CN1354211A - Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material - Google Patents

Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material Download PDF

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Publication number
CN1354211A
CN1354211A CN 01139089 CN01139089A CN1354211A CN 1354211 A CN1354211 A CN 1354211A CN 01139089 CN01139089 CN 01139089 CN 01139089 A CN01139089 A CN 01139089A CN 1354211 A CN1354211 A CN 1354211A
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CN
China
Prior art keywords
fluorosilicate
weatherability
water
nano sol
antifouling paint
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Pending
Application number
CN 01139089
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Chinese (zh)
Inventor
张人韬
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Shanghai University
University of Shanghai for Science and Technology
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University of Shanghai for Science and Technology
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Priority to CN 01139089 priority Critical patent/CN1354211A/en
Publication of CN1354211A publication Critical patent/CN1354211A/en
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Abstract

The present invention relates to a water fluorine silicon acrylic acid nano collosol superweatherability pollution-resisting coating material for coating decoration of internal wall and external wall of buildings and for coating decoration of the materials of concrete, plasterboard, wood-fibre board and metal. It is characterized by that it uses water fluorocarbon emulsion, acrylic acid emulsion and self-crosslinked organosilicon modified polyacrylic emulsion to form main film-forming material, and mixes it with nano material. Besides, said coating material also possesses good air permeability, and can meet the requirements for environment.

Description

The water propyl fluorosilicate nano sol weatherability antifouling paint
Technical field
Water propyl fluorosilicate nano sol weatherability antifouling paint of the present invention relates to a kind of coating material, is mainly used in the application of building inner, external wall, also can be applied to the application of materials such as concrete, plasterboard, wood fibre board and metal.
Background technology
The developing direction of building coating be high-decoration, strong resistance to soiling, high-durability and save resource, save the energy, nuisanceless, pollution-free, be beneficial to environmental protection, meet the requirement of Sustainable development.Consider from ornamental and the competent angle of resistant, the solvent based coating ratio is easier to meet the demands, as solvent-type acrylic coating, especially recently the solvent-borne type fluorocarbon coating that develops, its anti-contamination, ageing resistance have reached quite high level, but its solvent load is many, toxicity big, the coating ventilation property is poor, easily peeling peels off; Latex coatings such as water-borne coatings such as water-borne acrylic type, water-base epoxy class, waterborne polyester class and water-based silicon Class C, its contamination resistance, resistance to deterioration etc. are real in solvent based coating.For the contamination resistance, the resistance to deterioration that improve coating with improve its environmental-protecting performance, that realizes coating high-performance and the feature of environmental protection combines proposition the present invention.
Summary of the invention
The objective of the invention is to: provide a kind of ambient cure from layering water propyl fluorosilicate nano sol weatherability antifouling paint.To improve coating contamination resistance, resistance to deterioration and to improve its environmental-protecting performance.
Purpose of the present invention can be achieved through the following technical solutions: with the filmogen of water-base fluorocarbon emulsion and water-borne acrylic type emulsion composition, and mix nano material, achieve ambient cure from stratified water propyl fluorosilicate nano sol weatherability antifouling paint.The present invention can form main film forming substance by the organic-silicon-modified acrylic emulsions of water-base fluorocarbon emulsion, acrylic emulsions and self-cross linking type, and mixes nano material.Wherein, described nano material is SiO at least 2, TiO 2In a kind of.
The present invention fills a prescription as follows:
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.30--0.45
Nanometer SiO 2Slurry (SiO 2Content 10-15%) 0.00--0.80
Nano-TiO 2Slurry (TiO 2Content 10-15%) 0.00--0.80
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling breast 0.10--1.00
Special addition agent 0.45--1.00
In the present invention prescription, described wetting agent is non-ionic type Soxylat A 25-7s such as polyoxyethylene tetrafluoro carbon ether, Voranol EP 2001, and in the anionic alkyl hydrochlorates such as sodium alkyl benzene sulfonate, sodium alkyl sulfate one or more; Described dispersion agent is one or more in polyacrylic acid sodium salt, amine salt or the oleoyl epoxy alkane segmented copolymer; Described Antisepticize and mildew preventive is one or more in the aminated compoundss such as heterogeneous ring compounds such as benzoglyoxaline amino acid ester, benzisothiazole ketone or sulfo-amino acid esters, Salicylanlide, tetramethyl-thiuram disulfide; Described film coalescence aid is dibasic alcohol and ether compounds thereof such as propylene glycol, propylene glycol butyl ether, propylene glycol phenylate, or 2,2,2-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate; Described organic amine auxiliary agent is one or more in dimethylethanolamine, the 2-amino-2-methyl-1-propanol; Described defoamer is for containing the non-silicone Dormant oils of hydrophobic particles mixture; Described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin; Described special addition agent is one or more in polyether modified siloxane, the nonionic polyurethane.
The present invention carries out blend with water-base fluorocarbon emulsion and acrylic emulsions and the organic-silicon-modified acrylic emulsions of self-cross linking type, introduces nanometer SiO 2And nano-TiO 2Functional materials is made the good latex coating of package stability.Wherein, described nano material is SiO at least 2, TiO 2In a kind of.This coating is done in the solid process in film forming, and blending resin is owing to the polarity difference, and surface energy produces gradient from layering.Have the acrylic resin of C-C key and C-Si (C-Ti) key or organic-silicon-modified acrylic resin to basic unit's enrichment, form excellent adhesion basic unit; Fluorine carbon resin with F-C key is to the enrichment of air surface layer, makes film coated surface present excellent specific properties such as the super weather-proof resistant of fluorine resin coating and scratch resistance, wear-resisting, water-fast acid-and base-resisting.The comprehensive Practical Performance of coating promotes significantly like this, significantly reduces according to expensive fluoro-resin consumption, and cost reduces coating and has the good ratio of performance to price.
Technological process of the present invention is as follows: the first step: add weight part in container
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Stirring velocity is transferred to 500-600 rev/min, under whipped state, drops into following material successively:
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.20--0.30
Nanometer SiO 2Slurry (SiO 2Content 10-15%) 0.00--0.24
Nano-TiO 2Slurry (TiO 2Content 10-15%) 0.00--0.24
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Feeding intake finishes, and stirring velocity is promoted to 800-1000 rev/min again, high-speed stirring 30-40 minute, makes fineness≤15 μ m.Second step: after fineness of dispersion reaches requirement, stirring velocity is transferred to 400-500 rev/min drop into following material successively
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling emulsion 0.10--1.00
Special addition agent 0.45--1.00
Defoamer 0.10--0.15
Feeding intake finishes, and dispersed with stirring 30--40 minute, material is uniformly dispersed, use the filtration of 80--100 order nylon cloth again, pack, finished product.
Coating of the present invention had both had the super-weathering resistance and strong contamination resistance of solvent based coating excellence, had the good ventilation property and the environmental requirement of the unapproachable water-borne coatings of solvent based coating simultaneously.
Embodiment embodiment 1, and its proportioning of normal temperature solidifying water white paint is weight part (amounting to 1000Kg)
Water 124.00
Wetting agent (polyoxyethylene tetrafluoro carbon ether) 0.10
Dispersion agent (poly amic acid salt solid content body 30%) 5.00
Antisepticize and mildew preventive (isothiazolinone) 1.90
Propylene glycol 25.00
Propylene glycol phenylate 8.00
2-amino-2-methyl-1-propanol 2.00
Non-silicone mineral oil 3.50
Nano-TiO 2Slurry (solid content 12%) 3.50
Rutile type Titanium Dioxide 220.00
Wax powder (particle diameter 7 μ m) 30.00
Silicon-dioxide 20.00
Urine-methyl alcohol resin 10.00
Water-base fluorocarbon emulsion (solid content 50%) 150.00
Self-crosslinking organosilicon-modified acrylic emulsion (solid content 48%)
390.00
Alkali swells polypropylene yogurt liquid 3.00
Polyether modified siloxane 2.00
Nonionic urethane resin 2.00 abrasion resistances 〉=10000 times, the coating freeze-thaw resistance never degenerates, and the coating heatproof changes (10 times) no change.Embodiment 2, and its proportioning of the normal temperature solidifying water clear lacquer is weight part (amounting to 100Kg)
Water 15.60
Wetting agent (polyoxyethylene tetrafluoro carbon ether) 0.12
Dispersion agent (poly amic acid salt) 0.18
Antisepticize and mildew preventive (isothiazolinone) 0.10
Propylene glycol 2.30
Propylene glycol butyl ether 3.50
2-amino-2-methyl-1-propanol 0.14
Non-silicone mineral oil 0.18
Nanometer SiO 2Slurry (solid content 12%) 0.30
Rutile type Titanium Dioxide 220.00
Wax powder (particle diameter 7 μ m) 1.44
Silicon-dioxide 20.00
Urine-methyl alcohol resin 3.60
Water-base fluorocarbon emulsion (solid content 50%) 18.00
Self-crosslinking organosilicon-modified acrylic emulsion (solid content 48%)
54.00
Alkali swells polypropylene yogurt liquid 0.18
Polyether modified siloxane 0.14
Nonionic urethane resin 0.22 performance is close with embodiment 1, head and shoulders above national standard.

Claims (11)

1, the water propyl fluorosilicate nano sol weatherability antifouling paint is characterised in that: form main film forming substance by the acrylic emulsions that water-base fluorocarbon emulsion, acrylic emulsions and self-cross linking type are organic-silicon-modified, and mix nano material.
2, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 1 is characterised in that: described nano material is SiO at least 2, TiO 2In a kind of.
3, according to claim 1,2 described water propyl fluorosilicate nano sol weatherability antifouling paints, be characterised in that:
Water 12.00--14.00
Wetting agent 0.01--0.05
Dispersion agent 0.40--0.60
Antisepticize and mildew preventive 0.10--0.50
Film coalescence aid 3.00--4.50
Organic amine auxiliary agent 0.15--0.25
Defoamer 0.30--0.45
Nanometer SiO 2Slurry (SiO 2Content 10-15%) 0.00--0.80
Nano-TiO 2Slurry (TiO 2Content 10-15%) 0.00--0.80
Titanium dioxide (rutile-type is used for exterior wall, anatase titanium dioxide is used for interior wall)
0.00--24.00
Face, filler 0.00--24.00
Functional stuffing 2.00--8.00
Water-base fluorocarbon emulsion (solid content 40-55%) 10.00--20.00
Self-crosslinking organosilicon-modified acrylic emulsion and acrylic emulsions
(solid content 30-50%) 44.00--34.00
Propylene soda acid swelling emulsion 0.10--1.00
Special addition agent 0.45--1.00
4, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3, be characterised in that: described wetting agent is non-ionic type Soxylat A 25-7s such as polyoxyethylene tetrafluoro carbon ether, Voranol EP 2001, and in the anionic alkyl hydrochlorate such as sodium alkyl benzene sulfonate, sodium alkyl sulfate one or more.
5, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described dispersion agent is one or more in polyacrylic acid sodium salt, amine salt or the oleoyl epoxy alkane segmented copolymer.
6, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described Antisepticize and mildew preventive is one or more in the aminated compoundss such as heterogeneous ring compounds such as benzoglyoxaline amino acid ester, benzisothiazole ketone or sulfo-amino acid esters, Salicylanlide, tetramethyl-thiuram disulfide.
7, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3, be characterised in that: described film coalescence aid is dibasic alcohol and ether compounds thereof such as propylene glycol, propylene glycol butyl ether, propylene glycol phenylate, or 2,2,2-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate.
8, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described organic amine auxiliary agent is one or more in dimethylethanolamine, the 2-amino-2-methyl-1-propanol.
9, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described defoamer is for containing the non-silicone Dormant oils of hydrophobic particles mixture.
10, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin.
11, water propyl fluorosilicate nano sol weatherability antifouling paint according to claim 3 is characterised in that: described special addition agent is one or more in polyether modified siloxane, the nonionic polyurethane.
CN 01139089 2001-12-07 2001-12-07 Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material Pending CN1354211A (en)

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Application Number Priority Date Filing Date Title
CN 01139089 CN1354211A (en) 2001-12-07 2001-12-07 Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material

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Cited By (35)

* Cited by examiner, † Cited by third party
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CN1328344C (en) * 2003-04-09 2007-07-25 高明南星涂料科技有限公司 Colored heat insulation anti soak coating material
CN1333024C (en) * 2004-11-18 2007-08-22 复旦大学 Method for preparing multifunctional building engineering paint
CN100335578C (en) * 2005-05-26 2007-09-05 北京科技大学 Light catalyzed coating modified by nitrogen dopen Nano titanium dioxide and preparation method
CN100427706C (en) * 2006-01-10 2008-10-22 北京多尔佳科技有限公司 Fluorine carbon ceiling and mfg. method thereof
CN1903961B (en) * 2006-07-20 2011-05-18 上海申真企业发展有限公司 Lotus leaf effect self cleaning fluorocarbon paint
CN102190934A (en) * 2010-03-05 2011-09-21 上海耐齐建材有限公司 Aqueous concrete sealer
CN102459086A (en) * 2009-05-07 2012-05-16 南欧派克有限公司 Aqueous titanium dioxide paste composition and method for preparing same
CN102690563A (en) * 2012-06-14 2012-09-26 天长市银狐漆业有限公司 Long-acting antibacterial anti-contamination waterproof interior wall coating composition
CN103113796A (en) * 2011-11-16 2013-05-22 上海富臣化工有限公司 Elastic antifouling aqueous fluorocarbon exterior wall paint
CN103387783A (en) * 2012-05-08 2013-11-13 长春市三化实业有限责任公司 Fluorine-atom-modified acrylate automobile aqueous basecoat
CN103483951A (en) * 2012-06-12 2014-01-01 上海富臣化工有限公司 Nano water-based fluorocarbon insulated elastic exterior wall paint and preparation method thereof
CN103483944A (en) * 2013-09-30 2014-01-01 海南大学 Light-reflection, heat-insulation and anticorrosion paint and preparation method thereof
CN104098979A (en) * 2013-04-15 2014-10-15 四川远见实业有限公司 Self-crosslinked high-gloss aqueous woodware finishing coat
CN104294974A (en) * 2014-09-30 2015-01-21 浙江墙煌建材有限公司 Aqueous fluorinated polysiloxane simulated marbling spraying aluminum single plate and manufacture technology thereof
CN104513579A (en) * 2014-12-24 2015-04-15 常州大学 Super-hydrophobic coating and preparation method thereof
CN104629554A (en) * 2015-01-19 2015-05-20 安徽嘉年华漆业有限公司 Special modified acrylic resin paint for building external walls
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CN105131730A (en) * 2015-08-13 2015-12-09 蚌埠市时代电子有限公司 Environmental-protection heat-dissipating coating material and preparation method thereof
CN105384403A (en) * 2015-10-29 2016-03-09 合肥正拓装饰材料有限公司 Composite floor tiles having good stain resistance capacity
CN105505059A (en) * 2015-12-29 2016-04-20 浙江名匠实业股份有限公司 Water-borne fluoride-silicone-acrylic nano-sol super-weatherproof stain-resistant coating and preparation method thereof
CN105802472A (en) * 2016-05-12 2016-07-27 武汉赫斯特涂层材料股份有限公司 Waterborne polyurethane coating and preparation method thereof
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CN1328344C (en) * 2003-04-09 2007-07-25 高明南星涂料科技有限公司 Colored heat insulation anti soak coating material
CN1333024C (en) * 2004-11-18 2007-08-22 复旦大学 Method for preparing multifunctional building engineering paint
CN100335578C (en) * 2005-05-26 2007-09-05 北京科技大学 Light catalyzed coating modified by nitrogen dopen Nano titanium dioxide and preparation method
CN100427706C (en) * 2006-01-10 2008-10-22 北京多尔佳科技有限公司 Fluorine carbon ceiling and mfg. method thereof
CN1903961B (en) * 2006-07-20 2011-05-18 上海申真企业发展有限公司 Lotus leaf effect self cleaning fluorocarbon paint
CN102459086A (en) * 2009-05-07 2012-05-16 南欧派克有限公司 Aqueous titanium dioxide paste composition and method for preparing same
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CN110628283A (en) * 2019-09-29 2019-12-31 浙江华昱科技有限公司 Special interface agent for low-surface-energy antifouling paint and preparation method thereof
CN110724414A (en) * 2019-10-08 2020-01-24 武汉长弢新材料有限公司 Stain-resistant high-temperature-resistant water-based paint and preparation method thereof
CN111196904A (en) * 2020-03-06 2020-05-26 浙江威廉姆节能科技有限公司 Water-soluble transparent metal oxide-based repairing protection coating for wood structure ancient building
CN111849263A (en) * 2020-07-27 2020-10-30 三棵树涂料股份有限公司 High-weather-resistance photoinduced super-hydrophilic self-cleaning anti-fouling exterior wall paint and preparation method thereof
CN113831853A (en) * 2021-08-27 2021-12-24 上海自图新材料科技有限公司 Radome TPU protection film
CN113861777A (en) * 2021-10-13 2021-12-31 国网山东省电力公司电力科学研究院 Silicate concrete anticorrosive paint

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