CN1117509A - Water-in-water type multi-color decorative pattern paint - Google Patents
Water-in-water type multi-color decorative pattern paint Download PDFInfo
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- CN1117509A CN1117509A CN 94111425 CN94111425A CN1117509A CN 1117509 A CN1117509 A CN 1117509A CN 94111425 CN94111425 CN 94111425 CN 94111425 A CN94111425 A CN 94111425A CN 1117509 A CN1117509 A CN 1117509A
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Abstract
This paint is used to whitewash the inside wall. It involves the disperse phase and the dispersed medium. It is characterized by that the disperse phase consists of hydrophilic colloid, anion synthetic resin emulsion, stainer, filler and assistants etc. Due to the action of the metallic ion in the dispersed medium on the hydrophilic colloid in the disperse phase, the granular gel is resulted, and with the action of the cation water-soluble resin emulsion in the dispersed medium on the anion resin emulsion in the disperse phase, the films covered on the surface of the particles is resulted. The particles are soft and strength. The coating figure is smooth and clear.
Description
The present invention relates to the coating that a kind of inner wall decoration is used.
In the prior art, multicolor finish is by its principle classification, but oil-in-water-type, water-in-oil-type, oily oil-in and water-in-water type four classes.First three class all is oily particle (disperse phase) and aqueous medium (dispersion medium) or water-based particle and oil medium composition.No matter any, its oily matter all need be with a large amount of organic solvents, all scent of, poisonous, inflammable, contaminate environment and storage and transportation aspect existing problems.The technical scheme of water type multicolor paint for water drum employing at present is the tackifying resin latex and the waterborne polymeric reaction that contains cation radical that will contain anion-radicals, make particle surface be soft gel state and particle inside is the tackify state, the formed decorative pattern in spraying back is that a circle shape and pattern edge are unintelligible, and decorative effect is poor.The unit that has adopts the technical scheme of polyvinyl alcohol/borax, and formed decorative pattern is projection obviously.Adopt the hydrophilic colloid gel method in addition, resulting particle flexibility is poor, decorative pattern projection and unnatural, and effect is not good enough yet.
The objective of the invention is to adopt hydrophilic colloid gel method and negatively charged ion latex/cation dispersion medium system way of combining to make water-in-water type multi-color decorative pattern paint, make its color point be soft blocky particle such as various sheets, strip.
Technical scheme of the present invention is: the key problem in technology of water-in-water type multi-color decorative pattern paint is the insoluble system that selection adapts.It comprises disperse phase, dispersion medium; Described disperse phase by hydrophilic colloid, negatively charged ion synthetic resin emulsion, mill base, filler, auxiliary agent etc. and form, behind the metal ion and cation water-based resin liquid in its chance dispersion medium, described metal ion can form particle shape gel with hydrophilic colloid effect in the disperse phase, and described cation water-soluble resin liquid can form the film that be wrapped in particle surface with the resin anion(R.A) latex effect in the disperse phase.
The present invention compared with prior art has following advantage:
Adopt the hydrophilic colloid gel method to obtain sheet, strip particle, and then make particle surface parcel one deck flexible membrane, make particle soft and solid, the decorative pattern that obtains is smooth and clear.
Embodiment: disperse phase by following ingredients by weight ratio:
Resin anion(R.A) latex 40～60
Hydrophilic colloid 1.5～2.5
Water 300～400
Filler 8～12
Dispersion agent 0.1
Auxiliary agent 8～10
It is an amount of mill base
Contain metal ion and cation water-based resin liquid in the described dispersion medium.Contain the amount of monomer of carboxyl between 2～20% in the resin anion(R.A) latex that disperse phase adopts, to be cinnamic acrylic ester, styrene-acrylonitrile-acrylate, ethene-vinyl acetate, vinyl acetate between to for plastic-acrylate, vinyl chloride-vinyl acetate-acrylate etc. contain in the monomer of carboxylic acid more than one with vinylformic acid, methacrylic acid, toxilic acid, itaconicacid, maleic acid etc. to used latex carries out the latex that copolymerization forms, and the latex consumption is 20～30% (weight ratios) of disperse phase.Hydrophilic colloid in the described disperse phase is as sore glue, pectin, guar gum, phycocolloid, synthetic gum tragacanth, carrageenin, the locust bean gum etc. of healing, and its amount is 1～5% (weight ratio) of disperse phase.This class hydrophilic colloid can form gel with some metal ion effect, and is to form in moment, and its ability in conjunction with moisture content is stronger.Institute's metal ion in the dispersion medium, as calcium, zinc, boron, aluminium, chromium barium, iron, potassium etc., its amount is 0.05～0.5% (weight ratio) of dispersion medium.This metal ion can be with hydrophilic colloid effect in the disperse phase and is formed gel.Contained cation water-soluble resin liquid is as the polymkeric substance of the vinyl lactam of cationic polyacrylamide, cationization and the polymkeric substance of acrylate, organophosphorus and acrylate, cationic starch, vinyl pyridine, cationic polyvinyl alcohol etc. in the dispersion medium, and its amount is 0.2～2% (weight ratio) of dispersion medium.It can form the film that is wrapped in particle surface with the resin anion(R.A) latex effect in the disperse phase.Pigment that disperse phase is used and filler require that it is fast light, good weatherability, bright in luster, easily disperse and acid and alkali-resistance.Used filler is wollastonite powder, pure aluminium silicate, talcum powder, pearlescence etc. in the disperse phase, pigment (mill base) is titanium dioxide, phthalocyanine blue, phthalocyanine green, the husky Huang of the Chinese, toluidine red, iron oxide red, iron oxide yellow etc., and the consumption of pigment and filler is 2～10% (weight ratios) of disperse phase.Adjuvant used is propylene glycol butyl ether, propylene glycol, butyl glycol ether, ethylene glycol, Terpineol 350, tributyl phosphate, polyoxyethylene glycol etc.Described dispersion agent is anionic carboxylic acid multipolymer, polyacrylic acid amine salt etc.For improving package stability and easily spraying, also be added with protection glue in the coating, as methylcellulose gum, Natvosol, hydroxypropylcellulose, polyvinyl alcohol etc., also can add synthetic resin emulsion, as phenylpropyl alcohol latex, chlorine vinegar third latex, the inclined to one side latex of modification chlorine etc.Can make like this that decorative pattern after the spraying is water-fast, wet-rub resistance good, and can make decorative pattern have certain gloss.
Preparation technology of the present invention is as follows:
(1). prepare stock white earlier.Get the water yield of 0.8 times of pigment and amount of filler and put into stirred pot, add dispersion agent, pigment, filler then and break into pulpous state, obtain stock white through grinding.
(2). hydrophilic colloid is dissolved in the gauge water, stirs and to add stock white, synthetic resin emulsion and various auxiliary agent down, add at last required color mill base an amount of, obtaining color material is latex coating.
(3). in granulation tank, add gauge water, stir extremely all dissolvings of adding metallic salt down.
(4). stir down (2) coloured silk is expected that the thread formula is added in the granulation tank, regulate the distance of stirring velocity and agitating vane and the water surface simultaneously, make the latex coating particle that can obtain suitable shape and size, add until the coloured silk material.
(5). quantitative cation water-based polymer liquid is added in (4), mix quiet the stopping 2～3 hours in back, remove supernatant liquid, add the protection glue, this obtains monochromatic color grain coating.
(6). by the color of model requirement, a monochromatic coloured silk coating mixing of getting different colours more than two kinds promptly obtains water-in-water type multi-color decorative pattern paint.
Specific embodiment is as follows:
A. get 20 water, add dispersion agent polyacrylic acid amine salt 0.3, stir adding titanium dioxide 30 down, wollastonite powder 5, talcum powder 5 breaks into pulpous state, obtains stock white after colloidal mill grinds.
B. fetch water 600 to go in the mixing tank, add phycocolloid 7, synthetic gum tragacanth 3, be stirred to whole dissolvings, add stock white then, negatively charged ion synthetic resin emulsion (benzene diene-vinyl cyanide-acrylate-acrylic acid multielement copolymerized latex) 120 mixes, and adds propylene glycol 5, propylene glycol butyl ether 10, tributyl phosphate 2 again, adds required mill base an amount of (blueness) at last and stirs evenly and obtain color material.
C. in granulation tank, add water 700, zinc sulfate 3, stirring down, the thread formula adds color material.Regulate rotating speed and agitating vane apart from the water surface degree of depth, obtain suitable color grain, add until the coloured silk material.In this jar, add cationic polyacrylamide 2, stir evenly quiet the stopping 2～3 hours in back.Remove supernatant liquid, add methylcellulose gum (2% concentration) liquid 250, sterilant 1,2-benzisothiazole-3-ketone 0.1 (liquid state) obtains monochromatic color grain coating (blueness) after stirring evenly.
D. can obtain straight-shade coatings such as red, Huang with method,, get that monochromatic color grain coating is mixed in proportion more than two kinds, promptly obtain water-in-water type multi-color decorative pattern paint by the model requirement.
Claims (10)
1. water-in-water type multi-color decorative pattern paint, it comprises disperse phase, dispersion medium; It is characterized in that: described disperse phase by hydrophilic colloid, negatively charged ion synthetic resin emulsion, mill base, filler, auxiliary agent etc. and form, behind the metal ion and cation water-based resin liquid in its chance dispersion medium, described metal ion can form particle shape gel with hydrophilic colloid effect in the disperse phase, and described cation water-soluble resin liquid can form the film that be wrapped in particle surface with the resin anion(R.A) latex effect in the disperse phase.
2. water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described disperse phase by following ingredients by weight ratio:
Resin anion(R.A) latex 40～60
Hydrophilic colloid 1.5～2.5
Water 300～400
Filler 8～12
Dispersion agent 0.1
Auxiliary agent 8～10
It is an amount of mill base
Contain metal ion and cation water-based resin liquid in the described dispersion medium.
3. water-in-water type multi-color decorative pattern paint according to claim 1, it is characterized in that: contain the amount of monomer of carboxyl between 2～20% in the resin anion(R.A) latex that disperse phase adopts, used latex is a cinnamic acrylic ester, styrene-acrylonitrile-acrylate, ethene-vinyl acetate, vinyl acetate between to for plastic-acrylate, vinyl chloride-vinyl acetate-acrylate etc. and vinylformic acid, methacrylic acid, toxilic acid, itaconicacid, maleic acids etc. contain in the monomer of carboxylic acid more than one and carry out the latex that copolymerization forms, and the latex consumption is 20～30% (weight ratios) of disperse phase
4. water-in-water type multi-color decorative pattern paint according to claim 1, it is characterized in that: the hydrophilic colloid in the described disperse phase is as sore glue, pectin, guar gum, phycocolloid, synthetic gum tragacanth, carrageenin, the locust bean gum etc. of healing, and its amount is 1～5% (weight ratio) of disperse phase.
5. water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: institute's metal ion in the dispersion medium, as calcium, zinc, boron, aluminium, chromium, barium, iron, potassium etc., its amount is 0.05～0.5% (weight ratio) of dispersion medium.
6. water-in-water type multi-color decorative pattern paint according to claim 1, it is characterized in that: contained cation water-soluble resin liquid is as the polymkeric substance of the vinyl lactam of cationic polyacrylamide, cationization and the polymkeric substance of acrylate, organophosphorus and acrylate, cationic starch, vinyl pyridine, cationic polyvinyl alcohol etc. in the dispersion medium, and its amount is 0.2～2% (weight ratio) of dispersion medium.
7. water-in-water type multi-color decorative pattern paint according to claim 2, it is characterized in that: used filler is wollastonite powder, pure aluminium silicate, talcum powder, pearlescence etc. in the disperse phase, pigment (mill base) is titanium dioxide, phthalocyanine blue, phthalocyanine green, the husky Huang of the Chinese, toluidine red, iron oxide red, iron oxide yellow etc., and the consumption of pigment and filler is 2～10% (weight ratios) of disperse phase.
8. water-in-water type multi-color decorative pattern paint according to claim 2 is characterized in that: adjuvant used is propylene glycol butyl ether, propylene glycol, butyl glycol ether, ethylene glycol, Terpineol 350, tributyl phosphate, polyoxyethylene glycol etc.
9. water-in-water type multi-color decorative pattern paint according to claim 2 is characterized in that: described dispersion agent is anionic carboxylic acid multipolymer, polyacrylic acid amine salt etc.
10. water-in-water type multi-color decorative pattern paint according to claim 1; it is characterized in that: also contain protection glue in the coating; as methylcellulose gum, Natvosol, hydroxypropylcellulose, polyvinyl alcohol etc.; also can add synthetic resin emulsion, as phenylpropyl alcohol latex, chlorine vinegar third latex, the inclined to one side latex of modification chlorine etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94111425 CN1117509A (en) | 1994-08-24 | 1994-08-24 | Water-in-water type multi-color decorative pattern paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94111425 CN1117509A (en) | 1994-08-24 | 1994-08-24 | Water-in-water type multi-color decorative pattern paint |
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| CN1117509A true CN1117509A (en) | 1996-02-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94111425 Pending CN1117509A (en) | 1994-08-24 | 1994-08-24 | Water-in-water type multi-color decorative pattern paint |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453117A (en) * | 2010-10-28 | 2012-05-16 | 中国石油化工股份有限公司 | Alkali metal alkoxide and preparation method thereof |
| CN102876140A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Cloud wire coating and preparation method thereof |
| WO2013181800A1 (en) * | 2012-06-06 | 2013-12-12 | Dow Global Technologies Llc | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| CN103849278A (en) * | 2012-12-06 | 2014-06-11 | 天津市东鼎科技发展有限公司 | Preparation method of water-in-water multicolor paint |
| CN104151983A (en) * | 2014-08-20 | 2014-11-19 | 吴江华诚复合材料科技有限公司 | Two aqueous phase colorful pattern paint |
| CN104974576A (en) * | 2015-08-03 | 2015-10-14 | 苏州舒而适纺织新材料科技有限公司 | Quick-drying waterborne multicolor paint |
| CN105860590A (en) * | 2016-04-05 | 2016-08-17 | 江苏海明斯新材料科技有限公司 | Preparation method of modified hectorite for water-in-water multicolor paint protecting adhesives |
| CN106833298A (en) * | 2016-12-30 | 2017-06-13 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN107268906A (en) * | 2017-07-11 | 2017-10-20 | 霸州市瑞硕盈装饰装修工程有限公司 | A kind of construction technology of liquid granite coating |
| US10023757B2 (en) | 2013-09-04 | 2018-07-17 | Dow Global Technologies Llc | Process for preparing color dispersions and the color dispersions made thereof |
| US10030162B2 (en) | 2013-09-04 | 2018-07-24 | Dow Global Technologies Llc | Process for preparing transparent/semi-transparent color dispersions and the color dispersions made thereof |
| CN109627894A (en) * | 2018-12-04 | 2019-04-16 | 青岛天地彩涂料有限公司 | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method |
| CN109627893A (en) * | 2018-12-04 | 2019-04-16 | 青岛天地彩涂料有限公司 | A kind of true stone simulated tile coating of anti-aging glare thermal-insulating type and its manufacturing method |
| US10590271B2 (en) | 2015-03-31 | 2020-03-17 | Dow Global Technologies Llc | Binder composition and a paint formulation made thereof |
-
1994
- 1994-08-24 CN CN 94111425 patent/CN1117509A/en active Pending
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453117A (en) * | 2010-10-28 | 2012-05-16 | 中国石油化工股份有限公司 | Alkali metal alkoxide and preparation method thereof |
| AU2012381929B2 (en) * | 2012-06-06 | 2016-11-03 | Dow Global Technologies Llc | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| CN104334657B (en) * | 2012-06-06 | 2017-07-18 | 陶氏环球技术有限公司 | Prepare the method for polychrome dispersion and by its obtained polychrome dispersion |
| KR101954703B1 (en) | 2012-06-06 | 2019-03-06 | 다우 글로벌 테크놀로지스 엘엘씨 | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| CN104334657A (en) * | 2012-06-06 | 2015-02-04 | 陶氏环球技术有限公司 | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| KR20150024321A (en) * | 2012-06-06 | 2015-03-06 | 다우 글로벌 테크놀로지스 엘엘씨 | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| WO2013181800A1 (en) * | 2012-06-06 | 2013-12-12 | Dow Global Technologies Llc | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| US10767070B2 (en) | 2012-06-06 | 2020-09-08 | Dow Global Technologies Llc | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| CN102876140A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Cloud wire coating and preparation method thereof |
| CN103849278A (en) * | 2012-12-06 | 2014-06-11 | 天津市东鼎科技发展有限公司 | Preparation method of water-in-water multicolor paint |
| US10428235B2 (en) | 2013-09-04 | 2019-10-01 | Dow Global Technologies Llc | Process for preparing transparent/semi-transparent color dispersions and the color dispersions made thereof |
| US10023757B2 (en) | 2013-09-04 | 2018-07-17 | Dow Global Technologies Llc | Process for preparing color dispersions and the color dispersions made thereof |
| US10030162B2 (en) | 2013-09-04 | 2018-07-24 | Dow Global Technologies Llc | Process for preparing transparent/semi-transparent color dispersions and the color dispersions made thereof |
| CN104151983B (en) * | 2014-08-20 | 2016-09-21 | 吴江华诚复合材料科技有限公司 | A kind of dual-water-phase colour pattern paint |
| CN104151983A (en) * | 2014-08-20 | 2014-11-19 | 吴江华诚复合材料科技有限公司 | Two aqueous phase colorful pattern paint |
| US10590271B2 (en) | 2015-03-31 | 2020-03-17 | Dow Global Technologies Llc | Binder composition and a paint formulation made thereof |
| CN104974576A (en) * | 2015-08-03 | 2015-10-14 | 苏州舒而适纺织新材料科技有限公司 | Quick-drying waterborne multicolor paint |
| CN105860590A (en) * | 2016-04-05 | 2016-08-17 | 江苏海明斯新材料科技有限公司 | Preparation method of modified hectorite for water-in-water multicolor paint protecting adhesives |
| CN106833298B (en) * | 2016-12-30 | 2019-02-22 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN106833298A (en) * | 2016-12-30 | 2017-06-13 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN107268906A (en) * | 2017-07-11 | 2017-10-20 | 霸州市瑞硕盈装饰装修工程有限公司 | A kind of construction technology of liquid granite coating |
| CN109627893A (en) * | 2018-12-04 | 2019-04-16 | 青岛天地彩涂料有限公司 | A kind of true stone simulated tile coating of anti-aging glare thermal-insulating type and its manufacturing method |
| CN109627894A (en) * | 2018-12-04 | 2019-04-16 | 青岛天地彩涂料有限公司 | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method |
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