CN108727957A - A kind of anti-corrosive properties environment-friendly materials and preparation method thereof - Google Patents
A kind of anti-corrosive properties environment-friendly materials and preparation method thereof Download PDFInfo
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- CN108727957A CN108727957A CN201810398361.4A CN201810398361A CN108727957A CN 108727957 A CN108727957 A CN 108727957A CN 201810398361 A CN201810398361 A CN 201810398361A CN 108727957 A CN108727957 A CN 108727957A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to environment-friendly materials technical fields, more particularly to a kind of anti-corrosive properties environment-friendly materials and preparation method thereof, mainly it is made of formulated are stirred of raw materials such as 20-30 parts of adhesive for polyurethane, 10-20 parts of polyvinyl alcohol, 5-10 parts of sulfate-reducing conditions, 3-7 parts of preservative, 1-3 parts of thickener, 1-2 parts of antifoaming agent；Preservative is mainly taken, filtered through ultrasonic wave soldier by raw materials such as 8-10 parts of 20-30 parts of ginkgo biloba p.e, 10-20 parts of cinnamomum cassia extract, 15-20 parts of Flos Caryophylli extract, 10-15 parts of Rosmarinus officinalis extract, 10-30 parts of Red Yeast Rice P.E, 5-10 parts of pimiento extract and anise extracts, clarified, decolourized and ultrafiltration is made.The coating film performance is good, has significant antiseptic property, effectively prolongs the service life, nontoxic, environmental protection, and preparation method is simple, and production cost is low.
Description
Technical field
The present invention relates to environment-friendly materials technical fields, and in particular to a kind of anti-corrosive properties environment-friendly materials and preparation method thereof.
Background technology
Currently, interior wall for building is generally used paint spraying, paint finishing can be fine with basis material in body surface
Complete and tough and tensile protective film is bonded and is formed, building coating has the function of that decoration functions, defencive function and livability are improved.Respectively
Proportion shared by kind function is not quite similar because using purpose different.But building coating is susceptible to extraneous bacterium and corrodes, hair
Mildew change, turn sour and other issues, production man adds the chemical substance of anti-corrosion function to improve the anti-corrosive properties of coating, not only at
This raising, and pollute the environment.And about anti-corrosive properties coating is made using preservative made of plant extraction liquid, do not have but
It is used widely.
Invention content
The goal of the invention of the present invention is：In view of the above problems, a kind of anti-corrosive properties environment-friendly materials and its system are provided
Preparation Method, coating film performance is good, has significant antiseptic property, effectively prolongs the service life, nontoxic, environmental protection, and it is prepared
Method is simple, and production cost is low.
To achieve the goals above, the technical solution adopted by the present invention is as follows：
A kind of anti-corrosive properties environment-friendly materials, are mainly made of following raw material：20-30 parts of adhesive for polyurethane, poly- second
10-20 parts of enol, 5-10 parts of sulfate-reducing conditions, 3-7 parts of preservative, 1-3 parts of thickener, 1-2 parts of antifoaming agent and water 30-80
Part；
Wherein, the preservative is mainly made of following raw material：20-30 parts of ginkgo biloba p.e, Chinese cassia tree extraction
10-20 parts of object, 15-20 parts of Flos Caryophylli extract, 10-15 parts of Rosmarinus officinalis extract, 10-30 parts of Red Yeast Rice P.E, pimiento extract
5-10 parts and 8-10 parts of anise extract.
Preferably, it is mainly made of following raw material：25 parts of adhesive for polyurethane, 15 parts of polyvinyl alcohol, sulfate
55 parts of 7 parts of lignin, 5 parts of preservative, 2 parts of thickener, 1.5 parts of antifoaming agent and water；
Wherein, the preservative is mainly made of following raw material：25 parts of ginkgo biloba p.e, cinnamomum cassia extract 15
Part, 17 parts of Flos Caryophylli extract, 13 parts of Rosmarinus officinalis extract, 20 parts of Red Yeast Rice P.E, 7 parts of pimiento extract and anise extract 9
Part.
Preferably, the antifoaming agent is made of one or more in glycerin polyether, polyoxyethylene ether and polypropylene glycol.
Preferably, the thickener is made of one or more in modified alta-mud, concave convex rod, methylcellulose.
Preferably, the preparation method of the preservative is：By ginkgo leaf, Chinese cassia tree, cloves, rosemary, red yeast rice, pimiento and fennel
After celery cleans and cleans up, organic solvent ultrasonic wave soldier is carried out after rubbing respectively and is taken, and by high speed centrifugation, clarification,
Ginkgo biloba p.e, cinnamomum cassia extract, Flos Caryophylli extract, Rosmarinus officinalis extract, red yeast rice extraction is made in decoloration and ultrafiltration respectively
Object, pimiento extract and anise extract, and after mixing, obtain the preservative.
The preparation method of anti-corrosive properties environment-friendly materials as described above, specifically includes following steps：
(1) adhesive for polyurethane, polyvinyl alcohol, thickener and water are mixed evenly, low whipping speed 3000-
Under 5000 revs/min, 30-60min is stirred, sulfate-reducing conditions are added, continue to be uniformly mixed, obtains mixed dispersion liquid A, it is standby
With；
(2) preservative and antifoaming agent are added in mixed dispersion liquid A, continue to stir 20- under the mixing speed of step (1)
The anti-corrosive properties environment-friendly materials are made in 30min.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
The coating film performance of the present invention is good, is scraped with applying, and the preservative used is the plant extraction liquid extracted from plant,
It is environment-protecting and non-poisonous, it is at low cost, there is significant sterilizing insecticide oxidation resistance, bactericidal range is wide, and inoxidizability is strong, effectively reduces
Corrosion of the bacterium to coating makes coating maintain the color and luster and performance of script for a long time, effectively improves the antiseptic property of coating, extend
Service life, and preparation method is simple, easy to produce and nontoxic, environmental protection, production cost is low.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is only
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
The every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention
The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the Listed Items of pass.
Embodiment 1
A kind of anti-corrosive properties environment-friendly materials, are mainly made of following raw material：20 parts of adhesive for polyurethane, polyvinyl alcohol
30 parts of 10 parts, 5 parts of sulfate-reducing conditions, 3 parts of preservative, 1 part of thickener, 1 part of antifoaming agent and water；
Wherein, antifoaming agent is by glycerin polyether；Thickener is by modified alta-mud；
Preservative is mainly made of following raw material：20 parts of ginkgo biloba p.e, 10 parts of cinnamomum cassia extract, cloves carry
Take 8 parts of 15 parts of object, 10 parts of Rosmarinus officinalis extract, 10 parts of Red Yeast Rice P.E, 5 parts of pimiento extract and anise extract；It is prepared
Method is：After ginkgo leaf, Chinese cassia tree, cloves, rosemary, red yeast rice, pimiento and anise are cleaned and cleaned up, rub respectively laggard
Row organic solvent ultrasonic wave soldier takes, and by high speed centrifugation, clarification, decoloration and ultrafiltration, be made respectively ginkgo biloba p.e,
Cinnamomum cassia extract, Flos Caryophylli extract, Rosmarinus officinalis extract, Red Yeast Rice P.E, pimiento extract and anise extract, and mix equal
After even, the preservative is obtained.
The expectation of said ratio is prepared into anti-corrosive properties environment-friendly materials using following methods, specifically includes following steps：
(1) adhesive for polyurethane, polyvinyl alcohol, thickener and water are mixed evenly, low whipping speed be 3000 turns/
Under point, 30min is stirred, sulfate-reducing conditions are added, continue to be uniformly mixed, obtains mixed dispersion liquid A, it is spare；
(2) preservative and antifoaming agent are added in mixed dispersion liquid A, continue to stir under the mixing speed of step (1)
The anti-corrosive properties environment-friendly materials are made in 20min.
Embodiment 2
A kind of anti-corrosive properties environment-friendly materials, are mainly made of following raw material：25 parts of adhesive for polyurethane, polyvinyl alcohol
55 parts of 15 parts, 7 parts of sulfate-reducing conditions, 5 parts of preservative, 2 parts of thickener, 1.5 parts of antifoaming agent and water；
Wherein, antifoaming agent is made of polyoxyethylene ether and polypropylene glycol；Thickener is by modified alta-mud and concave convex rod
Composition；
Preservative is mainly made of following raw material：25 parts of ginkgo biloba p.e, 15 parts of cinnamomum cassia extract, cloves carry
Take 9 parts of 17 parts of object, 13 parts of Rosmarinus officinalis extract, 20 parts of Red Yeast Rice P.E, 7 parts of pimiento extract and anise extract；It is prepared
Method is：After ginkgo leaf, Chinese cassia tree, cloves, rosemary, red yeast rice, pimiento and anise are cleaned and cleaned up, rub respectively laggard
Row organic solvent ultrasonic wave soldier takes, and by high speed centrifugation, clarification, decoloration and ultrafiltration, be made respectively ginkgo biloba p.e,
Cinnamomum cassia extract, Flos Caryophylli extract, Rosmarinus officinalis extract, Red Yeast Rice P.E, pimiento extract and anise extract, and mix equal
After even, the preservative is obtained.
The expectation of said ratio is prepared into anti-corrosive properties environment-friendly materials using following methods, specifically includes following steps：
(1) adhesive for polyurethane, polyvinyl alcohol, thickener and water are mixed evenly, low whipping speed be 4000 turns/
Under point, 45min is stirred, sulfate-reducing conditions are added, continue to be uniformly mixed, obtains mixed dispersion liquid A, it is spare；
(2) preservative and antifoaming agent are added in mixed dispersion liquid A, continue to stir under the mixing speed of step (1)
The anti-corrosive properties environment-friendly materials are made in 25min.
Embodiment 3
A kind of anti-corrosive properties environment-friendly materials, are mainly made of following raw material：30 parts of adhesive for polyurethane, polyvinyl alcohol
80 parts of 20 parts, 10 parts of sulfate-reducing conditions, 7 parts of preservative, 3 parts of thickener, 2 parts of antifoaming agent and water；
Wherein, antifoaming agent is made of glycerin polyether, polyoxyethylene ether and polypropylene glycol；
Thickener is made of modified alta-mud, concave convex rod and methylcellulose；
Preservative is mainly made of following raw material：30 parts of ginkgo biloba p.e, 20 parts of cinnamomum cassia extract, cloves carry
Take 10 parts of 20 parts of object, 15 parts of Rosmarinus officinalis extract, 30 parts of Red Yeast Rice P.E, 10 parts of pimiento extract and anise extract；It is made
Preparation Method is：After ginkgo leaf, Chinese cassia tree, cloves, rosemary, red yeast rice, pimiento and anise are cleaned and cleaned up, after rubbing respectively
It carries out organic solvent ultrasonic wave soldier to take, and by high speed centrifugation, clarification, decoloration and ultrafiltration, ginkgo leaf extraction is made respectively
Object, cinnamomum cassia extract, Flos Caryophylli extract, Rosmarinus officinalis extract, Red Yeast Rice P.E, pimiento extract and anise extract, and mix
After closing uniformly, the preservative is obtained.
The expectation of said ratio is prepared into anti-corrosive properties environment-friendly materials using following methods, specifically includes following steps：
(1) adhesive for polyurethane, polyvinyl alcohol, thickener and water are mixed evenly, low whipping speed be 5000 turns/
Under point, 60min is stirred, sulfate-reducing conditions are added, continue to be uniformly mixed, obtains mixed dispersion liquid A, it is spare；
(2) preservative and antifoaming agent are added in mixed dispersion liquid A, continue to stir under the mixing speed of step (1)
The anti-corrosive properties environment-friendly materials are made in 30min.
Applicant carried out contrast experiments once, and carry out correlated performance test, and test method is as follows：By comparative example 1-4
And coating made from embodiment 1-3 is contained with bucket, is sealed In Shade standing and is detected the rotten corrosion condition of coating after 2 years, and
The corrosion percentage that goes bad is calculated, the results are shown in Table 1.
Comparative example 1：Decorate common coating.
Comparative example 2：The raw material of decorative paint be adhesive for polyurethane, polyvinyl alcohol, thickener, antifoaming agent and water, other
It is identical as the embodiment of the present invention 1.
Comparative example 3：The raw material of decorative paint be antifoaming agent adhesive for polyurethane, polyvinyl alcohol, thickener, preservative and
The raw material of water, preservative is cinnamomum cassia extract, Flos Caryophylli extract and Rosmarinus officinalis extract, other and 1 phase of the embodiment of the present invention
Together.
Comparative example 4：The raw material of decorative paint be antifoaming agent adhesive for polyurethane, polyvinyl alcohol, thickener, preservative and
The raw material of water, preservative is ginkgo biloba p.e, Red Yeast Rice P.E, pimiento extract and anise extract, other and this hair
Bright embodiment 1 is identical.
1 coating test result of table
Such as table 1, the results show that the coating obtained by 1-3 of the embodiment of the present invention goes bad, corrosion, performance remain good, make
Extended with the service life, when service life extends about 3.2 times and 27 that percentage is comparative example 1 respectively to rotten corrosion percentage
Times.Illustrate that the paint stability of the present invention is good, there is significant antiseptic property, effectively prolong the service life, nontoxic, environmental protection makes
With at low cost.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the claims of the present invention.
Claims (6)
1. a kind of anti-corrosive properties environment-friendly materials, which is characterized in that be mainly made of following raw material：Adhesive for polyurethane 20-
30 parts, 10-20 parts of polyvinyl alcohol, 5-10 parts of sulfate-reducing conditions, 3-7 parts of preservative, 1-3 parts of thickener, 1-2 parts of antifoaming agent and
30-80 parts of water；
Wherein, the preservative is mainly made of following raw material：20-30 parts of ginkgo biloba p.e, cinnamomum cassia extract 10-
20 parts, 15-20 parts of Flos Caryophylli extract, 10-15 parts of Rosmarinus officinalis extract, 10-30 parts of Red Yeast Rice P.E, 5-10 parts of pimiento extract
And 8-10 parts of anise extract.
2. anti-corrosive properties environment-friendly materials according to claim 1, which is characterized in that be mainly made of following raw material：
25 parts of adhesive for polyurethane, 15 parts of polyvinyl alcohol, 7 parts of sulfate-reducing conditions, 5 parts of preservative, 2 parts of thickener, 1.5 parts of antifoaming agent
And 55 parts of water；
Wherein, the preservative is mainly made of following raw material：25 parts of ginkgo biloba p.e, 15 parts of cinnamomum cassia extract,
9 parts of 17 parts of Flos Caryophylli extract, 13 parts of Rosmarinus officinalis extract, 20 parts of Red Yeast Rice P.E, 7 parts of pimiento extract and anise extract.
3. anti-corrosive properties environment-friendly materials according to claim 1 or 2, it is characterised in that：The antifoaming agent be by glycerin polyether,
One or more compositions in polyoxyethylene ether and polypropylene glycol.
4. anti-corrosive properties environment-friendly materials according to claim 1 or 2, it is characterised in that：The thickener is by bentone
One or more compositions in soil, concave convex rod, methylcellulose.
5. anti-corrosive properties environment-friendly materials according to claim 1 or 2, which is characterized in that the preparation method of the preservative is：
After ginkgo leaf, Chinese cassia tree, cloves, rosemary, red yeast rice, pimiento and anise are cleaned and cleaned up, carried out after rubbing respectively organic
Solvent supersonic wave soldier takes, and by high speed centrifugation, clarification, decoloration and ultrafiltration, ginkgo biloba p.e is made respectively, Chinese cassia tree carries
Object, Flos Caryophylli extract, Rosmarinus officinalis extract, Red Yeast Rice P.E, pimiento extract and anise extract are taken, and after mixing,
Obtain the preservative.
6. the preparation method of anti-corrosive properties environment-friendly materials according to any one of claims 1-5, which is characterized in that specific packet
Include following steps：
(1) adhesive for polyurethane, polyvinyl alcohol, thickener and water are mixed evenly, low whipping speed 3000-5000
Under rev/min, 30-60min is stirred, sulfate-reducing conditions are added, continue to be uniformly mixed, obtains mixed dispersion liquid A, it is spare；
(2) preservative and antifoaming agent are added in mixed dispersion liquid A, continue to stir 20- under the mixing speed of step (1)
The anti-corrosive properties environment-friendly materials are made in 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810398361.4A CN108727957A (en) | 2018-04-28 | 2018-04-28 | A kind of anti-corrosive properties environment-friendly materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810398361.4A CN108727957A (en) | 2018-04-28 | 2018-04-28 | A kind of anti-corrosive properties environment-friendly materials and preparation method thereof |
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| CN108727957A true CN108727957A (en) | 2018-11-02 |
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| CN201810398361.4A Pending CN108727957A (en) | 2018-04-28 | 2018-04-28 | A kind of anti-corrosive properties environment-friendly materials and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112137929A (en) * | 2020-10-10 | 2020-12-29 | 昆山市双友日用化工有限公司 | Novel cosmetic antiseptic composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112137929A (en) * | 2020-10-10 | 2020-12-29 | 昆山市双友日用化工有限公司 | Novel cosmetic antiseptic composition |
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