CN104098975A - Water-in-water multi-color coating synthetized by multi-color ultra-thin slices and production process - Google Patents

Water-in-water multi-color coating synthetized by multi-color ultra-thin slices and production process Download PDF

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Publication number
CN104098975A
CN104098975A CN201410337066.XA CN201410337066A CN104098975A CN 104098975 A CN104098975 A CN 104098975A CN 201410337066 A CN201410337066 A CN 201410337066A CN 104098975 A CN104098975 A CN 104098975A
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water
agent
parts
ultra
sliver
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CN201410337066.XA
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CN104098975B (en
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陈勇桦
戴殿峰
朱恺
边界
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Jiangxi newimage paint Limited by Share Ltd
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HANGZHOU NINGZHI SYNTHETIC MATERIALS CO Ltd
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Abstract

The invention relates to a water-in-water multi-color coating synthetized by multi-color ultra-thin slices and a production process. The water-in-water multi-color coating is prepared by raw materials in parts by weight as follows: 10-15 parts of water, 35-55 parts of ultra-thin slices with the thicknesses ranging from 0.01 mm to 0.1 mm, 30-35 parts of an organic silicone modified emulsion S66, 1.5-2.0 parts of a film coalescing aid c-12, 0.1-0.3 part of a defoaming agent NXP-1, 0.1-0.3 part of a defoaming agent NXP-2, 0.5-1.0 part of a thickening agent NZC-308, 0.2-0.8 part of a levelling thickening agent NLP-105, 0.1-1.0 part of a levelling agent PU-30, 0.2-0.6 part of an amine neutralizing agent AZH-95, 0.5-2.0 parts of a quick drying agent and 5-20 parts of a calcium carbonate filler. Compared with the prior art, the water-in-water multi-color coating and the production process have the benefits as follows: color points well prepared by the ultra-thin slices are produced by a synthetic emulsion, and hydrophilic colloid is not required, so that excellent water resisting property and water white resistance capacity are achieved; the sizes of particles of the ultra-thin slices are easy to control; and the abnormal condition of high probability of breaking of water-in-water color points can be completely avoided by means of the ultra-thin slices.

Description

A kind of colorful ultrathin sliver synthetic water bag water multicolor finish and production technique
Technical field
The present invention relates to application of paints field, especially a kind of colorful ultrathin sliver synthetic water bag water multicolor finish and production technique.
Background technology
Water bag water multicolor finish (the HG/T4343-2012| aqueous colorful building coating) existent defect of producing with colloid is at present as follows: 1: poor water resistance, easily whiting: the protective colloid of taking due to the color grains of this production water Bao Shui mainly: the wilkinite of the high viscosity neusilin of synthetic, natural phant colloid, natural formation, the poor water resistance of these colloids self, easily water-swelling; 2: between when the colorful coloured silk of water bag water is put large small-scale production batch, should not control, 3: water bag water spot is easily broken: in storage, transportation, the stirring that adds water of water bag watercolor point destructible, particularly construction stage, more easily coloured silk point is blended, thereby cause construction color.
Summary of the invention
Object of the present invention will solve the deficiency that above-mentioned technology exists just, and a kind of colorful ultrathin sliver synthetic water bag water multicolor finish and production technique are provided.
The present invention solves the technical scheme that its technical problem adopts: this colorful ultrathin sliver synthetic water bag water multicolor finish, each raw material is as follows according to weight part proportioning: water 10-15 part, thickness is the ultra-thin sliver of 0.01-0.1mm: 35-55 part, organic-silicon-modified emulsion S66:30-35 part, film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, thickening material NZC-308:0.5-1.0 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, amine neutralizing agent AZH-95:0.2-0.6 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part.
Described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part.
The production technique of this colorful ultrathin sliver synthetic water bag water multicolor finish, step is as follows:
(1), water 10-15 part is dropped into paint mixing cylinder;
(2), organic-silicon-modified emulsion S66:30-35 part is added to the water, stir;
(3), by color requirement, add ultra-thin sliver 35-55 part, stir;
(4), add in order film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part; The rotating speed of paint mixing kettle, at 500-800 rev/min, is used amine neutralizing agent AZH-95:0.2-0.6 part to regulate pH value after 8-9, then is thickened to the viscosity 80-120KU of requirement with thickening material NZC-308:0.5-1.0 part.
Described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part, take raw material by formula ratio, and mixing and stirring, filters and packages.
Compared with prior art, useful effect is in the present invention: the coloured silk point that ultra-thin sliver is made is to adopt synthetic emulsion to produce, and does not need to add hydrophilic colloid, so have excellent water tolerance and the white ability of water resistant; Ultra-thin sliver granular size is easy to control; Ultra-thin sliver can be avoided the appearance of above-mentioned water bag watercolor point destructible abnormal conditions completely.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
This colorful ultrathin sliver synthetic water bag water multicolor finish of the present invention, each raw material is as follows according to weight part proportioning: water 10-15 part, thickness is the ultra-thin sliver of 0.01-0.1mm: 35-55 part, organic-silicon-modified emulsion S66:30-35 part, film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, thickening material NZC-308:0.5-1.0 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, amine neutralizing agent AZH-95:0.2-0.6 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part.
Described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part.
The production technique of this colorful ultrathin sliver synthetic water bag water multicolor finish, step is as follows:
(1), water 10-15 part is dropped into paint mixing cylinder;
(2), organic-silicon-modified emulsion S66:30-35 part is added to the water, stir;
(3), by color requirement, add ultra-thin sliver 35-55 part, stir;
(4), add in order film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part; The rotating speed of paint mixing kettle, at 500-800 rev/min, is used amine neutralizing agent AZH-95:0.2-0.6 part to regulate pH value after 8-9, then is thickened to the viscosity 80-120KU of requirement with thickening material NZC-308:0.5-1.0 part.
Described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part, take raw material by formula ratio, and mixing and stirring, filters and packages.
One, formula for a product: (weight part)
Hangzhou rather causes:
Full name: Hangzhou Ning Zhi synthetic materials company limited
Yongshun, Ningbo:
Full name: Ningbo Yongshun Fine Chemical Co., Ltd.
Two, the formula of quick dry agent:
Sequence number Raw material Material name Weight part Raw material sources
1 C2H5OH Ethanol 40--60 Commercial
2 CH3O-COOCH3 Methylcarbonate 30--50 Commercial
3 HOC3H6OC4H9 Propandiol butyl ether 5--15 Commercial
Three, the main quality index of product:
Four: the effect of main raw material:
1: organic-silicon-modified emulsion S66: being a kind of organosilicon-modified acrylate emulsion without soap body system, high glass transition temperature, and having excellent water tolerance, is to ensure that product is stable, weather-proof, the basis of xanthochromia not;
2: defoamer: be the product of modified mineral oil and modified organic silicon class, the excellent dispersion in water, can not produce in " oil bloom ";
3: thickening material NZC-308: be the product that substitutes high-viscosity cellulose, have than the better water tolerance of Mierocrystalline cellulose;
4: quick dry agent: have the effect of furtherance film, have the feature of quick volatilization simultaneously, can improve early stage water tolerance and the quick-drying of product, these raw materials are environment-friendly type raw material.
Embodiment 1: this colorful ultrathin sliver synthetic water bag water multicolor finish of the present invention (marble: China Dark), each raw material is as follows according to weight part proportioning: 10 parts, water, thickness is the ultra-thin sliver of 0.01-0.1mm: 35 parts of (15 parts of black wadding muck sheets, white wadding muck sheet: 20 parts), organic-silicon-modified emulsion S66:30 part, film coalescence aid c-12:1.5 part, defoamer NXP-1:0.1 part, defoamer NXP-2:0.1 part, thickening material NZC-308:0.5 part, levelling thickening material NLP-105:0.2 part, flow agent PU-30:0.1 part, amine neutralizing agent AZH-95:0.2 part, 0.5 part of quick dry agent, 5 parts of pearl fillers.Described quick dry agent is formed according to weight part proportioning by following each raw material: 40 parts of ethanol, 30 parts of methylcarbonates, 5 parts of propandiol butyl ethers.
Performance index:
Embodiment 2: this colorful ultrathin sliver synthetic water bag water multicolor finish of the present invention, each raw material is as follows according to weight part proportioning: the ultra-thin sliver that 15 parts, water, thickness are 0.01-0.1mm: 55 parts, organic-silicon-modified emulsion S66:35 part, film coalescence aid c-12:2.0 part, defoamer NXP-1:0.3 part, defoamer NXP-2:0.3 part, thickening material NZC-308:1.0 part, levelling thickening material NLP-105:0.8 part, flow agent PU-30:1.0 part, amine neutralizing agent AZH-95:0.6 part, 2.0 parts of quick dry agents, 20 parts of pearl fillers.Described quick dry agent is formed according to weight part proportioning by following each raw material: 60 parts of ethanol, 50 parts of methylcarbonates, 15 parts of propandiol butyl ethers.
Embodiment 3: this colorful ultrathin sliver synthetic water bag water multicolor finish of the present invention, each raw material is as follows according to weight part proportioning: the ultra-thin sliver that 12 parts, water, thickness are 0.01-0.1mm: 40 parts, organic-silicon-modified emulsion S66:32 part, film coalescence aid c-12:1.8 part, defoamer NXP-1:0.2 part, defoamer NXP-2:0.2 part, thickening material NZC-308:0.8 part, levelling thickening material NLP-105:0.5 part, flow agent PU-30:0.5 part, amine neutralizing agent AZH-95:0.4 part, 1.0 parts of quick dry agents, 15 parts of pearl fillers.Described quick dry agent is formed according to weight part proportioning by following each raw material: 50 parts of ethanol, 40 parts of methylcarbonates, 10 parts of propandiol butyl ethers.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.

Claims (4)

1. a colorful ultrathin sliver synthetic water bag water multicolor finish, it is characterized in that: each raw material is as follows according to weight part proportioning: water 10-15 part, thickness is the ultra-thin sliver of 0.01-0.1mm: 35-55 part, organic-silicon-modified emulsion S66:30-35 part, film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, thickening material NZC-308:0.5-1.0 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, amine neutralizing agent AZH-95:0.2-0.6 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part.
2. colorful ultrathin sliver synthetic water bag water multicolor finish according to claim 1, is characterized in that: described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part.
3. a production technique for colorful ultrathin sliver synthetic water bag water multicolor finish as claimed in claim 1, is characterized in that: step is as follows:
(1), water 10-15 part is dropped into paint mixing cylinder;
(2), organic-silicon-modified emulsion S66:30-35 part is added to the water, stir;
(3), by color requirement, add ultra-thin sliver 35-55 part, stir;
(4), add in order film coalescence aid c-12:1.5-2.0 part, defoamer NXP-1:0.1-0.3 part, defoamer NXP-2:0.1-0.3 part, levelling thickening material NLP-105:0.2-0.8 part, flow agent PU-30:0.1-1.0 part, quick dry agent 0.5-2.0 part, pearl filler 5-20 part; The rotating speed of paint mixing kettle, at 500-800 rev/min, is used amine neutralizing agent AZH-95:0.2-0.6 part to regulate pH value after 8-9, then is thickened to the viscosity 80-120KU of requirement with thickening material NZC-308:0.5-1.0 part.
4. the production technique of colorful ultrathin sliver synthetic water bag water multicolor finish according to claim 3, it is characterized in that: described quick dry agent is formed according to weight part proportioning by following each raw material: ethanol 40-60 part, methylcarbonate 30-50 part, propandiol butyl ether 5-15 part, take raw material by formula ratio, mixing and stirring, filters and packages.
CN201410337066.XA 2014-07-15 A kind of colorful ultrathin sliver synthesis water-in-water multicolor coating and production technology Active CN104098975B (en)

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Cited By (5)

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CN105038601A (en) * 2015-08-31 2015-11-11 贵州耐尔福顺成建材有限公司 Rock slice paint and production method thereof
CN105086713A (en) * 2015-09-09 2015-11-25 山东秦恒科技有限公司 Composite waterborne multi-color architectural coating and preparation method thereof
CN105086545A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Quick-drying multi-color patterned coating
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN111978800A (en) * 2020-08-07 2020-11-24 安徽雅特兰新材料科技有限公司 Preparation method of sand-containing art rock paint

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CN102206447A (en) * 2011-05-16 2011-10-05 西南科技大学 Method for preparing glimmerite sheet type granite-imitated lacquer coating
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086545A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Quick-drying multi-color patterned coating
CN105038601A (en) * 2015-08-31 2015-11-11 贵州耐尔福顺成建材有限公司 Rock slice paint and production method thereof
CN105086713A (en) * 2015-09-09 2015-11-25 山东秦恒科技有限公司 Composite waterborne multi-color architectural coating and preparation method thereof
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105219195B (en) * 2015-09-30 2018-07-31 三棵树涂料股份有限公司 A kind of compound sliver paint of aqueous colorful and preparation method thereof
CN111978800A (en) * 2020-08-07 2020-11-24 安徽雅特兰新材料科技有限公司 Preparation method of sand-containing art rock paint

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Inventor after: Chen Ruijie

Inventor after: Zhao Shiwei

Inventor after: Lin Chuqi

Inventor after: Dai Dianfeng

Inventor after: Bian Jie

Inventor after: Zhao Huarong

Inventor after: Li Xuewu

Inventor before: Chen Yonghua

Inventor before: Dai Dianfeng

Inventor before: Zhu Kai

Inventor before: Bian Jie

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Effective date of registration: 20160512

Address after: 310012 room 4, building 533, 511 staff Road, Hangzhou, Zhejiang, Xihu District

Applicant after: Hangzhou green coating Chemical Technology Co., Ltd.

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Applicant before: Hangzhou Ningzhi Synthetic Materials Co.,Ltd.

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Patentee after: Jiangxi newimage paint Limited by Share Ltd

Address before: 310012 room 4, building 533, 511 staff Road, Hangzhou, Zhejiang, Xihu District

Patentee before: Hangzhou green coating Chemical Technology Co., Ltd.

TR01 Transfer of patent right