositions in oil, polyvinyl alcohol wax and polyamide wax.
4. environment-friendly materials according to claim 1 or 2, it is characterised in that：Other described auxiliary agents are by curing agent, thickening
Agent, antifoaming agent and coalescents mix.
5. environment-friendly materials according to claim 1 or 2, which is characterized in that the preparation method of the pigment is：
S1：It crushes, is boiled in water to 1-2h, filtering obtains mixed liquor A, standby after Cortex Phellodendri and crab apple bark are cleaned
With；
S2：It is twisted after beet, Flos Hibisci Mutabilis, St. john's wort, rose, Su Make fruits, madder, safflower, red yeast rice and pimiento are cleaned
It is broken, it impregnates 1-2 day in water, filtering, vegetation lime juice is added is stirred evenly in filter residue and be placed at 30-40 DEG C ultrasound and finally take 1-
2h obtains mixed liquid B after filtering, spare；
S3：Mixed liquor A and mixed liquid B are uniformly mixed, acid-base modifier is added and is adjusted to pH value 6-7, surpasses after clarified, homogeneous
The pigment is made in filter.
6. the preparation method of environment-friendly materials according to any one of claims 1-5, which is characterized in that specifically include following
Step：
(1) water-soluble epoxy resin, n-butyl acetate and deionized water are mixed, ultrasonic disperse 30-40min, obtains at 40-60 DEG C
It is spare to the first mixed liquor；
(2) polyvinyl acetate, vinyl formate, anti-settling agent and other auxiliary agents are added to above-mentioned first mixing after mixing
In liquid, 40-60min is stirred, the second mixed liquor is obtained, it is spare；
(3) pigment is added in above-mentioned second mixed liquor, stirs 20-40min, the environment-friendly materials are made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810398346.XA CN108659592A (en) | 2018-04-28 | 2018-04-28 | A kind of environment-friendly materials and preparation method thereof |
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| CN201810398346.XA CN108659592A (en) | 2018-04-28 | 2018-04-28 | A kind of environment-friendly materials and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109397971A (en) * | 2018-11-19 | 2019-03-01 | 北京工业大学 | It is a kind of to utilize artistic pictures and production method made of old and useless article |
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| WO2013091685A1 (en) * | 2011-12-21 | 2013-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Highly structured composite material and process for the manufacture of protective coatings for corroding substrates |
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2018
- 2018-04-28 CN CN201810398346.XA patent/CN108659592A/en active Pending
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| WO2013091685A1 (en) * | 2011-12-21 | 2013-06-27 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Highly structured composite material and process for the manufacture of protective coatings for corroding substrates |
| CN104119748A (en) * | 2014-08-06 | 2014-10-29 | 吴江华诚复合材料科技有限公司 | High-temperature resistant water-based multicolor paint |
| CN106634282A (en) * | 2016-12-28 | 2017-05-10 | 郑州圣莱特空心微珠新材料有限公司 | Heat preservation energy-saving coating applied to interior walls and preparation method thereof |
| CN107760110A (en) * | 2017-10-26 | 2018-03-06 | 蔡正泉 | Plant type environmental protection interior wall paint |
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| Title |
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| 罗伯特•格里斯贝克: "《甜甜化学》", 31 January 2014, 中国少年儿童出版社 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109397971A (en) * | 2018-11-19 | 2019-03-01 | 北京工业大学 | It is a kind of to utilize artistic pictures and production method made of old and useless article |
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