CN1354211A - Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material - Google Patents
Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material Download PDFInfo
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- CN1354211A CN1354211A CN 01139089 CN01139089A CN1354211A CN 1354211 A CN1354211 A CN 1354211A CN 01139089 CN01139089 CN 01139089 CN 01139089 A CN01139089 A CN 01139089A CN 1354211 A CN1354211 A CN 1354211A
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- fluorosilicate
- weatherability
- water
- nano sol
- antifouling paint
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Abstract
The present invention relates to a water fluorine silicon acrylic acid nano collosol superweatherability pollution-resisting coating material for coating decoration of internal wall and external wall of buildings and for coating decoration of the materials of concrete, plasterboard, wood-fibre board and metal. It is characterized by that it uses water fluorocarbon emulsion, acrylic acid emulsion and self-crosslinked organosilicon modified polyacrylic emulsion to form main film-forming material, and mixes it with nano material. Besides, said coating material also possesses good air permeability, and can meet the requirements for environment.
Description
Technical field
Water propyl fluorosilicate nano sol weatherability antifouling paint of the present invention relates to a kind of coating material, is mainly used in the application of building inner, external wall, also can be applied to the application of materials such as concrete, plasterboard, wood fibre board and metal.
Background technology
The developing direction of building coating be high-decoration, strong resistance to soiling, high-durability and save resource, save the energy, nuisanceless, pollution-free, be beneficial to environmental protection, meet the requirement of Sustainable development.Consider from ornamental and the competent angle of resistant, the solvent based coating ratio is easier to meet the demands, as solvent-type acrylic coating, especially recently the solvent-borne type fluorocarbon coating that develops, its anti-contamination, ageing resistance have reached quite high level, but its solvent load is many, toxicity big, the coating ventilation property is poor, easily peeling peels off; Latex coatings such as water-borne coatings such as water-borne acrylic type, water-base epoxy class, waterborne polyester class and water-based silicon Class C, its contamination resistance, resistance to deterioration etc. are real in solvent based coating.For the contamination resistance, the resistance to deterioration that improve coating with improve its environmental-protecting performance, that realizes coating high-performance and the feature of environmental protection combines proposition the present invention.
Summary of the invention
The objective of the invention is to: provide a kind of ambient cure from layering water propyl fluorosilicate nano sol weatherability antifouling paint.To improve coating contamination resistance, resistance to deterioration and to improve its environmental-protecting performance.
Purpose of the present invention can be achieved through the following technical solutions: with the filmogen of water-base fluorocarbon emulsion and water-borne acrylic type emulsion composition, and mix nano material, achieve ambient cure from stratified water propyl fluorosilicate nano sol weatherability antifouling paint.The present invention can form main film forming substance by the organic-silicon-modified acrylic emulsions of water-base fluorocarbon emulsion, acrylic emulsions and self-cross linking type, and mixes nano material.Wherein, described nano material is SiO at least
2, TiO
2In a kind of.
The present invention fills a prescription as follows:
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.30--0.45
Nanometer SiO
2Slurry (SiO
2Content 10-15%) 0.00--0.80
Nano-TiO
2Slurry (TiO
2Content 10-15%) 0.00--0.80
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling breast 0.10--1.00
Special addition agent 0.45--1.00
In the present invention prescription, described wetting agent is non-ionic type Soxylat A 25-7s such as polyoxyethylene tetrafluoro carbon ether, Voranol EP 2001, and in the anionic alkyl hydrochlorates such as sodium alkyl benzene sulfonate, sodium alkyl sulfate one or more; Described dispersion agent is one or more in polyacrylic acid sodium salt, amine salt or the oleoyl epoxy alkane segmented copolymer; Described Antisepticize and mildew preventive is one or more in the aminated compoundss such as heterogeneous ring compounds such as benzoglyoxaline amino acid ester, benzisothiazole ketone or sulfo-amino acid esters, Salicylanlide, tetramethyl-thiuram disulfide; Described film coalescence aid is dibasic alcohol and ether compounds thereof such as propylene glycol, propylene glycol butyl ether, propylene glycol phenylate, or 2,2,2-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate; Described organic amine auxiliary agent is one or more in dimethylethanolamine, the 2-amino-2-methyl-1-propanol; Described defoamer is for containing the non-silicone Dormant oils of hydrophobic particles mixture; Described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin; Described special addition agent is one or more in polyether modified siloxane, the nonionic polyurethane.
The present invention carries out blend with water-base fluorocarbon emulsion and acrylic emulsions and the organic-silicon-modified acrylic emulsions of self-cross linking type, introduces nanometer SiO
2And nano-TiO
2Functional materials is made the good latex coating of package stability.Wherein, described nano material is SiO at least
2, TiO
2In a kind of.This coating is done in the solid process in film forming, and blending resin is owing to the polarity difference, and surface energy produces gradient from layering.Have the acrylic resin of C-C key and C-Si (C-Ti) key or organic-silicon-modified acrylic resin to basic unit's enrichment, form excellent adhesion basic unit; Fluorine carbon resin with F-C key is to the enrichment of air surface layer, makes film coated surface present excellent specific properties such as the super weather-proof resistant of fluorine resin coating and scratch resistance, wear-resisting, water-fast acid-and base-resisting.The comprehensive Practical Performance of coating promotes significantly like this, significantly reduces according to expensive fluoro-resin consumption, and cost reduces coating and has the good ratio of performance to price.
Technological process of the present invention is as follows: the first step: add weight part in container
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Stirring velocity is transferred to 500-600 rev/min, under whipped state, drops into following material successively:
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.20--0.30
Nanometer SiO
2Slurry (SiO
2Content 10-15%) 0.00--0.24
Nano-TiO
2Slurry (TiO
2Content 10-15%) 0.00--0.24
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Feeding intake finishes, and stirring velocity is promoted to 800-1000 rev/min again, high-speed stirring 30-40 minute, makes fineness≤15 μ m.Second step: after fineness of dispersion reaches requirement, stirring velocity is transferred to 400-500 rev/min drop into following material successively
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling emulsion 0.10--1.00
Special addition agent 0.45--1.00
Defoamer 0.10--0.15
Feeding intake finishes, and dispersed with stirring 30--40 minute, material is uniformly dispersed, use the filtration of 80--100 order nylon cloth again, pack, finished product.
Coating of the present invention had both had the super-weathering resistance and strong contamination resistance of solvent based coating excellence, had the good ventilation property and the environmental requirement of the unapproachable water-borne coatings of solvent based coating simultaneously.
Embodiment embodiment 1, and its proportioning of normal temperature solidifying water white paint is weight part (amounting to 1000Kg)
Water 124.00
Wetting agent (polyoxyethylene tetrafluoro carbon ether) 0.10
Dispersion agent (poly amic acid salt solid content body 30%) 5.00
Antisepticize and mildew preventive (isothiazolinone) 1.90
Propylene glycol 25.00
Propylene glycol phenylate 8.00
2-amino-2-methyl-1-propanol 2.00
Non-silicone mineral oil 3.50
Nano-TiO
2Slurry (solid content 12%) 3.50
Rutile type Titanium Dioxide 220.00
Wax powder (particle diameter 7 μ m) 30.00
Silicon-dioxide 20.00
Urine-methyl alcohol resin 10.00
Water-base fluorocarbon emulsion (solid content 50%) 150.00
Self-crosslinking organosilicon-modified acrylic emulsion (solid content 48%)
390.00
Alkali swells polypropylene yogurt liquid 3.00
Polyether modified siloxane 2.00
Nonionic urethane resin 2.00 abrasion resistances 〉=10000 times, the coating freeze-thaw resistance never degenerates, and the coating heatproof changes (10 times) no change.Embodiment 2, and its proportioning of the normal temperature solidifying water clear lacquer is weight part (amounting to 100Kg)
Water 15.60
Wetting agent (polyoxyethylene tetrafluoro carbon ether) 0.12
Dispersion agent (poly amic acid salt) 0.18
Antisepticize and mildew preventive (isothiazolinone) 0.10
Propylene glycol 2.30
Propylene glycol butyl ether 3.50
2-amino-2-methyl-1-propanol 0.14
Non-silicone mineral oil 0.18
Nanometer SiO
2Slurry (solid content 12%) 0.30
Rutile type Titanium Dioxide 220.00
Wax powder (particle diameter 7 μ m) 1.44
Silicon-dioxide 20.00
Urine-methyl alcohol resin 3.60
Water-base fluorocarbon emulsion (solid content 50%) 18.00
Self-crosslinking organosilicon-modified acrylic emulsion (solid content 48%)
54.00
Alkali swells polypropylene yogurt liquid 0.18
Polyether modified siloxane 0.14
Nonionic urethane resin 0.22 performance is close with embodiment 1, head and shoulders above national standard.
Claims (11)
1, the water propyl fluorosilicate nano sol weatherability antifouling paint is characterised in that: form main film forming substance by the acrylic emulsions that water-base fluorocarbon emulsion, acrylic emulsions and self-cross linking type are organic-silicon-modified, and mix nano material.
2, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 1 is characterised in that: described nano material is SiO at least
2, TiO
2In a kind of.
3, according to claim 1,2 described water propyl fluorosilicate nano sol weatherability antifouling paints, be characterised in that:
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.30--0.45
Nanometer SiO
2Slurry (SiO
2Content 10-15%) 0.00--0.80
Nano-TiO
2Slurry (TiO
2Content 10-15%) 0.00--0.80
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling emulsion 0.10--1.00
Special addition agent 0.45--1.00
4, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3, be characterised in that: described wetting agent is non-ionic type Soxylat A 25-7s such as polyoxyethylene tetrafluoro carbon ether, Voranol EP 2001, and in the anionic alkyl hydrochlorate such as sodium alkyl benzene sulfonate, sodium alkyl sulfate one or more.
5, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described dispersion agent is one or more in polyacrylic acid sodium salt, amine salt or the oleoyl epoxy alkane segmented copolymer.
6, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described Antisepticize and mildew preventive is one or more in the aminated compoundss such as heterogeneous ring compounds such as benzoglyoxaline amino acid ester, benzisothiazole ketone or sulfo-amino acid esters, Salicylanlide, tetramethyl-thiuram disulfide.
7, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3, be characterised in that: described film coalescence aid is dibasic alcohol and ether compounds thereof such as propylene glycol, propylene glycol butyl ether, propylene glycol phenylate, or 2,2,2-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate.
8, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described organic amine auxiliary agent is one or more in dimethylethanolamine, the 2-amino-2-methyl-1-propanol.
9, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described defoamer is for containing the non-silicone Dormant oils of hydrophobic particles mixture.
10, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin.
11, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described special addition agent is one or more in polyether modified siloxane, the nonionic polyurethane.
Priority Applications (1)
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---|---|---|---|
CN 01139089 CN1354211A (en) | 2001-12-07 | 2001-12-07 | Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01139089 CN1354211A (en) | 2001-12-07 | 2001-12-07 | Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material |
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CN 01139089 Pending CN1354211A (en) | 2001-12-07 | 2001-12-07 | Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material |
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-
2001
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