CN104974576A - Quick-drying waterborne multicolor paint - Google Patents
Quick-drying waterborne multicolor paint Download PDFInfo
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- CN104974576A CN104974576A CN201510465439.6A CN201510465439A CN104974576A CN 104974576 A CN104974576 A CN 104974576A CN 201510465439 A CN201510465439 A CN 201510465439A CN 104974576 A CN104974576 A CN 104974576A
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Abstract
The invention discloses quick-drying waterborne multicolor paint which is prepared from the following raw materials: distilled water, pigment, polythene-2-oxopyrrolidine, polyvinyl acetate, light calcium carbonate, dolomite powder, methacrylic dimethylin methyl ester, talcum powder, methyl ethyl ether and gelatin gum. The product is free from agglomeration, and can form a homodispere body after being mixed. The quick-drying waterborne multicolor paint has viscosity of 75-95 at a temperature of 25 DEG C, has no change after being soaked with water for 40-60 days, has no change after being soaked with alkali liquor for 20-40 days, is washable and has no change after being washed for 3000-5000 times; a film formed by the quick-drying waterborne multicolor paint has the surface drying time of 0.5-1h, the solid drying time of 12-18h, the storage period of 8-14 months and the solid content of 18-22%, and can be widely produced so as to constantly replace existing materials.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of fast-drying aqueous multicolor finish.
Background technology
Water-water colorful marble paint rich color is colorful, and special color can be provided on request and emulation property high, it is unrestricted in designer, can change shape arbitrarily according to the intention of Designers.The general name of the ester class of vinylformic acid and homologue thereof.Important has methyl acrylate, polyethylene nitrogen penta cyclic ketones, 2-methyl methacrylate and 2-methyl polyethylene nitrogen penta cyclic ketones etc.Can autohemagglutination or and other monomer copolymerizations, be manufacture the monomer of tackiness agent, synthetic resins, specialty elastomer and plastics.
Multicolor finish is mainly used in copys stone material effect, so also known as liquid stone, is also local horizon exterior coating.Be made up of inconsistent two phase compositions, wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.This pattern formed by disposable spray finishing is completely different from the method being completed the multicolour pattern that could be formed by multiple working procedure successively.But along with China is more and more stricter to the protection of natural resources and national environmental protection and energy saving policy, relevant laws and regulations, make the exploitation of lithotome, processing, transportation cost constantly increase, this affects the application of lithotome in building decoration field to a certain extent.
Water-miscible paint is exactly take water as thinner, not containing the coating of organic solvent.Paint film plentiful, sparkling and crystal-clear bright, snappiness good and it is water-fast to have, wear-resisting, ageing-resistant, color inhibition, fast drying, the feature such as easy to use.Can be used in: in the various material such as woodenware, metal, plastics, glass, building surface.
Polyethylene nitrogen penta cyclic ketones, organic compound, white plates, cotton-shaped or pulverulent solids, tasteless.Water-soluble, be insoluble to gasoline, kerosene, vegetables oil, benzene, toluene, ethylene dichloride, tetracol phenixin, acetone, vinyl acetic monomer, methyl alcohol, ethylene glycol etc.Be slightly soluble in dimethyl sulfoxide (DMSO).Polyethylene nitrogen penta cyclic ketones is important industrial chemicals, for the manufacture of polyethylene nitrogen penta cyclic ketones acetal, resistance to gasoline pipeline and vinylon synthon, fabric-treating agent, emulsifying agent, paper coating, tackiness agent, glue etc.After coating, due to uneven, there is dispersion and multiple color decorative pattern can be obtained, stereoscopic sensation is strong, gloss is graceful, appearance tactile impression is good relief-type coating.Water-soluble take water soluble resin as film forming matter, with polyvinyl alcohol and various modifier thereof for representative, in addition also has water-soluble Synolac, water-soluble epoxy resin and inorganic polymer water-base resin etc.
Oil-in-water-type, oily bag vinylformic acid, oily oil-in and water bag vinylformic acid four class can be divided into by its medium condition, best with oily bag vinylformic acid package stability, and most widely used, water bag vinylformic acid environmental protection multicolor finish is being developed in practicality.The colorful marble paint of water-water is water-based coating, meet environmental requirement, non-harmful product during construction, because containing supra polymer element, construct after complete drying, have wear-resistant, wash away the characteristic changed with uviolizing, antistatic, high temperature resistant, acid rain resistant, waterproof, anti-be full of cracks, high strength, resistance to long-term multiple weather condition, property retention is constant, is easy to maintenance and cleaning, self-cleaning is excellent, multicolour once sprays, constructs easily, is a kind of excellent water tolerance, weathering resistance, a coating material.
Multicolor finish is the new decorative material for building of beautifying hotel, movie theatre, entertainment place, shop, office building, house etc.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan, therefore also known as liquid stone.The performance of polyethylene nitrogen penta cyclic ketones rubber affects by atomic number of alkyl carbon object in its principal monomer alkyl acrylate.Rubber based on polyethylene nitrogen penta cyclic ketones, oil resistant, thermotolerance are better; And the rubber based on butyl acrylate, because atomic number of alkyl carbon object increases, the shielding effect of ester group polar group is increased, therefore water tolerance is made to make moderate progress, simultaneously due to shielding effect, reduce power between rubber molecule, increase inner plasticity, thus temperature limit of brittleness is reduced, winter hardiness is better.If by above-mentioned two kinds of monomers and use, then can obtain the rubber between both performances.
1843, first find that acrolein oxidation generates vinylformic acid.1931, Rohm and Haas Company (US) Independenec Mall West, Philadelphia, Pennsy Lvania 1 of the U.S. succeeded in developing cyanoethanol hydrolysis acrylic acid process processed, is industrial unique production method for a long time.Nineteen thirty-nine, fritz W.J. thunder is worn and has been invented Carbonylation of Acetylene legal system vinylformic acid, within 1954, establishes full scale plant in the U.S..Meanwhile also successfully develop acrylonitrile hydrolysis acrylic acid process.Build up from U.S. combinating carbide company in 1969 with after propylene oxidation legal system vinylformic acid full scale plant, various countries adopt this method to produce in succession.In recent years, oxidation of propylene had carried out many improvement at catalyzer and process aspect, had become and had produced acrylic acid main method.Water-water multicolor finish is a kind of series product of Environmental Protective Water-paint system, is born for meeting the building external paint market of development now.That the pigment of modified resin and the good stability obtained with High-tech Research And Development is made, full water-based, the colorful granite coating of disposable spray finishing, the color produced is more true to nature, more durable, by the granite sample that Designers provides, emulator can reach 99%, is the best product of alternative exterior wall grouan.
Summary of the invention
The invention provides the multicolor finish that a kind of fast drying and period of storage are long, solve the technical problems such as the dry slow and period of storage of existing multicolor finish is short.
The present invention is by the following technical solutions: a kind of fast-drying aqueous multicolor finish, it is as follows that mass fraction proportioning pressed by its raw material: distilled water 100 parts, pigment 1-5 part, polyethylene nitrogen penta cyclic ketones 10-60 part, Vinyl Acetate Copolymer 10-30 part, light calcium carbonate 5-25 part, Bai Shiyun powder 30-50 part, dimethylaminoethyl methyl esters 5-25 part, talcum powder 6-14 part, methyl ethyl ether 6-14 part, jar (unit of capacitance) glue 12-28 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described fast-drying aqueous multicolor finish: distilled water 100 parts, pigment 2-4 part, polyethylene nitrogen penta cyclic ketones 20-40 part, Vinyl Acetate Copolymer 15-25 part, light calcium carbonate 10-20 part, Bai Shiyun powder 35-45 part, dimethylaminoethyl methyl esters 10-20 part, talcum powder 8-12 part, methyl ethyl ether 8-12 part, jar (unit of capacitance) glue 16-24 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described fast-drying aqueous multicolor finish: distilled water 100 parts, pigment 3 parts, polyethylene nitrogen penta cyclic ketones 30 parts, Vinyl Acetate Copolymer 20 parts, light calcium carbonate 15 parts, 40 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 15 parts, talcum powder 10 parts, methyl ethyl ether 10 parts, 20 parts, jar (unit of capacitance) glue.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide or phthalocyanine blue.
Beneficial effect: the fast-drying aqueous multicolor finish of one of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is without caking, uniformly dispersion after mixing; 2,25 DEG C of viscosity 75-95, soak 40-60d in water unchanged, soak 20-40d in alkali lye unchanged, and resistance to shampooing 3000-5000 time is unchanged; 3, film surface drying 0.5-1h, does solid work 12-18h, 8-14 month storage period, and solid content 18-22% the widespread production not division of history into periods can replace current material.
Embodiment
Below in conjunction with example, the invention will be further described, and embodiment, only for the present invention will be described, does not form the restriction to right, and other alternative means that it may occur to persons skilled in the art that, all within the scope of the claims in the present invention.
Embodiment 1:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 1 part, polyethylene nitrogen penta cyclic ketones 10 parts, Vinyl Acetate Copolymer 10 parts, light calcium carbonate 5 parts, 30 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 5 parts, talcum powder 6 parts, methyl ethyl ether 6 parts, 12 parts, jar (unit of capacitance) glue, is uniformly mixed in a kettle..
25 DEG C of viscosity 75-95, soak 40-60d in water unchanged, soak 20-40d in alkali lye unchanged, and resistance to shampooing 3000-5000 time is unchanged; Film surface drying 0.5-1h, does solid work 12-18h, 8-14 month storage period, solid content 18-22%.
Embodiment 2:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 5 parts, polyethylene nitrogen penta cyclic ketones 60 parts, Vinyl Acetate Copolymer 30 parts, light calcium carbonate 25 parts, 50 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 25 parts, talcum powder 14 parts, methyl ethyl ether 14 parts, 28 parts, jar (unit of capacitance) glue, is uniformly mixed in a kettle..
25 DEG C of viscosity 80, soak 45d in water unchanged, soak 25d in alkali lye unchanged, and resistance to shampooing 3500 times is unchanged; Film surface drying 0.9h, does solid work 16h, 9 months storage periods, solid content 19%.
Embodiment 3:
Distilled water 100 parts is taken according to mass fraction proportioning, phthalocyanine blue 2 parts, polyethylene nitrogen penta cyclic ketones 20 parts, Vinyl Acetate Copolymer 15 parts, light calcium carbonate 10 parts, 35 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 10 parts, talcum powder 8 parts, methyl ethyl ether 8 parts, 16 parts, jar (unit of capacitance) glue, is uniformly mixed in a kettle..
25 DEG C of viscosity 85, soak 50d in water unchanged, soak 30d in alkali lye unchanged, and resistance to shampooing 4000 times is unchanged; Film surface drying 0.8h, does solid work 15h, 11 months storage periods, solid content 20%.
Embodiment 4:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 4 parts, polyethylene nitrogen penta cyclic ketones 40 parts, Vinyl Acetate Copolymer 25 parts, light calcium carbonate 20 parts, 45 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 20 parts, talcum powder 12 parts, methyl ethyl ether 12 parts, 24 parts, jar (unit of capacitance) glue, is uniformly mixed in a kettle..
25 DEG C of viscosity 90, soak 55d in water unchanged, soak 35d in alkali lye unchanged, and resistance to shampooing 4500 times is unchanged; Film surface drying 0.6h, does solid work 14h, 13 months storage periods, solid content 21%.
Embodiment 5:
Distilled water 100 parts is taken according to mass fraction proportioning, red iron oxide 3 parts, polyethylene nitrogen penta cyclic ketones 30 parts, Vinyl Acetate Copolymer 20 parts, light calcium carbonate 15 parts, 40 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 15 parts, talcum powder 10 parts, methyl ethyl ether 10 parts, 20 parts, jar (unit of capacitance) glue, is uniformly mixed in a kettle..
25 DEG C of viscosity 95, soak 60d in water unchanged, soak 40d in alkali lye unchanged, and resistance to shampooing 5000 times is unchanged; Film surface drying 0.5h, does solid work 12h, 14 months storage periods, solid content 22%.
Claims (4)
1. a fast-drying aqueous multicolor finish, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described fast-drying aqueous multicolor finish: distilled water 100 parts, pigment 1-5 part, polyethylene nitrogen penta cyclic ketones 10-60 part, Vinyl Acetate Copolymer 10-30 part, light calcium carbonate 5-25 part, Bai Shiyun powder 30-50 part, dimethylaminoethyl methyl esters 5-25 part, talcum powder 6-14 part, methyl ethyl ether 6-14 part, jar (unit of capacitance) glue 12-28 part.
2. the fast-drying aqueous multicolor finish of one according to claim 1, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described fast-drying aqueous multicolor finish: distilled water 100 parts, pigment 2-4 part, polyethylene nitrogen penta cyclic ketones 20-40 part, Vinyl Acetate Copolymer 15-25 part, light calcium carbonate 10-20 part, Bai Shiyun powder 35-45 part, dimethylaminoethyl methyl esters 10-20 part, talcum powder 8-12 part, methyl ethyl ether 8-12 part, jar (unit of capacitance) glue 16-24 part.
3. the fast-drying aqueous multicolor finish of one according to claim 2, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described fast-drying aqueous multicolor finish: distilled water 100 parts, pigment 3 parts, polyethylene nitrogen penta cyclic ketones 30 parts, Vinyl Acetate Copolymer 20 parts, light calcium carbonate 15 parts, 40 parts, Bai Shiyun powder, dimethylaminoethyl methyl esters 15 parts, talcum powder 10 parts, methyl ethyl ether 10 parts, 20 parts, jar (unit of capacitance) glue.
4. the fast-drying aqueous multicolor finish of one according to claim 1, is characterized in that: described pigment adopts red iron oxide or phthalocyanine blue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510465439.6A CN104974576A (en) | 2015-08-03 | 2015-08-03 | Quick-drying waterborne multicolor paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510465439.6A CN104974576A (en) | 2015-08-03 | 2015-08-03 | Quick-drying waterborne multicolor paint |
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| CN104974576A true CN104974576A (en) | 2015-10-14 |
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| CN201510465439.6A Pending CN104974576A (en) | 2015-08-03 | 2015-08-03 | Quick-drying waterborne multicolor paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205689A (en) * | 2019-11-14 | 2020-05-29 | 浙江添艺新材料有限公司 | Production process of anti-corrosion and anti-aging stone-like water-based paint |
Citations (5)
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| CN1090871A (en) * | 1993-02-08 | 1994-08-17 | 河北省石家庄地区水利物资供应站 | Double-component multi-colour paint is produced and constructional method |
| CN1097782A (en) * | 1994-05-20 | 1995-01-25 | 苏州市建筑材料科学研究所 | Water-in-water aromatic multi-colour pattern paint |
| CN1103092A (en) * | 1993-11-26 | 1995-05-31 | 中国矿业大学 | Water-in-water type multi-colour figure paint |
| CN1108676A (en) * | 1994-03-18 | 1995-09-20 | 刘建军 | Water coating of multi-colour pattern |
| CN1117509A (en) * | 1994-08-24 | 1996-02-28 | 苏州市建筑科学研究所 | Water-in-water type multi-color decorative pattern paint |
-
2015
- 2015-08-03 CN CN201510465439.6A patent/CN104974576A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1090871A (en) * | 1993-02-08 | 1994-08-17 | 河北省石家庄地区水利物资供应站 | Double-component multi-colour paint is produced and constructional method |
| CN1103092A (en) * | 1993-11-26 | 1995-05-31 | 中国矿业大学 | Water-in-water type multi-colour figure paint |
| CN1108676A (en) * | 1994-03-18 | 1995-09-20 | 刘建军 | Water coating of multi-colour pattern |
| CN1097782A (en) * | 1994-05-20 | 1995-01-25 | 苏州市建筑材料科学研究所 | Water-in-water aromatic multi-colour pattern paint |
| CN1117509A (en) * | 1994-08-24 | 1996-02-28 | 苏州市建筑科学研究所 | Water-in-water type multi-color decorative pattern paint |
Non-Patent Citations (1)
| Title |
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| 崔春芳等: "《美术涂料与装饰技术手册》", 31 January 2010, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205689A (en) * | 2019-11-14 | 2020-05-29 | 浙江添艺新材料有限公司 | Production process of anti-corrosion and anti-aging stone-like water-based paint |
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