CN1454948A - Superclean external wall organic coating for building and preparing method thereof - Google Patents
Superclean external wall organic coating for building and preparing method thereof Download PDFInfo
- Publication number
- CN1454948A CN1454948A CN 03117023 CN03117023A CN1454948A CN 1454948 A CN1454948 A CN 1454948A CN 03117023 CN03117023 CN 03117023 CN 03117023 A CN03117023 A CN 03117023A CN 1454948 A CN1454948 A CN 1454948A
- Authority
- CN
- China
- Prior art keywords
- coating
- cleaning function
- external wall
- emulsion
- building
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The present invention relates to an organic coating material with super-self-cleaning function for external wall and its preparation method. Said invention selects inorganic pigment filling material with a certain size and form, hydrophobic adjuvant with low surface tension and nano titanium dioxide photocatalyst, and utilizes the properly-proportional mixing of emulsion base material, pigment filling material and adjuvant to obtain the invented product. Its preparation method is simple and low in cost.
Description
Technical field
The invention belongs to the chemical building material technical field, relate to a kind of super self-cleaning exterior wall building organic coating and preparation method thereof.
Background of invention
Along with the sustained, stable growth of China's economy and improving constantly of people's living standard, building and the positive fast development of decoration trade, the annual requirement of domestic construction exterior coating can reach more than 2,000,000 tons.But the exemplary shortcomings of outer wall building coating is that resistance to soiling is poor, outside durabitity is bad both at home and abroad at present, make skin, especially different kinds of roads (motorway, railway, urban road) nearby buildings and the usually various dusts of other Architectural Equipments, dirt, greasy dirt etc. (because tail gas produces) influence attractive in appearance.Silicon-third exterior wall latex coating and fluorocarbon coating, though its outside durabitity, water-repellancy and resistance to soiling increase, its resistance to soiling is still undesirable, does not especially have self-cleaning function.
How to have self-cleaning function be the hot subject that external in recent years colleges and universities and major company are researched and developed on surface design and the modification by the material surface that makes coating, for example, people such as the Kiyoharu Tadanaga of Osaka, Japan university (Chem.Mater.2000,12,590-592) prepare flower-shaped Al earlier
2O
3Film is again at Al
2O
3Form the thick TiO of 5-10nm by sol-gel method on the film
2Gel coat obtains super-hydrophobic super oleophobic boundary material thereby handle with fluorine-containing silane reagent at last.People such as the Toshiya Watanabe of Tokyo Univ Japan (Langmuir, 2000,16,7044-7047 7048-7050) obtains Al by sol-gel method earlier with Europe patent (EP0772514)
2O
3, or TiO
2Or SiO
2Film is handled the biomimetic material that obtains having the automatically cleaning effect with fluorine-containing silane reagent then.Jan Genzer and Kirill Efimenko (Science, 2000, Vol.290 2130-2133) assembles by machinery at Science290 (15) report in 2000, with polydimethyl silane mechanical stretching, with UV+O
3Handle and connect fluorine-containing silane reagent again, obtain having the ultra-hydrophobic polymer surface.Domestic then have the chemistry Jiang Lei researcher of institute of the Chinese Academy of Sciences to obtain two dredging or parents' binary boundary material by similar method.But mainly be up to now (as Al by inorganic coating
2O
3, SiO
2, TiO
2Deng) surface topography control and the use of super-hydrophobicity reagent, to obtain the hydrophobic oleophobic boundary material, though English is also referred to as coating, but also differ greatly from the coating (mainly being organic coating) of large-scale application on buildings truly.In German patent DE 19921876A1 and the Chinese patent 01142643.8, the use of surface modification, special shape inorganic color stuffing and low surface tension hydrophobizing agent by powder has reported that two kinds have self-cleaning function external wall of building organic coating and preparation method thereof, all be only limited to the metope dust and reach the automatically cleaning effect by rainwater, then powerless to being covered with dust again attached to the greasy dirt of metope with above the greasy dirt.
Summary of the invention
The object of the present invention is to provide a kind of starting material cheapness, preparation method easy, not only can be to the skin that adheres to dust, but also can all can obtain super self-cleaning exterior wall building organic coating of automatically cleaning effect and preparation method thereof to adhering to the smeary skin.
The super self-cleaning exterior wall building organic coating that the present invention proposes is made up of color stuffing, acrylic emulsions, low surface tension material and auxiliary agent.Wherein, (1) contains the inorganic color stuffing of a kind of particle diameter at 1-50 μ m at least; (2) contain a kind of nano titanium oxide at least; (3) contain a kind of acrylic emulsions at least; (4) contain a kind of compound or resin of low surface tension at least; (5) other latex coating used additives is with the exterior wall latex paint of prior art.
Particular content of the present invention further describes as follows:
Specifically consisting of of super self-cleaning exterior wall building organic coating of the present invention: (1) selects the inorganic color stuffing with special shape and certain grain size distribution for use, and consumption accounts for the 20-84wt% of coating total amount; (2) consumption of nano titanium oxide 1-10wt% (3) resin emulsion that accounts for the coating total amount accounts for the 15-70wt% of coating total amount; (4) select for use and have the hydrophobic auxiliary agent of low surface tension, this auxiliary agent can be dispersed in the emulsion paint, and can be in the film coated surface enrichment in the coating film process, forms to have very strong hydrophobic film, and consumption accounts for the 0.2-20wt% of emulsion binder total amount; (5) 0.5-5.0wt% that other usual auxiliaries such as dispersion agent, thickening material, film coalescence aid, defoamer etc. are pressed color stuffing and emulsion weight respectively in the coating adds; (6) visual coating application of the content of water and solids constituent suitably increase in the coating; (5) color of coating can be mixed colours on request.
Inorganic color stuffing such as titanium dioxide, wollastonite powder etc. in above-mentioned each component; The nano titanium oxide particle diameter is at 5-60nm; Resin emulsion such as organosilicon-modified acrylic emulsion or organic fluorine modified acrylic acid emulsion etc.; Hydrophobic auxiliary agent such as siliceous or fluorine-containing resin emulsion or nano-interface hydrophobizing agent of its modification etc.; All the other are same as the prior art.
Automatically cleaning external wall of building organic coating of the present invention can use following component preferably:
Inorganic color stuffing among the present invention be in titanium dioxide and other existing color stuffing one or more as talcum powder, silica powder, wollastonite, lime carbonate,, lithopone etc., its ratio of mixture is same as the prior art.
Inorganic color stuffing among the present invention is with at 5-50 μ m particle diameter, and effect is better.
The better particle diameter of inorganic color stuffing is 10-20 μ m.
Nano titanium oxide of the present invention is a nanometer anatase titania, or the mixture of nanometer anatase titania and rutile type nano titanic oxide, and blending ratio can be from 1-99wt%, or the modification nanometer anatase titania.
Inorganic color stuffing among the present invention is preferentially selected for use and is helped forming the coating structure with certain convex-concave surface, and they are the silica powder with acicular structure wollastonite, irregular sharp tooth, the calcite of diamond structure etc.
The hydrophobic auxiliary agent of low surface tension is preferentially selected the content of wax, siliceous or fluorine-containing resin emulsion or nano-interface hydrophobizing agent or its mixture of its modification for use.
Resin emulsion among the present invention is following a kind of or its mixture: organosilicon-modified acrylic emulsion, and the organic fluorine modified acrylic acid emulsion, the mixture of fluorine carbon emulsion and a small amount of pure acrylic acid ester emulsion or benzene emulsion, its ratio of mixture is same as the prior art.
Liquid phase in the coating of the present invention is a water, is aqueous, environmental protective coating, and the visual coating application of the content of water suitably adds.
Preparation method with super self-cleaning function external wall of building organic coating of the present invention is as follows:
An amount of dispersion agent, thickening material, anti-enzyme agent, defoamer, frostproofer etc. are dispersed in an amount of water, add powder or its slurry of titanium dioxide, other color stuffing, nano titanium oxide then according to the above ratio successively, in dispersion machine high speed dispersed with stirring.When color stuffing in water fineness of dispersion less than 75 μ m after, reduce stirring velocity, add the emulsion binder of above-mentioned amount, hydrophobic auxiliary agent, defoamer and film coalescence aid and fully stir, pH value and viscosity to the suitable use standard of prior art coating of adjusting coating at last get final product.
Product of the present invention directly casts in the above-mentioned coating system on metal sheet or the asbestos plate with standard lines rod or line box, after the drying at room temperature 7, measures the performance of filming.Its salient features characterizes as follows:
Surface contact angle is measured by the OCA video optics contact angle measurement that German Dataphysics instrument limited-liability company produces.The artificial anti-aging test that quickens is measured by the accelerated aging test case that U.S. Q-Pannel Lab Products company produces.Other performance is undertaken by GB/T9755-1995.
The organism decomposition efficiency is by gas Chromatographic Determination, and measurement result all is better than existing coating.
The inventive method is simple, nontoxic, pollution-free, the starting material source is abundant and cheap, product through the every index of These parameters test shows all above the national standard of existing exterior wall latex building coating, and coating is more than 98% to contact angle 〉=120 of water ℃ to the smeary capacity of decomposition, to having significant self-cleaning function attached to the dust of metope, greasy dirt etc.Practical application shows that this building coating can keep various skins and outdoor building facility totally to clean for a long time, and effect obviously is better than existing self-cleaning coating.
Embodiment
When being actually operating, following prescription fills a prescription, all within the scope of the invention.
Example 1
Coating basic recipe 1
Raw material consumption (wt%)
Water 25
Organosilicon crylic acid latex 20
Hydrophobic auxiliary agent 4
Titanium dioxide 17
Calcite (7 μ m) 20
Dichloride in anatase type titanium dioxide 10
Titanium
Thickening material 0.2～1
PH regulator agent 0.2～1
Defoamer 0.1～0.5
Dispersion agent 0.4
Film coalescence aid 1.5
Frostproofer 1
Method preparation by above-mentioned prescription is pressed exterior wall latex paint can obtain super self-cleaning function exterior wall organic architecture coating.It is filmed to the surface contact angle of water 〉=122 ℃, manually quickens ageing-resistant time 〉=700 hour, and to smeary rate of decomposition 〉=90%, other exterior wall latex paint performance is passed through.
Example 2
Coating basic recipe 2
Raw material consumption (wt%)
Water 28
Fluorine carbon emulsion 26
Hydrophobic auxiliary agent 4
Titanium dioxide 15
Silica powder (35 μ m) 10
Modification dichloride in anatase type titanium dioxide 5
Titanium
Wollastonite 10
Thickening material 0.2～1
PH regulator agent 0.2～1
Defoamer 0.1～0.5
Dispersion agent 0.4
Film coalescence aid 1.5
Frostproofer 1
Method preparation with above-mentioned prescription is pressed exterior wall latex paint can obtain having self-cleaning function exterior wall organic architecture coating.It is filmed to the surface contact angle of water 〉=130 ℃, manually quickens ageing-resistant time 〉=1000 hour, and to smeary rate of decomposition 〉=90%, other exterior wall latex paint performance is passed through.
Example 3
Coating basic recipe 3
Raw material consumption (wt%)
Water 28
Fluorine carbon emulsion (contains 5wt% pure the third 26
Olefin(e) acid ester emulsion)
Hydrophobic auxiliary agent 3
Titanium dioxide 15
Wollastonite powder (45 μ m) 8
Modification nanometer anatase titania 3
Calcite (7 μ m) 15
Thickening material 0.2～1
PH regulator agent 0.2～1
Defoamer 0.1～0.5
Dispersion agent 0.4
Film coalescence aid 1.5
Frostproofer 1
With the general method preparation that above-mentioned prescription is pressed exterior wall latex paint, can obtain having the exterior wall organic architecture coating of self-cleaning function.It is filmed to the surface contact angle of water 〉=150 ℃, manually quickens ageing-resistant time 〉=1000 hour, and to smeary rate of decomposition 〉=90%, other exterior wall latex paint performance is passed through.
Example 4
Coating basic recipe 3
Raw material consumption (wt%)
Water 28
Organic fluorine modified acrylic acid emulsion 20
Hydrophobic auxiliary agent 3
Titanium dioxide 15
Wollastonite powder (45 μ m) 11
Nanometer anatase titania and gold 6
Mixing of red stone type nano titanium oxide
Compound (90/10 quality is than percentage)
Calcite (7 μ m) 15
Thickening material 0.2～1
PH regulator agent 0.2～1
Defoamer 0.1～0.5
Dispersion agent 0.4
Film coalescence aid 1.5
Frostproofer 1
With the method preparation that above-mentioned prescription is pressed exterior wall latex paint, can obtain having the exterior wall organic architecture coating of self-cleaning function.It is filmed to the surface contact angle of water 〉=150 ℃, manually quickens ageing-resistant time 〉=800 hour, and to smeary rate of decomposition 〉=95%, other exterior wall latex paint performance is passed through.
Claims (10)
1. the external wall of building organic coating of a super self-cleaning function is characterized in that specifically adopting following component:
(1) the inorganic color stuffing particle diameter is 1-50 μ m; Consumption accounts for the 20-84wt% of coating total amount;
(2) consumption of nano titanium oxide accounts for the 1-10wt% of coating total amount;
(3) resinous emulsion in the coating, its consumption accounts for the 15-70wt% of coating total amount;
(4) the hydrophobic auxiliary agent of low surface tension, consumption accounts for the 0.2-20wt% of resin emulsion total amount;
(5) 0.5-5.0wt% that other usual auxiliaries is pressed color stuffing and emulsion gross weight respectively in the coating adds;
(6) visual coating application of the content of water and solids constituent suitably increase in the coating;
(7) color of coating can be mixed colours on request.
2. super self-cleaning function external wall of building organic coating according to claim 1 is characterized in that inorganic color stuffing is one or more in titanium dioxide and existing other color stuffing.
3. according to claim 1 have a self-cleaning function external wall of building organic coating, it is characterized in that the inorganic color stuffing particle diameter is 5-50 μ m.
4. according to claim 3 have a self-cleaning function external wall of building organic coating, it is characterized in that the inorganic color stuffing diameter is 10-20 μ m.
5. according to claim 2 have a self-cleaning function external wall of building organic coating, it is characterized in that other inorganic color stuffing is the silica powder of acicular structure wollastonite or irregular sharp tooth or the calcite of diamond structure.
6. super self-cleaning function external wall of building organic coating according to claim 1, it is characterized in that nano titanium oxide is a nanometer anatase titania, or the mixture of nanometer anatase titania and rutile type nano titanic oxide, or modification nanometer anatase titania.
7. super self-cleaning function external wall of building organic coating according to claim 1, the hydrophobic auxiliary agent that it is characterized in that low surface tension are nano-interface hydrophobizing agent or its mixtures of the siliceous or fluorine-containing resin emulsion of the content of wax or its modification.
8. super self-cleaning function external wall of building organic coating according to claim 1, it is characterized in that resin emulsion is following a kind of or its mixture: organosilicon-modified acrylic emulsion, the organic fluorine modified acrylic acid emulsion, the mixture of fluorine carbon emulsion and a small amount of pure acrylic acid ester emulsion or benzene emulsion.
9. super self-cleaning function external wall of building organic coating according to claim 1 is characterized in that liquid phase is a water in the coating.
10. the preparation method of the organic outer wall building coating of super self-cleaning function according to claim 1, it is characterized in that being mechanical stirring is being housed, thermometer, in the round-bottomed flask of prolong, with an amount of dispersion agent, thickening material, anti-enzyme agent, defoamer, frostproofers etc. are dispersed in an amount of water, add titanium dioxide and other color stuffings then in proportion successively, the powder of nano titanium oxide or its slurry, in dispersion machine high speed dispersed with stirring, when color stuffing in water fineness of dispersion less than 75 μ m after, reduce stirring velocity, the resin emulsion base-material that adds above-mentioned amount, hydrophobic auxiliary agent, defoamer and film coalescence aid fully stir, and adjust the pH value and the viscosity of coating at last.Can make and have super self-cleaning function external wall of building organic coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031170234A CN1195029C (en) | 2003-05-19 | 2003-05-19 | Superclean external wall organic coating for building and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031170234A CN1195029C (en) | 2003-05-19 | 2003-05-19 | Superclean external wall organic coating for building and preparing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1454948A true CN1454948A (en) | 2003-11-12 |
| CN1195029C CN1195029C (en) | 2005-03-30 |
Family
ID=29260078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031170234A Expired - Fee Related CN1195029C (en) | 2003-05-19 | 2003-05-19 | Superclean external wall organic coating for building and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1195029C (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333026C (en) * | 2005-05-02 | 2007-08-22 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN101824262A (en) * | 2010-04-12 | 2010-09-08 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN101067062B (en) * | 2007-06-08 | 2010-12-22 | 东莞拓扑实业有限公司 | High performance outer wall paint preparation method |
| CN102156021A (en) * | 2009-11-05 | 2011-08-17 | Abb技术股份公司 | Field device |
| CN102627895A (en) * | 2012-03-29 | 2012-08-08 | 黑龙江省玉琦装饰涂料有限公司 | Multifunctional dustproof self-cleaning wall paint |
| CN103059713A (en) * | 2011-10-20 | 2013-04-24 | 珠海东诚光固化材料有限公司 | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof |
| CN103122188A (en) * | 2011-11-18 | 2013-05-29 | 中国科学院兰州化学物理研究所 | Self-polished organic silicon fluorine modified acrylate antifouling paint with low surface energy |
| CN103351768A (en) * | 2013-07-18 | 2013-10-16 | 西安文昊新型建材有限公司 | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof |
| CN104893466A (en) * | 2015-05-27 | 2015-09-09 | 苏州德翔装饰工程有限公司 | Hydrophobic coating for external wall of building and preparation method of hydrophobic coating |
| CN104946058A (en) * | 2015-07-20 | 2015-09-30 | 安吉祺隆新型建材有限公司 | Energy-saving type building outer wall coating |
| CN104946057A (en) * | 2015-07-20 | 2015-09-30 | 安吉祺隆新型建材有限公司 | Building exterior wall coating with high contamination resistance |
| CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
| CN105462410A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | High dirt resistance exterior wall latex paint capable of degrading haze and production process thereof |
| CN106245809A (en) * | 2016-08-31 | 2016-12-21 | 浙江润阳新材料科技股份有限公司 | A kind of preparation method of the automatic cleaning coating of sound insulation automatically cleaning body of wall and automatically cleaning body of wall |
| CN106280741A (en) * | 2016-08-18 | 2017-01-04 | 苏州大乘环保建材有限公司 | Bottom surface unification exterior wall hydrophobic coating and preparation method thereof |
| CN106590184A (en) * | 2017-01-11 | 2017-04-26 | 合肥英索莱特新材料科技有限公司 | Aqueous insulating coating |
| CN106675406A (en) * | 2016-12-08 | 2017-05-17 | 广州艺砼科技有限公司 | High-strength and corrosion-resisting novel building exterior wall paint with worm expelling function and preparation process thereof |
| CN106675238A (en) * | 2016-12-11 | 2017-05-17 | 雷笑天 | Method for preparing photocatalysis glass self-cleaned coating |
| CN106700755A (en) * | 2016-12-28 | 2017-05-24 | 安徽超洋装饰工程股份有限公司 | Coating for building external wall |
| CN106752569A (en) * | 2016-12-01 | 2017-05-31 | 姚均甫 | A kind of exterior wall hydrophobic permeable adsorbs UV nano coating |
| CN107353718A (en) * | 2017-07-08 | 2017-11-17 | 佛山市正略信息科技有限公司 | A kind of nano outer wall surface coating material |
| CN107779084A (en) * | 2017-11-01 | 2018-03-09 | 浙江工业大学 | A kind of water-based super hydrophobic coating of external wall and preparation method and application |
| CN107880687A (en) * | 2017-11-24 | 2018-04-06 | 郑州科斗科技有限公司 | A kind of nano self-cleaning exterior wall latex paint and preparation method thereof |
| CN110028862A (en) * | 2019-04-10 | 2019-07-19 | 杭州央力科技有限公司 | A kind of compound super hydrophobic coating of modified Nano and preparation method thereof |
| CN110713768A (en) * | 2019-11-22 | 2020-01-21 | 湖南贵都建材有限公司 | Preparation method of self-cleaning building coating |
| CN112063255A (en) * | 2020-09-15 | 2020-12-11 | 三棵树涂料股份有限公司 | High-weather-resistance photocatalytic air purification exterior wall fireproof coating and preparation method thereof |
| CN112210257A (en) * | 2019-07-09 | 2021-01-12 | 常州市大使涂料有限公司 | Non-sticking clean-keeping self-cleaning coating |
-
2003
- 2003-05-19 CN CNB031170234A patent/CN1195029C/en not_active Expired - Fee Related
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333026C (en) * | 2005-05-02 | 2007-08-22 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN101067062B (en) * | 2007-06-08 | 2010-12-22 | 东莞拓扑实业有限公司 | High performance outer wall paint preparation method |
| CN102156021A (en) * | 2009-11-05 | 2011-08-17 | Abb技术股份公司 | Field device |
| CN101824262A (en) * | 2010-04-12 | 2010-09-08 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN101824262B (en) * | 2010-04-12 | 2012-07-25 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN103059713A (en) * | 2011-10-20 | 2013-04-24 | 珠海东诚光固化材料有限公司 | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof |
| CN103122188A (en) * | 2011-11-18 | 2013-05-29 | 中国科学院兰州化学物理研究所 | Self-polished organic silicon fluorine modified acrylate antifouling paint with low surface energy |
| CN102627895A (en) * | 2012-03-29 | 2012-08-08 | 黑龙江省玉琦装饰涂料有限公司 | Multifunctional dustproof self-cleaning wall paint |
| CN103351768A (en) * | 2013-07-18 | 2013-10-16 | 西安文昊新型建材有限公司 | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof |
| CN104893466A (en) * | 2015-05-27 | 2015-09-09 | 苏州德翔装饰工程有限公司 | Hydrophobic coating for external wall of building and preparation method of hydrophobic coating |
| CN104946058A (en) * | 2015-07-20 | 2015-09-30 | 安吉祺隆新型建材有限公司 | Energy-saving type building outer wall coating |
| CN104946057A (en) * | 2015-07-20 | 2015-09-30 | 安吉祺隆新型建材有限公司 | Building exterior wall coating with high contamination resistance |
| CN105462410A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | High dirt resistance exterior wall latex paint capable of degrading haze and production process thereof |
| CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
| CN106280741A (en) * | 2016-08-18 | 2017-01-04 | 苏州大乘环保建材有限公司 | Bottom surface unification exterior wall hydrophobic coating and preparation method thereof |
| CN106245809A (en) * | 2016-08-31 | 2016-12-21 | 浙江润阳新材料科技股份有限公司 | A kind of preparation method of the automatic cleaning coating of sound insulation automatically cleaning body of wall and automatically cleaning body of wall |
| CN106752569A (en) * | 2016-12-01 | 2017-05-31 | 姚均甫 | A kind of exterior wall hydrophobic permeable adsorbs UV nano coating |
| CN106675406A (en) * | 2016-12-08 | 2017-05-17 | 广州艺砼科技有限公司 | High-strength and corrosion-resisting novel building exterior wall paint with worm expelling function and preparation process thereof |
| CN106675238A (en) * | 2016-12-11 | 2017-05-17 | 雷笑天 | Method for preparing photocatalysis glass self-cleaned coating |
| CN106700755A (en) * | 2016-12-28 | 2017-05-24 | 安徽超洋装饰工程股份有限公司 | Coating for building external wall |
| CN106590184A (en) * | 2017-01-11 | 2017-04-26 | 合肥英索莱特新材料科技有限公司 | Aqueous insulating coating |
| CN107353718A (en) * | 2017-07-08 | 2017-11-17 | 佛山市正略信息科技有限公司 | A kind of nano outer wall surface coating material |
| CN107779084A (en) * | 2017-11-01 | 2018-03-09 | 浙江工业大学 | A kind of water-based super hydrophobic coating of external wall and preparation method and application |
| CN107880687A (en) * | 2017-11-24 | 2018-04-06 | 郑州科斗科技有限公司 | A kind of nano self-cleaning exterior wall latex paint and preparation method thereof |
| CN110028862A (en) * | 2019-04-10 | 2019-07-19 | 杭州央力科技有限公司 | A kind of compound super hydrophobic coating of modified Nano and preparation method thereof |
| CN112210257A (en) * | 2019-07-09 | 2021-01-12 | 常州市大使涂料有限公司 | Non-sticking clean-keeping self-cleaning coating |
| CN110713768A (en) * | 2019-11-22 | 2020-01-21 | 湖南贵都建材有限公司 | Preparation method of self-cleaning building coating |
| CN112063255A (en) * | 2020-09-15 | 2020-12-11 | 三棵树涂料股份有限公司 | High-weather-resistance photocatalytic air purification exterior wall fireproof coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1195029C (en) | 2005-03-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1195029C (en) | Superclean external wall organic coating for building and preparing method thereof | |
| CN101067062B (en) | High performance outer wall paint preparation method | |
| CN102627895A (en) | Multifunctional dustproof self-cleaning wall paint | |
| CN1696219A (en) | Environmental protection type Nano Coating | |
| CN1916092A (en) | Insulating mold coating, and prepartion method | |
| CN1304502C (en) | Curing nanometer building paint from fluoride carbon resin at normal temperature and production thereof | |
| CN1354211A (en) | Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material | |
| CN1861714A (en) | Nano composite top facing paint with hydrophobic foul resisting sticking-proof and preparation process thereof | |
| CN1401713A (en) | Water fluorine-carbon nanapaint and producing process thereof | |
| CN107266944A (en) | A kind of novel environment-friendly water-based inorganic coating and preparation method thereof | |
| CN107400398A (en) | A kind of Internal wall water-fast putty powder and preparation method thereof | |
| CN1810726A (en) | Sol-gel process of preparing anti-fouling silica coating on the surface of polished ceramic tile | |
| CN1290285A (en) | Photocatalytic oxide composition, thin film, and composite | |
| JP2012092289A (en) | Aqueous coating composition | |
| CN1195030C (en) | Self-cleaning external wall organic coating for building and preparing method thereof | |
| CN104927504A (en) | Building external wall coating | |
| TW201821385A (en) | Photocatalytic compositions, and uses thereof for obtaining water paints | |
| CN1171958C (en) | Process for preparing self-cleaning bionic organic paint with lotus leaf function of external wall of building | |
| CN102010157B (en) | Bi-component environment-friendly inorganic polymer coating material and preparation method thereof | |
| CN1398931A (en) | Water-thinned latex paint containing nano calcium carbonate for cuter wall and its prepn process | |
| CN1171959C (en) | Water-thinned latex paint containing nanometer calcium carbonate for inner wall and its prepn process | |
| CN1427049A (en) | Water curable water paint composition | |
| CN1566240A (en) | Thermoplastic fast-dry traffic paint | |
| CN105567023B (en) | A kind of carbon fibre composite and its manufacture method | |
| CN1364838A (en) | Water-thinned Normal temperature hardening fluorosilicious paint with metal texture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050330 Termination date: 20170519 |