CN1103092A - Water-in-water type multi-colour figure paint - Google Patents
Water-in-water type multi-colour figure paint Download PDFInfo
- Publication number
- CN1103092A CN1103092A CN 93115122 CN93115122A CN1103092A CN 1103092 A CN1103092 A CN 1103092A CN 93115122 CN93115122 CN 93115122 CN 93115122 A CN93115122 A CN 93115122A CN 1103092 A CN1103092 A CN 1103092A
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- China
- Prior art keywords
- water
- type multi
- decorative pattern
- color decorative
- water type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000003973 paint Substances 0.000 title claims description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- -1 glycol fatty acid ester Chemical class 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012296 anti-solvent Substances 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 238000004581 coalescence Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 229920000620 organic polymer Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 3
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 2
- JCIIKRHCWVHVFF-UHFFFAOYSA-N 1,2,4-thiadiazol-5-amine;hydrochloride Chemical compound Cl.NC1=NC=NS1 JCIIKRHCWVHVFF-UHFFFAOYSA-N 0.000 claims description 2
- WGIMXKDCVCTHGW-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCO WGIMXKDCVCTHGW-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- LBPACUJFGRCWDF-UHFFFAOYSA-L Cl[Mg]Cl.[Na] Chemical compound Cl[Mg]Cl.[Na] LBPACUJFGRCWDF-UHFFFAOYSA-L 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229920006026 co-polymeric resin Polymers 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229940096826 phenylmercuric acetate Drugs 0.000 claims description 2
- 229920005990 polystyrene resin Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 229920003987 resole Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 2
- 239000001593 sorbitan monooleate Substances 0.000 claims description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 2
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- 239000000084 colloidal system Substances 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000004816 latex Substances 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000287127 Passeridae Species 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- PEJVLWCOQVHCAF-UHFFFAOYSA-N dioctyl oxalate Chemical compound CCCCCCCCOC(=O)C(=O)OCCCCCCCC PEJVLWCOQVHCAF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invented coating utilizes the emulsifying technology and solubility resisting technology simultaneously. Through the lipophilicity emulgent and resin the aqueous film forming material, pigment and filler etc. are emulsified into stringy colour colloid, then dispersed in the water solution of protective gum to form into colour pattern coating. Said coating has the same decorating result of oil-in-water type multi-colour pattern coating, but the productive equipment needed is greatly decreased and the productive technological process is much simplified and the productive cost lowers down about 60%.
Description
The present invention relates to a kind of coating, a kind of water-in-water type multi-color decorative pattern paint of more specifically saying so.
Along with improving constantly of living standards of the people and building decoration standard, the early 1990s, China has introduced the oil-in-water-type coating of multi-colour pattern of the U.S. and Japan, this coating once is sprayed on the chromatic pattern that can obtain multiple color on the metope, and with rich color, decorate luxurious and good washable and wipe and stain resistance is subjected to consumers in general's welcome.But the main raw material nitro-cotton of this oil-in-water-type coating of multi-colour pattern is inflammable and explosive, and production unit is many, complex manufacturing, production cost are higher, also must use a large amount of noxious solvents.Therefore, domesticly develop a kind of water-in-water type multi-color decorative pattern paint again on this basis, build worker institute and Suzhou building materials institute as Beijing.But mostly be sparrow pecked on the metope because the water-in-water type multi-color decorative pattern paint of domestic present exploitation is sprayed on, compare with the oil-in-water-type colo(u)r coating, its decorative effect difference is bigger, and effect is undesirable, so the user still has a preference for the oil-in-water-type coating of multi-colour pattern.
The objective of the invention is to produce a kind of decorative effect water-in-water type multi-color decorative pattern paint suitable, and can simplify production technique, reduce production unit, reduce production costs significantly with the oil-in-water-type coating of multi-colour pattern.
Purpose of the present invention can realize by the following method:
A kind of water-in-water type multi-color decorative pattern paint mainly is made up of waterborne film-forming material, filler, auxiliary agent, lipophilic emulsifier, resin, protection glue, pigment and water.Its weight proportion is:
Waterborne film-forming material: 9～45%
Filler: 1.5～11%
Auxiliary agent: 1.8～9%
Lipophilic emulsifier: 0.4～4%
Resin: 5～18%
Protection glue: 0.2～4%
Water: 40～72%
Pigment: a little is an amount of
Said waterborne film-forming material is a kind of mixed type organic polymer water emulsion, it is the main film forming substance of this coating, has strong adhesion, advantages such as degree of scatter is easy to control, adaptable organic polymer water miscible liquid has chlorine partial emulsion, benzene emulsion, polyvinyl acetate emulsion, ethene-vinyl acetate copolymer emulsion, ethylene-acrylate copolymer emulsion, ethylene-propylene acid derivative copolymer emulsion.
Said filler can be zinc sulfide white, titanium dioxide, mica powder, wollastonite powder, talcum powder and light calcium carbonate.
Said lipophilic emulsifier and resin, its effect one is with the emulsification of waterborne film-forming material, coating, avoids colour contamination in the protection glue solution; the 2nd, the toughness of raising color latex body; so that its dispersion becomes the color grain of strand shape, in addition, they are also as complementary filmogen.Lipophilic emulsifier is oleophilic hydrophil balance value less than 8 tensio-active agent, can be Zerol, glycol fatty acid ester, sorbitan monooleate, Diethylene Glycol mono-laurate.The resin of using with mentioned emulsifier can be resol, Synolac, vibrin, polystyrene resin, polyvinyl acetal resin, ethene-vinyl acetate copolymer resins; In addition, also can use fatty acid ester and siccative oil.
Said protection glue solution, its effect are that the discontinuous phase color latex body of different colours is disperseed the color grain that becomes shape and vary in size, and colour contamination, not coalescent mutually or not, so that spraying application.Can with protection glue Natvosol, propyloic fiber, carboxymethyl cellulose, modified polyethylene alcohol, modified polyethylene acetal are arranged.
Said auxiliary agent comprises film coalescence aid, softening agent, anti-solvent, mould inhibitor, sanitas and defoamer etc., its objective is snappiness and the stability of discontinuous phase in external phase for the film-forming properties that improves this coating, levelling property, discontinuous phase color latex body.Film coalescence aid can be ethylene glycol, propylene glycol, Pyranton, ethylene glycol ethyl ether and butyl glycol ether; Softening agent can be dibutyl phthalate, Tritolyl Phosphate, oxalic acid dioctyl ester, clorafin and glycerol; Anti-solvent can be boric acid, borax, contain the clay of montmorillonite, silicon sol, sal epsom, Tai-Ace S 150, sodium-chlor, magnesium chloride, calcium chloride, ammonium phosphate and tertiary sodium phosphate; Mould inhibitor can be Phenylmercuric Acetate, tributyl tin, sodium pentachlorophenate and 75
#Mould inhibitor; Sanitas can be phenol, formaldehyde, Sodium Benzoate.
Production process of the present invention is: waterborne film-forming material, filler, auxiliary agent and pigment are mixed, grind; add lipophilic emulsifier and resin then; emulsification becomes the color latex body; under the stepless speed regulation stirring action color latex body is being disperseed to become the color grain of the strand shape that differs in size in the protection glue solution then; the color grain of varicolored strand shape mixes in another kind protection glue solution, promptly becomes oil-in-water type water bag water coating of multi-colour pattern.
The oil-in-water type water bag water coating of multi-colour pattern that adopts the present invention to produce, its decorative effect is suitable with the oil-in-water-type coating of multi-colour pattern, and the technical performance index of product meets Japanese JISK-5667 standard, and its production technique is simple, facility investment is few, and product cost reduces significantly.
Embodiments of the invention:
1. the preparation of color latex body:
A. fill a prescription (weight ratio %):
Composite white latex 30 benzene emulsions 15
Light calcium carbonate 10 auxiliary agents 5
Water 33 emulsifying agents 2
Resin liquid 5 pigment are an amount of
B. technology: composite white latex, benzene emulsion, light calcium carbonate, water, pigment and auxiliary agent are mixed, grind, thickening, join then in the mixed solution of emulsifying agent and resin liquid and stir, carry out emulsification, promptly become colored emulsifying collid after 15～20 minutes.
2. the preparation of protection glue:
A. fill a prescription (weight ratio %):
Glue 95 auxiliary agents 5
B. technology: under agitation auxiliary agent is joined in the glue successively, mix and get final product.
3. making of oil-in-water type water bag water coating of multi-colour pattern:
A. fill a prescription (weight ratio %):
Color latex body 48 protection glue solutions 52
B. technology: under the effect that stepless speed regulation is stirred; the color latex body joins in the dispersion medium with the thread shape at leisure; different according to stirring velocity and churning time; promptly form the color grains that differs in size; varicolored color grain is joined another kind of the protection in the glue solution in proportion mix, can make coating of multi-colour pattern.
Claims (9)
1, a kind of water-in-water type multi-color decorative pattern paint suitable with oil-in-water-type coating of multi-colour pattern decorative effect; it is characterized in that it mainly is made up of waterborne film-forming material, filler, auxiliary agent, lipophilic emulsifier, resin, protection glue, pigment and water, its weight ratio is:
Waterborne film-forming material: 9～45%; Filler: 1.5～11%;
Auxiliary agent: 1.8～9%; Lipophilic emulsifier: 0.4～4%;
Resin: 5～18%; Protection glue: 0.2～4%;
Water: 40～72%; Pigment: a little is an amount of.
2, water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described waterborne film-forming material mainly is made up of several organic polymer water miscible liquids.
3, according to claim 1,2 described water-in-water type multi-color decorative pattern paints, it is characterized in that: described organic polymer water miscible liquid is selected for use: chlorine partial emulsion, benzene emulsion, polyvinyl acetate emulsion, ethene-vinyl acetate copolymer emulsion, ethylene-acrylate copolymer emulsion and ethylene-propylene acid derivative copolymer emulsion.
4, water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described filler is selected zinc sulfide white, titanium dioxide, mica powder, wollastonite powder, talcum powder and light calcium carbonate for use.
5, water-in-water type multi-color decorative pattern paint according to claim 1, it is characterized in that: described lipophilic emulsifier is an oleophilic hydrophil balance value less than 8 tensio-active agent, selects Zerol, glycol fatty acid ester, sorbitan monooleate, Diethylene Glycol mono-laurate for use.
6, water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described resin is selected resol, Synolac, vibrin, polystyrene resin, polyalkenylalcohols Derlin, ethene-vinyl acetate copolymer resins for use; In addition, also can use fatty acid ester and dryness white.
7, water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described protection glue is selected Natvosol, propyloic fiber, carboxymethyl cellulose for use, the pure and mild modified polyethylene acetal of modified polyethylene.
8, water-in-water type multi-color decorative pattern paint according to claim 1 is characterized in that: described auxiliary agent comprises film coalescence aid, softening agent, anti-solvent, mould inhibitor, sanitas and defoamer.
9, according to claim 1,8 described water-in-water type multi-color decorative pattern paints, it is characterized in that: film coalescence aid is selected ethylene glycol, propylene glycol, Pyranton, ethylene glycol ethyl ether and butyl glycol ether for use; Softening agent is selected phthalic acid, dibutylester, Tritolyl Phosphate, ethylene glycol bisthioglycolate monooctyl ester, clorafin and glycerol for use; Anti-solvent is selected boric acid, borax for use, is contained the clay of montmorillonite, sal epsom, silicon sol, Tai-Ace S 150, sodium-chlor, magnesium chloride, calcium chloride, ammonium phosphate and tertiary sodium phosphate; Mould inhibitor is selected Phenylmercuric Acetate, tributyl tin, sodium pentachlorophenate and 75 for use
#Mould inhibitor; Sanitas is selected phenol, formaldehyde, Sodium Benzoate for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93115122 CN1103092A (en) | 1993-11-26 | 1993-11-26 | Water-in-water type multi-colour figure paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93115122 CN1103092A (en) | 1993-11-26 | 1993-11-26 | Water-in-water type multi-colour figure paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1103092A true CN1103092A (en) | 1995-05-31 |
Family
ID=4990811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93115122 Pending CN1103092A (en) | 1993-11-26 | 1993-11-26 | Water-in-water type multi-colour figure paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1103092A (en) |
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| CN100593031C (en) * | 2008-08-12 | 2010-03-03 | 无锡市虎皇漆业有限公司 | Full-aqueous imitated marble granite paint and preparation thereof |
| CN101429368B (en) * | 2008-12-06 | 2011-07-20 | 王月琴 | Method for producing water-in-water type multicolor paint |
| CN102690567A (en) * | 2012-06-01 | 2012-09-26 | 安徽省金盾涂料有限责任公司 | Aqueous multicolor paint and preparation method thereof |
| CN102850856A (en) * | 2012-09-03 | 2013-01-02 | 南通市兴宇漆业有限责任公司 | Aqueous multi-color coating material |
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| CN104151983A (en) * | 2014-08-20 | 2014-11-19 | 吴江华诚复合材料科技有限公司 | Two aqueous phase colorful pattern paint |
| CN104178002A (en) * | 2014-08-20 | 2014-12-03 | 吴江华诚复合材料科技有限公司 | Oil-in-oil alkyd resin multicolor internal wall paint |
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| CN104592854A (en) * | 2015-01-05 | 2015-05-06 | 王红玉 | Thermal insulation coating for building exterior wall |
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1993
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| CN104592854A (en) * | 2015-01-05 | 2015-05-06 | 王红玉 | Thermal insulation coating for building exterior wall |
| CN104974576A (en) * | 2015-08-03 | 2015-10-14 | 苏州舒而适纺织新材料科技有限公司 | Quick-drying waterborne multicolor paint |
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