CN104151951A - Abrasion-resistant multicolored coating material - Google Patents

Abrasion-resistant multicolored coating material Download PDF

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Publication number
CN104151951A
CN104151951A CN201410382127.4A CN201410382127A CN104151951A CN 104151951 A CN104151951 A CN 104151951A CN 201410382127 A CN201410382127 A CN 201410382127A CN 104151951 A CN104151951 A CN 104151951A
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parts
resisting
wear
abrasion
resistant
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CN201410382127.4A
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CN104151951B (en
Inventor
费金华
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Changsha Good Landscape Paint Co.,Ltd.
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

The invention provides an abrasion-resistant multicolored coating material. The abrasion-resistant multicolored coating material comprises the following raw materials in parts by weight: 100 parts of chloroethylene,15-25 parts of nitro cotton, 20-30 parts of vinyl acetate, 5-15 parts of cinene, 10-20 parts of acetic acid n-butyl ester, 5-25 parts of acrylic acid modified alkyd resin,80-90 parts of deionized water, 15-35 parts of zinc stearate, 10-20 parts of pigment, 25-35 parts of ethyl acetate, 30-40 parts of titanium dioxide, 35-45 parts of silicon dioxide, 4-10 parts of plasticizers, 25-45 parts of isobutyl acetate,10-30 parts of nitrocellulose and 20-40 parts of methyl isobutyl ketone. The dispersity of the abrasion-resistant multicolored coating material is good; the abrasion-resistant multicolored coating material does not foam and pluck after soaking for 20-30d in water; a coating film can endure 2500-3500 times of scrubbing; the wastage of a reciprocating-type testing machine is 0.004-0.006g/ cm<2> for 2000 times; the adhesive power is 100 %; the decorative effect is good, therefore, the abrasion-resistant multicolored coating material can be extensively produced and can replace conventional materials continuously.

Description

A kind of wear-resisting multicolor finish
Technical field
The application belongs to paint field, relates in particular to a kind of wear-resisting multicolor finish.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally take resin or oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of n-butyl acetate.China's coating circle more authoritative < < coating process > > mono-book is definition like this: " coating is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name forming is like this filmed, and claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can forms the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be for inner wall of building, and exterior wall, ceiling, ground, the coating of toilet is called building coating.It is a kind of important monomer that is applied to macromolecule chemical industry that vinylchlorid has another name called vinyl chloride, can be made by ethene or acetylene.For colourless, easy liquefied gas, boiling point-13.9 ℃, 142 ℃ of critical temperatures, emergent pressure 5.22MPa.Vinylchlorid is toxic substance, and liver cancer sucks with to contact vinylchlorid relevant with long-term.It and air form explosive mixture, and limits of explosion 4%~22% (volume) is depressed more explosive adding, and must be noted that the airtight and nitrogen envelope of container, and should add a small amount of stopper during storing.
So-called wear-resisting multicolor finish is comprised of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, wear-resisting colorful pattern.Two or more different colours, size and the different band look particulate of sneaking into liquid or gel in basic coating, a kind of compound suspended dispersed body coating of composition.Multicolor finish is the new decorative material for building of beautifying hotel, movie theatre, entertainment place, shop, office building, house etc.And universal along with humanity concept, and the formation of novel harmonious society, the wear-resisting multicolor finish that designs a kind of water tolerance, scrub resistance and excellent in abrasion resistance is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of wear-resisting multicolor finish, solves existing wear-resisting multicolor finish water tolerance and scrub resistance is poor, bad dispersibility, the technical problem such as rub resistance not.
Technical scheme:
A wear-resisting multicolor finish, the raw materials by weight portion proportioning of described wear-resisting multicolor finish is as follows: 100 parts, vinylchlorid; Nitro-cotton 15-25 part; Vinyl acetate between to for plastic 20-30 part; Kautschin 5-15 part; N-butyl acetate 10-20 part; Acrylic acid modified alkyd resin 5-25 part; Deionized water 80-90 part; Zinic stearas 15-35 part; Pigment 10-20 part; Vinyl acetic monomer 25-35 part; Titanium dioxide 30-40 part; Silicon-dioxide 35-45 part; Softening agent 4-10 part; Isobutyl acetate 25-45 part; Nitrocellulose 10-30 part; Mibk 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described wear-resisting multicolor finish is as follows: 100 parts, vinylchlorid; 20 parts of nitro-cottons; 25 parts of vinyl acetate between to for plastics; 10 parts of kautschins; 15 parts of n-butyl acetates; 15 parts of acrylic acid modified alkyd resins; 85 parts of deionized waters; 25 parts of Zinic stearass; 15 parts of pigment; 30 parts of vinyl acetic monomers; 35 parts of titanium dioxide; 40 parts of silicon-dioxide; 7 parts, softening agent; 35 parts of isobutyl acetates; 20 parts, nitrocellulose; 30 parts of mibks.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
As a preferred technical solution of the present invention: described softening agent adopts DBP.
Beneficial effect:
A kind of wear-resisting multicolor finish of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, good product dispersibility, in water, soak non-foaming after 20-30d, dry linting not; 2, film scrubbing resistance 2500-3500 time; 3,2000 loss 0.004-0.006g/cm of reciprocating trier 2; 4, sticking power 100%, and good decorating effect can the not division of history into periods of widespread production be replaced current material.
Embodiment
Embodiment 1:
A wear-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts, vinylchlorid; 15 parts of nitro-cottons; 20 parts of vinyl acetate between to for plastics; 5 parts of kautschins; 10 parts of n-butyl acetates; 5 parts of acrylic acid modified alkyd resins; 80 parts of deionized waters; 15 parts of Zinic stearass; 10 parts of iron oxide yellow; 25 parts of vinyl acetic monomers; 30 parts of titanium dioxide; 35 parts of silicon-dioxide; DBP4 part; 25 parts of isobutyl acetates; 10 parts, nitrocellulose; 20 parts of mibks.
Vinylchlorid, vinyl acetate between to for plastic, kautschin, n-butyl acetate and acrylic acid modified alkyd resin are added in deionized water, be heated to 40 ℃ and stir 3h, add Zinic stearas, vinyl acetic monomer, titanium dioxide, silicon-dioxide, nitrocellulose and DBP, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
In water, soak non-foaming after 20d, dry linting not; The scrubbing resistance of filming 2500 times; 2000 loss 0.006g/cm of reciprocating trier 2; Sticking power 100%.
Embodiment 2:
A wear-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts, vinylchlorid; 25 parts of nitro-cottons; 30 parts of vinyl acetate between to for plastics; 15 parts of kautschins; 20 parts of n-butyl acetates; 25 parts of acrylic acid modified alkyd resins; 90 parts of deionized waters; 35 parts of Zinic stearass; 20 parts of red iron oxides; 35 parts of vinyl acetic monomers; 40 parts of titanium dioxide; 45 parts of silicon-dioxide; DBP10 part; 45 parts of isobutyl acetates; 30 parts, nitrocellulose; 30 parts of mibks.
Vinylchlorid, vinyl acetate between to for plastic, kautschin, n-butyl acetate and acrylic acid modified alkyd resin are added in deionized water, be heated to 40 ℃ and stir 3h, add Zinic stearas, vinyl acetic monomer, titanium dioxide, silicon-dioxide, nitrocellulose and DBP, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
In water, soak non-foaming after 25d, dry linting not; The scrubbing resistance of filming 3000 times; 2000 loss 0.005g/cm of reciprocating trier 2; Sticking power 100%.
Embodiment 3:
A wear-resisting multicolor finish, its raw materials by weight portion proportioning is as follows: 100 parts, vinylchlorid; 20 parts of nitro-cottons; 25 parts of vinyl acetate between to for plastics; 10 parts of kautschins; 15 parts of n-butyl acetates; 15 parts of acrylic acid modified alkyd resins; 85 parts of deionized waters; 25 parts of Zinic stearass; 15 parts of iron oxide greens; 30 parts of vinyl acetic monomers; 35 parts of titanium dioxide; 40 parts of silicon-dioxide; DBP7 part; 35 parts of isobutyl acetates; 20 parts, nitrocellulose; 30 parts of mibks.
Vinylchlorid, vinyl acetate between to for plastic, kautschin, n-butyl acetate and acrylic acid modified alkyd resin are added in deionized water, be heated to 40 ℃ and stir 3h, add Zinic stearas, vinyl acetic monomer, titanium dioxide, silicon-dioxide, nitrocellulose and DBP, be warming up to 50 ℃ with ball mill ball milling 10min, add nitro-cotton and surplus stock, be warming up to 60 ℃ and both stir after 10h to obtain finished product.
In water, soak non-foaming after 30d, dry linting not; The scrubbing resistance of filming 3500 times; 2000 loss 0.004g/cm of reciprocating trier 2; Sticking power 100%.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.

Claims (4)

1. a wear-resisting multicolor finish, is characterized in that the raw materials by weight portion proportioning of described wear-resisting multicolor finish is as follows: 100 parts, vinylchlorid; Nitro-cotton 15-25 part; Vinyl acetate between to for plastic 20-30 part; Kautschin 5-15 part; N-butyl acetate 10-20 part; Acrylic acid modified alkyd resin 5-25 part; Deionized water 80-90 part; Zinic stearas 15-35 part; Pigment 10-20 part; Vinyl acetic monomer 25-35 part; Titanium dioxide 30-40 part; Silicon-dioxide 35-45 part; Softening agent 4-10 part; Isobutyl acetate 25-45 part; Nitrocellulose 10-30 part; Mibk 20-40 part.
2. a kind of wear-resisting multicolor finish according to claim 1, is characterized in that the raw materials by weight portion proportioning of described wear-resisting multicolor finish is as follows: 100 parts, vinylchlorid; 20 parts of nitro-cottons; 25 parts of vinyl acetate between to for plastics; 10 parts of kautschins; 15 parts of n-butyl acetates; 15 parts of acrylic acid modified alkyd resins; 85 parts of deionized waters; 25 parts of Zinic stearass; 15 parts of pigment; 30 parts of vinyl acetic monomers; 35 parts of titanium dioxide; 40 parts of silicon-dioxide; 7 parts, softening agent; 35 parts of isobutyl acetates; 20 parts, nitrocellulose; 30 parts of mibks.
3. a kind of wear-resisting multicolor finish according to claim 1, is characterized in that: described pigment adopts red iron oxide, iron oxide green or iron oxide yellow.
4. a kind of wear-resisting multicolor finish according to claim 1, is characterized in that: described softening agent adopts DBP.
CN201410382127.4A 2014-08-06 2014-08-06 A kind of wear-resisting multicolor finish Active CN104151951B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104805708A (en) * 2015-05-05 2015-07-29 湖州圣航纺织有限公司 Novel woven fabric pigment
CN106752548A (en) * 2016-10-14 2017-05-31 佛山沛涂科技有限公司 A kind of water-based paint compositions of high abrasion

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076466A (en) * 1993-03-05 1993-09-22 王学铭 A kind of pearlite plastic spraying coating and preparation method thereof
CN101967326A (en) * 2010-07-15 2011-02-09 宋光华 Exterior-wall reflectorized soluble paint
CN103436105A (en) * 2013-07-05 2013-12-11 丹阳市永生涂料有限公司 Formula for multi-color reddish orange paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076466A (en) * 1993-03-05 1993-09-22 王学铭 A kind of pearlite plastic spraying coating and preparation method thereof
CN101967326A (en) * 2010-07-15 2011-02-09 宋光华 Exterior-wall reflectorized soluble paint
CN103436105A (en) * 2013-07-05 2013-12-11 丹阳市永生涂料有限公司 Formula for multi-color reddish orange paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
夏叶清: "《精细化工产品大全》", 31 January 2005, article "多彩涂料" *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104805708A (en) * 2015-05-05 2015-07-29 湖州圣航纺织有限公司 Novel woven fabric pigment
CN106752548A (en) * 2016-10-14 2017-05-31 佛山沛涂科技有限公司 A kind of water-based paint compositions of high abrasion

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Effective date of registration: 20220905

Address after: Room 101, 102, 201, 202, Building 1, Advanced Energy Storage and Energy Saving Creative Demonstration Industrial Park, No. 169, Section 2, Renmin East Road, Economic and Technological Development Zone, Changsha City, Hunan Province 410000

Patentee after: Changsha Good Landscape Paint Co.,Ltd.

Address before: 215200 Lao Wu Tong Highway, Songling Town, Wujiang District, Suzhou, Jiangsu

Patentee before: WUJIANG HUACHENG COMPOSITE MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd.