CN105384403A - Composite floor tiles having good stain resistance capacity - Google Patents

Composite floor tiles having good stain resistance capacity Download PDF

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Publication number
CN105384403A
CN105384403A CN201510723275.2A CN201510723275A CN105384403A CN 105384403 A CN105384403 A CN 105384403A CN 201510723275 A CN201510723275 A CN 201510723275A CN 105384403 A CN105384403 A CN 105384403A
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parts
water
sand
stain resistance
minutes
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CN201510723275.2A
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Chinese (zh)
Inventor
高翠莲
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Hefei Zhengtuo Decoration Materials Co Ltd
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Hefei Zhengtuo Decoration Materials Co Ltd
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Priority to CN201510723275.2A priority Critical patent/CN105384403A/en
Publication of CN105384403A publication Critical patent/CN105384403A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1018Coating or impregnating with organic materials
    • C04B20/1029Macromolecular compounds
    • C04B20/1037Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2682Halogen containing polymers, e.g. PVC
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction

Abstract

The invention discloses composite floor tiles having the good stain resistance capacity. The composite floor tiles are prepared from, by weight, 50-53 parts of desert sand, 4-5 parts of thermoplastic phenolic resin, 0.6-0.7 part of methenamine, 0.2-0.22 part of calcium stearate, an appropriate amount of water, 42-45 parts of Portland cement of the mark number 42.5, 5-6 parts of fly ash, 1.6-2 parts of sodium sulfate, 1.5-2 parts of polyvinyl alcohol, 4-5 parts of waterborne fluorocarbon emulsion, 40-44 parts of silica sand, 80-83 parts of waste ceramics, 19-23 parts of industrial smelting waste, 11-13 parts of nano titanium dioxide, 2-2.2 parts of melamine and 1.5-2 parts of an antioxidant 1010. The waterborne fluorocarbon emulsion, the nano titanium dioxide and the like are added in a surface material, the composite floor tiles have the good stain resistance performance and can overcome the defects of poor stain resistance, poor water permeability and the like of water-permeable floor tiles in the prior art, and the products made of the composite floor tiles have the excellent stain resistance capacity and good water permeability, are low in cost and are anti-slip.

Description

The composite permeable floor tile that a kind of stain resistance is strong
Technical field
The present invention relates to building material technical field, particularly relate to the composite permeable floor tile that a kind of stain resistance is strong.
Background technology
Along with the aggravation of Development of Urbanization speed, urban surface progressively cover by the water preventing ability such as buildings and various concrete material, waterproof regional percentage is significantly increasing, and its fraction of coverage of some areas is more than 80%.Due to city drainability worse and worse, many cities one run into heavy rain, and its rainwater on road surface cannot seepage fast, is easy to cause urban waterlogging.Therefore, for solving urban surface sclerosis problem, build high-quality natural living environment, safeguard balance of city ecosystem, the building material product-water-permeable brick of environmental protection arises at the historic moment, and is developed rapidly.
At present, common on market water-permeable brick mainly contains concrete permeable brick, ceramic water-permeable brick, sand base water-permeable brick etc.And the raw material that ceramic water-permeable brick is commonly used mainly contains phase red mud for many years, gold tailings, flyash, glazed ceramic, concrete etc.And the water-permeable brick prepared by these raw materials generally all needs the high temperature sintering through 1000-1400 DEG C, waste fossil oil, and produce industrial gaseous waste and cause topsoil.Sand base water-permeable brick is the novel water permeable brick grown up in recent years, with the drift-sand in desert for aggregate.Because sand base water-permeable brick emerges just trivial several years, extensive use is not also formed, and does not more further investigate the benefit that it produces.Store a large amount of drift-sand resources in desert, these drift-sands have the advantages that particle is tiny, water ratio is low, for development sand base water-permeable brick provides cheap starting material.From the angle of research, development and the performance analysis work of carrying out sand base water-permeable brick are conducive to improving China's water-permeable brick research system, and play and promote that sand base water-permeable brick is applied; From the angle of city ecology construction, be conducive to advancing Application of Urban Rain Water paces, alleviate the situation of city water resource scarcity; From the angle of desert treatment, be conducive to alleviating Desertification, and bring huge social economy and ecological benefits.As can be seen here, the research carrying out sand base water-permeable brick has major and immediate significance.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides the composite permeable floor tile that a kind of stain resistance is strong.
The present invention is achieved by the following technical solutions:
The composite permeable floor tile that stain resistance is strong, is made up of the raw material of following weight part: Desert Sand 50-53, novolac resin 4-5, urotropine 0.6-0.7, calcium stearate 0.2-0.22, water are appropriate, label is 42.5 silicate cement 42-45, flyash 5-6, sodium sulfate 1.6-2, polyvinyl alcohol 1.5-2, water-base fluorocarbon emulsion 4-5, silica sand 40-44, waste ceramic 80-83, industrial melting waste slag 19-23, nano titanium oxide 11-13, trimeric cyanamide 2-2.2, antioxidant 1010 1.5-2.
The composite permeable floor tile that described a kind of stain resistance is strong, be made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) polyvinyl alcohol is dissolved in the water of 5 times amount, mix with water-base fluorocarbon emulsion, be stirred to after being uniformly dispersed, add nano titanium oxide, sonic oscillation was sent in mixer after 40 minutes, continue to add the overlay film Desert Sand that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) particle of about 2mm will be worn into after waste ceramic fragmentation, put into water after then mixing with industrial melting waste slag and soak 1 hour, filter and take out to obtain mixing wet feed; Wet feed will be mixed mix with flyash, put into stirrer, continue after stirring 5 minutes with the speed of 600 revs/min to add silicate cement, all the other remaining components that label is 42.5, the water adding total amount 10% after stirring 10 minutes with the speed of 800 revs/min continues stirring 15 minutes, obtains primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
Advantage of the present invention is: first the present invention carries out the process of coating thermoplastic resol to baked sand, obtain overlay film Desert Sand, the compositions such as tackiness agent are coordinated to make skin-material, give the permeable hole that water-permeable brick top layer is small, the macropore improving concrete brick body, easily by the shortcoming that mud blocks, also enhances aesthetic property; Coordinate the application of bottom concrete material, improve intensity and the water-permeable of brick body, and not only reduce production cost, also solve the environmental protection object of desert improvement.
The present invention adds the composition such as water-base fluorocarbon emulsion, nano titanium oxide in skin-material, there is good contaminated resistance, can overcome pervious floor tile resistance to soiling difference and the defect such as bad hydraulic permeability that prior art manufactures, the product that the present invention makes has that the stain resistance of excellence, good water permeability, cost are low, anti-skidding, environmental protection.
Embodiment
The composite permeable floor tile that stain resistance is strong, is made up of the raw material of following weight part (kilogram): Desert Sand 50, novolac resin 4, urotropine 0.6, calcium stearate 0.2, water are appropriate, label is 42.5 silicate cement 42, flyash 5, sodium sulfate 1.6, polyvinyl alcohol 1.5, water-base fluorocarbon emulsion 4, silica sand 40, waste ceramic 80, industrial melting waste slag 19, nano titanium oxide 11, trimeric cyanamide 2, antioxidant 1010 1.5.
The composite permeable floor tile that described a kind of stain resistance is strong, be made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) polyvinyl alcohol is dissolved in the water of 5 times amount, mix with water-base fluorocarbon emulsion, be stirred to after being uniformly dispersed, add nano titanium oxide, sonic oscillation was sent in mixer after 40 minutes, continue to add the overlay film Desert Sand that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) particle of about 2mm will be worn into after waste ceramic fragmentation, put into water after then mixing with industrial melting waste slag and soak 1 hour, filter and take out to obtain mixing wet feed; Wet feed will be mixed mix with flyash, put into stirrer, continue after stirring 5 minutes with the speed of 600 revs/min to add silicate cement, all the other remaining components that label is 42.5, the water adding total amount 10% after stirring 10 minutes with the speed of 800 revs/min continues stirring 15 minutes, obtains primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
Carry out properties test to the pervious floor tile that the embodiment of the present invention is made, water-retentivity is greater than 0.6g/cm 2, coefficient of permeability is 3.05 × 10 -2cm/s, bending strength is 48.4MPa, and 25 freeze-thaw cycle ultimate compression strength losses are less than 20%, meet industry standard.

Claims (2)

1. the composite permeable floor tile that a stain resistance is strong, it is characterized in that, be made up of the raw material of following weight part: Desert Sand 50-53, novolac resin 4-5, urotropine 0.6-0.7, calcium stearate 0.2-0.22, water are appropriate, label is 42.5 silicate cement 42-45, flyash 5-6, sodium sulfate 1.6-2, polyvinyl alcohol 1.5-2, water-base fluorocarbon emulsion 4-5, silica sand 40-44, waste ceramic 80-83, industrial melting waste slag 19-23, nano titanium oxide 11-13, trimeric cyanamide 2-2.2, antioxidant 1010 1.5-2.
2. the composite permeable floor tile that a kind of stain resistance is strong according to claim 1, is characterized in that, is made up of following concrete steps:
(1) Desert Sand is washed post-drying and obtain baked sand, baked sand is put into fluidizing furnace, heating makes the temperature of baked sand rise to 160 DEG C, then baked sand is shifted in sand mill, keep constant temperature 160 DEG C, slowly novolac resin is added while mixed grind, mixed grind slowly adds the urotropine being dissolved in 10 times of water gagings in 80 seconds afterwards, continue mixed grind 60 seconds, when being blown into cold front heavy rain to 100 DEG C afterwards, add calcium stearate equably, mixed 30 seconds, shake out in crusher, air-cooled to fragmentation when 35 DEG C, cross 30 mesh sieves, obtain overlay film Desert Sand;
(2) polyvinyl alcohol is dissolved in the water of 5 times amount, mix with water-base fluorocarbon emulsion, be stirred to after being uniformly dispersed, add nano titanium oxide, sonic oscillation was sent in mixer after 40 minutes, continue to add the overlay film Desert Sand that step (1) obtains, stir 30 minutes with the speed of 600 revs/min, obtain skin-material;
(3) particle of about 2mm will be worn into after waste ceramic fragmentation, put into water after then mixing with industrial melting waste slag and soak 1 hour, filter and take out to obtain mixing wet feed; Wet feed will be mixed mix with flyash, put into stirrer, continue after stirring 5 minutes with the speed of 600 revs/min to add silicate cement, all the other remaining components that label is 42.5, the water adding total amount 10% after stirring 10 minutes with the speed of 800 revs/min continues stirring 15 minutes, obtains primer;
(4) primer is poured in mould, jolt ramming primer flattening surface, again skin-material is poured in mould, in the pressure system of 3MPa after 15 minutes after jolt ramming, freeze-day with constant temperature 48 hours at 25 DEG C, puts into standard concrete curing box maintenance 21 days and get final product on request by brick body after the demoulding.
CN201510723275.2A 2015-10-29 2015-10-29 Composite floor tiles having good stain resistance capacity Pending CN105384403A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106146025A (en) * 2016-06-28 2016-11-23 蚌埠市方阵商品混凝土有限公司 A kind of pervious concrete
CN107325788A (en) * 2017-06-13 2017-11-07 上海世卿防滑防护科技有限公司 A kind of preparation method of floor tile antilubricant
CN107601999A (en) * 2017-10-31 2018-01-19 黄志鹏 A kind of method for the Anti-slip ground cushion that absorbed water with Han Jiang sand and waste ceramic bathroom
CN107721259A (en) * 2017-09-26 2018-02-23 苏州米颜生物科技有限公司 A kind of high-performance pervious brick
CN108314405A (en) * 2018-02-07 2018-07-24 广东英超陶瓷有限公司 A kind of resistant water-permeable brick
CN108314406A (en) * 2018-02-07 2018-07-24 广东英超陶瓷有限公司 A kind of preparation method of resistant water-permeable brick
CN109020491A (en) * 2018-09-30 2018-12-18 柳晶(长春)环保科技有限公司 A kind of high resistance to compression pervious floor tile
CN110590278A (en) * 2019-09-12 2019-12-20 杨国曙 Production method of nano composite sand-based self-cleaning environment-friendly water permeable brick and road
CN112551946A (en) * 2020-11-27 2021-03-26 重庆市智翔铺道技术工程有限公司 Permeable sand base paving material, preparation method thereof and paving structure

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CN1354211A (en) * 2001-12-07 2002-06-19 上海大学 Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material
CN101249545A (en) * 2008-04-03 2008-08-27 天津市雅步新技术有限公司 Non-phenols overlay film sand and producing method thereof
CN201981461U (en) * 2011-03-28 2011-09-21 韶关学院 Structural gradient type composite pervious brick
CN102503201A (en) * 2011-10-21 2012-06-20 李国辉 Pre-coated sand, preparation method thereof and composite water permeable brick

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CN1354211A (en) * 2001-12-07 2002-06-19 上海大学 Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material
CN101249545A (en) * 2008-04-03 2008-08-27 天津市雅步新技术有限公司 Non-phenols overlay film sand and producing method thereof
CN201981461U (en) * 2011-03-28 2011-09-21 韶关学院 Structural gradient type composite pervious brick
CN102503201A (en) * 2011-10-21 2012-06-20 李国辉 Pre-coated sand, preparation method thereof and composite water permeable brick

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106146025A (en) * 2016-06-28 2016-11-23 蚌埠市方阵商品混凝土有限公司 A kind of pervious concrete
CN107325788A (en) * 2017-06-13 2017-11-07 上海世卿防滑防护科技有限公司 A kind of preparation method of floor tile antilubricant
CN107721259A (en) * 2017-09-26 2018-02-23 苏州米颜生物科技有限公司 A kind of high-performance pervious brick
CN107721259B (en) * 2017-09-26 2020-08-18 苏州米颜生物科技有限公司 High-performance water permeable brick
CN107601999A (en) * 2017-10-31 2018-01-19 黄志鹏 A kind of method for the Anti-slip ground cushion that absorbed water with Han Jiang sand and waste ceramic bathroom
CN108314405A (en) * 2018-02-07 2018-07-24 广东英超陶瓷有限公司 A kind of resistant water-permeable brick
CN108314406A (en) * 2018-02-07 2018-07-24 广东英超陶瓷有限公司 A kind of preparation method of resistant water-permeable brick
CN109020491A (en) * 2018-09-30 2018-12-18 柳晶(长春)环保科技有限公司 A kind of high resistance to compression pervious floor tile
CN110590278A (en) * 2019-09-12 2019-12-20 杨国曙 Production method of nano composite sand-based self-cleaning environment-friendly water permeable brick and road
CN112551946A (en) * 2020-11-27 2021-03-26 重庆市智翔铺道技术工程有限公司 Permeable sand base paving material, preparation method thereof and paving structure

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Application publication date: 20160309