CN109627894A - A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method - Google Patents
A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method Download PDFInfo
- Publication number
- CN109627894A CN109627894A CN201811473861.6A CN201811473861A CN109627894A CN 109627894 A CN109627894 A CN 109627894A CN 201811473861 A CN201811473861 A CN 201811473861A CN 109627894 A CN109627894 A CN 109627894A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- powder
- stage
- function
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The invention discloses a kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing methods, the component of the multicolor finish is by three kinds of function components and accounts for the deionized water of coating total weight 30%-35% and forms, wherein the first function component A is modified through rosin pentaerythritol ester, the graft copolymer prepared using acrylic acid, acrylonitrile, styrene as raw material；Second of function component B is basalt powder, quartzite powder；The third function component C is glass microballoon, silver powder；The component relationship of three kinds of compositions are as follows: component C and component B in the form of solid powder disperse in component A micelle micel or it is muddy in deionized water.Multicolor finish environmental protection and public nuisance free of the invention, anti-aging, weatherproof, from antibacterial, binding force is good, long service life.
Description
Technical field
The present invention relates to decorative paint field more particularly to a kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its
Manufacturing method.
Background technique
" water-water " is high-grade decorative paint truly, also known as liquid artificial granite paint." water-water " is rich
There is higher scientific and technological gold content, compared with the sand textured coatings product such as natural real stone paint, granite mineral varnish, texture paint, sandstone paint,
There is entirely different concept in itself.Finished product through air brushing highlight it is simple and unsophisticated, beautiful, elegant, flower hilllock texture it is natural and tripping, it is muddy
So blending, any surface finish is soft smooth, and feel is not crude.The attachment of film height is not cracked, and high durable temperature resistance becomes, and high resistant is easily clear
It washes, self-cleaning function is strong.Since the kind has many unique outstanding representations and extremely convenient construction characteristic, thus extensively by
Social recognition obtains all circles' concern and promotes and applies.Can arbitrarily mix colours, grab color etc., finally reach designer's ideal design as a result,
While reservation lithotome texture true to nature, more exquisite effect can be also arbitrarily created, Bartlit decorative pattern is overcome
Stiff property, the property met by chance, limitation.
But restricted to be, when high-storey house facade is using conventional multicolor finish, coating this first is not true
Stone, but burnt-in sand starches cold coating, thus have the shortcomings that hardness is low, weatherability is poor, and the lacquer that cost is relatively higher
Then just on the contrary, its poor with the binding force of metope, not acidproof (based on carbonization salt).
In the prior art, although such coating type is numerous, due to not yet will the hardness of " true stone " and weatherability and
The relevant technologies that the binding force of " imitative brick " combines with corrosion resistance are not only difficult to ensure in terms of color effects, what is more may
Surface Differentiation, cracking etc. are caused, and then influences heat-insulation system and basal plane, main body is damaged.
In conclusion need on the market a kind of environmental protection and public nuisance free, anti-aging, weatherproof, from antibacterial, binding force is good, uses
The sandstone packet water multicolor finish and its manufacturing method of service life length.
Summary of the invention
To solve drawbacks described above existing in the prior art, the present invention is intended to provide a kind of environmental protection and public nuisance free, anti-aging, resistance to
Wind erosion, from antibacterial, binding force is good, efflorescence prevention high-bond sandstone packet water multicolor finish with long service life and its manufacturing method.
To achieve the goals above, the invention adopts the following technical scheme: a kind of efflorescence prevention high-bond sandstone Bao Shui is more
The manufacturing method of color coating material, comprising the following steps:
1) prepare before production
1. raw material prepare: preparation 30 parts -35 parts of float stone basalt, 20 parts -25 parts of quartzite, 6 parts of glass microballoon-by weight
8 parts, 2 parts -3 parts of silver powder, 8 parts -10 parts of rosin pentaerythritol ester, 30 parts -35 parts of acrylic resin, 15 parts -20 parts of acrylonitrile,
15 parts -20 parts of styrene, 1 part -1.5 parts of dodecyl sodium sulfate, 0.3 part -0.5 part of tert-butyl hydroperoxide, sodium peroxydisulfate 0.3
Part -0.5 part, 3 parts -5 parts of EDETATE SODIUM, 3 parts -5 parts of frerrous chloride；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of substrate latex liquid
1. using the stage 1) acrylic resin that 1. prepares of step is raw material, and it is to help with EDETATE SODIUM using frerrous chloride as initiator
Agent prepares substrate latex using dodecyl sodium sulfate as emulsifier；
2. using 1.5 times -1.8 times of the stage 1 of substrate latex total weight) deionized water that 2. prepares of step is diluent, by matrix
The mixed liquor uniform stirring of latex and deionized water, until substrate latex is completely dissolved in deionized water, that is, matrix glue needed for obtaining
Lotion；
3) preparation of functional auxiliary materials
1. using the stage 1) step 1. prepare acrylonitrile, styrene as raw material, heat obtains organic liquor after melting, the organic liquor be function
Auxiliary agent；
2. by the stage 1) step 1. prepare float stone basalt, quartzite mechanical lapping at partial size 0.1mm-0.2mm powder, so
Afterwards by the float stone basalt powder of acquisition, quartzite powder and stage 1) glass microballoon that 1. prepares of step and silver powder mix simultaneously
It stirs evenly, obtains function mixed-powder；
4) coating synthesizes
1. in the stage 2) whole stages 3 are added in the substrate latex liquid that obtains) the function mixed-powder that 2. prepares of step, stirring is equal
Prefabricated dirty solution is obtained after even；
2. being added dropwise in 1. prefabricated dirty solution that step obtains based on the quality G of dirty solution with the rate of G/1000s-G/1200s
Stage 3) function additive that 1. prepares of step until being added dropwise to complete obtains matrix stoste；
3. the first stage carries out initiation polymerization with tert-butyl hydroperoxide in 2. matrix stoste that step obtains；Second stage
Secondary initiation polymerization is carried out by initiator of sodium peroxydisulfate；After the completion of secondary initiation polymerization, starting the dropwise addition stage 1) step is 1.
The drop rate of the rosin pentaerythritol ester of preparation, rosin pentaerythritol ester is G/500s-G/600s, after being added dropwise to complete, with
200-220 DEG C of temperature to water content is the 30%-35% for obtaining object gross mass, i.e. acquisition kinematic viscosity 60mm2/s-
80mm2The thick latex solution of/s, the thick latex solution are required efflorescence prevention high-bond sandstone packet water multicolor finish.
A kind of efflorescence prevention high-bond sandstone packet water multicolor finish, the component of the multicolor finish is by weight by three kinds of function
Energy component and the deionized water composition for accounting for coating total weight 30%-35%, wherein the first function component A is through rosin pentaerythritol ester
8 parts -10 parts of ester are modified, with 30 parts -35 parts of acrylic resin, 15 parts -20 parts of acrylonitrile, 15 parts -20 parts of styrene be raw material
The graft copolymer of the acrylic acid of preparation and acrylonitrile, styrene；Second of function component B is the floating of partial size 0.1mm-0.2mm
20 parts -25 parts of quartzite powder of 30 parts -35 parts of stone basalt powder and partial size 0.1mm-0.2mm；The third function component C is
6 parts -8 parts and 2 parts -3 parts of silver powder of glass microballoon；The component relationship of three kinds of compositions are as follows: component C and component B are with solid powder
Form disperse in component A micelle micel or it is muddy in deionized water.
Compared with prior art, the invention has the following advantages that (1) most crucial technical concept of the invention is exactly with this
It carries out taking structure based on the ASA resin that technical field is not applied also entirely, it is loose using the more stomatas of ASA resin, space frame
Architectural characteristic realize the technical purpose of heat preservation, fixed function composition, the fundamental significance of the technical concept is ASA and coating phase
The basic characteristic of pass only has that weatherability is good (even if being exposed under ultraviolet light, wet steam, heat, cold and impact for a long time, to be still able to maintain its face
Color stability), self-cleaning preferably a kind of (being antistatic material, surface can be made to lack dust stratification dirt) two kinds of characteristics, other indispensability
Can such as hardness, resistance to acid attack (flavescence can be aoxidized), antibacterial performance, poor with metope binding force, this be also the resinoid never
Used basic reason is really answered in the art.The present invention also has high miscibility (since it dredges the sky in hole using it
Between structure and flexible matrix construct jointly, be easier to form the physical characteristic of stable structure object with other immiscible functions)
Advantage, reasonable in its synthesis process, effectively physical doping large scale functional mixture, does so the mixing of one side function
Object can sufficiently, uniformly, disperse mix in the base, on the other hand can also maximally utilize the space structure of ASA resin, most
Afterwards, and for matrix the space of the modified enhancing of sufficient mechanical performance is left.(2) function component of the invention is mainly by two kinds of skills
The building stones of art feature are constituted, and wherein float stone basalt is the stone that hardness is higher, composition is more complex due to well-known
Powder, there are also good self-lubrications, sturdy and durable, while having the features such as sound insulation, heat-insulated；Quartzite is good decorating effect, hardness
High, the lower decorative mountain flour of water suction, the two have complementary functions, and promote surface hardness of the invention, wearability, self-lubrication jointly
And dicoration, simultaneously because both mountain flours provide for the solid content of a variety of different colours so that the present invention dazzle it is beautiful
Colorful, ornamental value is preferable.(3) the invention also includes two kinds of miscellaneous function components: glass microballoon and silver powder, both components one
Fabulous reflective colorful, oleophyllie hydrophobic performance kind be provided, a kind of offer glare, anti-microbial property, improve resistance to acid attack of the invention,
Anti-aging, anti-microbial property further promotes thermal insulation property, improves decorative effect.(4) although the present invention apply it is a variety of not
Same function component, but what is be most difficult to is that ASA resin that the component of these different function is passed through matrix, can containing is synthesizing
In just all solidify and does not influence completely the polymerizations of ASA resin itself, in the stage 4) 3. step causes to send out should start preceding each raw material
Component or disperse completely are mixed, are non-interfering, and when being modified again with rosin pentaerythritol ester after causing twice, polymerization is anti-
Answer and the chain link of remaining hydrogen bond react the micel to be formed could be composition curing within molecule shell structure by partial function, it is another
Partial function component adhering and solidifying finally makes entire final molecule shell structure surface (utilizing the electrostatic attraction of remaining hydrogen bond)
Coating function component exists with glued state, and due to being modified using rosin pentaerythritol ester, enhances ASA resin base
Plinth mechanical property, with the binding force into increase and metope after use.Therefore make of the invention finally there is environmental protection and public nuisance free, anti-ageing
Change, weatherproof, from antibacterial, binding force is good, characteristic with long service life.
Specific embodiment
Embodiment 1:
A kind of efflorescence prevention high-bond sandstone packet water multicolor finish, the component of the multicolor finish is by weight by three kinds of functional groups
Part and the deionized water composition for accounting for coating total weight 35%, wherein the first function component A is changed through rosin pentaerythritol ester 10Kg
Property, the acrylic acid and acrylonitrile, styrene prepared using acrylic resin 30Kg, acrylonitrile 20Kg, styrene 20Kg as raw material
Graft copolymer；Float stone the basalt powder 35Kg and partial size 0.1mm- that second of function component B is partial size 0.1mm-0.2mm
The quartzite powder 25Kg of 0.2mm；The third function component C is glass microballoon 8Kg and silver powder 3Kg；The composition of three kinds of compositions
Relationship are as follows: component C and component B in the form of solid powder disperse in component A micelle micel or it is muddy in deionized water.
The manufacturing method of above-mentioned efflorescence prevention high-bond sandstone packet water multicolor finish, comprising the following steps:
1) prepare before production
1. raw material prepare: by weight preparation float stone basalt 35Kg, quartzite 25Kg, glass microballoon 8Kg, silver powder 3Kg,
Rosin pentaerythritol ester 10Kg, acrylic resin 30Kg, acrylonitrile 20Kg, styrene 20Kg, dodecyl sodium sulfate 1.5Kg,
Tert-butyl hydroperoxide 0.5Kg, sodium peroxydisulfate 0.5Kg, EDETATE SODIUM 5Kg, frerrous chloride 5Kg；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of substrate latex liquid
1. using the stage 1) acrylic resin that 1. prepares of step is raw material, and it is to help with EDETATE SODIUM using frerrous chloride as initiator
Agent prepares substrate latex using dodecyl sodium sulfate as emulsifier；
2. using 1.8 times of the stage 1 of substrate latex total weight) deionized water that 2. prepares of step as diluent, by substrate latex with
The mixed liquor uniform stirring of deionized water, until substrate latex is completely dissolved in deionized water, that is, substrate latex liquid needed for obtaining；
3) preparation of functional auxiliary materials
1. using the stage 1) step 1. prepare acrylonitrile, styrene as raw material, heat obtains organic liquor after melting, the organic liquor be function
Auxiliary agent；
2. by the stage 1) step 1. prepare float stone basalt, quartzite mechanical lapping at partial size 0.1mm-0.2mm powder, so
Afterwards by the float stone basalt powder of acquisition, quartzite powder and stage 1) glass microballoon that 1. prepares of step and silver powder mix simultaneously
It stirs evenly, obtains function mixed-powder；
4) coating synthesizes
1. in the stage 2) whole stages 3 are added in the substrate latex liquid that obtains) the function mixed-powder that 2. prepares of step, stirring is equal
Prefabricated dirty solution is obtained after even；
2. the stage 3 is added dropwise with the rate of G/1200s in 1. prefabricated dirty solution that step obtains based on the quality G of dirty solution) step
Suddenly the function additive 1. prepared obtains matrix stoste until being added dropwise to complete；
3. the first stage carries out initiation polymerization with tert-butyl hydroperoxide in 2. matrix stoste that step obtains；Second stage
Secondary initiation polymerization is carried out by initiator of sodium peroxydisulfate；After the completion of secondary initiation polymerization, starting the dropwise addition stage 1) step is 1.
The drop rate of the rosin pentaerythritol ester of preparation, rosin pentaerythritol ester is G/600s, after being added dropwise to complete, with 220 DEG C of temperature
Degree heat preservation to water content is obtain object gross mass 35%, i.e. acquisition kinematic viscosity 60mm2The thick latex solution of/s, this is sticky
Shape latex solution is required efflorescence prevention high-bond sandstone packet water multicolor finish.
After efflorescence prevention high-bond sandstone packet water multicolor finish use by the present embodiment production, water resistance is up to immersion
150h is without cracking, peeling, discoloration, and the 96h that soaks in the pickle of pH value 2-3 is without cracking, peeling, discoloration, and stain resistant is by mark
It is not higher than 1 grade after 5 circulations of quasi- test, artificial ageing resistance performance accelerated test 2000h do not crack, peeling, 0 grade of dusting, discoloration 0
Grade (similarly hereinafter).
Embodiment 2:
It is whole consistent with embodiment 1, it is in place of difference:
A kind of efflorescence prevention high-bond sandstone packet water multicolor finish, the component of the multicolor finish is by weight by three kinds of functional groups
Part and the deionized water composition for accounting for coating total weight 30%, wherein the first function component A is changed through rosin pentaerythritol ester 8Kg
Property, the acrylic acid and acrylonitrile, styrene prepared using acrylic resin 35Kg, acrylonitrile 15Kg, styrene 15Kg as raw material
Graft copolymer；Float stone the basalt powder 30Kg and partial size 0.1mm- that second of function component B is partial size 0.1mm-0.2mm
The quartzite powder 20Kg of 0.2mm；The third function component C is glass microballoon 6Kg and silver powder 2Kg；The composition of three kinds of compositions
Relationship are as follows: component C and component B in the form of solid powder disperse in component A micelle micel or it is muddy in deionized water.
The manufacturing method of above-mentioned efflorescence prevention high-bond sandstone packet water multicolor finish, comprising the following steps:
1) prepare before production
1. raw material prepare: by weight preparation float stone basalt 30Kg, quartzite 20Kg, glass microballoon 6Kg, silver powder 2Kg,
Rosin pentaerythritol ester 8Kg, acrylic resin 35Kg, acrylonitrile 15Kg, styrene 15Kg, dodecyl sodium sulfate 1Kg, tertiary fourth
Base hydrogen peroxidase 10 .3Kg, sodium peroxydisulfate 0.3Kg, EDETATE SODIUM 3Kg, frerrous chloride 3Kg；
2) preparation of substrate latex liquid
2. using 1.5 times of the stage 1 of substrate latex total weight) deionized water that 2. prepares of step as diluent, by substrate latex with
The mixed liquor uniform stirring of deionized water, until substrate latex is completely dissolved in deionized water, that is, substrate latex liquid needed for obtaining；
4) coating synthesizes
2. the stage 3 is added dropwise with the rate of G/1000s in 1. prefabricated dirty solution that step obtains based on the quality G of dirty solution) step
Suddenly the function additive 1. prepared obtains matrix stoste until being added dropwise to complete；
3. the first stage carries out initiation polymerization with tert-butyl hydroperoxide in 2. matrix stoste that step obtains；Second stage
Secondary initiation polymerization is carried out by initiator of sodium peroxydisulfate；After the completion of secondary initiation polymerization, starting the dropwise addition stage 1) step is 1.
The drop rate of the rosin pentaerythritol ester of preparation, rosin pentaerythritol ester is G/500s, after being added dropwise to complete, with 200 DEG C of temperature
Degree heat preservation to water content is obtain object gross mass 30%, i.e. acquisition kinematic viscosity 80mm2The thick latex solution of/s, this is sticky
Shape latex solution is required efflorescence prevention high-bond sandstone packet water multicolor finish.
The foregoing description of the disclosed embodiments, only for can be realized professional and technical personnel in the field or use this
Invention.Various modifications to these embodiments will be readily apparent to those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention will not be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (2)
1. a kind of manufacturing method of efflorescence prevention high-bond sandstone packet water multicolor finish, it is characterised in that the following steps are included:
1) prepare before production
1. raw material prepare: preparation 30 parts -35 parts of float stone basalt, 20 parts -25 parts of quartzite, 6 parts of glass microballoon-by weight
8 parts, 2 parts -3 parts of silver powder, 8 parts -10 parts of rosin pentaerythritol ester, 30 parts -35 parts of acrylic resin, 15 parts -20 parts of acrylonitrile,
15 parts -20 parts of styrene, 1 part -1.5 parts of dodecyl sodium sulfate, 0.3 part -0.5 part of tert-butyl hydroperoxide, sodium peroxydisulfate 0.3
Part -0.5 part, 3 parts -5 parts of EDETATE SODIUM, 3 parts -5 parts of frerrous chloride；
2. auxiliary material prepares: preparing Enough Dl water；
2) preparation of substrate latex liquid
1. using the stage 1) acrylic resin that 1. prepares of step is raw material, and it is to help with EDETATE SODIUM using frerrous chloride as initiator
Agent prepares substrate latex using dodecyl sodium sulfate as emulsifier；
2. using 1.5 times -1.8 times of the stage 1 of substrate latex total weight) deionized water that 2. prepares of step is diluent, by matrix
The mixed liquor uniform stirring of latex and deionized water, until substrate latex is completely dissolved in deionized water, that is, matrix glue needed for obtaining
Lotion；
3) preparation of functional auxiliary materials
1. using the stage 1) step 1. prepare acrylonitrile, styrene as raw material, heat obtains organic liquor after melting, the organic liquor be function
Auxiliary agent；
2. by the stage 1) step 1. prepare float stone basalt, quartzite mechanical lapping at partial size 0.1mm-0.2mm powder, so
Afterwards by the float stone basalt powder of acquisition, quartzite powder and stage 1) glass microballoon that 1. prepares of step and silver powder mix simultaneously
It stirs evenly, obtains function mixed-powder；
4) coating synthesizes
1. in the stage 2) whole stages 3 are added in the substrate latex liquid that obtains) the function mixed-powder that 2. prepares of step, stirring is equal
Prefabricated dirty solution is obtained after even；
2. being added dropwise in 1. prefabricated dirty solution that step obtains based on the quality G of dirty solution with the rate of G/1000s-G/1200s
Stage 3) function additive that 1. prepares of step until being added dropwise to complete obtains matrix stoste；
3. the first stage carries out initiation polymerization with tert-butyl hydroperoxide in 2. matrix stoste that step obtains；Second stage
Secondary initiation polymerization is carried out by initiator of sodium peroxydisulfate；After the completion of secondary initiation polymerization, starting the dropwise addition stage 1) step is 1.
The drop rate of the rosin pentaerythritol ester of preparation, rosin pentaerythritol ester is G/500s-G/600s, after being added dropwise to complete, with
200-220 DEG C of temperature to water content is the 30%-35% for obtaining object gross mass, i.e. acquisition kinematic viscosity 60mm2/s-
80mm2The thick latex solution of/s, the thick latex solution are required efflorescence prevention high-bond sandstone packet water multicolor finish.
2. a kind of efflorescence prevention high-bond sandstone packet water multicolor finish, it is characterised in that: the component of the multicolor finish is by weight
Meter is by three kinds of function components and accounts for the deionized water of coating total weight 30%-35% and forms, and wherein the first function component A is through season
Penta 8 parts -10 parts of tetrol rosin ester is modified, with 30 parts -35 parts of acrylic resin, 15 parts -20 parts of acrylonitrile, 15 parts of styrene -
20 parts are the acrylic acid of raw material preparation and the graft copolymer of acrylonitrile, styrene；Second of function component B is partial size 0.1mm-
20 parts -25 parts of quartzite powder of 30 parts -35 parts of the float stone basalt powder of 0.2mm and partial size 0.1mm-0.2mm；The third function
Energy component C is 6 parts -8 parts and 2 parts -3 parts of silver powder of glass microballoon；The component relationship of three kinds of compositions are as follows: component C and component B are with solid
The form disperse of body powder in component A micelle micel or it is muddy in deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811473861.6A CN109627894A (en) | 2018-12-04 | 2018-12-04 | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811473861.6A CN109627894A (en) | 2018-12-04 | 2018-12-04 | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109627894A true CN109627894A (en) | 2019-04-16 |
Family
ID=66070992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811473861.6A Pending CN109627894A (en) | 2018-12-04 | 2018-12-04 | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109627894A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1117509A (en) * | 1994-08-24 | 1996-02-28 | 苏州市建筑科学研究所 | Water-in-water type multi-color decorative pattern paint |
| CN1130663A (en) * | 1995-12-27 | 1996-09-11 | 吴钢 | Cloud paint and preparation process thereof |
| CN103570882A (en) * | 2013-11-01 | 2014-02-12 | 杭州华创实业有限公司 | ASA (acrylonitrile styrene acrylate) graft copolymerization resin rubber powder and preparation method thereof |
| JP2018104535A (en) * | 2016-12-26 | 2018-07-05 | Dic株式会社 | Aqueous resin composition, coating agent and article |
-
2018
- 2018-12-04 CN CN201811473861.6A patent/CN109627894A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1117509A (en) * | 1994-08-24 | 1996-02-28 | 苏州市建筑科学研究所 | Water-in-water type multi-color decorative pattern paint |
| CN1130663A (en) * | 1995-12-27 | 1996-09-11 | 吴钢 | Cloud paint and preparation process thereof |
| CN103570882A (en) * | 2013-11-01 | 2014-02-12 | 杭州华创实业有限公司 | ASA (acrylonitrile styrene acrylate) graft copolymerization resin rubber powder and preparation method thereof |
| JP2018104535A (en) * | 2016-12-26 | 2018-07-05 | Dic株式会社 | Aqueous resin composition, coating agent and article |
Non-Patent Citations (3)
| Title |
|---|
| 张新宇等: "基于BA/St/AN共聚乳液的水性防锈涂料研究 ", 《材料保护》 * |
| 曹高华等: "《AAS/DMPA对水性聚氨酯胶膜结晶性能的影响》", 《化工学报》 * |
| 石安富等: "《工程塑料手册》", 31 March 2003, 上海科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101250345B (en) | Method for preparing natural sliver paint | |
| CN102070310B (en) | Novel stone-like paint and preparation method thereof | |
| CN103450767A (en) | Super-weather-resistant anti-fouling real stone paint | |
| CN101250361B (en) | Anti-cracking environment-protection paint and method for preparing the same | |
| CN103740177A (en) | Development of super weather-proof marble coating rock slice paint | |
| CN101255049A (en) | Flexible tapestry brick of external wall outer insulation system and production method thereof | |
| CN101638544A (en) | Coating for forming flexible imitation marble facing and preparation method thereof | |
| CN104559788A (en) | Base paint of litchi surface stone-like paint and preparation method of base paint | |
| CN102863898B (en) | Cracking resistance texture coating preparation method and goods thereof | |
| CN109593417A (en) | A kind of coating aggregate, coating and its preparation method and application | |
| CN101265391A (en) | Colorful drying powder wall paint with marble effect | |
| CN103660425B (en) | A kind of preparation method of the colour-fast wood-like sheet of high intensity | |
| CN101607805B (en) | Sand wall sand textured architectural coating and production technology thereof | |
| CN105219198B (en) | A kind of heat-insulating, fire-preventing stone-like coating | |
| CN110436831A (en) | A kind of lacquer and preparation method thereof | |
| CN101723705A (en) | Fully water based granite multicolor paint | |
| CN102719157A (en) | Spraying rubber cement for decoration and preparation method thereof | |
| CN104610831A (en) | Water-proof composite water-based exterior wall coating with good weatherability and preparation method of water-proof composite water-based exterior wall coating | |
| CN107573788A (en) | A kind of true mineral varnish coating of exterior wall | |
| CN109627894A (en) | A kind of efflorescence prevention high-bond sandstone packet water multicolor finish and its manufacturing method | |
| CN104650679A (en) | Outer wall decoration material of rock quartz slice paint and preparation technology of outer wall decoration material | |
| CN103449760A (en) | Development of high-grade elastic multi-color granite paint | |
| CN109627893A (en) | A kind of true stone simulated tile coating of anti-aging glare thermal-insulating type and its manufacturing method | |
| CN103468080A (en) | Preparation research of ultra weather-proof granite colorful paint | |
| CN113122089A (en) | Reflective heat-insulation composite rock slice paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190416 |